CN106118058A - The fuse silicone pipes that a kind of resistance to calcination performance is good - Google Patents

The fuse silicone pipes that a kind of resistance to calcination performance is good Download PDF

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Publication number
CN106118058A
CN106118058A CN201610628027.4A CN201610628027A CN106118058A CN 106118058 A CN106118058 A CN 106118058A CN 201610628027 A CN201610628027 A CN 201610628027A CN 106118058 A CN106118058 A CN 106118058A
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temperature
good
hydrocarbon
fuse
silicone
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CN201610628027.4A
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Chinese (zh)
Inventor
戴文忠
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Anhui Yifala Electrical Co Ltd
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Anhui Yifala Electrical Co Ltd
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Priority to CN201610628027.4A priority Critical patent/CN106118058A/en
Publication of CN106118058A publication Critical patent/CN106118058A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/062—HDPE
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses the fuse silicone pipes that a kind of resistance to calcination performance is good, be made up of the raw material of following weight portion: positive last of the ten Heavenly stems hydrocarbon 190 200, straight chain endecatylene hydrocarbon 65 75, containing hydrogen silicone oil 190 200, hydroxy stearic acid 15 20, Lithium hydrate 46, PE vector resin 45 55, Masterbatch 57, high density polyethylene (HDPE) 60 70, expanded perlite 35, organosilicon auxiliary agent 23, sodium tripolyphosphate 12, waterglass 0.8 1.2, deionized water appropriate；Silicone pipes hot strength prepared by technique of the present invention is high, elongation at break is good, can better meet market and use demand, be worthy to be popularized.

Description

The fuse silicone pipes that a kind of resistance to calcination performance is good
Technical field
The present invention relates to silicone pipes technical field, particularly relate to the fuse silicone pipes that a kind of resistance to calcination performance is good.
Background technology
21 century is the epoch of information, and with fastest developing speed is information industry, and in the transmission of information, optical cable is most important logical Road, because only that optical cable can transmit substantial amounts of information with the fastest speed, also will not be disturbed, will not give away secrets, and China is the most several Year telecommunication cause develop the stages of historical development having had passed over from cable communication to optical cable rapidly, from civilian to military, from Phone all enters optical-fibre communications epoch, the biggest development having promoted plastic optical fiber cable jacket ducts to multimedia.Light Cable is typically buried in underground, for being effectively protected optical cable, generally adds a protection sleeve pipe outside optical cable, in cable run process In, the tubing used at first is steel pipe, pipe of cement, pvc pipe and double-wall corrugated pipe, and the problem using middle maximum is how to solve to wear The lubrication problem of inner-walls of duct in cable, typically uses the way of coating lubricant by aforementioned tubes, i.e. before wearing cable first when constructing The lubricant of liquid is coated in pipe material inner wall, but due to the effect of gravity, makes lubricant can not be uniformly distributed in pipe material inner wall, And the cable being also dried by leading portion when wearing cable takes away, therefore no matter select drawing method when wearing cable or blow afloat method, lubrication Problem all directly affects length and the speed wearing cable, uses these methods all to considerably increase the artificial and increase of resource expense. Silicone pipes friction factor is less, and pipe joint is few, quick construction, be not required to outer increasing protection of pipe, greatly reduces construction costs, due to Inwall silicon core layer is permanent solid lubrication oxidant layer, and frictional behaviour keeps constant, and cable can extract in pipe repeatedly, will not shell Falling, depart from, ageing-resistant service life was up to more than 50 years, so silicon core cable tube is widely used in a variety of applications.
Studying more person in silicone oil grease is methyl-silicone oil grease, due to the thickening poor-performing of dimethicone, The compatibility with organic material is the poorest, so, there is the problems such as greasy property is not good enough in methyl-silicone oil grease, limits its application Scope." alkyl modified silicon oil preparation of greases and performance study " Wen Zhongzhu state builds employing containing hydrogen silicone oil and linear alpha olefin Carry out hydrosilylation, prepare alkyl modified silicon oil, then itself and 12 hydroxy stearic acids are carried out saponification, prepare alkyl Modified silicon oil grease, result shows that, under close viscosity, the film strength of alkyl modified silicon oil is bigger than methyl-silicone oil, lubrication Property more preferable, the refractive index ratio methyl-silicone oil of alkyl modified silicon oil is high, closer to Dormant oils, fat and Organic substance, compatible with them Property more preferable, the transparency is higher, but sintering load is close with methyl-silicone oil, not raising, and weatherability, oxidative resistance and resistance to The characteristics such as solvent are general, reduce use field, in order to enable silicone oil grease well to be utilized in silicone pipes, this It is expanded modification by invention on its basis, makes the silicone pipes of preparation disclosure satisfy that the nowadays optical fiber requirement to silicone pipes, actively Accomplish to reduce cost, economize on resources and protect environment.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that the fuse silicon that a kind of resistance to calcination performance is good Core pipe.
The present invention is achieved by the following technical solutions:
The fuse silicone pipes that a kind of resistance to calcination performance is good, is made up of the raw material of following weight portion: just hydrocarbon 190-in the last of the ten Heavenly stems 200, straight chain endecatylene hydrocarbon 65-75, containing hydrogen silicone oil 190-200, hydroxy stearic acid 15-20, Lithium hydrate 4-6, PE carrier tree Fat 45-55, Masterbatch 5-7, high density polyethylene (HDPE) 60-70, expanded perlite 3-5, organosilicon auxiliary agent 2-3, sodium tripolyphosphate 1- 2, waterglass 0.8-1.2, deionized water are appropriate.
The fuse silicone pipes that described a kind of resistance to calcination performance is good, is made up of following concrete steps:
(1) hydrocarbon in positive last of the ten Heavenly stems and straight chain endecatylene hydrocarbon are uniformly mixed, rise high-temperature to 120 DEG C, react 3-4h, the most slowly Adding containing hydrogen silicone oil and appropriate chloroplatinic acid, continuation liter high-temperature is to 130-140 DEG C, and stirring reaction 6-8h, reaction removes after terminating Remove low-boiling-point substance, obtain olefin-modified silicone oil standby；
(2) waterglass and deionized water are mixed according to volume ratio 1:10-20, the solution that stirred for several minute is uniformly mixed, Add organosilicon auxiliary agent mixing and stirring, expanded perlite is placed in vacuum tank, is evacuated to-0.1MPa, be heated to Dry temperature and be 120-180 DEG C, dry to constant weight, then proceed to evacuation and to be down to temperature be 25 DEG C, inject above-mentioned mixing molten Liquid, then proceedes to evacuation, and vacuum tank air-breathing boosts to 1.5MPa, voltage stabilizing 20-30min, is then dried by expanded perlite and grinds Broken standby；
(3) modified silicon oil prepared by the step (1) of hydroxy stearic acid, formula ratio 1/3 is added in reactor, rises high-temperature extremely 80-90 DEG C, stirring makes hydroxy stearic acid all dissolve, then rises high-temperature to 90-110 DEG C, adds Lithium hydrate, saponification 1- 2h, reacts complete, liter high-temperature to 120-140 DEG C of dehydration, and is constantly rising the alkyl modified silicon oil that warming middle-JIAO adds 1/3 successively, When temperature is increased to 200-220 DEG C, stops heating, add remaining alkyl modified silicon oil, make temperature in the kettle drop to rapidly 120-140 DEG C, adding step (2) product prepared, stirring reaction naturally cools to discharging during ＜ 100 DEG C, grinds, deaerates, standby With；
(4) product PE vector resin, step (3) prepared and sodium tripolyphosphate are together added to mixed milling type parallel double-screw extrusion Carrying out pelletize in machine, temperature is 195-205 DEG C, makes silicone pipes master batch, then with Masterbatch, high density polyethylene (HDPE) and remaining Surplus materials synchronizes extrusion claddings by three extruders, by Vacuum refrigerator and soak cooling water tank to extrusion cladding after Tubing carries out cooling and shaping, and metering prints, and draws and crimp the most available.
The invention have the advantage that the present invention uses alhpa olefin and containing hydrogen silicone oil hydrosilylation to prepare copoly type alkyl Modified silicon oil, and oil based on it, carry out saponification with hydroxy stearic acid, and it is glossy that addition lithium soap is made for modified silicon Consistent lubricant, utilize expanded perlite light weight porous, do not fire, the characteristic such as nontoxic, chemical stability is good, as the enhancing material of grease Material, improves hydrophobic, the lubrication of silicone pipes, does not fires and the characteristic such as heat-resistant stable, recycle grease and PE vector resin etc. Making master batch, lubricity is good, thermostability is high, antifriction effect is high, not sticking, and is easy to storage, saves space, then with highly dense Degree polyethylene associating extrusioning shaping, the silicone pipes good forming effect of preparation, yield rate is high, good stability, technique of the present invention The silicone pipes hot strength of preparation is high, elongation at break is good, can better meet market and use demand, be worthy to be popularized.
Detailed description of the invention
The fuse silicone pipes that a kind of resistance to calcination performance is good, is made up of the raw material of following weight portion (kilogram): just The last of the ten Heavenly stems hydrocarbon 190, straight chain endecatylene hydrocarbon 65, containing hydrogen silicone oil 190, hydroxy stearic acid 15, Lithium hydrate 4, PE vector resin 45, color masterbatch Grain 5, high density polyethylene (HDPE) 60, expanded perlite 3, organosilicon auxiliary agent 2, sodium tripolyphosphate 1, waterglass 0.8, deionized water are fitted Amount.
The fuse silicone pipes that described a kind of resistance to calcination performance is good, is made up of following concrete steps:
(1) hydrocarbon in positive last of the ten Heavenly stems and straight chain endecatylene hydrocarbon are uniformly mixed, rise high-temperature to 120 DEG C, react 3h, the most slowly add Entering containing hydrogen silicone oil and appropriate chloroplatinic acid, continuation liter high-temperature is to 130 DEG C, and 6h is reacted in stirring, reacts removing low-boiling-point substance after terminating, Obtain olefin-modified silicone oil standby；
(2) waterglass and deionized water are mixed according to volume ratio 1:10, the solution that stirred for several minute is uniformly mixed, then add Enter organosilicon auxiliary agent mixing and stirring, expanded perlite is placed in vacuum tank, is evacuated to MPa, be heated to drying temperature It is 120 DEG C, dries to constant weight, then proceed to evacuation and to be down to temperature be 25 DEG C, inject above-mentioned mixed solution, then proceed to take out Vacuum, vacuum tank air-breathing boosts to 1.5MPa, voltage stabilizing 20min, then expanded perlite is dried grinding standby；
(3) modified silicon oil prepared by the step (1) of hydroxy stearic acid, formula ratio 1/3 is added in reactor, rises high-temperature to 80 DEG C, stirring makes hydroxy stearic acid all dissolve, then rises high-temperature to 90 DEG C, adds Lithium hydrate, saponification 1h, has reacted Finish, liter high-temperature to 120 DEG C of dehydrations, and constantly rising the alkyl modified silicon oil that warming middle-JIAO adds 1/3 successively, when temperature is increased to When 200 DEG C, stop heating, add remaining alkyl modified silicon oil, make temperature in the kettle drop to rapidly 120 DEG C, add step (2) The product of preparation, stirring reaction naturally cools to discharging during ＜ 100 DEG C, grinds, deaerates, standby；
(4) product PE vector resin, step (3) prepared and sodium tripolyphosphate are together added to mixed milling type parallel double-screw extrusion Carrying out pelletize in machine, temperature is 195 DEG C, makes silicone pipes master batch, then with Masterbatch, high density polyethylene (HDPE) and remaining residue Material synchronizes extrusion claddings by three extruders, by Vacuum refrigerator and soak cooling water tank to the tubing after extrusion cladding Carrying out cooling and shaping, metering prints, and draws and crimp the most available.
The silicone pipes preparing embodiment carries out performance measurement, and result is as follows:
Friction factor: 0.13；Hot strength (MPa): 33；Elongation at break (%): 419；Breaking resistance (MPa): 3；Acid corrosion-resistant Property (40% concentrated sulphuric acid, 24h): without obvious corrosion phenomenon；Alkali corrosion resistance (40% sodium hydroxide, 24h): surface is existing without substantially corrosion As.

Claims (2)

1. the fuse silicone pipes that a resistance to calcination performance is good, it is characterised in that be made up of the raw material of following weight portion: Just hydrocarbon 190-200 in the last of the ten Heavenly stems, straight chain endecatylene hydrocarbon 65-75, containing hydrogen silicone oil 190-200, hydroxy stearic acid 15-20, Lithium hydrate 4- 6, PE vector resin 45-55, Masterbatch 5-7, high density polyethylene (HDPE) 60-70, expanded perlite 3-5, organosilicon auxiliary agent 2-3, three Polyphosphate sodium 1-2, waterglass 0.8-1.2, deionized water are appropriate.
The fuse silicone pipes that a kind of resistance to calcination performance is good, it is characterised in that by following specifically Step is made:
(1) hydrocarbon in positive last of the ten Heavenly stems and straight chain endecatylene hydrocarbon are uniformly mixed, rise high-temperature to 120 DEG C, react 3-4h, the most slowly Adding containing hydrogen silicone oil and appropriate chloroplatinic acid, continuation liter high-temperature is to 130-140 DEG C, and stirring reaction 6-8h, reaction removes after terminating Remove low-boiling-point substance, obtain olefin-modified silicone oil standby；
(2) waterglass and deionized water are mixed according to volume ratio 1:10-20, the solution that stirred for several minute is uniformly mixed, Add organosilicon auxiliary agent mixing and stirring, expanded perlite is placed in vacuum tank, is evacuated to-0.1MPa, be heated to Dry temperature and be 120-180 DEG C, dry to constant weight, then proceed to evacuation and to be down to temperature be 25 DEG C, inject above-mentioned mixing molten Liquid, then proceedes to evacuation, and vacuum tank air-breathing boosts to 1.5MPa, voltage stabilizing 20-30min, is then dried by expanded perlite and grinds Broken standby；
(3) modified silicon oil prepared by the step (1) of hydroxy stearic acid, formula ratio 1/3 is added in reactor, rises high-temperature extremely 80-90 DEG C, stirring makes hydroxy stearic acid all dissolve, then rises high-temperature to 90-110 DEG C, adds Lithium hydrate, saponification 1- 2h, reacts complete, liter high-temperature to 120-140 DEG C of dehydration, and is constantly rising the alkyl modified silicon oil that warming middle-JIAO adds 1/3 successively, When temperature is increased to 200-220 DEG C, stops heating, add remaining alkyl modified silicon oil, make temperature in the kettle drop to rapidly 120-140 DEG C, adding step (2) product prepared, stirring reaction naturally cools to discharging during ＜ 100 DEG C, grinds, deaerates, standby With；
(4) product PE vector resin, step (3) prepared and sodium tripolyphosphate are together added to mixed milling type parallel double-screw extrusion Carrying out pelletize in machine, temperature is 195-205 DEG C, makes silicone pipes master batch, then with Masterbatch, high density polyethylene (HDPE) and remaining Surplus materials synchronizes extrusion claddings by three extruders, by Vacuum refrigerator and soak cooling water tank to extrusion cladding after Tubing carries out cooling and shaping, and metering prints, and draws and crimp the most available.
CN201610628027.4A 2016-08-04 2016-08-04 The fuse silicone pipes that a kind of resistance to calcination performance is good Pending CN106118058A (en)

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CN201610628027.4A CN106118058A (en) 2016-08-04 2016-08-04 The fuse silicone pipes that a kind of resistance to calcination performance is good

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Application Number Priority Date Filing Date Title
CN201610628027.4A CN106118058A (en) 2016-08-04 2016-08-04 The fuse silicone pipes that a kind of resistance to calcination performance is good

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Publication Number Publication Date
CN106118058A true CN106118058A (en) 2016-11-16

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Country Status (1)

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