CN106128757A - A kind of high square resistance safety diaphragm with the isolation of lateral clearance bar - Google Patents

A kind of high square resistance safety diaphragm with the isolation of lateral clearance bar Download PDF

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Publication number
CN106128757A
CN106128757A CN201610625666.5A CN201610625666A CN106128757A CN 106128757 A CN106128757 A CN 106128757A CN 201610625666 A CN201610625666 A CN 201610625666A CN 106128757 A CN106128757 A CN 106128757A
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coating
webbing
electrode
lateral clearance
isolation
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CN201610625666.5A
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吴克明
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/005Electrodes
    • H01G4/015Special provisions for self-healing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/32Wound capacitors

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)

Abstract

The present invention relates to a kind of capacitor electrode structure with the high square resistance metal metallized safety film with the isolation of lateral clearance bar; constituting composite membrane for plating zinc on polypropylene media basement membrane/aluminum metal electrode coating, the blank of this composite membrane stays limit and coating add between webbing by some being parallel to each other, spacing is equal lateral clearance bar to be connected with the contact of metal spraying and make sectionalised protection adding webbing.Thickness of electrode between adjacent transverse gap strip is subtracted the thinnest, remakes trapezoidal profile, to alleviate the degree of injury that in the evaporation course of processing, basement membrane is subject to, improves the work field intensity of medium;And make the energy demultiplication needed for spontaneous recovery, it is ensured that reach the purpose of safe spontaneous recovery.

Description

A kind of high square resistance safety diaphragm with the isolation of lateral clearance bar
Technical field
The present invention relates to capacitor metallized film materials, particularly relate to a kind of metallizing safety membrane used in capacitor electricity The improvement of electrode structure.
Background technology
In existing metalized film technology significant drawback be medium basement membrane during electrode evaporation, accept metal steam During the high temperature of vapour, high-velocity molecular precipitation, sustain damage, make the work field intensity (or claiming proof voltage) of medium be substantially reduced. Another significant deficiency is that metalized film adds the connection of webbing and metal spraying and belongs to weak link, limits impact resistance electric current and work longevity Life.And these problems be there is no essence solution.
It is known it addition, utilize metal metallized safety membrane technology to improve the effectiveness of electricity weak point breakdown spontaneous recovery in capacitor. Metallizing safety membrane used in capacitor electrode structure, is that the metallization the narrowest gap strip of coating electrode being deposited with on medium is divided Being divided into various fritter electrode units, each small electrode unit has had small coating fillet and the electric capacity of fuse effect Device overall electrode is connected, and time on the film of this structure if any electricity weak point breakdown, disruptive discharge electric current can little this place The coating fillet connected outside electrode unit block blows, and breakdown current is extinguished, and makes the small electrode unit with breakdown point with overall Capacitor cut off, reach spontaneous recovery, though and integral capacitor device have lost the capacitance being isolated small electrode unit, can maintenance Normal work, so that capacitor improves running voltage and service life.It there is also shortcoming: first, punctures and oneself when having When more giving birth to, though the capacitance being isolated small electrode unit is the least, area about 50mm2, but with puncture spontaneous recovery point face normally Long-pending 0.5mm2Comparing, differ hundreds of times, so often making peace membrane capacitance in spontaneous recovery is tested, capacity loss values is than common metal change Membrane capacitance standard index value is great many times, it is impossible to qualified by this examination criteria.Second, small electrode cell block there is voltage When puncturing, though there being the coating fillet of outer company to play fuse protection, but the many outer coating connected not being blown under normal work is narrow Bar, they are gathered when flowing through by the charge/discharge operation electric current of capacitor, and around current density ratio, electrode abruptly increase is a lot, makes coating narrow Bar becomes heat generating spot, owing to heating necessarily reduces dielectric withstanding voltage, thus reduces the media operation field intensity of capacitor.And make metal The overall equivalent series resistance of polarizing electrode increases to 2 to 3 times, depending on the direction of small electrode cell block (as shown in Figure 6).
Summary of the invention
It is an object of the invention to overcome the above-mentioned deficiency of existing safety diaphragm technology, it is provided that the improvement of a kind of safe film electrode Design, eliminates gap strip and the coating fillet of the spaced electrodes unit bringing the heating side effect that heats up, but also can make capacitor The power on effectiveness of weak point breakdown spontaneous recovery of middle safety diaphragm obtains Reliable guarantee, and the capacity loss values that spontaneous recovery punctures will not increase; The media operation field intensity simultaneously solved in the metalized film evaporation course of processing by this improvement reduces problem, and metalized film The impact resistance electric current of capacitor and working life problem.
The technology used in the present invention design is:
The electrode structure of a kind of metallizing safety membrane used in capacitor, for plating zinc/aluminum metal on polypropylene media basement membrane Layer electrodes constitutes compound film strips, it is characterised in that the dual-side of compound film strips is formed respectively with upper continuous print functional bands, institute The functional bands side stated be stay limit, opposite side without coating be that coating adds webbing;Limit and the gold adding between webbing is stayed described Belong to coating electrode structure and there is the lateral clearance bar that make that longitudinally isolation is used a plurality of is parallel to each other, spacing is equal;And adjacent horizontal stroke Electrode between gap strip is the continuous coating electrode in working area, does not has longitudinal void as conventional security film in this region Row culture isolation is used, and has also abolished the coating fillet being used as fuse;
The continuous coating electrode in working area between described adjacent transverse gap strip is characterised by thickness of coating, is common The 1/2 to 1/5 of metalized film thickness of electrode, namely the sheet resistance of coating is 15 Ω/~40 Ω/;This layer electrodes is thick Degree make trapezoidal profile in the horizontal, with add webbing adjacent the thickest (sheet resistance of coating is 15 Ω/about), with stay Limit adjacent the thinnest (sheet resistance of coating is 40 Ω/about);It is 2 Ω/~4 that thickness of coating reaches metal surface resistance Ω/, adding webbing to the transition width of the thickness of coating of working area electrode is 5~7mm.
Described work longitudinally isolate the lateral clearance bar being used be characterised by all lateral clearance bars be parallel to each other, spacing Equal, orientation and film strips laterally between angle be 6 °~10 °, its spacing value 10mm~60mm (preferably 20mm~30mm), its Width value 0.15mm~0.5mm (preferably 0.2mm~0.3mm), length adapts with film strips width so that it is one end with stay limit phase Logical, the other end intersects with adding webbing, deeply adds webbing about 0.8mm;
The electrode structure of the described metal metallized safety film with the isolation of lateral clearance bar, it is characterised in that described symmetry When stacking rolls capacitor element, stay limit and the coating of upper layer film S and lower membrane X add the interlaced correspondence of webbing, i.e. coating Add webbing and transition region and another floor stays limit corresponding with coating Bao district.So can ensure any portion of the medium of capacitor In two electrodes up and down of position, always having an electrode is relatively thin electrodes, reaches the safe spontaneous recovery punctured.
Described staying limit with to add webbing identical with common metal film, the hem width degree that stays without coating is 1.5mm~2.5mm; It is 2mm~3mm that coating thickeies hem width degree,
The technical solution adopted in the present invention, takes the corrective measure of innovation in the design, and has problems with Good technique effect:
1., in the technical solution adopted in the present invention design, do not use gap strip separate metal plating as conventional security film Layer becomes electrode junior unit, does not use the coating fillet protection as the weak point breakdown that powers on basement membrane of fuse effect, and plays Metallization coating to electricity weak point breakdown intrinsic self-healed protection function, i.e. medium power on weakness breakdown time, breakdown point is adjacent Layer electrodes can breakdown electric current energy fusing vapor away, formation area≤0.5mm around breakdown point2Blank Circle, is dielectrically separated from breakdown point, makes puncturing of capacitor reach spontaneous recovery, and keeps normal work, and capacity loss values ratio passes The capacitance loss that the breakdown protection of system metallized safety film capacitor causes reduces hundreds of times.
2. though Technical Design does not use the protected mode of conventional security film, but non-security to common metallization In membrane capacitance, electricity weakness the problem of effective spontaneous recovery can not have employed special measure sometimes, and this measure is thinning capacitor working area The thickness of layer electrodes, reaches the 1/2 to 1/5 of common metal safety diaphragm, hits so that puncturing in self-healing procedure for vaporing away Wear the insulation of a coating formation around energy needed for blank coil and be reduced to original more than 1/3, to reach not injure breakdown point Surrounding medium and the purpose of safe spontaneous recovery.
3. and layer electrodes thickness makees trapezoidal profile in the horizontal, exchange the electric current density of charge and discharge operating current with capacitor Be distributed consistent the most in echelon, thick at the big local coating of electric current density, resistance is little, with reduce capacitor loss and Caloric value.
4. the technical program design in use thinning capacitor working area layer electrodes thickness 1/2 to 1/5 another dash forward Go out advantage, be the work field intensity that improve metalized film.Because medium basement membrane is during electrode evaporation, the knot that coating is thinning Really, basement membrane accepts the high temperature of metallic vapour, the quantity of high-velocity molecular precipitation reduces, and the degree sustained damage during evaporation is also Considerably reduce, make the work field intensity of medium obtain and significantly improve.Due also in the technical program design not as conventional security film that Sample longitudinal void bar and be used as the coating fillet of fuse, eliminate the additional heat generating spot produced because of this structure and The heating of additional equivalent series resistance, also makes the work field intensity of medium obtain and improves.So the product of this programme design is one Plant the metal metallized safety film with high workload field intensity electrode structure.
5. the technical program design is not the most continuous print at Liu Bian and the coat of metal electrode added between webbing, and A plurality of be parallel to each other, lateral clearance bar isolation segmentation that spacing is equal.It practice, in capacitor under alternate current operation, hand over The sense of current of stream discharge and recharge connects limit to staying edge direction stream from metal spraying, namely the work sense of current of discharge and recharge and metal Change the laterally uniform of film, parallel with lateral clearance bar, therefore the running current of capacitor is not acted as by lateral clearance bar With;But once the quality that webbing is connected with the contact of metal spraying that adds of somewhere layer electrodes exists and weakens, and has bigger contact electricity Hinder and generate heat, or in the case of capacitor-end somewhere occurs localized corona electric discharge, or capacitor is by greater impact electric current Time, making to add at this webbing and be connected with the contact of metal spraying and completely disengage from, damage the former road of operating current in district obstructed, the flow direction must Make fore-and-aft tilt, transfer of changing its course, flow to damage the most unspoiled bonding pad that contacts adding webbing and metal spraying of both sides, district, thus increase Add and contacted, with damage district adjacent, the electric current density and temperature rise connected, and and then damaged, made damage district extend to both sides.Expanding During exhibition, damage region electrode area and corresponding transfer current increases therewith, make what adjacent contact connected breakdown speed add Hurry up, enter vicious cycle, this is an important damage mechanism about capacitor life-span the most unheeded.And the technical program In electrode structure be not the most continuous print, but a plurality of be parallel to each other, lateral clearance bar isolation point that spacing is equal Section, vertical transfer current blocking, makes this reduction damage and is placed restrictions between two adjacent lateral clearance bars, not to both sides Add webbing to spread with metal spraying bonding pad.This to add webbing contact with metal spraying connection damage district restriction protection, make capacitor Impact resistance electric current and working life there has also been raising.
Accompanying drawing explanation
Fig. 1 is the high square resistance safe film electrode structure plane graph that the embodiment of the present invention has the isolation of lateral clearance bar.
The profile that Fig. 2 is done by the B-B along Fig. 1.
Fig. 3 is safety diaphragm two-layer laminate schematic diagram shown in Fig. 1.
Fig. 4 is that the two membranes stacking in Fig. 3 is wound into cylindrical elements, two ends metal spraying and outer membrane displaying figure.
Fig. 5 is the profile done along Fig. 3, A-A in 4.
Fig. 6 is the parsing schematic diagram of the equivalent series resistance increase of the electrode of the mesh type metal safety diaphragm not improved.
Description of reference numerals: coating adds webbing 1.1, working area coating 1.2, stays limit 2.1, lateral clearance bar 2.2, gilding layer 1.3, basement membrane J, upper layer film S, lower membrane X,
Detailed description of the invention:
Below in conjunction with drawings and Examples, the present invention is further illustrated.
Embodiment:
Embodiment is to being deposited with zinc/aluminum metal electrode coating composition on the polypropylene media material basement membrane J that width is 60mm Compound film strips, a side of this compound film strips is for staying limit 2.1, and width is 2.5mm;Another side is that coating adds webbing 1.1, wide 2.2mm;Liu Bian with have on the coat of metal added between webbing make that longitudinally isolation is used a plurality of be parallel to each other, spacing equal Lateral clearance bar 2.2;The width of lateral clearance bar 2.2 is 0.2~0.3mm, and length adapts with film strips width so that it is one end Communicating with staying limit, the other end intersects with adding webbing 1.1, deeply adds webbing about 0.8mm;The spacing of lateral clearance bar 2.2 selects 17 Or 34mm (should be the approximate number of evaporation graining roll outer perimeter), its orientation and film strips laterally between angle be 6 °.By adjacent two Lateral clearance bar 2.2 and both sides stay limit 2.1, to add the centre that webbing 1.1 is surrounding border be normal working area layer electrodes 1.2, its thickness of coating makees trapezoidal profile in the horizontal, i.e. with add webbing adjacent the thickest (sheet resistance of coating be 15 Ω/ About), with stay limit adjacent the thinnest (sheet resistance of coating is 40 Ω/about).Add the sheet resistance of webbing coating Being 2~4 Ω/, adding webbing to the transition width of the thickness of coating of working area electrode is 5~7mm.This have lateral clearance bar The planar structure of the high square resistance safe film electrode of isolation is as it is shown in figure 1, its layer electrodes thickness makees trapezoidal profile in the horizontal Section is as shown in Figure 2.
In the present embodiment, when above-mentioned for two-layer metal metallized safety film symmetry stacking is rolled into capacitor element, as Fig. 3, 4, shown in 5, stay limit 2.1 and the coating of upper layer film S and lower membrane X add the interlaced correspondence of webbing 1.1, the i.e. coating of this tunic Add webbing and transition region and another floor stay limit corresponding with coating Bao district, vice versa.So can ensure capacitor In two electrodes up and down at any position of medium, always having an electrode is relatively thin electrodes, reaches the safe spontaneous recovery of breakdown point.Additionally exist During two membranes stacking, stagger distance 0.8~1.5mm in the horizontal in both sides, makes the coating of both sides add what webbing 1.1 was all located at highlighting Position, it is simple to coating adds webbing and is connected with outside metal spraying 1.3.
The film width of the present embodiment is not limited to 60mm, particularly when material of the present invention is for high voltage direct current filter capacitor, Requiring that the capacitance of discrete component is very big, film width can be more than 60mm, reaches more than 100mm.But when material of the present invention is used for high pressure When ac filter and compensation capacitor, film width is unsuitable excessive, is preferred less than 40mm.
Above-described embodiment is only the object lesson of the present invention, all equivalence changes made according to the content of the present patent application scope Change and modify, all should be the protection domain of technical solution of the present invention.

Claims (4)

1. a capacitor electrode structure for the high square resistance metal metallized safety film with the isolation of lateral clearance bar, at polypropylene Plating zinc on medium basement membrane/aluminum metal electrode coating constitutes compound film strips, and two-layer can be combined film strips symmetrical layers is folded rolls electric capacity Device element, it is characterised in that the dual-side of compound film strips is formed respectively with upper continuous print functional bands, and side is staying without coating Limit 2.1, opposite side are that coating adds webbing 1.1;At described stay limit and the coat of metal electrode structure added between webbing, there is work The lateral clearance bar 2.2 that what longitudinally isolation was used a plurality of be parallel to each other, spacing is equal;And between adjacent transverse gap strip 2.2 be The continuous coating electrode in working area 1.2.
The electrode structure of the high square resistance metal metallized safety film with the isolation of lateral clearance bar the most according to claim 1, its The electrode being characterised by between described adjacent transverse gap strip 2.2 is continuous coating 1.2, and thickness of coating is the thinnest, is common gold The 1/2 to 1/5 of genusization membrane electrode thickness, to alleviate the degree of injury that in the evaporation course of processing, basement membrane is subject to, improves the work of medium Make field intensity;The sixth of the twelve Earthly Branches, thinning layer electrodes thickness remake trapezoidal profile, in the horizontal with the electric current of capacitor charging/discharging operating current Density is distributed consistent the most in echelon, the thickest (sheet resistance of coating is 15 Ω/ with adding webbing adjacent coating Left and right), with stay limit adjacent coating the thinnest (sheet resistance of coating is 40 Ω/about);Add the surface electricity of webbing coating Resistance is 2~4 Ω/, adds the webbing transition width 5~7mm to the thickness of coating of working area electrode.
3. according to the electrode structure of the high square resistance metal metallized safety film with the isolation of lateral clearance bar described in claim 1,2, It is characterized in that, described time two-layer is combined that film strips symmetrical layers is folded rolls capacitor element, upper layer film S and lower membrane X stay limit 2.1 and coating add the interlaced correspondence of webbing 1.1, i.e. coating add webbing and transition region and another layer stay limit and coating the thinnest District is corresponding, and vice versa.So can ensure in two electrodes up and down at any position of the medium of capacitor, always have the electrode to be Relatively thin electrodes, reaches the safe spontaneous recovery punctured, and the capacitance loss that this spontaneous recovery produces is much smaller than common safety diaphragm spontaneous recovery generation Capacitance loss.
4. according to the electrode structure of the high square resistance metal metallized safety film with the isolation of lateral clearance bar described in claim 1,2, It is characterized in that described all lateral clearance bars 2.2, be parallel to each other, spacing is equal, orientation and film strips laterally between angle be 6 °~10 °, its spacing value 10mm~60mm (preferably 20mm~30mm), its width value 0.15mm~0.5mm are (preferably 0.2mm~0.3mm), length adapts with film strips width so that it is one end communicates with staying limit, and the other end intersects with adding webbing 1.1, Deeply add webbing about 0.8mm, there is reduction damage with the webbing that adds of fully partition layer electrodes with the quality of connection that contacts of metal spraying In bad time, adjacent region spread impact.
CN201610625666.5A 2016-07-28 2016-07-28 A kind of high square resistance safety diaphragm with the isolation of lateral clearance bar Pending CN106128757A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108550465A (en) * 2018-04-18 2018-09-18 钱立文 A kind of interior and structured metallization film
CN108565115A (en) * 2018-04-18 2018-09-21 钱立文 Sheet resistance gradual change internal parallel metal metallized safety film
CN112885599A (en) * 2020-12-09 2021-06-01 中国电力科学研究院有限公司 Metallized safety film design method and device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5757607A (en) * 1996-02-09 1998-05-26 Icar S.P.A.-Industria-Condensatori Applicazioni Elettroelettroniche Metallized dielectric film of variable resistance and relative capacitor
JP2014049711A (en) * 2012-09-04 2014-03-17 Nichicon Corp Metalization film capacitor
CN204946723U (en) * 2015-10-09 2016-01-06 成都宏明电子股份有限公司 A kind of not containing the metal metallized safety film of fuse structure
CN205384948U (en) * 2016-02-03 2016-07-13 四川省科学城久信科技有限公司 Condenser is with oblique comb type continuity safety film
CN206194539U (en) * 2016-07-25 2017-05-24 吴克明 Condenser hinders metallization safety film electrode structure with height side that has strip isolation of horizontal space

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5757607A (en) * 1996-02-09 1998-05-26 Icar S.P.A.-Industria-Condensatori Applicazioni Elettroelettroniche Metallized dielectric film of variable resistance and relative capacitor
JP2014049711A (en) * 2012-09-04 2014-03-17 Nichicon Corp Metalization film capacitor
CN204946723U (en) * 2015-10-09 2016-01-06 成都宏明电子股份有限公司 A kind of not containing the metal metallized safety film of fuse structure
CN205384948U (en) * 2016-02-03 2016-07-13 四川省科学城久信科技有限公司 Condenser is with oblique comb type continuity safety film
CN206194539U (en) * 2016-07-25 2017-05-24 吴克明 Condenser hinders metallization safety film electrode structure with height side that has strip isolation of horizontal space

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108550465A (en) * 2018-04-18 2018-09-18 钱立文 A kind of interior and structured metallization film
CN108565115A (en) * 2018-04-18 2018-09-21 钱立文 Sheet resistance gradual change internal parallel metal metallized safety film
CN112885599A (en) * 2020-12-09 2021-06-01 中国电力科学研究院有限公司 Metallized safety film design method and device

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