CN106120316A - The preparation method of one Plant Extracts modification uvioresistant gel fabric finishing agent - Google Patents
The preparation method of one Plant Extracts modification uvioresistant gel fabric finishing agent Download PDFInfo
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- CN106120316A CN106120316A CN201610568552.1A CN201610568552A CN106120316A CN 106120316 A CN106120316 A CN 106120316A CN 201610568552 A CN201610568552 A CN 201610568552A CN 106120316 A CN106120316 A CN 106120316A
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- 230000004048 modification Effects 0.000 title claims abstract description 42
- 238000012986 modification Methods 0.000 title claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 28
- 239000000419 plant extract Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000000675 fabric finishing Substances 0.000 title claims abstract description 21
- 238000009962 finishing (textile) Methods 0.000 title claims abstract description 21
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000007788 liquid Substances 0.000 claims abstract description 28
- 241000196324 Embryophyta Species 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 19
- 230000008569 process Effects 0.000 claims abstract description 19
- 241000628997 Flos Species 0.000 claims abstract description 8
- 241000218628 Ginkgo Species 0.000 claims abstract description 8
- 235000011201 Ginkgo Nutrition 0.000 claims abstract description 8
- 235000008100 Ginkgo biloba Nutrition 0.000 claims abstract description 8
- 229960000583 acetic acid Drugs 0.000 claims description 19
- 239000012362 glacial acetic acid Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 230000005855 radiation Effects 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 241000219780 Pueraria Species 0.000 claims description 6
- 230000033228 biological regulation Effects 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 239000004570 mortar (masonry) Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- 239000000701 coagulant Substances 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 13
- 238000000605 extraction Methods 0.000 abstract description 8
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 4
- 238000004062 sedimentation Methods 0.000 abstract description 4
- 208000027418 Wounds and injury Diseases 0.000 abstract description 3
- 230000006378 damage Effects 0.000 abstract description 3
- 208000014674 injury Diseases 0.000 abstract description 3
- 206010020751 Hypersensitivity Diseases 0.000 abstract description 2
- 241001464837 Viridiplantae Species 0.000 abstract description 2
- 238000002835 absorbance Methods 0.000 abstract description 2
- 208000026935 allergic disease Diseases 0.000 abstract description 2
- 230000007815 allergy Effects 0.000 abstract description 2
- 239000000284 extract Substances 0.000 abstract description 2
- 206010025482 malaise Diseases 0.000 abstract description 2
- 208000024891 symptom Diseases 0.000 abstract description 2
- 239000004408 titanium dioxide Substances 0.000 abstract description 2
- 238000009988 textile finishing Methods 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 241000245240 Lonicera Species 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 230000010355 oscillation Effects 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 241000283898 Ovis Species 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention discloses the preparation method of a Plant Extracts modification uvioresistant gel fabric finishing agent, belongs to fabric finishing agent preparing technical field.For existing nano-TiO2In anti-ultraviolet material preparation process, owing to it is easily reunited in organic media, and produce sedimentation, by relatively big to human injury during Organic substance grafted moiety modification, the problem that human body skin is damaged from fabric by Organic substance, it is provided that a kind of by by Cortex Phellodendri.Folium Ginkgo, Flos Lonicerae and Radix Puerariae are milled and extract concentrated solution, by the feature that plant extraction liquid is stronger to ultraviolet light absorbance, itself and acetic acid, butyl titanate are mixed with titania gel liquid, effectively dispersability of titanium dioxide is improved, clothes fabric uvioresistant grade after plant extraction liquid modification uvioresistant gel fabric finishing agent prepared by the present invention processes improves 2～3 grades, fabric uvioresistant grade UPF is up to 45～50, and carry out extracting preparation by green plants, without allergy malaise symptoms after medicated clothing dress.
Description
Technical field
The invention discloses the preparation method of a Plant Extracts modification uvioresistant gel fabric finishing agent, belong to fabric
Finishing agent preparing technical field.
Background technology
Relatively for terylene, Pilus Caprae seu Ovis etc., bafta is the most meable fabric of ultraviolet, and bafta is through conventional
Summer fabric, so it is necessary to carry out uvioresistant Final finishing on pure cotton fabric.As the cotton fiber of cotton spinning raw material, it is a kind of
Senior native cellulose fibre, by it has been recognized that for being " green fiber ".Its bafta quality is plentiful abundant, has the whitest
Degree, soft feel, good moisture permeability, excellent warming effect and excellent wearing comfort, always by people
Favor, at home and abroad have market and development prospect widely.It is the most frequently used garment material in summer, is also currently used
Most commonly used garment material.But, bafta has, in ultraviolet 280～400nln wave-length coverage, the ultraviolet that comparison is high
Radiation transmission, compared with Pilus Caprae seu Ovis, silkworm silk, fiber crops, polyster fibre, the ultraviolet radiation preventing poor-performing of cotton fiber.Therefore, improve
Bafta ultraviolet radiation preventing performance is just particularly important.
The raising of standard of living, the enhancing of environmental consciousness and the rise of green consumption, comfortable to life products of people
Property, safety and health care are paid attention to increasingly, and UV resistance product such as sunscreen cream, UV resistance fabric etc. are the most in one's favour.Along with receiving
The development of rice technology, provides new development space for nano inorganic ultraviolet light screener, especially prepares and develop nano-TiO2
More become the focus of domestic and international scientific and technological circle research.And undressed TiO2Surface has the strongest polarity and hydrophilic oleophobic property,
Easily reuniting in organic media, and produce sedimentation, its dispersibility and dispersion stabilization are the most very poor, directly affect TiO2Itself is excellent
The performance of property, so the stronger anti-UV fabric finishing agent of the stability of preparing a kind of environmental type is necessary.
Summary of the invention
The technical problem that present invention mainly solves: for existing nano-TiO2In anti-ultraviolet material preparation process, due to it
Organic media is easily reunited, and produces sedimentation, by relatively big to human injury during Organic substance grafted moiety modification, Organic substance from
The problem on fabric, human body skin damaged, it is provided that a kind of by by Cortex Phellodendri.Folium Ginkgo, Flos Lonicerae and Radix Puerariae are milled also
Extract concentrated solution, by the feature that plant extraction liquid is stronger to ultraviolet light absorbance, it is mixed with acetic acid, with butyl titanate
It is mixed with titania gel liquid, effectively dispersability of titanium dioxide is improved, well solve it organic Jie
Matter is easily reunited, and produces sedimentation, relatively big to human injury when being modified by Organic substance, Organic substance from fabric to human body
The problem that skin damages.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
(1) count by weight, weigh 20～25 portions of Cortex Phellodendris, 10～15 parts of Folium Ginkgos, 15～20 parts of Radix Puerariaes and 5～10 parts respectively
Flos Lonicerae is placed in mortar, mills and is prepared into plant mill serosity, the most in mass ratio 1:5, by plant mill after 15～20min
Serosity mixes with absolute ethyl alcohol and stirring and is placed in conical flask, heating in water bath 10～15min at 65～80 DEG C；
(2) after heating in water bath completes, stand and be cooled to room temperature, then ultrasonic disperse processes 10～15min under 200～300W,
Filter subsequently and collect filtrate, rotating at 65～80 DEG C and be evaporated to the 1/5 of original volume, be prepared into plant extract concentrated solution；
(3) 1:1 by volume, mixes plant extract concentrated solution with glacial acetic acid stirring and is placed in beaker, under 200～300W
After ultrasonic disperse 10～15min, being placed in by beaker in ultraviolet irradiation case, regulation uviol lamp is 10～15cm with beaker distance, right
In irradiation box, logical nitrogen gets rid of air, the most in a nitrogen atmosphere, radiation modification 25～30min；
(4), after modification to be irradiated completes, beaker is taken out and collects glacial acetic acid modification liquid, the most in mass ratio 1:10, by metatitanic acid
Four butyl esters add to glacial acetic acid modification liquid, and under 300～350r/min, magnetic agitation mixing 10～15min, is prepared into mixing
Coagulant liquid；
(5) 1:5 in mass ratio, adds to the mixed gel drop of above-mentioned preparation in mass concentration 10% hydrochloric acid solution, controls dropping
Time is 10～15min, and after being added dropwise to complete, then under 200～300W, ultrasonic disperse processes 10～15min, stands old subsequently
Change 6～8h, a Plant Extracts modification uvioresistant gel fabric finishing agent can be prepared into.
The application process of the present invention is: 1:5 in mass ratio, and polyacrylate is modified with the plant extraction liquid of above-mentioned preparation
The stirring mixing of uvioresistant gel fabric finishing agent, after sonic oscillation processes 10～15min under 200～300W, prepares fabric whole
Reason agent mixed liquor, the most in mass ratio 1:10, impregnated in fabric finishing agent mixed liquor by fabric, after standing 10～12h, takes out
And naturally dry, fabric uvioresistant grade UPF is up to 45～50, and relatively common fabric uvioresistant grade improves 2～3 grades.
The invention has the beneficial effects as follows:
(1) the clothes fabric uvioresistant after the plant extraction liquid modification uvioresistant gel fabric finishing agent process that prepared by the present invention
Grade improves 2～3 grades, and fabric uvioresistant grade UPF is up to 45～50；
(2) present invention carries out extracting preparation by green plants, without allergy malaise symptoms after medicated clothing dress.
Detailed description of the invention
Count the most by weight, weigh 20～25 parts of Cortex Phellodendris, 10～15 parts of Folium Ginkgos, 15～20 parts of Radix Puerariaes and 5 respectively
～10 portions of Flos Loniceraes are placed in mortar, mill and be prepared into plant mill serosity, the most in mass ratio 1:5 after 15～20min, will plant
Thing grinding milk mixes with absolute ethyl alcohol and stirring and is placed in conical flask, heating in water bath 10～15min at 65～80 DEG C；Treat water
After bath heating completes, stand and be cooled to room temperature, then ultrasonic disperse processes 10～15min under 200～300W, filters subsequently and receives
Collection filtrate, rotates at 65～80 DEG C and is evaporated to the 1/5 of original volume, be prepared into plant extract concentrated solution；1:1 by volume, will
Plant extract concentrated solution stirs to mix with glacial acetic acid and is placed in beaker, under 200～300W after ultrasonic disperse 10～15min,
Being placed in by beaker in ultraviolet irradiation case, regulation uviol lamp is 10～15cm with beaker distance, and nitrogen logical in irradiation box is got rid of sky
Gas, the most in a nitrogen atmosphere, radiation modification 25～30min；After modification to be irradiated completes, beaker is taken out and collects glacial acetic acid
Modification liquid, the most in mass ratio 1:10, add butyl titanate to glacial acetic acid modification liquid, magnetic under 300～350r/min
Power stirring mixing 10～15min, is prepared into mixed gel liquid；1:5 in mass ratio, adds to the mixed gel drop of above-mentioned preparation
In mass concentration 10% hydrochloric acid solution, controlling time for adding is 10～15min, after being added dropwise to complete then super under 200～300W
Sound dispersion process 10～15min, the most still aging 6～8h, a Plant Extracts modification uvioresistant gel can be prepared into
Fabric finishing agent.
Example 1
Count the most by weight, weigh 20 portions of Cortex Phellodendris, 10 parts of Folium Ginkgos, 15 parts of Radix Puerariaes and 5 portions of Flos Loniceraes respectively and be placed in mortar
In, it is prepared into plant mill serosity, the most in mass ratio 1:5 after the 15min that mills, by plant mill serosity and absolute ethyl alcohol and stirring
Mixing is placed in conical flask, heating in water bath 10min at 65 DEG C；After heating in water bath completes, stand and be cooled to room temperature, then
Under 200W, ultrasonic disperse processes 10min, filters subsequently and collects filtrate, rotates and be evaporated to the 1/5 of original volume at 65 DEG C, preparation
Obtain plant extract concentrated solution；1:1 by volume, mixes plant extract concentrated solution with glacial acetic acid stirring and is placed in beaker,
Under 200W after ultrasonic disperse 10min, being placed in by beaker in ultraviolet irradiation case, regulation uviol lamp is 10cm with beaker distance, to spoke
Air, the most in a nitrogen atmosphere, radiation modification 25min is got rid of according to nitrogen logical in case；After modification to be irradiated completes, beaker is taken
Go out and collect glacial acetic acid modification liquid, the most in mass ratio 1:10, butyl titanate is added to glacial acetic acid modification liquid,
Under 300r/min, magnetic agitation mixing 10min, is prepared into mixed gel liquid；1:5 in mass ratio, by the mixed gel of above-mentioned preparation
Drop adds in mass concentration 10% hydrochloric acid solution, and control time for adding is 10min, after being added dropwise to complete then ultrasonic under 200W
Dispersion processes 10min, the most still aging 6h, can be prepared into a Plant Extracts modification uvioresistant gel textile finishing
Agent.
1:5 in mass ratio, by the plant extraction liquid modification uvioresistant gel textile finishing of polyacrylate Yu above-mentioned preparation
Agent stirring mixing, after sonic oscillation processes 10min under 200W, prepares fabric finishing agent mixed liquor, the most in mass ratio 1:10,
Be impregnated in by fabric in fabric finishing agent mixed liquor, after standing 10h, take out and naturally dry, fabric uvioresistant grade UPF can
Reaching 45, relatively common fabric uvioresistant grade improves 2 grades.
Example 2
Count the most by weight, weigh 22 portions of Cortex Phellodendris, 12 parts of Folium Ginkgos, 17 parts of Radix Puerariaes and 7 portions of Flos Loniceraes respectively and be placed in mortar
In, it is prepared into plant mill serosity, the most in mass ratio 1:5 after the 12min that mills, by plant mill serosity and absolute ethyl alcohol and stirring
Mixing is placed in conical flask, heating in water bath 12min at 67 DEG C；After heating in water bath completes, stand and be cooled to room temperature, then
Under 250W, ultrasonic disperse processes 12min, filters subsequently and collects filtrate, rotates and be evaporated to the 1/5 of original volume at 70 DEG C, preparation
Obtain plant extract concentrated solution；1:1 by volume, mixes plant extract concentrated solution with glacial acetic acid stirring and is placed in beaker,
Under 250W after ultrasonic disperse 12min, being placed in by beaker in ultraviolet irradiation case, regulation uviol lamp is 12cm with beaker distance, to spoke
Air, the most in a nitrogen atmosphere, radiation modification 27min is got rid of according to nitrogen logical in case；After modification to be irradiated completes, beaker is taken
Go out and collect glacial acetic acid modification liquid, the most in mass ratio 1:10, butyl titanate is added to glacial acetic acid modification liquid,
Under 325r/min, magnetic agitation mixing 12min, is prepared into mixed gel liquid；1:5 in mass ratio, by the mixed gel of above-mentioned preparation
Drop adds in mass concentration 10% hydrochloric acid solution, and control time for adding is 12min, after being added dropwise to complete then ultrasonic under 250W
Dispersion processes 12min, the most still aging 7h, can be prepared into a Plant Extracts modification uvioresistant gel textile finishing
Agent.
1:5 in mass ratio, by the plant extraction liquid modification uvioresistant gel textile finishing of polyacrylate Yu above-mentioned preparation
Agent stirring mixing, after sonic oscillation processes 12min under 250W, prepares fabric finishing agent mixed liquor, the most in mass ratio 1:10,
Be impregnated in by fabric in fabric finishing agent mixed liquor, after standing 11h, take out and naturally dry, fabric uvioresistant grade UPF can
Reaching 45, relatively common fabric uvioresistant grade improves 2 grades.
Example 3
Count the most by weight, weigh 25 portions of Cortex Phellodendris, 15 parts of Folium Ginkgos, 20 parts of Radix Puerariaes and 10 portions of Flos Loniceraes respectively and be placed in mortar
In, it is prepared into plant mill serosity, the most in mass ratio 1:5 after the 20min that mills, by plant mill serosity and absolute ethyl alcohol and stirring
Mixing is placed in conical flask, heating in water bath 15min at 80 DEG C；After heating in water bath completes, stand and be cooled to room temperature, then
Under 300W, ultrasonic disperse processes 15min, filters subsequently and collects filtrate, rotates and be evaporated to the 1/5 of original volume at 80 DEG C, preparation
Obtain plant extract concentrated solution；1:1 by volume, mixes plant extract concentrated solution with glacial acetic acid stirring and is placed in beaker,
Under 300W after ultrasonic disperse 15min, being placed in by beaker in ultraviolet irradiation case, regulation uviol lamp is 15cm with beaker distance, to spoke
Air, the most in a nitrogen atmosphere, radiation modification 30min is got rid of according to nitrogen logical in case；After modification to be irradiated completes, beaker is taken
Go out and collect glacial acetic acid modification liquid, the most in mass ratio 1:10, butyl titanate is added to glacial acetic acid modification liquid,
Under 350r/min, magnetic agitation mixing 15min, is prepared into mixed gel liquid；1:5 in mass ratio, by the mixed gel of above-mentioned preparation
Drop adds in mass concentration 10% hydrochloric acid solution, and control time for adding is 15min, after being added dropwise to complete then ultrasonic under 300W
Dispersion processes 15min, the most still aging 8h, can be prepared into a Plant Extracts modification uvioresistant gel textile finishing
Agent.
1:5 in mass ratio, by the plant extraction liquid modification uvioresistant gel textile finishing of polyacrylate Yu above-mentioned preparation
Agent stirring mixing, after sonic oscillation processes 15min under 300W, prepares fabric finishing agent mixed liquor, the most in mass ratio 1:10,
Be impregnated in by fabric in fabric finishing agent mixed liquor, after standing 12h, take out and naturally dry, fabric uvioresistant grade UPF can
Reaching 50, relatively common fabric uvioresistant grade improves 3 grades.
Claims (1)
1. the preparation method of a Plant Extracts modification uvioresistant gel fabric finishing agent, it is characterised in that concrete preparation process
For:
(1) count by weight, weigh 20～25 portions of Cortex Phellodendris, 10～15 parts of Folium Ginkgos, 15～20 parts of Radix Puerariaes and 5～10 parts respectively
Flos Lonicerae is placed in mortar, mills and is prepared into plant mill serosity, the most in mass ratio 1:5, by plant mill after 15～20min
Serosity mixes with absolute ethyl alcohol and stirring and is placed in conical flask, heating in water bath 10～15min at 65～80 DEG C；
(2) after heating in water bath completes, stand and be cooled to room temperature, then ultrasonic disperse processes 10～15min under 200～300W,
Filter subsequently and collect filtrate, rotating at 65～80 DEG C and be evaporated to the 1/5 of original volume, be prepared into plant extract concentrated solution；
(3) 1:1 by volume, mixes plant extract concentrated solution with glacial acetic acid stirring and is placed in beaker, under 200～300W
After ultrasonic disperse 10～15min, being placed in by beaker in ultraviolet irradiation case, regulation uviol lamp is 10～15cm with beaker distance, right
In irradiation box, logical nitrogen gets rid of air, the most in a nitrogen atmosphere, radiation modification 25～30min；
(4), after modification to be irradiated completes, beaker is taken out and collects glacial acetic acid modification liquid, the most in mass ratio 1:10, by metatitanic acid
Four butyl esters add to glacial acetic acid modification liquid, and under 300～350r/min, magnetic agitation mixing 10～15min, is prepared into mixing
Coagulant liquid；
(5) 1:5 in mass ratio, adds to the mixed gel drop of above-mentioned preparation in mass concentration 10% hydrochloric acid solution, controls dropping
Time is 10～15min, and after being added dropwise to complete, then under 200～300W, ultrasonic disperse processes 10～15min, stands old subsequently
Change 6～8h, a Plant Extracts modification uvioresistant gel fabric finishing agent can be prepared into.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610568552.1A CN106120316B (en) | 2016-07-19 | 2016-07-19 | The preparation method of the modified uvioresistant gel fabric finishing agent of one Plant Extracts |
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| CN201610568552.1A CN106120316B (en) | 2016-07-19 | 2016-07-19 | The preparation method of the modified uvioresistant gel fabric finishing agent of one Plant Extracts |
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| CN106120316A true CN106120316A (en) | 2016-11-16 |
| CN106120316B CN106120316B (en) | 2019-02-12 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107935661A (en) * | 2017-12-06 | 2018-04-20 | 赖英权 | Eat the preparation method of section melon special nutrient fluid raw |
| CN108130712A (en) * | 2017-12-30 | 2018-06-08 | 雷笑天 | A kind of biomass ferment is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent |
| CN110965358A (en) * | 2019-10-10 | 2020-04-07 | 四川圣达高环保科技有限公司 | Negative oxygen ion mask processing technology |
| CN110965357A (en) * | 2019-10-10 | 2020-04-07 | 四川圣达高环保科技有限公司 | Negative oxygen ion eye patch processing technology |
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| CN103497467A (en) * | 2013-08-14 | 2014-01-08 | 武汉华工图像技术开发有限公司 | Preparation method of composite material of polyacrylate polymer and nano titanium dioxide |
| CN105420919A (en) * | 2015-11-05 | 2016-03-23 | 镇江通达内饰材料有限公司 | Preparation method of photocatalyst formaldehyde-removal blanket |
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| CN102535160A (en) * | 2011-12-16 | 2012-07-04 | 江南大学 | Method for preparing yew leaf extract by using high-pressure micro jet and method for applying yew leaf extract to fabrics |
| CN103437144A (en) * | 2013-07-22 | 2013-12-11 | 苏州三和开泰花线织造有限公司 | Preparation method for nanometer titanium dioxide finishing agent |
| CN103497467A (en) * | 2013-08-14 | 2014-01-08 | 武汉华工图像技术开发有限公司 | Preparation method of composite material of polyacrylate polymer and nano titanium dioxide |
| CN105420919A (en) * | 2015-11-05 | 2016-03-23 | 镇江通达内饰材料有限公司 | Preparation method of photocatalyst formaldehyde-removal blanket |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107935661A (en) * | 2017-12-06 | 2018-04-20 | 赖英权 | Eat the preparation method of section melon special nutrient fluid raw |
| CN108130712A (en) * | 2017-12-30 | 2018-06-08 | 雷笑天 | A kind of biomass ferment is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent |
| CN110965358A (en) * | 2019-10-10 | 2020-04-07 | 四川圣达高环保科技有限公司 | Negative oxygen ion mask processing technology |
| CN110965357A (en) * | 2019-10-10 | 2020-04-07 | 四川圣达高环保科技有限公司 | Negative oxygen ion eye patch processing technology |
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