CN106113860B - 干爽型服装面料用复合透气膜 - Google Patents

干爽型服装面料用复合透气膜 Download PDF

Info

Publication number
CN106113860B
CN106113860B CN201610477975.2A CN201610477975A CN106113860B CN 106113860 B CN106113860 B CN 106113860B CN 201610477975 A CN201610477975 A CN 201610477975A CN 106113860 B CN106113860 B CN 106113860B
Authority
CN
China
Prior art keywords
film
dry
polyurethane
polytetrafluoroethylene
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610477975.2A
Other languages
English (en)
Other versions
CN106113860A (zh
Inventor
张子睿
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunshan Huayang New Material Ltd Co
Original Assignee
Kunshan Huayang New Material Ltd Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kunshan Huayang New Material Ltd Co filed Critical Kunshan Huayang New Material Ltd Co
Priority to CN201610477975.2A priority Critical patent/CN106113860B/zh
Publication of CN106113860A publication Critical patent/CN106113860A/zh
Application granted granted Critical
Publication of CN106113860B publication Critical patent/CN106113860B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/02—Layered materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/18—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by an internal layer formed of separate pieces of material which are juxtaposed side-by-side
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/02—2 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/73—Hydrophobic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • B32B2327/12—Polyvinylhalogenides containing fluorine
    • B32B2327/18—PTFE, i.e. polytetrafluoroethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/24—Homopolymers or copolymers of amides or imides
    • C08J2433/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)

Abstract

本发明公开一种干爽型服装面料用复合透气膜，其特征在于：包括微孔型聚氨酯薄膜、聚四氟乙烯薄膜，所述微孔型聚氨酯薄膜、聚四氟乙烯薄膜之间通过胶粘层粘合；所述微孔型聚氨酯薄膜由预制聚氨酯浆料刮涂于硅油离型纸上并依次在烘箱烘烤，当达到150度并保温后再降温至常温获得；所述预制聚氨酯浆料由以下组分组成：聚氨酯树脂、二甲基甲酰胺、甲苯、丁酮、热膨胀微球、1，4一丁二醇、聚丙烯酰胺、丙烯酸酯、有机硅氧烷乳液。本发明干爽型服装面料用复合透气膜提高了弹性和适应性，同时具有高强度、不吸水、耐磨性能。

Description

干爽型服装面料用复合透气膜
技术领域
本发明涉及一种干爽型服装面料用复合透气膜，属于纺织面料技术领域。
背景技术
聚氨酯面料是一类仿真皮面料，具有真皮的质感，故而又被称为人造革。它不仅结实耐用，而且因人工合成技术成熟价格较为低廉，在服装领域应用广泛。现有技术的PU面料为单一PU结构层的面料，由于PU面料耐水性较差，因而PU面料的服装一般不可水洗，只能采用干洗，提高了使用成本。PU面料透气性较差，降低了PU面料衣服穿着时的舒适度，例如在穿着时出汗无法排出。除此之外，PU面料的耐磨性较差而表面出现龟裂、脱落的现象。
而聚四氟乙烯薄膜，由于其特殊的微孔结构(呈网状)使其具有微孔型聚氨酯薄膜所不能有的防风防水、透湿性能，优于传统的聚氨酯微孔薄膜，但是其缺点也是显然的，这种材料其弹性基本为零，因此这种薄膜材料无论是在与面料的复合过程中还是在高强度的剧烈运动过程中都不能很好的适应面料拉伸 所带来的薄膜损伤。
发明内容
本发明目的是提供一种干爽型服装面料用复合透气膜，该复合透气膜提高了弹性和适应性，也避免由于微孔型聚四氟乙烯薄膜层吸附空汽中的粉尘、汗液中的盐份、油脂化妆品以及洗涤剂等物质，实现了长时间地保持稳定的防水和排汗汽性能，同时具有高强度、不吸水、耐磨性能。
为达到上述目的，本发明采用的技术方案是：一种干爽型服装面料用复合透气膜，包括微孔型聚氨酯薄膜、聚四氟乙烯薄膜，所述微孔型聚氨酯薄膜、聚四氟乙烯薄膜之间通过胶粘层粘合，所述聚四氟乙烯薄膜每平方英寸孔洞的数目为85～95亿个，孔洞的平均直径为0.2μm～10μm；
所述微孔型聚氨酯薄膜由预制聚氨酯浆料刮涂于硅油离型纸上并依次在80～150度温度梯度的烘箱烘烤，当达到150度并保温后再降温至常温获得；
所述预制聚氨酯浆料由以下组分组成：聚氨酯树脂100份、二甲基甲酰胺 22份、甲苯32份、丁酮13份、热膨胀微球8.5份、1,4-丁二醇1.8份、聚丙烯酰胺1.5份、丙烯酸酯0.35份、有机硅氧烷乳液0.25份。
上述技术方案中进一步改进的技术方案如下：
作为优选，所述聚四氟乙烯薄膜中孔洞的体积占聚四氟乙烯薄膜体积的 80～82％。
作为优选，所述聚四氟乙烯薄膜和微孔型聚氨酯薄膜之间的质量比为1:6.5～7，厚度比为1:0.3～0.6。
作为优选，所述80～150度温度梯度的烘箱烘烤具体包括以下阶段：
第一阶段：在80℃的条件下，且在低速流动的空气氛围下进行；
第二阶段：在90℃的条件下，且在中速流动的空气氛围下进行；
第三阶段：在110℃的条件下，且在强速流动的空气氛围下进行；
第四阶段：在140℃的条件下，且在低速流动的空气氛围下进行。
作为优选，所述热膨胀微球为akzonobel公司热膨胀微球，其具有弹性的壳内含有异丁烷、丙烷、戊烷等低沸点物质。
由于上述技术方案运用，本发明与现有技术相比具有下列优点和效果：
1.本发明干爽型服装面料用复合透气膜，在可以避免由于微孔型聚四氟乙烯薄膜层吸附空汽中的粉尘、汗液中的盐份、油脂化妆品以及洗涤剂等物质，实现了长时间地保持稳定的防水和排汗汽性能；其次，结合了具有亲水拒油的聚氨酯层和聚四氟乙烯薄膜层，在提高对外的阻止雨水性能的同时，有增强了 对内排出人体汗汽的性能，使得织物面料具有更佳舒适性能和更广阔的应用范围；再次，由于这种双组份薄膜材料具有大量均匀的孔洞，以及具有亲水拒油的型的微孔聚氨酯树脂层，从而更有利于来自人体水蒸汽的排出，大大降低了残留聚氨酯薄膜层表面的水分含量，从而提高了涂层面料的耐磨性且穿着干爽，最主要的是大大提高了聚四氟乙烯薄膜材料的弹性，使服装衣服在高强运动和极端条件下也具有良好的力学性能。
2.本发明干爽型服装面料用复合透气膜，针对与聚四氟乙烯薄膜的特定组合，优化了微孔型聚氨酯薄膜的配方，从而提高了弹性和适应性，同时具有高强度、不吸水、耐磨性能。
具体实施方式
下面结合实施例对本发明作进一步描述：
实施例：一种干爽型服装面料用复合透气膜，包括微孔型聚氨酯薄膜、聚四氟乙烯薄膜，所述微孔型聚氨酯薄膜、聚四氟乙烯薄膜之间通过胶粘层粘合， 所述聚四氟乙烯薄膜每平方英寸孔洞的数目为85～95亿个，孔洞的平均直径为 0.2μm～10μm；
所述微孔型聚氨酯薄膜由预制聚氨酯浆料刮涂于硅油离型纸上并依次在80～150度温度梯度的烘箱烘烤，当达到150度并保温后再降温至常温获得；
所述预制聚氨酯浆料由以下组分组成：
聚氨酯树脂 100份，
二甲基甲酰胺 22份，
甲苯 32份，
丁酮 13份，
热膨胀微球 8.5份，
1,4-丁二醇 1.8份；
聚丙烯酰胺 1.5份；
丙烯酸酯 0.35份，
有机硅氧烷乳液 0.25份。
上述聚四氟乙烯薄膜中孔洞的体积占聚四氟乙烯薄膜体积的80～82％。
上述聚四氟乙烯薄膜和微孔型聚氨酯薄膜之间的质量比为1:6.5～7，厚度比为1:0.3～0.6。
上述80～150度温度梯度的烘箱烘烤具体包括以下阶段：
第一阶段：在80℃的条件下，且在低速流动的空气氛围下进行；
第二阶段：在90℃的条件下，且在中速流动的空气氛围下进行；
第三阶段：在110℃的条件下，且在强速流动的空气氛围下进行；
第四阶段：在140℃的条件下，且在低速流动的空气氛围下进行。
上述热膨胀微球为akzonobel公司热膨胀微球，其具有弹性的壳内含有异丁烷、丙烷、戊烷等低沸点物质。
本发明具体指标数值如下：
a.静水压值洗前＞12000mmH2O，五次洗涤后＞8000mmH2O(洗涤方法ISO 6330，测试方法ISO 811)，
b.透湿量：10000g/m2·24h(JIS 1099 A1)，
c.阻燃性通过(GB8965.2-2009)判定标准为B级，
d.抗剥离强度(GB11042-89)：4N，
e.耐寒可达-150℃以下，耐热可达+150℃，(ISO 2136标准)耐曲折9000次无裂，
f.薄膜拉伸率25％，
g.薄膜回复率96％，
h.防风性能：完全防风(＞10级)，
i.热阻抗(GB/T 11048-2008 A法)：0.1097m2·K/W。
采用上述干爽型服装面料用复合透气膜时，在可以避免由于微孔型聚四氟乙烯薄膜层吸附空汽中的粉尘、汗液中的盐份、油脂化妆品以及洗涤剂等物质，实现了长时间地保持稳定的防水和排汗汽性能；其次，结合了具有亲水拒油的 聚氨酯层和聚四氟乙烯薄膜层，在提高对外的阻止雨水性能的同时，有增强了对内排出人体汗汽的性能，使得织物面料具有更佳舒适性能和更广阔的应用范围；再次，由于这种双组份薄膜材料具有大量均匀的孔洞，以及具有亲水拒油的型的微孔聚氨酯树脂层，从而更有利于来自人体水蒸汽的排出，大大降低了残留聚氨酯薄膜层表面的水分含量，从而提高了涂层面料的耐磨性且穿着干爽，最主要的是大大提高了聚四氟乙烯薄膜材料的弹性，使服装衣服在高强运动和极端条件下也具有良好的力学性能；其次，其针对与聚四氟乙烯薄膜的特定组合，优化了微孔型聚氨酯薄膜的配方，从而提高了弹性和适应性，同时具有高强度、不吸水、耐磨性能。
上述实施例只为说明本发明的技术构思及特点，其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施，并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰，都应涵盖在本发明的保护范围之内。

Claims (4)

1.一种干爽型服装面料用复合透气膜，其特征在于：包括微孔型聚氨酯薄膜、聚四氟乙烯薄膜，所述微孔型聚氨酯薄膜、聚四氟乙烯薄膜之间通过胶粘层粘合；所述聚四氟乙烯薄膜每平方英寸孔洞的数目为85~95亿个，所述孔洞的平均直径为0.2μm ~10μm；
所述微孔型聚氨酯薄膜由预制聚氨酯浆料刮涂于硅油离型纸上并依次在80~150度温度梯度的烘箱烘烤，当达到150度并保温后再降温至常温获得；
所述预制聚氨酯浆料由以下组分组成：聚氨酯树脂100份、二甲基甲酰胺22份、甲苯32份、丁酮13份、热膨胀微球8.5份、1,4-丁二醇1.8份、聚丙烯酰胺1.5份、丙烯酸酯0.35份、有机硅氧烷乳液0.25份。
2.根据权利要求1所述的干爽型服装面料用复合透气膜，其特征在于：所述聚四氟乙烯薄膜中孔洞的体积占聚四氟乙烯薄膜体积的80~82%。
3.根据权利要求1所述的干爽型服装面料用复合透气膜，其特征在于：所述80~150度温度梯度的烘箱烘烤具体包括以下阶段：
第一阶段：在80℃的条件下，且在低速流动的空气氛围下进行；
第二阶段：在90℃的条件下，且在中速流动的空气氛围下进行；
第三阶段：在110℃的条件下，且在强速流动的空气氛围下进行；
第四阶段：在140℃的条件下，且在低速流动的空气氛围下进行。
4.根据权利要求1所述的干爽型服装面料用复合透气膜，其特征在于：所述聚四氟乙烯薄膜和微孔型聚氨酯薄膜之间的质量比为1:6.5~7，厚度比为1:0.3~0.6。
CN201610477975.2A 2015-02-25 2015-02-25 干爽型服装面料用复合透气膜 Active CN106113860B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610477975.2A CN106113860B (zh) 2015-02-25 2015-02-25 干爽型服装面料用复合透气膜

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610477975.2A CN106113860B (zh) 2015-02-25 2015-02-25 干爽型服装面料用复合透气膜
CN201510087391.XA CN104647848B (zh) 2015-02-25 2015-02-25 具有防水透湿高弹性能的双组份微孔薄膜

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201510087391.XA Division CN104647848B (zh) 2015-02-25 2015-02-25 具有防水透湿高弹性能的双组份微孔薄膜

Publications (2)

Publication Number Publication Date
CN106113860A CN106113860A (zh) 2016-11-16
CN106113860B true CN106113860B (zh) 2018-04-10

Family

ID=53239704

Family Applications (5)

Application Number Title Priority Date Filing Date
CN201610480395.9A Active CN106079799B (zh) 2015-02-25 2015-02-25 疏水型透湿聚四氟乙烯复合膜
CN201510087391.XA Active CN104647848B (zh) 2015-02-25 2015-02-25 具有防水透湿高弹性能的双组份微孔薄膜
CN201610481570.6A Active CN106113862B (zh) 2015-02-25 2015-02-25 便于人体水蒸汽排出的双层面料薄膜
CN201610480894.8A Active CN106010185B (zh) 2015-02-25 2015-02-25 用于服装面料的高强度双组份薄膜
CN201610477975.2A Active CN106113860B (zh) 2015-02-25 2015-02-25 干爽型服装面料用复合透气膜

Family Applications Before (4)

Application Number Title Priority Date Filing Date
CN201610480395.9A Active CN106079799B (zh) 2015-02-25 2015-02-25 疏水型透湿聚四氟乙烯复合膜
CN201510087391.XA Active CN104647848B (zh) 2015-02-25 2015-02-25 具有防水透湿高弹性能的双组份微孔薄膜
CN201610481570.6A Active CN106113862B (zh) 2015-02-25 2015-02-25 便于人体水蒸汽排出的双层面料薄膜
CN201610480894.8A Active CN106010185B (zh) 2015-02-25 2015-02-25 用于服装面料的高强度双组份薄膜

Country Status (1)

Country Link
CN (5) CN106079799B (zh)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106589901A (zh) * 2016-11-30 2017-04-26 昆山华阳新材料股份有限公司 一种基于托玛琳粉末的远红外负离子薄膜及其制备工艺
CN107189300A (zh) * 2017-07-07 2017-09-22 昆山金有利新材料科技有限公司 一种弹性透气薄膜及制备方法
CN107163553A (zh) * 2017-07-07 2017-09-15 昆山金有利新材料科技有限公司 一种具有香味的pu薄膜及制备方法
CN107825799A (zh) * 2017-09-30 2018-03-23 江苏悦达家纺有限公司 基于复合膜层结构的防水透湿复合膜及其制备工艺
CN108078097A (zh) * 2017-12-11 2018-05-29 海宁文硕科技咨询有限公司 一种改良的雨伞及其制造方法
CN111996811A (zh) * 2020-08-26 2020-11-27 安徽达钰新材料科技有限公司 一种ptfe双组份防水透湿膜及其制备方法
CN112571907A (zh) * 2020-12-03 2021-03-30 安徽嘉明新材料科技有限公司 一种医疗防护服用tpu防水透湿阻隔膜

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102068924A (zh) * 2010-12-22 2011-05-25 中国科学院长春应用化学研究所 一种聚四氟乙烯复合膜及其制备方法
WO2012074160A1 (en) * 2010-11-29 2012-06-07 Gwangju Institute Of Science And Technology Carbon nanofiber catalysts using nanofiber including low cost transition metal for fuel cells and manufacturing method thereof
CN104275882A (zh) * 2014-09-28 2015-01-14 江阴泽万贸易有限公司 防水保暖医用面料
CN104309201A (zh) * 2014-09-13 2015-01-28 江阴市雅顺服饰有限公司 抗菌医用面料

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100316588A1 (en) * 2009-04-22 2010-12-16 Messier Pierre J Method for coating an elastomeric material with a layer of antitoxic material
CN201541785U (zh) * 2009-10-30 2010-08-11 江苏三川染整有限公司 一种多功能面料
NL2005845C2 (en) * 2010-12-09 2012-06-12 Kooiker Bedrijfswagenspuiterij En Carrosserie B V Structural material and method of manufacturing thereof.
KR20130033794A (ko) * 2011-09-27 2013-04-04 한국전자통신연구원 필터 제조 방법 및 이에 의해 제조된 필터
CN202507608U (zh) * 2012-01-04 2012-10-31 昆山华阳复合材料科技有限公司 高性能微多孔环保防水透气高新复合织物
CN202507633U (zh) * 2012-01-04 2012-10-31 昆山华阳复合材料科技有限公司 干法微多孔透湿复合织物
CN202507632U (zh) * 2012-01-04 2012-10-31 昆山华阳复合材料科技有限公司 具备防水透湿功能的复合织物
CN102555380B (zh) * 2012-01-21 2014-08-13 昆山华阳复合材料科技有限公司 用于面料的透湿防水薄膜及其制造工艺
CN202528513U (zh) * 2012-04-03 2012-11-14 昆山华阳复合材料科技有限公司 透气透湿防水的多功能双组份复合织物
CN102772120A (zh) * 2012-07-24 2012-11-14 常熟市建华织造有限责任公司 一种窗帘面料
US9988746B2 (en) * 2012-10-01 2018-06-05 The Board Of Trustees Of The University Of Illinois Partially degradable fibers and microvascular materials formed from the fibers
CN102963091B (zh) * 2012-12-06 2015-04-22 中材科技股份有限公司 薄膜复合织物的制备方法
CN103829429A (zh) * 2013-12-16 2014-06-04 江苏圣夫岛纺织生物科技有限公司 一种发光运动服纺织面料

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012074160A1 (en) * 2010-11-29 2012-06-07 Gwangju Institute Of Science And Technology Carbon nanofiber catalysts using nanofiber including low cost transition metal for fuel cells and manufacturing method thereof
CN102068924A (zh) * 2010-12-22 2011-05-25 中国科学院长春应用化学研究所 一种聚四氟乙烯复合膜及其制备方法
CN104309201A (zh) * 2014-09-13 2015-01-28 江阴市雅顺服饰有限公司 抗菌医用面料
CN104275882A (zh) * 2014-09-28 2015-01-14 江阴泽万贸易有限公司 防水保暖医用面料

Also Published As

Publication number Publication date
CN106113862A (zh) 2016-11-16
CN106113862B (zh) 2018-04-10
CN104647848B (zh) 2016-09-28
CN106079799A (zh) 2016-11-09
CN106010185A (zh) 2016-10-12
CN106079799B (zh) 2018-04-10
CN106010185B (zh) 2018-05-18
CN106113860A (zh) 2016-11-16
CN104647848A (zh) 2015-05-27

Similar Documents

Publication Publication Date Title
CN106113860B (zh) 干爽型服装面料用复合透气膜
CN106142695B (zh) 用于复合面料的防水复合膜
Lomax Breathable polyurethane membranes for textile and related industries
KR101822957B1 (ko) 발수성 원단 및 이를 포함하는 발수 다운 제품
JPH08506537A (ja) 屋外運動衣服用の防水通気性布地
CN102978901A (zh) 一种防水、防油、防污的纺织布料的制备工艺
WO2015058419A1 (zh) 环保型服装革及其制备方法
CN102517896A (zh) 耐洗防泼水织物及其制备方法
KR20180001715A (ko) 나노 산화아연 표면처리를 이용한 폴리에스터 및 면 교직 고일광 아웃웨어 직물의 제조 및 그 제조 방법
CN109680509B (zh) 一种应用于交通工具内饰或座椅的硅胶皮革及其制备方法
Kim et al. Thermal insulation and morphology of natural and synthetic filled outdoor sportswear by repeated water washing and dry cleaning
CN206941091U (zh) 织物及服装
CN205853509U (zh) 一种新型面料
CN107338653A (zh) 一种免洗面料及其制备方法
CN208104862U (zh) 一种具有单向透湿、抗静电功能的皮革制品
CN201770820U (zh) 一种拒水拒油的羊毛针织物
CN209775771U (zh) 一种耐腐蚀面料
CN115503314A (zh) 一种防水防污面料
CN105297435A (zh) 提高衬衫领子和袖克夫防污、易去污性整理液及整理方法
CN104975510A (zh) 一种提高衬衫领子、袖克夫耐磨性的整理液及整理方法
CN205853476U (zh) 一种新型环保面料
CN203449695U (zh) 一种环保型防油防水透气性布料
CN108754736A (zh) 一种用于户外服装的新型尼龙线
CN204059069U (zh) 有机硅绒面革
JPH06123002A (ja) スーツ、ジャケット、スラックス、スカート等の外衣

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant