CN103710123A - Environmentally friendly cutting fluid containing graphene and preparation method therefor - Google Patents
Environmentally friendly cutting fluid containing graphene and preparation method therefor Download PDFInfo
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- CN103710123A CN103710123A CN201310654161.8A CN201310654161A CN103710123A CN 103710123 A CN103710123 A CN 103710123A CN 201310654161 A CN201310654161 A CN 201310654161A CN 103710123 A CN103710123 A CN 103710123A
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Abstract
Provided is a environmentally friendly cutting fluid containing graphene. The cutting fluid is prepared from the following raw materials, by weight, 2-3 parts of graphene, 1-2 parts of silane coupling agent KH-550, 3-4 parts of vinyl acetate, 4-5 parts of dibutyl phosphate, 10-12 parts of drainage oil, 13-15 parts of propylene glycol, 2-3 parts of zirconium fluoride, 3-4 parts of ricinoleic acid, 1-2 parts of polyoxyethylene octylphenol ether, 1-2 parts of sodium butylnaphthalenesulfonate, 6-8 parts of auxiliary agents and 200 parts of water. Through application of graphene and zirconium fluoride, the lubricating property and abrasion resistance of the cutting fluid are enhanced greatly, and the service life of the cutting fluid is prolonged. Through application of drainage oil, the lubricating property is raised, and the cutting fluid is beneficial for environmental protection. Through application of surfactants, high-molecular monomers, solvents and coupling agents, the cutting fluid is advantaged by stable emulsification and no sedimentation.
Description
Technical field
The present invention relates to cutting fluid technical field, relate in particular to a kind of graphene-containing environmental protection cutting fluid and preparation method thereof.
Background technology
Cutting fluid should possess good cooling performance, lubricity, rustless property, oil removing cleaning function, anti-corrosion function, easily dilutable feature.Cutting fluid can be divided into two classes, oil soluble cutting fluid and water-soluble metalworking liquid at present.General oil soluble cutting fluid lubrication performance is good, but poor cooling performance, and contain large amount of organic, contaminate environment.Although some water-soluble metalworking liquid cooling performances are good, there is again the poor problem of oilness and rust-proof effect, therefore research and development have concurrently oilness, cooling, rust-preventing characteristic, easy cleaning, nontoxic, tasteless, non-corrosive to human body, to equipment not burn into the non-staining cutting fluid of environment is just seemed to very important.
Summary of the invention
The object of the present invention is to provide a kind of graphene-containing environmental protection cutting fluid and preparation method thereof, that this cutting fluid has is stable, oilness good, resistance to abrasion good, the feature of environmental protection.
Technical scheme of the present invention is as follows:
A graphene-containing environmental protection cutting fluid, is characterized in that being made by the raw material of following weight part: Graphene 2-3, silane resin acceptor kh-550 1-2, vinyl acetate 3-4, di-n-butyl phosphite 4-5, sewer oil 10-12, propylene glycol 13-15, Zirconium tetrafluoride 2-3, ricinolic acid 3-4, polyoxyethylene octylphenol ether 1-2, sodium butylnaphthalenesulfonate 1-2, auxiliary agent 6-8, deionized water 200; Described auxiliary agent is made by the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, aluminum nitride powder 0.1-0.2, boric acid 2-3, morpholine 1-2, water glass 1-2, silane coupling agent KH-560 1-2, Potassium Persulphate 1-2, peach gum 3-4, water 20-24; Preparation method be Potassium Persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of described graphene-containing environmental protection cutting fluid, is characterized in that comprising the following steps: Jiang Shui, base phenol polyethenoxy ether, sodium butylnaphthalenesulfonate mix, and are heated to 40-50 ℃; Under 3000-4000 rev/min of stirring, add silane resin acceptor kh-550, vinyl acetate, di-n-butyl phosphite, sewer oil, propylene glycol, ricinolic acid, auxiliary agent, continue to be heated to 70-80 ℃, stir 10-15 minute; Add other remaining components, continue to stir 15-25 minute, obtain.
Beneficial effect of the present invention
Cutting fluid of the present invention, by using Graphene, Zirconium tetrafluoride, strengthens cutting fluid lubrication, resistance to abrasion greatly, has extended the work-ing life of cutting fluid; By using sewer oil, not only increased oilness, and be conducive to again environmental protection; By using tensio-active agent, high polymer monomer, solvent and coupling agent, make cutting fluid stable emulsifying, not sedimentation.
Embodiment
A graphene-containing environmental protection cutting fluid, by following weight part (kilogram) raw material make: Graphene 2.5, silane resin acceptor kh-550 1.5, vinyl acetate 3.5, di-n-butyl phosphite 4.5, sewer oil 11, propylene glycol 14, Zirconium tetrafluoride 2.5, ricinolic acid 3.5, polyoxyethylene octylphenol ether 1.5, sodium butylnaphthalenesulfonate 1.5, auxiliary agent 7, deionized water 200; Described auxiliary agent by following weight part (kilogram) raw material make: polyoxyethylene sorbitan monooleate 2, aluminum nitride powder 0.1, boric acid 2, morpholine 1, water glass 2, silane coupling agent KH-5601, Potassium Persulphate 1, peach gum 3, water 20; Preparation method be Potassium Persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of described graphene-containing environmental protection cutting fluid, comprises the following steps: Jiang Shui, base phenol polyethenoxy ether, sodium butylnaphthalenesulfonate mix, and are heated to 45 ℃; Under 3500 revs/min of stirrings, add silane resin acceptor kh-550, vinyl acetate, di-n-butyl phosphite, sewer oil, propylene glycol, ricinolic acid, auxiliary agent, continue to be heated to 75 ℃, stir 13 minutes; Add other remaining components, continue to stir 20 minutes, obtain.
The graphene-containing environmental protection cutting fluid testing data that this embodiment obtains is as follows:
Claims (2)
1. a graphene-containing environmental protection cutting fluid, is characterized in that being made by the raw material of following weight part: Graphene 2-3, silane resin acceptor kh-550 1-2, vinyl acetate 3-4, di-n-butyl phosphite 4-5, sewer oil 10-12, propylene glycol 13-15, Zirconium tetrafluoride 2-3, ricinolic acid 3-4, polyoxyethylene octylphenol ether 1-2, sodium butylnaphthalenesulfonate 1-2, auxiliary agent 6-8, deionized water 200; Described auxiliary agent is made by the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, aluminum nitride powder 0.1-0.2, boric acid 2-3, morpholine 1-2, water glass 1-2, silane coupling agent KH-560 1-2, Potassium Persulphate 1-2, peach gum 3-4, water 20-24; Preparation method be Potassium Persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
2. the preparation method of graphene-containing environmental protection cutting fluid according to claim 1, is characterized in that comprising the following steps: Jiang Shui, base phenol polyethenoxy ether, sodium butylnaphthalenesulfonate mix, and are heated to 40-50 ℃; Under 3000-4000 rev/min of stirring, add silane resin acceptor kh-550, vinyl acetate, di-n-butyl phosphite, sewer oil, propylene glycol, ricinolic acid, auxiliary agent, continue to be heated to 70-80 ℃, stir 10-15 minute; Add other remaining components, continue to stir 15-25 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310654161.8A CN103710123A (en) | 2013-12-05 | 2013-12-05 | Environmentally friendly cutting fluid containing graphene and preparation method therefor |
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| CN201310654161.8A CN103710123A (en) | 2013-12-05 | 2013-12-05 | Environmentally friendly cutting fluid containing graphene and preparation method therefor |
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| CN103710123A true CN103710123A (en) | 2014-04-09 |
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| CN201310654161.8A Pending CN103710123A (en) | 2013-12-05 | 2013-12-05 | Environmentally friendly cutting fluid containing graphene and preparation method therefor |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103992838A (en) * | 2014-04-25 | 2014-08-20 | 蚌埠市时代电子有限公司 | Drawing oil containing nano-silver |
| CN103992854A (en) * | 2014-04-25 | 2014-08-20 | 蚌埠市时代电子有限公司 | Hard water-resistant high-efficiency drawing oil |
| CN104046419A (en) * | 2014-04-25 | 2014-09-17 | 蚌埠市时代电子有限公司 | Lubricating oil for magnesuim-aluminium alloy wire-drawing |
| CN104046406A (en) * | 2014-04-25 | 2014-09-17 | 蚌埠市时代电子有限公司 | Easily-degradable environmentally-friendly high-efficiency drawing oil |
| CN104371798A (en) * | 2014-10-22 | 2015-02-25 | 安徽荣达阀门有限公司 | Special diluted emulsion cutting oil for alloy and preparation method of emulsion cutting oil |
| CN109679758A (en) * | 2019-01-21 | 2019-04-26 | 江苏捷达油品有限公司 | A kind of environment-friendly water-based diamond wire silicon wafer circulation cutting liquid of the clean type of low COD and application |
| CN110591793A (en) * | 2019-09-20 | 2019-12-20 | 安徽省聚科石墨烯科技股份公司 | Graphene lubricating oil and preparation method thereof |
| CN112300852A (en) * | 2019-07-29 | 2021-02-02 | 新疆工程学院 | Nano carbon material composite additive based on surface modification and preparation method thereof |
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| CN101240217A (en) * | 2008-02-29 | 2008-08-13 | 益田润石（北京）化工有限公司 | Micro-emulsion type metal cutting liquor composition |
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Patent Citations (1)
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| CN101240217A (en) * | 2008-02-29 | 2008-08-13 | 益田润石（北京）化工有限公司 | Micro-emulsion type metal cutting liquor composition |
Non-Patent Citations (1)
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| 周雍鑫，周俊: "《金属加工液使用指南》", 31 May 2000, 中国石化出版社 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103992838A (en) * | 2014-04-25 | 2014-08-20 | 蚌埠市时代电子有限公司 | Drawing oil containing nano-silver |
| CN103992854A (en) * | 2014-04-25 | 2014-08-20 | 蚌埠市时代电子有限公司 | Hard water-resistant high-efficiency drawing oil |
| CN104046419A (en) * | 2014-04-25 | 2014-09-17 | 蚌埠市时代电子有限公司 | Lubricating oil for magnesuim-aluminium alloy wire-drawing |
| CN104046406A (en) * | 2014-04-25 | 2014-09-17 | 蚌埠市时代电子有限公司 | Easily-degradable environmentally-friendly high-efficiency drawing oil |
| CN103992854B (en) * | 2014-04-25 | 2016-12-07 | 王兴民 | A kind of resistance to hard water efficient wire drawing oil |
| CN104371798A (en) * | 2014-10-22 | 2015-02-25 | 安徽荣达阀门有限公司 | Special diluted emulsion cutting oil for alloy and preparation method of emulsion cutting oil |
| CN109679758A (en) * | 2019-01-21 | 2019-04-26 | 江苏捷达油品有限公司 | A kind of environment-friendly water-based diamond wire silicon wafer circulation cutting liquid of the clean type of low COD and application |
| CN109679758B (en) * | 2019-01-21 | 2021-10-01 | 江苏捷达油品有限公司 | Low-COD clean type environment-friendly water-based diamond wire silicon wafer circulating cutting fluid and application |
| CN112300852A (en) * | 2019-07-29 | 2021-02-02 | 新疆工程学院 | Nano carbon material composite additive based on surface modification and preparation method thereof |
| CN112300852B (en) * | 2019-07-29 | 2022-05-13 | 新疆工程学院 | Nano carbon material composite additive based on surface modification and preparation method thereof |
| CN110591793A (en) * | 2019-09-20 | 2019-12-20 | 安徽省聚科石墨烯科技股份公司 | Graphene lubricating oil and preparation method thereof |
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Application publication date: 20140409 |
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