CN106120316B - The preparation method of the modified uvioresistant gel fabric finishing agent of one Plant Extracts - Google Patents
The preparation method of the modified uvioresistant gel fabric finishing agent of one Plant Extracts Download PDFInfo
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- CN106120316B CN106120316B CN201610568552.1A CN201610568552A CN106120316B CN 106120316 B CN106120316 B CN 106120316B CN 201610568552 A CN201610568552 A CN 201610568552A CN 106120316 B CN106120316 B CN 106120316B
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 28
- 239000000419 plant extract Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 239000000675 fabric finishing Substances 0.000 title claims abstract description 21
- 238000009962 finishing (textile) Methods 0.000 title claims abstract description 21
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000007788 liquid Substances 0.000 claims abstract description 29
- 241000196324 Embryophyta Species 0.000 claims abstract description 19
- 239000012141 concentrate Substances 0.000 claims abstract description 13
- 235000011201 Ginkgo Nutrition 0.000 claims abstract description 8
- 235000008100 Ginkgo biloba Nutrition 0.000 claims abstract description 8
- 235000010575 Pueraria lobata Nutrition 0.000 claims abstract description 8
- 241000205585 Aquilegia canadensis Species 0.000 claims abstract 2
- 244000194101 Ginkgo biloba Species 0.000 claims abstract 2
- 241000219781 Pueraria montana var. lobata Species 0.000 claims abstract 2
- 238000012986 modification Methods 0.000 claims description 24
- 230000004048 modification Effects 0.000 claims description 24
- 229960000583 acetic acid Drugs 0.000 claims description 19
- 239000012362 glacial acetic acid Substances 0.000 claims description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 239000008236 heating water Substances 0.000 claims description 11
- 239000002002 slurry Substances 0.000 claims description 10
- 230000005855 radiation Effects 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 239000004570 mortar (masonry) Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000000701 coagulant Substances 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 29
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 13
- 238000000605 extraction Methods 0.000 abstract description 8
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 abstract description 7
- 239000005416 organic matter Substances 0.000 abstract description 6
- 230000006378 damage Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 238000004062 sedimentation Methods 0.000 abstract description 4
- 208000027418 Wounds and injury Diseases 0.000 abstract description 3
- 208000014674 injury Diseases 0.000 abstract description 3
- 206010020751 Hypersensitivity Diseases 0.000 abstract description 2
- 241001464837 Viridiplantae Species 0.000 abstract description 2
- 238000002835 absorbance Methods 0.000 abstract description 2
- 208000026935 allergic disease Diseases 0.000 abstract description 2
- 230000007815 allergy Effects 0.000 abstract description 2
- 239000000284 extract Substances 0.000 abstract description 2
- 206010025482 malaise Diseases 0.000 abstract description 2
- 230000003287 optical effect Effects 0.000 abstract description 2
- 208000024891 symptom Diseases 0.000 abstract description 2
- 239000004408 titanium dioxide Substances 0.000 abstract description 2
- 229920000742 Cotton Polymers 0.000 description 9
- 238000012545 processing Methods 0.000 description 8
- 241000218628 Ginkgo Species 0.000 description 6
- 244000046146 Pueraria lobata Species 0.000 description 6
- 238000009988 textile finishing Methods 0.000 description 6
- 241000245240 Lonicera Species 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- 230000010355 oscillation Effects 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 229960000935 dehydrated alcohol Drugs 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 230000006750 UV protection Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 241001570521 Lonicera periclymenum Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- -1 wool etc. Polymers 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention discloses the preparation method of the modified uvioresistant gel fabric finishing agent of a Plant Extracts, belongs to fabric finishing agent preparation technical field.For existing nano-TiO2In anti-ultraviolet material preparation process, since it is easy to reunite in organic media, and sedimentation is generated, larger to human injury when modified by organic matter grafted moiety, the problem of organic matter damages human skin from fabric provides a kind of by by Cortex Phellodendri.Ginkgo leaf, honeysuckle and pueraria lobata mill and extract concentrate, by plant extraction liquid to the stronger feature of ultraviolet optical absorbance, it is mixed with titania gel liquid with acetic acid, butyl titanate, effectively dispersability of titanium dioxide is improved, treated that clothes fabric uvioresistant grade improves 2~3 grades for the modified uvioresistant gel fabric finishing agent of plant extraction liquid prepared by the present invention, UPF is up to 45~50 for fabric uvioresistant grade, and preparation is extracted by green plants, without allergy malaise symptoms after clothing dress.
Description
Technical field
The invention discloses the preparation methods of the modified uvioresistant gel fabric finishing agent of a Plant Extracts, belong to fabric
Finishing agent preparation technical field.
Background technique
For opposite terylene, wool etc., cotton fabric is the most meable fabric of ultraviolet light, and cotton fabric is through common
Summer fabric, so it is necessary to carry out uvioresistant final finishing on pure cotton fabric.It is a kind of as the cotton fiber of cotton spinning raw material
Advanced native cellulose fibre is known as being " green fiber " by people.Its cotton fabric quality is plentiful thick and solid, has preferable white
Degree, soft feel, good moisture permeability, excellent warming effect and excellent wearing comfort, always by people
Favor, at home and abroad have extensive market and development prospect.It is summer the most frequently used garment material, and is used at present
Most commonly used garment material.But cotton fabric has relatively high ultraviolet light in ultraviolet light 280~400nln wave-length coverage
Radiation transmission, compared with wool, silk, fiber crops, polyester fiber, the ultraviolet radiation preventing performance of cotton fiber is poor.Therefore, it improves
Cotton fabric ultraviolet radiation preventing performance is just particularly important.
The raising of standard of living, the rise of enhancing and the green consumption of environmental consciousness, people are to the comfortable of life products
Property, safety and health care are paid attention to increasingly, and UV resistance product such as suncream, UV resistance fabric etc. is gradually in one's favour.With receiving
The development of rice technology, new development space is provided for nano inorganic ultraviolet light screener, especially prepares and develop nano-TiO2
More become the hot spot of domestic and international scientific and technological circle research.And untreated TiO2Surface has very strong polarity and hydrophilic and oleophobic property,
It is easy to reunite in organic media, and sedimentation is generated, dispersibility and dispersion stabilization are all very poor, directly affect TiO2Itself is excellent
The performance of property, so a kind of stronger anti-UV fabric finishing agent of the stability for preparing environmental type is necessary.
Summary of the invention
Present invention mainly solves the technical issues of: be directed to existing nano-TiO2In anti-ultraviolet material preparation process, due to it
It is easy to reunite in organic media, and generate sedimentation, it is larger to human injury when modified by organic matter grafted moiety, organic matter from
The problem of damaging on fabric to human skin provides one kind by the way that Cortex Phellodendri, ginkgo leaf, honeysuckle and pueraria lobata are milled simultaneously
Concentrate is extracted to mix it with acetic acid, by plant extraction liquid to the stronger feature of ultraviolet optical absorbance with butyl titanate
Be mixed with titania gel liquid, effectively dispersability of titanium dioxide improved, very good solution its in organic Jie
It is easy to reunite in matter, and sedimentation is generated, larger to human injury when being modified by organic matter, organic matter is from fabric to human body
The problem of skin damages.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
(1) according to parts by weight, weigh respectively 20~25 portions of Cortex Phellodendris, 10~15 parts of ginkgo leaves, 15~20 parts of pueraria lobatas and 5~
10 portions of honeysuckles are placed in mortar, and plant mill slurries are prepared into after the 15~20min that mills, then 1:5 in mass ratio, by plant
Grinding milk is mixed with absolute ethyl alcohol and stirring and is placed in conical flask, 10~15min of heating water bath at 65~80 DEG C；
(2) after the completion of heating water bath, standing is cooled to room temperature, then at 200~300W ultrasonic disperse processing 10~
15min then filters and collects filtrate, and rotation is evaporated to the 1/5 of original volume at 65~80 DEG C, is prepared into plant extract concentration
Liquid；
(3) plant extract concentrate and glacial acetic acid are stirred and are placed in beaker by 1:1 by volume, 200~
Under 300W after 10~15min of ultrasonic disperse, place the beaker in ultraviolet irradiation case, adjust ultraviolet lamp and beaker distance for 10~
15cm excludes air, then in a nitrogen atmosphere, 25~30min of radiation modification to nitrogen is led in irradiation box；
(4) after the completion of modification to be irradiated, beaker is taken out and collects glacial acetic acid modification liquid, then 1:10 in mass ratio, it will
Butyl titanate is added in glacial acetic acid modification liquid, and magnetic agitation mixes 10~15min at 300~350r/min, is prepared into
Mixed gel liquid；
(5) 1:5 in mass ratio adds to the mixed gel drop of above-mentioned preparation in 10% hydrochloric acid solution of mass concentration, control
Time for adding is 10~15min, and ultrasonic disperse handles 10~15min after being added dropwise to complete, then at 200~300W, then quiet
6~8h of ageing is set, the modified uvioresistant gel fabric finishing agent of a Plant Extracts can be prepared into.
Application method of the invention is: 1:5 in mass ratio, and polyacrylate and the plant extraction liquid of above-mentioned preparation is modified
Uvioresistant gel fabric finishing agent is stirred, and after sonic oscillation handles 10~15min at 200~300W, it is whole to prepare fabric
Agent mixed liquor is managed, then 1:10 in mass ratio, fabric is impregnated in fabric finishing agent mixed liquor, after standing 10~12h, is taken out
And naturally dry, fabric uvioresistant grade UPF improve 2~3 grades up to 45~50, compared with common fabric uvioresistant grade.
The beneficial effects of the present invention are:
(1) the modified uvioresistant gel fabric finishing agent of plant extraction liquid prepared by the present invention treated the anti-purple of clothes fabric
Outside line grade improves 2~3 grades, and UPF is up to 45~50 for fabric uvioresistant grade；
(2) present invention extracts preparation by green plants, without allergy malaise symptoms after clothing dress.
Specific embodiment
First according to parts by weight, 20~25 portions of Cortex Phellodendris, 10~15 parts of ginkgo leaves, 15~20 parts of pueraria lobatas and 5 are weighed respectively
~10 portions of honeysuckles are placed in mortar, and plant mill slurries are prepared into after the 15~20min that mills, then 1:5 in mass ratio, will be planted
Object grinding milk is mixed with absolute ethyl alcohol and stirring to be placed in conical flask, 10~15min of heating water bath at 65~80 DEG C；To water
After the completion of bath heating, standing is cooled to room temperature, then ultrasonic disperse handles 10~15min at 200~300W, then filters and receives
Collect filtrate, rotation is evaporated to the 1/5 of original volume at 65~80 DEG C, is prepared into plant extract concentrate；1:1 by volume, will
Plant extract concentrate and glacial acetic acid, which are stirred, to be placed in beaker, at 200~300W after 10~15min of ultrasonic disperse,
It places the beaker in ultraviolet irradiation case, adjusting ultraviolet lamp and beaker distance is 10~15cm, is excluded to nitrogen logical in irradiation box empty
Gas, then in a nitrogen atmosphere, 25~30min of radiation modification；After the completion of modification to be irradiated, beaker is taken out and collects glacial acetic acid
Modification liquid, then 1:10 in mass ratio, butyl titanate is added in glacial acetic acid modification liquid, the magnetic at 300~350r/min
Power is stirred 10~15min, is prepared into mixed gel liquid；1:5 in mass ratio adds to the mixed gel drop of above-mentioned preparation
In 10% hydrochloric acid solution of mass concentration, control time for adding is 10~15min, is surpassed after being added dropwise to complete, then at 200~300W
Sound 10~15min of decentralized processing, subsequent still aging 6~8h can be prepared into the modified uvioresistant gel of a Plant Extracts
Fabric finishing agent.
Example 1
First according to parts by weight, 20 portions of Cortex Phellodendris, 10 parts of ginkgo leaves, 15 parts of pueraria lobatas and 5 portions of honeysuckles are weighed respectively to be placed in
In mortar, plant mill slurries are prepared into after the 15min that mills, then 1:5 in mass ratio, by plant mill slurries and dehydrated alcohol
It is stirred and is placed in conical flask, the heating water bath 10min at 65 DEG C；After the completion of heating water bath, standing is cooled to room temperature,
Ultrasonic disperse handles 10min at 200W again, then filters and collect filtrate, and rotation is evaporated to the 1/5 of original volume at 65 DEG C,
It is prepared into plant extract concentrate；Plant extract concentrate and glacial acetic acid are stirred and are placed in beaker by 1:1 by volume
In, at 200W after ultrasonic disperse 10min, place the beaker in ultraviolet irradiation case, adjusting ultraviolet lamp and beaker distance is 10cm,
Air, then in a nitrogen atmosphere, radiation modification 25min are excluded to nitrogen is led in irradiation box；After the completion of modification to be irradiated, it will burn
Cup takes out and collects glacial acetic acid modification liquid, and then 1:10 in mass ratio, butyl titanate is added in glacial acetic acid modification liquid,
Magnetic agitation mixes 10min under 300r/min, is prepared into mixed gel liquid；1:5 in mass ratio, by the mixed gel of above-mentioned preparation
Drop adds in 10% hydrochloric acid solution of mass concentration, and control time for adding is 10min, ultrasonic after being added dropwise to complete, then at 200W
Decentralized processing 10min, subsequent still aging 6h can be prepared into the modified uvioresistant gel textile finishing of a Plant Extracts
Agent.
1:5 in mass ratio, by polyacrylate and the modified uvioresistant gel textile finishing of the plant extraction liquid of above-mentioned preparation
Agent is stirred, and at 200W after sonic oscillation processing 10min, prepares fabric finishing agent mixed liquor, then 1:10 in mass ratio,
Fabric is impregnated in fabric finishing agent mixed liquor, after standing 10h, takes out simultaneously naturally dry, fabric uvioresistant grade UPF can
Up to 45,2 grades are improved compared with common fabric uvioresistant grade.
Example 2
First according to parts by weight, 22 portions of Cortex Phellodendris, 12 parts of ginkgo leaves, 17 parts of pueraria lobatas and 7 portions of honeysuckles are weighed respectively to be placed in
In mortar, plant mill slurries are prepared into after the 12min that mills, then 1:5 in mass ratio, by plant mill slurries and dehydrated alcohol
It is stirred and is placed in conical flask, the heating water bath 12min at 67 DEG C；After the completion of heating water bath, standing is cooled to room temperature,
Ultrasonic disperse handles 12min at 250W again, then filters and collect filtrate, and rotation is evaporated to the 1/5 of original volume at 70 DEG C,
It is prepared into plant extract concentrate；Plant extract concentrate and glacial acetic acid are stirred and are placed in beaker by 1:1 by volume
In, at 250W after ultrasonic disperse 12min, place the beaker in ultraviolet irradiation case, adjusting ultraviolet lamp and beaker distance is 12cm,
Air, then in a nitrogen atmosphere, radiation modification 27min are excluded to nitrogen is led in irradiation box；After the completion of modification to be irradiated, it will burn
Cup takes out and collects glacial acetic acid modification liquid, and then 1:10 in mass ratio, butyl titanate is added in glacial acetic acid modification liquid,
Magnetic agitation mixes 12min under 325r/min, is prepared into mixed gel liquid；1:5 in mass ratio, by the mixed gel of above-mentioned preparation
Drop adds in 10% hydrochloric acid solution of mass concentration, and control time for adding is 12min, ultrasonic after being added dropwise to complete, then at 250W
Decentralized processing 12min, subsequent still aging 7h can be prepared into the modified uvioresistant gel textile finishing of a Plant Extracts
Agent.
1:5 in mass ratio, by polyacrylate and the modified uvioresistant gel textile finishing of the plant extraction liquid of above-mentioned preparation
Agent is stirred, and at 250W after sonic oscillation processing 12min, prepares fabric finishing agent mixed liquor, then 1:10 in mass ratio,
Fabric is impregnated in fabric finishing agent mixed liquor, after standing 11h, takes out simultaneously naturally dry, fabric uvioresistant grade UPF can
Up to 45,2 grades are improved compared with common fabric uvioresistant grade.
Example 3
First according to parts by weight, 25 portions of Cortex Phellodendris, 15 parts of ginkgo leaves, 20 parts of pueraria lobatas and 10 portions of honeysuckles are weighed respectively to be placed in
In mortar, plant mill slurries are prepared into after the 20min that mills, then 1:5 in mass ratio, by plant mill slurries and dehydrated alcohol
It is stirred and is placed in conical flask, the heating water bath 15min at 80 DEG C；After the completion of heating water bath, standing is cooled to room temperature,
Ultrasonic disperse handles 15min at 300W again, then filters and collect filtrate, and rotation is evaporated to the 1/5 of original volume at 80 DEG C,
It is prepared into plant extract concentrate；Plant extract concentrate and glacial acetic acid are stirred and are placed in beaker by 1:1 by volume
In, at 300W after ultrasonic disperse 15min, place the beaker in ultraviolet irradiation case, adjusting ultraviolet lamp and beaker distance is 15cm,
Air, then in a nitrogen atmosphere, radiation modification 30min are excluded to nitrogen is led in irradiation box；After the completion of modification to be irradiated, it will burn
Cup takes out and collects glacial acetic acid modification liquid, and then 1:10 in mass ratio, butyl titanate is added in glacial acetic acid modification liquid,
Magnetic agitation mixes 15min under 350r/min, is prepared into mixed gel liquid；1:5 in mass ratio, by the mixed gel of above-mentioned preparation
Drop adds in 10% hydrochloric acid solution of mass concentration, and control time for adding is 15min, ultrasonic after being added dropwise to complete, then at 300W
Decentralized processing 15min, subsequent still aging 8h can be prepared into the modified uvioresistant gel textile finishing of a Plant Extracts
Agent.
1:5 in mass ratio, by polyacrylate and the modified uvioresistant gel textile finishing of the plant extraction liquid of above-mentioned preparation
Agent is stirred, and at 300W after sonic oscillation processing 15min, prepares fabric finishing agent mixed liquor, then 1:10 in mass ratio,
Fabric is impregnated in fabric finishing agent mixed liquor, after standing 12h, takes out simultaneously naturally dry, fabric uvioresistant grade UPF can
Up to 50,3 grades are improved compared with common fabric uvioresistant grade.
Claims (1)
1. the preparation method of the modified uvioresistant gel fabric finishing agent of a Plant Extracts, it is characterised in that specific preparation step
Are as follows:
(1) according to parts by weight, 20~25 portions of Cortex Phellodendris, 10~15 parts of ginkgo leaves, 15~20 parts of pueraria lobatas and 5~10 parts are weighed respectively
Honeysuckle is placed in mortar, and plant mill slurries are prepared into after the 15~20min that mills, then 1:5 in mass ratio, by plant mill
Slurries are mixed with absolute ethyl alcohol and stirring and are placed in conical flask, 10~15min of heating water bath at 65~80 DEG C；
(2) after the completion of heating water bath, standing is cooled to room temperature, then ultrasonic disperse handles 10~15min at 200~300W,
Filtrate is then filtered and collects, rotation is evaporated to the 1/5 of original volume at 65~80 DEG C, is prepared into plant extract concentrate；
(3) plant extract concentrate and glacial acetic acid are stirred and are placed in beaker, at 200~300W by 1:1 by volume
It after 10~15min of ultrasonic disperse, places the beaker in ultraviolet irradiation case, adjusting ultraviolet lamp and beaker distance is 10~15cm, right
Lead to nitrogen in irradiation box and excludes air, then in a nitrogen atmosphere, 25~30min of radiation modification；
(4) after the completion of modification to be irradiated, beaker is taken out and collects glacial acetic acid modification liquid, then 1:10 in mass ratio, by metatitanic acid
Four butyl esters are added in glacial acetic acid modification liquid, and magnetic agitation mixes 10~15min at 300~350r/min, are prepared into mixing
Coagulant liquid；
(5) 1:5 in mass ratio adds to the mixed gel drop of above-mentioned preparation in 10% hydrochloric acid solution of mass concentration, and control is added dropwise
Time is 10~15min, and ultrasonic disperse handles 10~15min after being added dropwise to complete, then at 200~300W, is then stood old
Change 6~8h, the modified uvioresistant gel fabric finishing agent of a Plant Extracts can be prepared into.
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| CN201610568552.1A CN106120316B (en) | 2016-07-19 | 2016-07-19 | The preparation method of the modified uvioresistant gel fabric finishing agent of one Plant Extracts |
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| CN201610568552.1A CN106120316B (en) | 2016-07-19 | 2016-07-19 | The preparation method of the modified uvioresistant gel fabric finishing agent of one Plant Extracts |
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| CN106120316B true CN106120316B (en) | 2019-02-12 |
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| CN107935661A (en) * | 2017-12-06 | 2018-04-20 | 赖英权 | Eat the preparation method of section melon special nutrient fluid raw |
| CN108130712A (en) * | 2017-12-30 | 2018-06-08 | 雷笑天 | A kind of biomass ferment is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent |
| CN110965358A (en) * | 2019-10-10 | 2020-04-07 | 四川圣达高环保科技有限公司 | Negative oxygen ion mask processing technology |
| CN110965357A (en) * | 2019-10-10 | 2020-04-07 | 四川圣达高环保科技有限公司 | Negative oxygen ion eye patch processing technology |
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| CN102535160A (en) * | 2011-12-16 | 2012-07-04 | 江南大学 | Method for preparing yew leaf extract by using high-pressure micro jet and method for applying yew leaf extract to fabrics |
| CN103437144A (en) * | 2013-07-22 | 2013-12-11 | 苏州三和开泰花线织造有限公司 | Preparation method for nanometer titanium dioxide finishing agent |
| CN103497467A (en) * | 2013-08-14 | 2014-01-08 | 武汉华工图像技术开发有限公司 | Preparation method of composite material of polyacrylate polymer and nano titanium dioxide |
| CN105420919A (en) * | 2015-11-05 | 2016-03-23 | 镇江通达内饰材料有限公司 | Preparation method of photocatalyst formaldehyde-removal blanket |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102535160A (en) * | 2011-12-16 | 2012-07-04 | 江南大学 | Method for preparing yew leaf extract by using high-pressure micro jet and method for applying yew leaf extract to fabrics |
| CN103437144A (en) * | 2013-07-22 | 2013-12-11 | 苏州三和开泰花线织造有限公司 | Preparation method for nanometer titanium dioxide finishing agent |
| CN103497467A (en) * | 2013-08-14 | 2014-01-08 | 武汉华工图像技术开发有限公司 | Preparation method of composite material of polyacrylate polymer and nano titanium dioxide |
| CN105420919A (en) * | 2015-11-05 | 2016-03-23 | 镇江通达内饰材料有限公司 | Preparation method of photocatalyst formaldehyde-removal blanket |
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