A kind of processing system of industrial wastewater
Technical field
The present invention relates to a kind of processing systems of inorganic salts in removal wastewater of steel industry, belong to useless in environmental protection
Water treatment field.
Background technique
Low-carbon warp under the background of Global climate change and energy shortages, based on low energy consumption, low pollution, low emission
Ji development model is just taken seriously, and the section that steel and iron industry is advocated as high energy consumption, multiple rows of industry put in global low-carbon economy
Great responsibility can be carry in the work of emission reduction.
It is important to have become one for leading world steel industrial for basic industry of the steel and iron industry as China's industrial development
Strength, the scale and growth momentum of China's steel industry enable the world attract attention.But steel and iron industry is both with water rich and influential family and blowdown
Rich and influential family, with the rapid development of modernization industry, the problems such as water consumption sharp increase, shortage of water resources, serious water pollution, it has also become I
The bottleneck of state's development of iron & steel industry.Solve the problems, such as this, it is most direct, most economical at present, also most effective approach is exactly to study
Develop the purification treatment technology of a whole set of advanced wastewater of steel industry.
Wastewater of steel industry purification treatment technology and equipment research work are a great Social benefit and economic benefits
Work, but in the wastewater treatment process of iron and steel enterprise, if being not provided with desalting processing technique, waste water salt content meeting that treated
It is very high, if such waste water as recirculated water after high power is concentrated, one of the various ion concentrations increase, and can generate a series of objects
Reason, chemical change lead to pipe-line system corrosion and fouling, seriously affect the normal operation of equipment, and shorten the use longevity of equipment
Life.
Currently, the desalting technology of China's wastewater of steel industry mainly includes ion-exchange, double film desalination methods and Electro Sorb
Three kinds of desalination method.
(1) ion-exchange:
Ion-exchange is a kind of effective water treatment technology of maturation, and desalting effect is preferable.But there are equipment for this method
It takes up a large area, the frequent complicated, effluent quality of system operation maintenance is in the defect of cyclic fluctuation, and needs to add flocculant
With a large amount of soda acid of consuming, it is easy to produce secondary pollution, is unfavorable for the protection of ecological environment.
(2) double film desalination methods:
Double film desalination methods are primarily referred to as the treatment process of ultrafiltration+reverse osmosis, which is mainly produced using membrane separation technique
Desalted water.
Ultrafiltration principle is a kind of membrane separating process principle, using organic or inorganic ultrafiltration membrane, under the action of ambient pressure
The substance of colloid, particle and macromolecule in trap water, and hydrone and small particles of solute can penetrate ultrafiltration membrane.Work as water
After ultrafiltration membrane, the most of colloidal silicon contained in water can be removed, while can remove a large amount of organic matter etc..It is reverse osmosis to be
Separate the solvent in solution by reverse osmosis membrane with enough pressure, the direction phase of this process and naturally osmotic
Instead, because referred to herein as reverse osmosis.
Double film desalination methods have many advantages, such as to produce water quality height, automatically control degree height, easily operated control.But the party
Method there is also requiring the disadvantages of high, impact resistance is small, membrane damage is not easily repaired to influent quality, meanwhile, embrane method water outlet makes
With being needed in the process using chemical agents such as a large amount of antisludging agents.
(3) electro-adsorption demineralization method:
Electro-adsorption demineralization technology is a kind of emerging water purification technology, the basic principle is that using brackish water anodic-cathodic it
Between flow, water intermediate ion is by respectively to the electrode transfer of oppositely charged when energization, and by the electrode adsorption in electrode surface shape
At electric double layer.It is concentrated as ion/charged particle is enriched in electrode surface, dissolved salts, colloidal solid and other bands in water
The concentration of isoelectric substance substantially reduces, to realize the desalination of water, go hardness and purification.It only needs to be shorted electrode, quilt when regeneration
The ion of absorption is discharged from electrode surface again, and electrode is regenerated.
Electro-adsorption demineralization method is people because of practicability with higher and the wider scope of application, lower processing cost
It is of interest.Field is utilized in steel and iron industry recirculated water desalting processing, Sewage treatment, before Electro Sorb technology has a wide range of applications
Scape.But there is also shortcomings, such as desalting efficiency to need to be further increased for electro-adsorption demineralization technology, electrode is from when regenerating
Between it is longer, typically constitute from the one third of whole cycle, influence producing water ratio.
Currently, in existing processing wastewater of steel industry inorganic salts method there are occupation area of equipment big, system behaviour
Make to safeguard that frequently complicated, impact resistance is small, equipment is easy to damage, desalting efficiency is low, can generate secondary pollution problems.Therefore,
It is necessary to get rid of existing processing technique thinking, the new way of processing steel and iron industry brine waste is hewed out, and then develops one kind
The processing technique of inorganic salts in the wastewater of steel industry of new type.
Summary of the invention
To solve the deficiencies in the prior art, the present invention provides a kind of processing system of industrial wastewater, the systems
Reunite including sump, coarse rack, flocculation tank, inclined-plate clarifying basin, weak electric pulse activation-chilling except salt reactor, aeration
Pond, biological oxidation filter tank, secondary sedimentation tank, water purifying tank etc.;Wherein, the wastewater of steel industry containing inorganic salts passes through waste pipe
Line enters sump, and the outlet of sump connects coarse rack by waste line, and the outlet of coarse rack is connected by waste line
The outlet of flocculation tank, flocculation tank connects inclined-plate clarifying basin by waste line, and the outlet of inclined-plate clarifying basin passes through useless
Water pipeline connects weak electric pulse activation-chilling and reunites except salt reactor, and weak electric pulse activation-chilling, which is reunited, removes going out for salt reactor
Mouth connects aeration tank by waste line, and the outlet of aeration tank passes through waste line and connects biological oxidation filter tank, biological oxidation filter
The outlet in pond connects secondary sedimentation tank by waste line, and the outlet of secondary sedimentation tank connects water purifying tank by waste line, only
The outlet in pond by waste line will by this system treated purification water outlet outlet;Wherein, weak electric pulse activation-chilling
Reunite except salt reactor uses hard glass steel material, reactor head is equipped with inlet valve, and middle position is fixed in reactor
There is 1 fan to magnetize nickel metal mesh, magnetization nickel metal mesh two sides are respectively equipped with electrode under 1 low pressure water, set below magnetization nickel metal mesh
There is 1 group of cooling tube, cooling pipe end connects 1 set of circularly cooling unit, and reactor bottom is equipped with 1 set of heat preservation precipitation tank, and heat preservation is heavy
Shallow lake slot right upper portion is equipped with water discharging valve, and bottom right side is equipped with sludge and arranges mouth, and left bottom is equipped with 1 and electronic pushes away mud machine;
Wherein, the wastewater of steel industry containing inorganic salts is reunited by being located at weak electric pulse activation-chilling except reactant salt
Inlet valve at the top of device enters inside reactor, at this point, electrode starts under the low pressure water being located on reactor two sidewalls, with arteries and veins
The form of impulse electricity is activated the inorganic ion in waste water, and the inorganic ion by activation can be located at
Magnetization nickel metal net surface in the middle part of reactor converges and is converted into that a kind of specific surface energy is high, ion powder of thermodynamic instability
When passing through cooling tube rapid cooling occurs for group, the waste water containing above-mentioned ion powder group, and the ion powder group in waste water can be rapid
Molecularization occurs to agglomerate and be detached from solution formation suspended matter, to reduce the free enthalpy of entire solution decentralized system, later, containing upper
The waste water for stating suspended matter enters in the heat preservation precipitation tank of reactor bottom, outstanding in waste water in the state of keeping low temperature
Floating object will not dissolve, and can gradually be settled down to heat preservation precipitating trench bottom, salt sludge be formed, in the electronic promotion for pushing away mud machine
Under, the sludge by being located at heat preservation precipitation tank bottom right side arranges mouth and reactor is discharged, and carries out recycling and reusing, meanwhile, pass through
Waste water after desalination purified treatment passes through the water discharging valve discharge reactor for being located at heat preservation precipitation tank right upper portion, and enters next
Treatment process.Wherein, the effect of aeration tank is to carry out preliminary oxidation decomposition to COD remaining in waste water by aerobic aeration process
Processing;Wherein, the effect in biological oxidation filter tank is that COD remaining to waste water carries out last deep purifying processing.
Wherein, weak electric pulse activation-chilling is reunited except the dischargeable capacity of salt reactor is 260m3, keep the temperature precipitation tank has
Effect volume is 225m3, thermal insulation material selection phenol formaldehyde foam resin, thermal coefficient 0.028W/mk, Applicable temperature range
It is -60 ~ 150 DEG C.
Wherein, weak electric pulse activation-chilling is reunited except the crest voltage of electrode under the low pressure water of salt reactor is 45V, arteries and veins
Impulse electricity frequency is 25 ~ 35 times/second, and service life is greater than 8000h.
Wherein, weak electric pulse activation-chilling is reunited except the refrigerating capacity of the circularly cooling unit of salt reactor is
99760kcal/h, power 116kW, operating voltage 220V, the average flow rate of cooling tube are 30m3/h。
By this system treated waste water, the removal efficiency of inorganic ion is up to 99.5%.
The present invention has the advantages that
(1) this system gets rid of the processing technique thinking of inorganic salts in existing wastewater of steel industry, creative benefit
With inorganic salts in aqueous solution by light current effect can occur powderization converge characteristic, to contain higher concentration inorganic salts
Waste water in apply low-voltage pulse current, inorganic ion can converge by magnetized metal surface and be converted into ion powder
Group, when the aqueous solution is to the cold and when rapid cooling, the ion powder group in solution can occur rapidly molecularization and agglomerate and be detached from molten
Liquid forms suspended matter, and in the state of keeping low temperature, is removed suspended matter from aqueous solution by way of precipitating.
(2) this system uses pure physical means, is removed in waste water by electrochemistry and thermochemical synergistic effect
Inorganic salts, any chemical substance is not suitable for, to eliminate the risk for introducing and endangering bigger chemical substance, fundamentally
Avoid secondary pollution.
(3) after this system purified treatment, isolated inorganic salts sludge can be used to by centralized recovery
The building materials such as cement are produced, to realize the recycling of resource.
(4) this system design principle is advanced, and occupation area of equipment is small, and construction cost is lower, and treatment effect is preferable, fortune
Row maintenance cost is very low, is conducive to promote and apply on a large scale.
Detailed description of the invention
Fig. 1 is equipment schematic diagram of the invention.
In figure: 1- sump, 2- coarse rack, 3- flocculation tank, 4- inclined-plate clarifying basin, 5- weak electric pulse activation-chilling
Reunite and removes salt reactor, the aeration tank 6-, 7- biological oxidation filter tank, 8- secondary sedimentation tank, 9- water purifying tank
Fig. 2 is the schematic diagram that weak electric pulse activation-chilling is reunited except salt reactor.
Electrode, 54- cooling tube, 55- circulating refrigerator under 51- inlet valve, 52- magnetization nickel metal mesh, 53- low pressure water
Group, 56- heat preservation precipitation tank, 57- water discharging valve, 58- are electronic to push away mud machine, 59- sludge row's mouth
Specific embodiment
As shown in Figure 1, in industrial wastewater inorganic salts processing system, which includes 1- sump, 2- coarse rack, 3-
Flocculation tank, 4- inclined-plate clarifying basin, 5- weak electric pulse activation-chilling, which are reunited, removes salt reactor, the aeration tank 6-, 7- biological oxidation
Filter tank, 8- secondary sedimentation tank, 9- water purifying tank etc.;Wherein, the wastewater of steel industry containing inorganic ion by waste line into
Enter sump 1, carries out centralized collection herein and preliminarily stabilised is adjusted, the outlet of sump 1 connects coarse rack by waste line
2, the major diameter solid matter in waste water is removed herein, the outlet of coarse rack 2 connects flocculation tank 3 by waste line,
This adds chemical floc into waste water, makes suspended matter and larger molecular organics in waste water that flocculation reaction occur, to concentrate
Convergence is agglomerate insoluble matter, and the outlet of flocculation tank 3 connects inclined-plate clarifying basin 4 by waste line, herein by that will wad a quilt with cotton
The agglomerate insoluble matter that solidifying reaction generates is removed by coprecipitation mode, and the outlet of inclined-plate clarifying basin 4 is connected by waste line
It connects weak electric pulse activation-chilling to reunite except salt reactor 5, weak electric pulse activation-chilling is reunited except the outlet of salt reactor 5 passes through
Waste line connects aeration tank 6, is carried out at preliminary oxidation decomposition by aerobic aeration process to COD remaining in waste water herein
The outlet of reason, aeration tank 6 connects biological oxidation filter tank 7 by waste line, and at this, COD remaining to waste water carries out last depth
Purified treatment is spent, the outlet in biological oxidation filter tank 7 connects secondary sedimentation tank 8 by waste line, herein by the residue in waste water
Insoluble matter all removes, and the outlet of secondary sedimentation tank 8 connects water purifying tank 9 by waste line, and the outlet of water purifying tank 9 passes through useless
Water pipeline will by this system treated purification water outlet outlet;Wherein, weak electric pulse activation-chilling, which is reunited, removes salt reactor 5
Using hard glass steel material, reactor head is equipped with inlet valve 51, and middle position is fixed with 1 fan magnetization nickel gold in reactor
Belong to net 52, magnetization 52 two sides of nickel metal mesh are respectively equipped with electrode 53 under 1 low pressure water, magnetize and be equipped with 1 group below nickel metal mesh 52
Cooling tube 54,54 end of cooling tube connect 1 set of circularly cooling unit 55, and reactor bottom is equipped with 1 set of heat preservation precipitation tank 56, heat preservation
56 right upper portion of precipitation tank is equipped with water discharging valve 57, and bottom right side is equipped with sludge and arranges mouth 59, and left bottom is equipped with 1 and electronic pushes away
Mud machine 58;Wastewater of steel industry containing inorganic salts is reunited by being located at weak electric pulse activation-chilling except 5 top of salt reactor
Inlet valve 51 enter inside reactor, at this point, be located at reactor two sidewalls on low pressure water under electrode 53 start, with pulse
The form of electric discharge is activated the inorganic ion in waste water, and the inorganic ion by activation can be located at instead
It answers 52 surface of magnetization nickel metal mesh in the middle part of device to converge and is converted into that a kind of specific surface energy is high, ion powder of thermodynamic instability
When passing through cooling tube 54 rapid cooling occurs for group, the waste water containing above-mentioned ion powder group, and the ion powder group in waste water can be fast
Speed occurs molecularization and agglomerates and be detached from solution formation suspended matter, is contained later with reducing the free enthalpy of entire solution decentralized system
The waste water of above-mentioned suspended matter enters in the heat preservation precipitation tank 56 of reactor bottom, in the state of keeping low temperature, in waste water
Suspended matter will not dissolve, and can gradually be settled down to heat preservation 56 bottom of precipitation tank, formed salt sludge, push away mud machine electronic
Under 58 promotion, the sludge by being located at heat preservation 56 bottom right side of precipitation tank arranges mouth 59 and reactor is discharged, and is recycled again sharp
With, meanwhile, the waste water after desalination purified treatment passes through the discharge of water discharging valve 57 for being located at heat preservation 56 right upper portion of precipitation tank
Reactor, and enter next treatment process.Wherein, the effect of aeration tank 6 is by aerobic aeration process to remaining in waste water
COD carries out preliminary oxidation resolution process;Wherein, the effect in biological oxidation filter tank 7 is that COD remaining to waste water carries out last depth
Spend purified treatment.Wherein, weak electric pulse activation-chilling is reunited except the dischargeable capacity of salt reactor 5 is 260m3, keep the temperature precipitation tank
56 dischargeable capacity is 225m3, thermal insulation material selection phenol formaldehyde foam resin, thermal coefficient 0.028W/mk, Applicable temperature
Range is -60 ~ 150 DEG C;Wherein, weak electric pulse activation-chilling, which is reunited, removes salt reactor 5, the peak value of electrode 53 under low pressure water
Voltage is 45V, and pulsed discharge frequency is 25 ~ 35 times/second, and service life is greater than 8000h;Wherein, weak electric pulse activation-chilling group
Poly- to remove salt reactor 5, the refrigerating capacity of circularly cooling unit 55 is 99760kcal/h, power 116kW, and operating voltage is
220V, the average flow rate of cooling tube 54 are 30m3/h。
By this system treated waste water, the removal efficiency of inorganic ion is up to 99.5%.