CN105968682A - Silicon core pipe for cable - Google Patents
Silicon core pipe for cable Download PDFInfo
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- CN105968682A CN105968682A CN201610622893.2A CN201610622893A CN105968682A CN 105968682 A CN105968682 A CN 105968682A CN 201610622893 A CN201610622893 A CN 201610622893A CN 105968682 A CN105968682 A CN 105968682A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a silicon core pipe for a cable. The silicon core pipe is prepared from, by weight, 190-200 parts of n-decyl hydrocarbon, 65-75 parts of linear-chain undecylenic hydrocarbon, 190-200 parts of hydrogen-containing silicone oil, 15-20 parts of hydroxystearic acid, 4-6 parts of lithium hydrate, 45-55 parts of PE carrier resin, 5-7 parts of color master batch, 60-70 parts of high density polyethylene, 2.2-2.6 parts of antimonous oxide, 0.4-0.6 part of zirconium oxide, 2.5-3 parts of methyl silicone oil, 1.4-1.7 parts of polyethylene wax, 2.1-2.4 parts of zinc stearate, 0.3-0.4 part of sodium hexametaphosphate and 0.2-0.4 part of glycerin monostearate. The silicon core pipe is simple in preparation process, convenient to construct and small in investment, saves cost, can be used for laying various cables underground in the severe environment and protecting cables against damage, and is worthy of popularization, and the service life is prolonged.
Description
Technical field
The present invention relates to silicone pipes technical field, particularly relate to a kind of optical cable silicone pipes.
Background technology
21 century is the epoch of information, and with fastest developing speed is information industry, and in the transmission of information, optical cable is most important logical
Road, because only that optical cable can transmit substantial amounts of information with the fastest speed, also will not be disturbed, will not give away secrets, and China is the most several
Year telecommunication cause develop the stages of historical development having had passed over from cable communication to optical cable rapidly, from civilian to military, from
Phone all enters optical-fibre communications epoch, the biggest development having promoted plastic optical fiber cable jacket ducts to multimedia.Light
Cable is typically buried in underground, for being effectively protected optical cable, generally adds a protection sleeve pipe outside optical cable, in cable run process
In, the tubing used at first is steel pipe, pipe of cement, pvc pipe and double-wall corrugated pipe, and the problem using middle maximum is how to solve to wear
The lubrication problem of inner-walls of duct in cable, typically uses the way of coating lubricant by aforementioned tubes, i.e. before wearing cable first when constructing
The lubricant of liquid is coated in pipe material inner wall, but due to the effect of gravity, makes lubricant can not be uniformly distributed in pipe material inner wall,
And the cable being also dried by leading portion when wearing cable takes away, therefore no matter select drawing method when wearing cable or blow afloat method, lubrication
Problem all directly affects length and the speed wearing cable, uses these methods all to considerably increase the artificial and increase of resource expense.
Silicone pipes friction factor is less, and pipe joint is few, quick construction, be not required to outer increasing protection of pipe, greatly reduces construction costs, due to
Inwall silicon core layer is permanent solid lubrication oxidant layer, and frictional behaviour keeps constant, and cable can extract in pipe repeatedly, will not shell
Falling, depart from, ageing-resistant service life was up to more than 50 years, so silicon core cable tube is widely used in a variety of applications.
Studying more person in silicone oil grease is methyl-silicone oil grease, due to the thickening poor-performing of dimethicone,
The compatibility with organic material is the poorest, so, there is the problems such as greasy property is not good enough in methyl-silicone oil grease, limits its application
Scope." alkyl modified silicon oil preparation of greases and performance study " Wen Zhongzhu state builds employing containing hydrogen silicone oil and linear alpha olefin
Carry out hydrosilylation, prepare alkyl modified silicon oil, then itself and 12 hydroxy stearic acids are carried out saponification, prepare alkyl
Modified silicon oil grease, result shows that, under close viscosity, the film strength of alkyl modified silicon oil is bigger than methyl-silicone oil, lubrication
Property more preferable, the refractive index ratio methyl-silicone oil of alkyl modified silicon oil is high, closer to Dormant oils, fat and Organic substance, compatible with them
Property more preferable, the transparency is higher, but sintering load is close with methyl-silicone oil, not raising, and weatherability, oxidative resistance and resistance to
The characteristics such as solvent are general, reduce use field, in order to enable silicone oil grease well to be utilized in silicone pipes, this
It is expanded modification by invention on its basis, makes the silicone pipes of preparation disclosure satisfy that the nowadays optical fiber requirement to silicone pipes, actively
Accomplish to reduce cost, economize on resources and protect environment.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of optical cable silicone pipes.
The present invention is achieved by the following technical solutions:
A kind of optical cable silicone pipes, is made up of the raw material of following weight portion: just hydrocarbon 190-200 in the last of the ten Heavenly stems, straight chain endecatylene hydrocarbon
65-75, containing hydrogen silicone oil 190-200, hydroxy stearic acid 15-20, Lithium hydrate 4-6, PE vector resin 45-55, Masterbatch 5-7,
High density polyethylene (HDPE) 60-70, antimony oxide 2.2-2.6, zirconium oxide 0.4-0.6, methyl-silicone oil 2.5-3, Tissuemat E 1.4-
1.7, zinc stearate 2.1-2.4, sodium hexameta phosphate 0.3-0.4, glyceryl monostearate 0.2-0.4.
Described a kind of optical cable silicone pipes, is made up of following concrete steps:
(1) hydrocarbon in positive last of the ten Heavenly stems and straight chain endecatylene hydrocarbon are uniformly mixed, rise high-temperature to 120 DEG C, react 3-4h, the most slowly
Adding containing hydrogen silicone oil and appropriate chloroplatinic acid, continuation liter high-temperature is to 130-140 DEG C, and stirring reaction 6-8h, reaction removes after terminating
Remove low-boiling-point substance, obtain olefin-modified silicone oil standby;
(2) by methyl-silicone oil, Tissuemat E and zinc stearate high-speed stirred mix homogeneously, it is then added to total weight parts 5-7 times amount
In dehydrated alcohol, ultrasonic disperse obtains mixed and modified liquid, and antimony oxide and zirconium oxide are added in mixed and modified liquid ultrasonic point
Dissipate 10-20min, power 900kw, be spray-dried standby after ultrasonic end;
(3) modified silicon oil prepared by the step (1) of hydroxy stearic acid, formula ratio 1/3 is added in reactor, rises high-temperature extremely
80-90 DEG C, stirring makes hydroxy stearic acid all dissolve, then rises high-temperature to 90-110 DEG C, adds Lithium hydrate, saponification 1-
2h, reacts complete, liter high-temperature to 120-140 DEG C of dehydration, and is constantly rising the alkyl modified silicon oil that warming middle-JIAO adds 1/3 successively,
When temperature is increased to 200-220 DEG C, stops heating, add remaining alkyl modified silicon oil, make temperature in the kettle drop to rapidly
120-140 DEG C, adding step (2) product prepared, stirring reaction naturally cools to discharging during < 100 DEG C, grinds, deaerates, standby
With;
(4) product, sodium hexameta phosphate and glyceryl monostearate prepared by PE vector resin, step (3) are together added to mixing
Carrying out pelletize in type parallel double-screw extruder, temperature is 195-205 DEG C, makes silicone pipes master batch, then with Masterbatch, highly dense
Degree polyethylene and remaining surplus materials synchronize extrusion cladding by three extruders, by Vacuum refrigerator and immersion cooling water
Case carries out cooling and shaping to the tubing after extrusion cladding, and metering prints, and draws and crimp the most available.
The invention have the advantage that the present invention uses alhpa olefin and containing hydrogen silicone oil hydrosilylation to prepare copoly type alkyl
Modified silicon oil, and oil based on it, carry out saponification with hydroxy stearic acid, and it is glossy that addition lithium soap is made for modified silicon
Consistent lubricant, improves powder surface moistening by the modifying agent such as methyl-silicone oil, zinc stearate to zirconium oxide and antimony oxide etc. are modified
Property, reduce surface tension, reduce and reunite and make its good dispersion in silicone pipes, reach to strengthen silicone pipes inner sandwich layer antioxygen
The performance of the aspects such as change, fire-retardant, fire prevention, recycles grease and PE vector resin etc. and makes master batch, and lubricity is good, thermostability
High, antifriction effect height, not sticking, and it is easy to storage, save space, then combine extrusioning shaping, system with high density polyethylene (HDPE)
Standby silicone pipes good forming effect, yield rate is high, good stability, and the preparation technology of the present invention is simple, and easy construction puts into little,
Cost-effective, can be used for laying of the various cable in underground under adverse circumstances, protection cable preserves from, and increases the service life, value
Must promote.
Detailed description of the invention
A kind of optical cable silicone pipes, is made up of the raw material of following weight portion (kilogram): just hydrocarbon in the last of the ten Heavenly stems 190, straight chain 11
Carbon olefin 65, containing hydrogen silicone oil 190, hydroxy stearic acid 15, Lithium hydrate 4, PE vector resin 45, Masterbatch 5, high density polyethylene (HDPE)
60, antimony oxide 2.2, zirconium oxide 0.4, methyl-silicone oil 2.5, Tissuemat E 1.4, zinc stearate 2.1, sodium hexameta phosphate 0.3,
Glyceryl monostearate 0.2.
Described a kind of optical cable silicone pipes, is made up of following concrete steps:
(1) hydrocarbon in positive last of the ten Heavenly stems and straight chain endecatylene hydrocarbon are uniformly mixed, rise high-temperature to 120 DEG C, react 3h, the most slowly add
Entering containing hydrogen silicone oil and appropriate chloroplatinic acid, continuation liter high-temperature is to 130 DEG C, and 6h is reacted in stirring, reacts removing low-boiling-point substance after terminating,
Obtain olefin-modified silicone oil standby;
(2) by methyl-silicone oil, Tissuemat E and zinc stearate high-speed stirred mix homogeneously, it is then added to the nothing of total weight parts 5 times amount
In water-ethanol, ultrasonic disperse obtains mixed and modified liquid, and antimony oxide and zirconium oxide are added to ultrasonic disperse in mixed and modified liquid
10min, power 900kw, be spray-dried standby after ultrasonic end;
(3) modified silicon oil prepared by the step (1) of hydroxy stearic acid, formula ratio 1/3 is added in reactor, rises high-temperature to 80
DEG C, stirring makes hydroxy stearic acid all dissolve, then rises high-temperature to 90 DEG C, adds Lithium hydrate, saponification 1h, has reacted
Finish, liter high-temperature to 120 DEG C of dehydrations, and constantly rising the alkyl modified silicon oil that warming middle-JIAO adds 1/3 successively, when temperature is increased to
When 200 DEG C, stop heating, add remaining alkyl modified silicon oil, make temperature in the kettle drop to rapidly 120 DEG C, add step (2)
The product of preparation, stirring reaction naturally cools to discharging during < 100 DEG C, grinds, deaerates, standby;
(4) product, sodium hexameta phosphate and glyceryl monostearate prepared by PE vector resin, step (3) are together added to mixing
Carrying out pelletize in type parallel double-screw extruder, temperature is 195 DEG C, makes silicone pipes master batch, then gathers with Masterbatch, high density
Ethylene and remaining surplus materials synchronize extrusion cladding by three extruders, by Vacuum refrigerator and immersion cooling water tank pair
Tubing after extrusion cladding carries out cooling and shaping, and metering prints, and draws and crimp the most available.
The silicone pipes preparing embodiment carries out performance measurement, and result is as follows:
Friction factor: 0.13;Hot strength (MPa): 36;Elongation at break (%): 415;Breaking resistance (MPa): 5;Acid corrosion-resistant
Property (40% concentrated sulphuric acid, 24h): without obvious corrosion phenomenon;Alkali corrosion resistance (40% sodium hydroxide, 24h): surface is existing without substantially corrosion
As.
Claims (2)
1. an optical cable silicone pipes, it is characterised in that be made up of the raw material of following weight portion: positive last of the ten Heavenly stems hydrocarbon 190-200, straight
Chain endecatylene hydrocarbon 65-75, containing hydrogen silicone oil 190-200, hydroxy stearic acid 15-20, Lithium hydrate 4-6, PE vector resin 45-
55, Masterbatch 5-7, high density polyethylene (HDPE) 60-70, antimony oxide 2.2-2.6, zirconium oxide 0.4-0.6, methyl-silicone oil 2.5-3,
Tissuemat E 1.4-1.7, zinc stearate 2.1-2.4, sodium hexameta phosphate 0.3-0.4, glyceryl monostearate 0.2-0.4.
A kind of optical cable silicone pipes, it is characterised in that be made up of following concrete steps:
(1) hydrocarbon in positive last of the ten Heavenly stems and straight chain endecatylene hydrocarbon are uniformly mixed, rise high-temperature to 120 DEG C, react 3-4h, the most slowly
Adding containing hydrogen silicone oil and appropriate chloroplatinic acid, continuation liter high-temperature is to 130-140 DEG C, and stirring reaction 6-8h, reaction removes after terminating
Remove low-boiling-point substance, obtain olefin-modified silicone oil standby;
(2) by methyl-silicone oil, Tissuemat E and zinc stearate high-speed stirred mix homogeneously, it is then added to total weight parts 5-7 times amount
In dehydrated alcohol, ultrasonic disperse obtains mixed and modified liquid, and antimony oxide and zirconium oxide are added in mixed and modified liquid ultrasonic point
Dissipate 10-20min, power 900kw, be spray-dried standby after ultrasonic end;
(3) modified silicon oil prepared by the step (1) of hydroxy stearic acid, formula ratio 1/3 is added in reactor, rises high-temperature extremely
80-90 DEG C, stirring makes hydroxy stearic acid all dissolve, then rises high-temperature to 90-110 DEG C, adds Lithium hydrate, saponification 1-
2h, reacts complete, liter high-temperature to 120-140 DEG C of dehydration, and is constantly rising the alkyl modified silicon oil that warming middle-JIAO adds 1/3 successively,
When temperature is increased to 200-220 DEG C, stops heating, add remaining alkyl modified silicon oil, make temperature in the kettle drop to rapidly
120-140 DEG C, adding step (2) product prepared, stirring reaction naturally cools to discharging during < 100 DEG C, grinds, deaerates, standby
With;
(4) product, sodium hexameta phosphate and glyceryl monostearate prepared by PE vector resin, step (3) are together added to mixing
Carrying out pelletize in type parallel double-screw extruder, temperature is 195-205 DEG C, makes silicone pipes master batch, then with Masterbatch, highly dense
Degree polyethylene and remaining surplus materials synchronize extrusion cladding by three extruders, by Vacuum refrigerator and immersion cooling water
Case carries out cooling and shaping to the tubing after extrusion cladding, and metering prints, and draws and crimp the most available.
Priority Applications (1)
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CN201610622893.2A CN105968682A (en) | 2016-08-02 | 2016-08-02 | Silicon core pipe for cable |
Applications Claiming Priority (1)
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CN201610622893.2A CN105968682A (en) | 2016-08-02 | 2016-08-02 | Silicon core pipe for cable |
Publications (1)
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CN105968682A true CN105968682A (en) | 2016-09-28 |
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CN201610622893.2A Pending CN105968682A (en) | 2016-08-02 | 2016-08-02 | Silicon core pipe for cable |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102399386A (en) * | 2010-09-15 | 2012-04-04 | 中国石油天然气股份有限公司 | Method for preparing silicon-containing polyethylene high-lubrication composite material |
CN103885147A (en) * | 2014-04-10 | 2014-06-25 | 太仓市晨洲塑业有限公司 | Anti-corrosion inflaming retarding silicon core tube for communication |
CN105566935A (en) * | 2014-10-12 | 2016-05-11 | 吴江佳通光缆有限公司 | Silicon-cored pipe production technology |
-
2016
- 2016-08-02 CN CN201610622893.2A patent/CN105968682A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102399386A (en) * | 2010-09-15 | 2012-04-04 | 中国石油天然气股份有限公司 | Method for preparing silicon-containing polyethylene high-lubrication composite material |
CN103885147A (en) * | 2014-04-10 | 2014-06-25 | 太仓市晨洲塑业有限公司 | Anti-corrosion inflaming retarding silicon core tube for communication |
CN105566935A (en) * | 2014-10-12 | 2016-05-11 | 吴江佳通光缆有限公司 | Silicon-cored pipe production technology |
Non-Patent Citations (2)
Title |
---|
宗大全等: "硅芯管生产与应用技术", 《工程塑料应用》 * |
诸国建: "烃基改性硅油润滑脂的制备及性能研究", 《有机硅材料》 * |
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