CN1061222C - Production process for microcapsule of fragrant and pungent oil extract - Google Patents
Production process for microcapsule of fragrant and pungent oil extract Download PDFInfo
- Publication number
- CN1061222C CN1061222C CN96117699A CN96117699A CN1061222C CN 1061222 C CN1061222 C CN 1061222C CN 96117699 A CN96117699 A CN 96117699A CN 96117699 A CN96117699 A CN 96117699A CN 1061222 C CN1061222 C CN 1061222C
- Authority
- CN
- China
- Prior art keywords
- oleoresin
- microcapsule
- fragrant
- extraction
- pungent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The present invention relates to a production technology for microcapsules of fragrant and pungent oleoresin, which belongs to the flavoring class. The present invention comprises the processes of treatment of raw materials, a percolation method or CO2 supercritical fluid extraction of oleoresin for serving as a core material, emulsification for encapsulation, low temperature spray dryness, etc. The present invention overcomes the disadvantages of large consumption of raw materials, poor mouth feel and fragrance, low pick-up rate, etc. when essential oil serves as core materials through spray drying at high temperature, but also overcomes the deficiencies of high technology cost, difficulty of forming powder of the product, etc. when single arabic gum serves as a wall material through dehydration of anhydrous alcohol and vacuum drying. The present invention has the characteristics of reliable technology, tender and smooth mouth feel, proximity to a natural product by the coordination of perfume and pungent tastes, high availability of resources, low energy consumption, etc.
Description
The invention belongs to the production method of aromatic condiment spice in the food industry, particularly a kind of method of producing microcapsule of fragrant and pungent oil extract.Be particularly suitable for transferring product to be refined into not only easy to use, but also powdery or the granular condiment being convenient to preserve natural flavors such as garlic, ginger, capsicum, Chinese prickly ash.
At present, after often some natural flavor flavouring of use carry out the microencapsulation processing in food cooking and the food service industry, be directly used in the cooking and food production again, because of it can reach the raising resource utilization, prolong preservation (aquatic foods) phase and the purpose such as easy to use of flavouring, and more and more be subject to people's attention.Above-mentioned flavouring is carried out microencapsulation handle-make microcapsules, mainly take dual mode: the first at first will extract as heartwood as the volatile essential oil that is the main body of distinguishing the flavor of in the natural flavor, and then with this essential oil and wall material mixing emulsifying, packing, after high temperature spray-drying and make corresponding essential oil microcapsules.Lin Bo etc. go up disclosed " the high-pressure homogenization legal system is equipped with the research of microencapsulation " in " chemistry world " (the 8th phase of nineteen ninety, P351～353); Xiang Yunfeng etc. are in the 5th phase of " food industry " nineteen ninety-five, disclosed on P29～31 " garlic oil microcapsules preparation technology's experimental study " and Chen Shusheng etc. are in the 3rd phase of " food research and development " nineteen ninety-five, and disclosed on P22～25 " microcapsules technology application in flavouring " etc. all belongs to this class production method.Adopt essential oil to make heartwood in this type of technology and be that by the weak point that high temperature spray-drying makes microcapsules essential oil and volatile materials loss thereof are bigger, embedding rate is low; The component that has during high temperature drying is destroyed, and produces some new components and makes fragrance, mouthfeel become bad and influence the quality of product; In addition, also exist the fragrance in the raw material in the essential oil leaching process, sense of taste composition to be difficult to propose fully, pick-up rate is lower, and prepared using is insufficient, and high temperature drying need be equipped with high-pressure boiler, defective such as equipment investment is bigger; It two is to adopt oleoresin to make heartwood, because of both having contained the essential oil of representing spice fragrance in the oleoresin, also contain the higher sequiterpene of boiling point and represent fragrant hot resin and natural composition of distinguishing the flavor of, thereby has a good anti-oxidant capacity of decomposition, sense of taste is soft mellow and full, effective ingredient in the harmony such as fragrance and acid, storage period long and spice can more intactly obtain advantages such as extraction.R, Zilberboim etc. be Journalof Food Science (Food Science) 1986, disclosed on VO, 51 №, 5 P1301～1306 " dehydrate microencapsulation: the reservation of capsicum oleoresin and aromatic ester (embedding) rate " just belongs to this class technology.Adopt oleoresin to make the plurality of advantages that heartwood is produced microcapsules though this technology has, it only makes the wall material with single Arabic gum, behind the emulsifying packing, through the absolute ethyl alcohol dehydration, makes microcapsules through vacuum drying more earlier.Wherein the Arabic gum final concentration reaches 40%, and absolute ethyl alcohol and emulsion ratio are that 10: 1 o'clock heartwood embedding rates only reach 83%, essential simultaneously ethanol recovery and the refining plant of increasing; And microcapsules adhesion caking and be difficult to into powder or granular very easily during vacuum drying influences product quality.Therefore, there is the production cost height again in this method, and the auxiliary device investment is poor than big and powder, granularity, is difficult to guarantee disadvantages such as product quality.
The objective of the invention is to produce microcapsules and keep on the basis of its plurality of advantages and improve embedding rate and product quality adopting oleoresin to make heartwood, reduce production costs and improve purposes such as resource utilization, energy savings.
Solution of the present invention be on basis of background technology still routinely operation raw material is carried out preliminary treatment, then with pretreated raw material through CO
2Supercritical fluid extraction or adopt 35～95% ethanol be solvent at room temperature continuously diacolation prepare oleoresin; And adopt edible glue soluble in water, easy film forming such as a certain proportion of Arabic gum, maltodextrin, yellow source glue soluble starch is that the emulsification of wall material is raw material, homogeneous is an O/W type emulsification packing under room temperature and 10～40MPa condition, after low temperature spray drying and make powdery or granular microcapsules.Therefore, production method of the present invention comprises:
A. pretreatment of raw material: select quality raw materials, select being broken into fine powder or slurry after clean, it is stand-by to sieve;
B. the extraction of oleoresin: with above-mentioned raw materials powder or slurry, at room temperature adopting ethanol is that solvent carries out continuous diacolation extraction, or adopts CO
2Supercritical fluid extraction is to make moisture or the anhydrous oil resin;
C. emulsification packing: in anhydrous oil portions of resin edible glue: the ratio of water=1: 1～3: 5～10, at first emulsification is former breast, send into again in the homogenizer, under 10～40MPa, be O/W type emulsion through 1～2 emulsifying;
D. dehydrating emulsion after utilizing spray gun with emulsifying sprays in the low temperature spray drying machine and dehydrates, the dryer entrance temperature is 80 °～100 ℃, 40 °～60 ℃ of leaving air temps, thus make the powdery oleoresin microcapsule product that particle diameter is 10～70 μ m; Or warp again:
E. granulation: make carrier with D gained powdery microcapsules, be placed in the spray dryer fluidized bed granulation chamber, the emulsion behind the absorption atomizing spray people's that suspends the homogeneous, the output of dry back promptly gets the granular microcapsule product that particle diameter is 80～110 μ m.
Above-mentioned employing CO
2Supercritical fluid extraction to make anhydrous or the wet oil resin, is meant material powder or slurry is sent into extraction cell and 32 °～36 ℃, the CO under 25～35MPa supercriticality
2The fluid mixing extracts, and extracts after 60～120 minutes, carries out melt cinder and separate under high pressure conditions; Residue enters the storage slag chute, and contains the CO of extract oleoresin
2Fluid is then put into the low pressure separation chamber, carries out liquid, gas separation under 0.1～0.3MPa pressure; CO wherein
2Being gas is recovered and enters that next is recycling after the processing, to send into reservoir stand-by and oleoresin is disengaged, described edible glue as the wall material is meant two or more edible glue that mixes by a certain percentage in Arabic gum, maltodextrin, yellow source glue and the soluble starch, and describedly utilize spray gun will the emulsion after emulsifying to spray into to dehydrate in the low temperature spray drying machine, the pressure that sprays into of its spray gun is 0.2～0.3MPa, and the aperture of nozzle is 0.8～1.2mm.
The present invention is owing to utilize the oleoresin of spice as heartwood, and employing room temperature or low-temperature extraction, thereby it is minimum to the loss of the volatilization composition in the spice of thermal sensitivity, oxidation reaction also can be controlled in bottom line, particularly adopt the CO2 supercritical extract more not can with each component generation chemical reaction, and the component of extract oleoresin and raw material are close; Adopt low temperature spray drying technology, can avoid high temperature drying to cause the part component to go to pot again and mouthfeel etc. is degenerated and the easy disadvantage such as caking of vacuum drying; Adopt edible glue such as Arabic gum, maltodextrin to mix in addition and make the wall material, can reduce cost to a certain extent again.Therefore, it is reliable that the present invention has production technology, scope of application broad, characteristics such as product component and natural goods are close, and sense of taste is soft mellow and full, and fragrance and acid are coordinated, and anti-storage and resource utilization are higher, and energy consumption is low.
Embodiment 1
Present embodiment is an example to produce oleoresin ginger microcapsule.1, pretreatment of raw material: adopt bright old ginger (moisture content 87%) to make raw material, remove impurity and rotten part, clean and drain the heavy 4000g in back, send in the DS-1 type high-speed tissue mashing machine, in the making beating in 3 minutes of 10,000 rev/mins, batch (-type), cross 20 mesh sieves remove crude fibre etc. ginger mud; 2, oleoresin extraction: with concentration is that 90% ethanol 10kg is a solvent, and gained ginger mud dipping was sent in the continuous diacolation device after 24 hours, and at room temperature, the flow velocity that divides with 5ml/ carries out diacolation; Percolate is placed the HHS water bath with thermostatic control, under 8.4～8.5kPa pressure and 40 °～45 ℃ conditions, decompression distillation to be reclaiming ethanol again, thus wet oil resin 2520g (moisture content 88.44%); Slag after the diacolation extraction is removed (quantity of slag 1980g) after also reclaiming ethanol with above-mentioned vacuum distillation apparatus; Merge and reclaim solvent, with utilizing again after the 1% activated carbon deodorization; 3, emulsification packing: present embodiment wall material adopts Arabic gum 29.1g, maltodextrin 261.9g preparation, add water 99g, itself and above-mentioned gained wet oil resin 2520g are added in the DS-1 type high-speed tissue mashing machine, also adopt 10,000 rev/mins, be emulsified into former breast, at this moment former Ruzhong: anhydrous oil portions of resin edible glue: water=1: 1: 8; And then former breast sent into emulsifying at room temperature in the JHG type homogenizer, present embodiment adopts twice emulsifying, 10～20MPa homogeneous is 6 minutes for the first time, 30～40MPa for the second time, homogeneous 9 minutes, get uniform and stable O/W type emulsion 2910g (emulsion moisture content 80%) 4, dehydrate: above-mentioned emulsion is heated to 45 °～50 ℃, pumps in the PGL-3 type spray dryer and carry out the low-temperature atomizing drying; Pump pressure 0.2MPa, nozzle diameter 1mm; 80 ℃ of dryer entrance temperature, 50 ° of leaving air temps make powdery ginger oleoresin microcapsules 558g.
In these embodiment gained microcapsules: moisture content: 3.81%; Heartwood embedding rate: 96.76%; Recovery rate: 95.88%; Effective component content: 1.62%; Ethanol residual quantity: 0.45%; Particle diameter: adopt the S-450 of Hitachi type electron microscope to select scanning, average grain diameter is 39.5 μ m.
Embodiment 2
Present embodiment is an example to produce the garlic oil resin microcapsule:
1, pretreatment of raw material: bright garlic (moisture content 70%) is selected, distinguish removes stem, cleaning drains and also places the high speed bruisher, under 10,000 rev/mins of conditions of rotating speed, and batch (-type) making beating in 3 minutes, the peeling of sieving gets mashed garlic 5000g;
2, preparation oleoresin: above-mentioned mashed garlic is placed 12kg, and concentration is that dipping was sent in the continuous diacolation device after 24 hours in 55% the ethanol, press mode diacolation and the recovery solvent of embodiment 1 then, makes wet oil resin 3666g (moisture content 85.57%);
3, emulsification packing: the wall material is got Arabic gum 52.9g, maltodextrin 476.1g adds water 37g, becomes former breast with the wet oil resin 3666g mixing and emulsifying that makes under the condition identical with embodiment 1, at this moment: anhydrous oil portions of resin edible glue: water=1: 1: 6, Arabic gum: maltodextrin=1: 9; Identical with embodiment one again mode is carried out twice homogeneous and is got O/W type emulsion 4232g (moisture content 75%);
4, dehydrate: with embodiment together, at last powdery garlic oleoresin capsule 1020g.
In these embodiment garlic microcapsules: moisture content 7.12%, embedding rate 97%, recovery rate 96.4% effective component content 0.48%, ethanol residual quantity 0.42%, micro-capsule particle mean size 47.25 μ m.
Embodiment 3
With the xanthoxylum oleoresin microcapsules is example
1, pretreatment of raw material: Chinese prickly ash (moisture content 12.5%) selected removes impurity only and be placed in the DS-1 high-speed tissue mashing machine and be ground into powder, cross 40 mesh sieves, zanthoxylum powder 5000g;
2, the extraction of oleoresin: it is that 55% ethanol dipping is sent into continuous diacolation device and carried out diacolation with the flow velocity of 5 ml/min after 24 hours that above-mentioned zanthoxylum powder is placed 12kg concentration, and percolate and slag are respectively 8.4～8。Under the 5kPa pressure, in HHS type constant temperature is water-soluble, get wet oil resin 3506g (moisture content 57.9%), slag 6907g (moisture content 57 behind 85 °～90 ℃ vacuum distillation recovered solvents.9％)；
3, emulsification packing: by anhydrous oil portions of resin edible glue: be emulsified into former breast after the proportional arrangement of water=1: 1: 5, wherein Arabic gum: maltodextrin=1: 9, i.e. Arabic gum 147.3g, maltodextrin 1325.7g; Still adopt the JHG homogenizer to carry out homogeneous twice after then former breast being heated to 70 ℃, get O/W type emulsion 10311g (moisture content 71.42％)；
4, dehydrate: present embodiment drier EAT is 90 °～95 ℃, and leaving air temp is that 50 ℃ of all the other operations are same with embodiment 1, gets powdery xanthoxylum oleoresin microcapsules 2828g.
This microcapsules moisture content 2.98%, embedding rate 94.2%, recovery rate 96%.Effective component content 9.8%, ethanol residual quantity 0.45%, average grain diameter 12 μ m.
Embodiment 4
Present embodiment is an example to produce the capsicum oleoresin microcapsules
1, pretreatment of raw material: with chilli (moisture content 8.9%) select only, after the pulverizing, cross 60 mesh standard sieves, stand-by;
2, oleoresin extraction: with above-mentioned chilli powder 5000g input extraction cell, then by compressor with 35 ℃ and 30MPa supercritical CO
220kg sends into extraction cell, extracts, and extracts the CO that will carry material (chilli powder) after 100 minutes
2Liquid is sent into the high pressure separation chamber and is carried out melt cinder separation, the CO that carries oleoresin after the separation
2Fluid is then put into the low pressure separation chamber, carries out liquid, gas separation under 0.1～0.3MPa pressure; Residue then enters the storage slag chute by the one-way high-pressure valve; CO in the low pressure separation chamber
2Transport to charcoal filter after changing gas into, material that adsorption gas molecule is taken reclaims and to enter that next is recycling; And oleoresin is disengaged and is sent into reservoir, wet oil resin 1785g (moisture content 8.9%);
3, emulsification packing: present embodiment adopts yellow source glue 406.5g, soluble starch 1219.5g makes the wall material, add water 6345g and with after the wet oil resin 1785g mixing and emulsifying that makes becomes former breast, input JHG type homogenizer is under 20～40MPa and room temperature, through 12～15 minutes homogeneous, get O/W type emulsion 9754g (moisture content 66.68%);
4, dehydrate: get above-mentioned emulsion 4877g earlier and carry out the drying processing; Present embodiment dryer entrance temperature is 90 °～95 ℃, and leaving air temp is controlled at about 50 ℃, and all the other get powdery capsicum oleoresin microcapsules 1561g with embodiment 1;
5, granulation: with gained 1561g powdery oleoresin as carrier, in PLG-3 type spray dryer fluidized bed granulation chamber, agitate and suspend into fluidized state, again the atomizing of second half emulsion 4877g behind the homogeneous is sprayed in the granulation chamber, the powdery microcapsules are carried out granulating and drying handle, at last granular capsicum oleoresin microcapsules 3100g.
Above-mentioned microcapsules: moisture content 4%, embedding rate 92.6%, recovery rate 95.3%, effective component content 0.38%, ethanol residual quantity 0.4%, micro-capsule average grain diameter 107.2 μ m.
Claims (4)
1, a kind of production method of microcapsule of fragrant and pungent oil extract is characterised in that its production method comprises:
A. pretreatment of raw material: select quality raw materials, select being broken into fine powder or slurry after clean, it is stand-by to sieve;
B. the extraction of oleoresin: with above-mentioned raw materials powder or slurry, at room temperature adopting ethanol is that solvent carries out continuous diacolation extraction, or adopts CO
2Supercritical fluid extraction is to make moisture or the anhydrous oil resin;
C. emulsification packing: in anhydrous oil portions of resin edible glue: the ratio of water=1: 1～3: 5～10, at first emulsification is former breast, send into again in the homogenizer, under 10～40MPa, be O/W type emulsion through 1～2 emulsifying;
D. dehydrate: the emulsion after utilizing spray gun with emulsifying sprays in the low temperature spray drying machine and dehydrates, the dryer entrance temperature is 80 °～100 ℃, 40 °～60 ℃ of leaving air temps, thus make the powdery oleoresin microcapsule product that particle diameter is 10～70 μ m; Or warp again:
E. granulation: make carrier with D gained powdery microcapsules, be placed in the spray dryer fluidized bed granulation chamber, the emulsion behind the homogeneous that the absorption atomizing that suspends sprays into, the output of dry back promptly gets the granular microcapsule product that particle diameter is 80～110 μ m.
2, by the production method of the described microcapsule of fragrant and pungent oil extract of claim 1, it is characterized in that described employing CO
2Supercritical fluid extraction is meant material powder or slurry is sent into extraction cell and 32 °～36 ℃, the CO under 25～35MPa supercriticality
2The fluid mixing extracts, and extracts after 60～120 minutes, carries out liquid, slag separation under high pressure conditions; Residue enters the storage slag chute, and contains the CO of extract oleoresin
2Fluid is then put into the low pressure separation chamber, carries out liquid, gas separation under 0.1～0.3MPa pressure; CO wherein
2Be gas and be recovered and handle laggard people next is recycling, and oleoresin is disengaged, it is stand-by to send into reservoir.
3, press the production method of the described microcapsule of fragrant and pungent oil extract of claim 1; It is characterized in that described emulsion after utilizing spray gun with emulsifying sprays in the low temperature spray drying machine dehydrates, and the pressure that sprays into of its spray gun is 0.2～0.3MPa, and the aperture of nozzle is 0.8～1.2mm.
4, press the production method of the described microcapsule of fragrant and pungent oil extract of claim 1; It is characterized in that described edible glue as the wall material is Arabic gum and maltodextrin or yellow source glue and soluble starch, its proportioning is an Arabic gum: maltodextrin=1: 9; Yellow source glue: soluble starch=1: 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96117699A CN1061222C (en) | 1996-09-02 | 1996-09-02 | Production process for microcapsule of fragrant and pungent oil extract |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96117699A CN1061222C (en) | 1996-09-02 | 1996-09-02 | Production process for microcapsule of fragrant and pungent oil extract |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1146303A CN1146303A (en) | 1997-04-02 |
| CN1061222C true CN1061222C (en) | 2001-01-31 |
Family
ID=5124527
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96117699A Expired - Fee Related CN1061222C (en) | 1996-09-02 | 1996-09-02 | Production process for microcapsule of fragrant and pungent oil extract |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1061222C (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003275578A1 (en) * | 2002-10-25 | 2004-05-13 | Mitsubishi-Kagaku Foods Corporation | Humidity-dependent antibacterial powdery composition, process for producing the same, humidity-dependent antibacterial food storing article and method of storing food |
| ZA200807865B (en) * | 2006-02-15 | 2010-04-28 | Botanocap Ltd | Applications of microencapsulated essential oils |
| CN102041170B (en) * | 2009-10-15 | 2013-04-17 | 福建中烟工业有限责任公司 | Technology and equipment for integrating essence and spice extraction and micro-capsule preparation |
| CN102188037B (en) * | 2010-03-08 | 2013-12-04 | 宏芳香料（昆山）有限公司 | Microcapsule granule and preparation process thereof |
| CN102150807B (en) * | 2011-01-31 | 2012-10-17 | 新疆隆平高科弘安天然色素有限公司 | Method for preparing microcapsule water-soluble powdery capsaicine from capsicum oleoresin serving as raw material |
| CN102630791B (en) * | 2012-05-22 | 2013-08-07 | 韶关学院 | Preparation method of solid low-sugar ginger tea |
| CN103251025B (en) * | 2013-05-03 | 2014-12-10 | 郑州雪麦龙食品香料有限公司 | Spice seasoning and preparation method thereof |
| CN104959088B (en) * | 2015-06-16 | 2017-07-11 | 南阳汇萃植物制品有限公司 | A kind of spicy essential oil microcapsules and preparation method thereof |
| DE102017004720A1 (en) * | 2017-05-17 | 2018-11-22 | Viverno UG (haftungsbeschränkt) | Process and device for the production of high-purity Aquatic Scovillin Compositions (HASC) with definable sharpness and products that can be produced therewith |
| CN108030053A (en) * | 2017-12-21 | 2018-05-15 | 洛阳味之泉调味技术有限公司 | A kind of preparation method of instant spice powder |
| CN108576750A (en) * | 2018-04-03 | 2018-09-28 | 洛阳泮甡园科技有限公司 | A kind of preparation method of sauced meat seasoning |
| CN108477615A (en) * | 2018-04-16 | 2018-09-04 | 福建省力菲克生物技术有限公司 | A kind of celestial grass composite powder and preparation method thereof |
| CN108967987A (en) * | 2018-06-20 | 2018-12-11 | 漯河双汇生物工程技术有限公司 | A kind of garlicky essence of blending type and preparation method thereof |
| CN109567117A (en) * | 2018-11-20 | 2019-04-05 | 安徽强旺调味食品有限公司 | A kind of cryopreservation answers heat-staple flavouring and preparation method thereof |
| CN109567126A (en) * | 2018-11-20 | 2019-04-05 | 安徽强旺调味食品有限公司 | A kind of capsicum oleoresin microcapsules and its processing method |
| CN110367502A (en) * | 2019-07-16 | 2019-10-25 | 内蒙古红太阳食品有限公司 | The implementation method of spicy compound seasoner is prepared using oil extraction technology |
| CN110613750B (en) * | 2019-09-30 | 2021-05-18 | 河南牧翔动物药业有限公司 | Preparation method of soluble cinnamomum longepaniculatum essential oil powder |
| CN111387461A (en) * | 2020-03-18 | 2020-07-10 | 内蒙古红太阳食品有限公司 | Method for preparing curry beef tallow hotpot condiment by applying embedding technology and low-temperature grease extraction technology |
| CN113170873A (en) * | 2021-05-31 | 2021-07-27 | 四川省雅士科技有限公司 | Preparation method of microcapsule spicy seasoning |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1096423A (en) * | 1994-03-26 | 1994-12-21 | 北京市味珍食品调料厂 | Microcapsule embedded instant soy sauce powder |
| CN1119074A (en) * | 1995-08-30 | 1996-03-27 | 北京市食品研究所 | Micro-capsulized nutritive flavouring for meat |
-
1996
- 1996-09-02 CN CN96117699A patent/CN1061222C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1096423A (en) * | 1994-03-26 | 1994-12-21 | 北京市味珍食品调料厂 | Microcapsule embedded instant soy sauce powder |
| CN1119074A (en) * | 1995-08-30 | 1996-03-27 | 北京市食品研究所 | Micro-capsulized nutritive flavouring for meat |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1146303A (en) | 1997-04-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1061222C (en) | Production process for microcapsule of fragrant and pungent oil extract | |
| CN100452998C (en) | Integrated utilization process for separating solanesol, tobacco extract and residue from waste and inferior tobacco leaf | |
| CN102630791B (en) | Preparation method of solid low-sugar ginger tea | |
| CN103468403B (en) | A kind of water extraction and supercritical CO 2extraction process method of flavor matter in directed compound collecting tobacco from tobacco material | |
| CN107011988B (en) | A kind of coconut oil extraction process and its coconut oil | |
| CN107299002A (en) | The extracting method of agilawood essential oil | |
| CN111990475A (en) | Lycium seed oil microcapsule rich in lycium erythrophyll and preparation method thereof | |
| CN102423049B (en) | Instant fern powder and production method thereof | |
| CN1212079C (en) | Method for producing condiment seasoning oil resin micro capsule | |
| CN102533433A (en) | Method for supercritical extraction of sea buckthorn oil | |
| CN112457918A (en) | Preparation method and application of citrus essential oil series products | |
| CN104342282A (en) | Method for preparing functional grease and active protein powder from abelmoschus manilhot | |
| CN106281638B (en) | A kind of method that camellia seed oil and oil tea saponin and camellia seed meal feed are extracted from camellia seed kernel | |
| CN107048393A (en) | A kind of preparation method of microencapsulation natural | |
| US7060313B2 (en) | Citrus peel processing system and method | |
| CN107418720A (en) | Supercritical CO2The technique for extracting Zanthoxylum essential oil | |
| CN102960680B (en) | Multidirectional extraction process for fresh peppers | |
| CN1163155C (en) | Productive technology for microcapsule plant extract | |
| CN101524099A (en) | Method of utilizing supercritical CO2 extraction technology to prepare primitive coconut oil | |
| CN103462206A (en) | Reconstituted tobacco containing directionally compound-extracted tobacco endogenous incense matter, and cigarette prepared therefrom | |
| CN107523410A (en) | Utilize the method for fruit of a cubeb litsea tree litsea citrate oil | |
| CN109567126A (en) | A kind of capsicum oleoresin microcapsules and its processing method | |
| CN1687052A (en) | Method for extracting coumarin substances from rhodiola root of natural plant | |
| CN1112416C (en) | Technology for producing flaxseed gum | |
| CN1158224A (en) | Zanthoxylum bungeanum gourmet powder and its prodn. tech. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |