CN106112304A - A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire and preparation method thereof - Google Patents

A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire and preparation method thereof Download PDF

Info

Publication number
CN106112304A
CN106112304A CN201610607718.6A CN201610607718A CN106112304A CN 106112304 A CN106112304 A CN 106112304A CN 201610607718 A CN201610607718 A CN 201610607718A CN 106112304 A CN106112304 A CN 106112304A
Authority
CN
China
Prior art keywords
mesh
welding wire
welding
cast iron
ferro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610607718.6A
Other languages
Chinese (zh)
Other versions
CN106112304B (en
Inventor
刘大双
祁凯
魏萍
卢聪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu University of Science and Technology
Original Assignee
Jiangsu University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu University of Science and Technology filed Critical Jiangsu University of Science and Technology
Priority to CN201610607718.6A priority Critical patent/CN106112304B/en
Publication of CN106112304A publication Critical patent/CN106112304A/en
Application granted granted Critical
Publication of CN106112304B publication Critical patent/CN106112304B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261Rods, electrodes, wires
    • B23K35/0266Rods, electrodes, wires flux-cored
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • B23K35/3086Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

The open a kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire of the present invention; with mild-carbon steel strip as crust, drug core component is by mass percentage: 60~the 80 mesh high carbon ferro-chromes of 72%, 12~the 80 mesh electrolytic manganese powders of 18%; 1~the graphite of 2%; 2~the ferro-boron of 8%, 1~the 60 mesh almags of 4%, 2~the ferrosilicon of 6%; surplus is 80 mesh iron powders; wherein, graphite, ferro-boron, almag and ferrosilicon all add with 60 mesh and two kinds of granularities of 200 mesh, and medicated core powder accounts for the 54 58% of welding wire gross weight.The welding wire that the present invention provides, ensure that, by the interpolation of many granularities deoxidizer, the processing performance that welding wire is good, by with the addition of more large content of Mn element in medicated core, effectively facilitating the formation of " Binder Phase " austenite structure, effectively improve the toughness of hardfacing alloy, thus improve its crack resistance.And owing to Mn is solid-solution in M7C3Among, further increase M7C3Hardness.The comprehensive function of two aspects so that the wearability of rich chromium cast iron hardfacing alloy is effectively improved.

Description

A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire and preparation method thereof
Technical field
The invention belongs to the welding field in Materials Processing Engineering, more particularly to a kind of manganese Strengthening and Toughening rich chromium cast iron self-insurance Protect flux-cored wire and preparation method thereof.
Background technology
Built-up welding, as a kind of green manufacturing technique, is widely used in the reparation of all kinds of wear parts or remanufactures.Owing to becoming This cheap being in addition easy to is prepared, with M7C3Type carbide (M=Cr, Fe) is that the rich chromium cast iron hardfacing alloy of wear-resisting skeleton obtains extensively General application.M thick in the hypereutectic tissue of rich chromium cast iron hardfacing alloy7C3Type carbide, on the one hand has for raising wearability more Benifit, on the other hand easily there is metallurgical imperfection and micro-crack in itself, and fragility is very big, become hardfacing alloy under arms during Develop into the macroscopic cracking even major reason of cracking destruction.Therefore, tradition high-chromium cast iron-type hardfacing alloy crack resistance is overcome The defect of difference, is a hot subject of development in recent years technique for overlaying.
Generally use and reduce C and the way of alloying element content so that high-chromium cast iron-type hardfacing alloy is by hypereutectic tissue Change to hypoeutectic structure, to obtain enough toughness;But reducing C and alloying element content, to also result in hardfacing alloy hard Degree is decreased obviously, and wearability also cannot be ensured.It should be noted that the austenitic type in high-chromium cast iron-type hardfacing alloy seemingly " Binder Phase " in hard alloy.By the method that composition is modified, suitably increase this " Binder Phase " austenite, will be to change The new thought of kind high-chromium cast iron-type hardfacing alloy crack resistance.
Summary of the invention
Goal of the invention: for solving technical problem present in prior art, the present invention provides a kind of manganese Strengthening and Toughening height chromium casting Ferrum self protection pile-up welding flux core welding wire and preparation method thereof.
Technology contents: for realizing above-mentioned technical purpose, the present invention proposes a kind of manganese Strengthening and Toughening rich chromium cast iron self-shield built-up welding Flux-cored wire, including mild-carbon steel strip and medicated core, flux cored filler is in steel band, and described drug core component weight/mass percentage composition scope is such as Under: 60~the 80 mesh high carbon ferro-chromes of 72%, 12~the 80 mesh electrolytic manganese powders of 18%, 1~the graphite of 2%, 2~the ferro-boron of 8%, 1 ~the 60 mesh almags of 4%, 2~the ferrosilicon of 6%, surplus is 80 mesh iron powders, wherein, graphite, ferro-boron, almag and ferrosilicon All add with 60 mesh and two kinds of granularities of 200 mesh, wherein, medicated core powder accounts for the 54-58% of welding wire gross weight.
As preferably, described high carbon ferro-chrome phosphorus content is 9~10wt%, and chrome content is 60~70wt%, and remaining is ferrum; Described ferrosilicon silicon content is 72~80wt%, and remaining is ferrum;Described ferro-boron boron content is 19~25wt%, and remaining is ferrum; Described almag aluminum content is 47~53wt%, and remaining is magnesium.
Preferably, varigrained graphite in described medicated core: the graphite of 60 mesh and the graphite of 200 mesh, and with mass ratio 1:1 The mode of combination adds.
Preferably, varigrained ferro-boron in described medicated core: the graphite of 60 mesh and the graphite of 200 mesh, and with mass ratio 1:1 The mode of combination adds.
Preferably, the almag of different-grain diameter in described medicated core: the almag of 60 mesh and the almag of 200 mesh, And add in the way of mass ratio 1:1 combination.
Preferably, the ferrosilicon of different-grain diameter in described medicated core: the ferrosilicon of 60 mesh and the ferrosilicon of 200 mesh, and with mass ratio 1:1 The mode of combination adds.
Preferably, in described medicated core, the particle diameter of high carbon ferro-chrome, ferrosilicon and iron powder component in described medicated core is equal to 80 Mesh.
Preferably, in described medicated core, described mild-carbon steel strip thickness × width is 0.5 × 21mm.
Preferably, in described medicated core, in a diameter of 2.8mm, 3.2mm, 3.5mm, 3.8mm and 4.2mm of described welding wire Any one.
The preparation method of above-mentioned manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, comprises the steps:
(1) utilize molding roller that mild steel steel band is rolled into U-shaped, then by dust feeder by the medicated core powder of the present invention Join in U-lag by the 54-58% of welding wire gross weight of the present invention;
(2) U-lag is healed up, make medicated core wrap up wherein, by wire drawing die, by road drawing, tube reducing, finally make its diameter To 2.8~4.2mm, obtain final products.
In above-mentioned medicated core, each component Main Function is as follows:
High carbon ferro-chrome: transition alloy elements Cr in deposited metal, and C element is provided.
Manganese powder: transition alloy elements Mn, solution strengthening M7C3Carbide, promotes the formation of " Binder Phase " austenite.
Ferro-boron: deoxidation, reduces weld pool surface tension force, improves figuration of bead.
Graphite: provide C element, deoxidation forms CO, and reduces the partial pressure of oxygen in welding atmosphere and nitrogen partial pressure.
Almag: deoxidation, fixed nitrogen, strengthen self-shield effect.
Ferrosilicon: deoxidation, oozes Si.
Sketched by the effect of component each in technique scheme and medicated core it is understood that due to the fact that and add in medicated core More large content of Mn element, it is primarily present in M in hardfacing alloy tissue7C3Among, and small amount is present in matrix, Mn is as a kind of austenite former simultaneously, promotes the formation of " Binder Phase " austenite structure, effectively improves hardfacing alloy Toughness, thus improve its crack resistance, improve wearability.On the other hand, it is solid-solution in M due to Mn7C3Among, further increase M7C3Hardness.
Additionally, in medicated core, the granularity of graphite, ferro-boron, almag and ferrosilicon all has two kinds: 60 mesh and 200 mesh, with granularity The mode of difference combination is added.In whole welding process, in the molten drop stage of existing extreme temperatures, there is again the molten bath that temperature is slightly lower In the stage, whichever is required for being prevented effectively from air pollution and just can obtain qualified welding deposited metal in stage, and seminar passes through The substantial amounts of engineer testing of early stage finds, the self-shield that can be obviously improved welding wire by varigrained above-mentioned medicated core component is imitated Really.This is that varigrained powder has different oxidation activities.The new of chemical metallurgy reactivity is controlled by component particle size Thinking, adds superfine 200 mesh graphite, ferro-boron, almag and ferrosilicon in medicated core, utilizes it to carry out in the welding temperature rise period Effective precedent desoxydation, adds thicker 60 mesh graphite, almag and ferrosilicon in medicated core simultaneously, is retained in molten drop high temperature rank Section and molten bath stage, it is also possible to carry out effective deoxidation gas making, thus ensure to be heated at whole welding wire, melt, form molten drop, melt Drip transition, form molten bath and start the Welding Metallurgy whole process of solidification and be provided with good self-shield effect, it is achieved thereby that this weldering Silk, in the case of not adding any mineral powder slag former, remains able to possess good welding technological properties and welding metal Shaping surface.Meanwhile, the interpolation of many granularities deoxidizer, it is ensured that under the adding conditional of less deoxidizer, obtains good self-shield Effect, for medicated core formula medium high carbon ferrochrome, manganese powder etc. enough interpolations and with great transition coefficient transition create steric requirements and Environmental condition.
Beneficial effect: the present invention is by with the addition of more large content of Mn element in medicated core, and on the one hand it effectively facilitate " viscous Knot phase " formation of austenite structure, effectively improve the toughness of hardfacing alloy, thus improve its crack resistance.On the other hand, due to Mn is solid-solution in M7C3Among, further increase M7C3Hardness.The comprehensive function of two aspects so that rich chromium cast iron heap seam The wearability of gold is effectively improved.Additionally, control the new approaches of chemical metallurgy reactivity also by component particle size, at medicated core In be respectively combined interpolation 200 superfine mesh and thicker 60 mesh graphite, ferro-boron, almag and ferrosilicon, be effectively ensured whole Welding wire is heated, melt, form molten drop, droplet transfer, formation molten bath and start the Welding Metallurgy whole process of solidification and be provided with good Self-shield effect, it is achieved thereby that this welding wire is not in the case of adding any mineral powder slag former, remains able to possess good Good welding technological properties and welding bead shaping surface.The flux-cored wire welding technological properties of the present invention is good, and alloy structure refinement is bright Aobvious, overlay surface hardness is uniform, and toughness is preferable, and average hardness is in 62~66HRC scopes.Wearability is 30 times of left sides of Q235 Right.
Detailed description of the invention
According to following embodiment, the present invention be may be better understood.But, the concrete medicated core component described by embodiment Proportioning, process conditions and result thereof are merely to illustrate the present invention, and should also not retouch in detail without limitation in claims The present invention stated.Wherein, the high carbon ferro-chrome phosphorus content used in following examples is 9~10wt%, chrome content be 60~ 70wt%, remaining is ferrum;Described ferrosilicon silicon content is 72~80wt%, and remaining is ferrum;Described ferro-boron boron content be 19~ 25wt%, remaining is ferrum;Described almag aluminum content is 47~53wt%, and remaining is magnesium.
Embodiment 1
A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, including mild-carbon steel strip and medicated core, flux cored filler in In steel band, drug core component is prepared by following quality: the 80 mesh high carbon ferro-chromes of 72g, the 80 mesh electrolytic manganese powders of 12g, the stone of 1g Ink, the ferro-boron of 3g, the 60 mesh almags of 1g, the ferrosilicon of 2g, the 80 mesh iron powders of 9g, wherein, graphite, ferro-boron, almag and Ferrosilicon all adds with 60 mesh and two kinds of granularities of 200 mesh, and it is equal each of to be added the mass fraction of 60 mesh and 200 mesh in powder Respectively account for 50%.Taken various powder are inserted in mixed powder machine, mix 40 minutes, then mixed-powder add U-shaped 21 × In the H08A carbon steel steel band groove of 0.5mm, filling rate is 54%.Again U-lag is healed up, make medicated powder wrap up wherein.Then its point is made Not Tong Guo one or more in the wire drawing die of a diameter of 4.2mm, 3.8mm, 3.5mm, 3.2mm, 2.8mm, by road drawing, subtract Footpath, finally obtains the product of a diameter of 2.8~4.2mm.Welding current is 280~420A, and weldingvoltage is 30~42V, welding Speed is 0.4m/min, and interlayer temperature controls at 150~250 DEG C, built-up welding 3 layers.Deposited metal hardness and wearability are shown in Table 1.
Embodiment 2
A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, including mild-carbon steel strip and medicated core, flux cored filler in In steel band, drug core component is prepared by following quality: the 80 mesh high carbon ferro-chromes of 65g, the 80 mesh electrolytic manganese powders of 14g, 1.5g's Graphite, the ferro-boron of 2g, the 60 mesh almags of 4g, the ferrosilicon of 6g, the 80 mesh iron powders of 7.5g, wherein, graphite, ferro-boron, magnalium close Gold and ferrosilicon all add with 60 mesh and two kinds of granularities of 200 mesh, and each of are added the quality of 60 mesh and 200 mesh in powder and divide Number respectively accounts for 50%.Taken various powder are inserted in mixed powder machine, mix 40 minutes, then mixed-powder is added the 21 of U-shaped In the H08A carbon steel steel band groove of × 0.5mm, filling rate is 55%.Again U-lag is healed up, make medicated powder wrap up wherein.Then it is made Respectively by one or more in the wire drawing die of a diameter of 4.2mm, 3.8mm, 3.5mm, 3.2mm, 2.8mm, by road drawing, subtract Footpath, finally obtains the product of a diameter of 2.8~4.2mm.Welding current is 280~420A, and weldingvoltage is 30~42V, welding Speed is 0.4m/min, and interlayer temperature controls at 150~250 DEG C, built-up welding 3 layers.Deposited metal hardness and wearability are shown in Table 1.
Embodiment 3
A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, including mild-carbon steel strip and medicated core, flux cored filler in In steel band, drug core component is prepared by following quality: the 80 mesh high carbon ferro-chromes of 70g, the 80 mesh electrolytic manganese powders of 16g, 1.5g's Graphite, the ferro-boron of 5g, the 60 mesh almags of 2g, the ferrosilicon of 4g, the 80 mesh iron powders of 4.5g, wherein, graphite, ferro-boron, magnalium close Gold and ferrosilicon all add with 60 mesh and two kinds of granularities of 200 mesh, and each of are added the quality of 60 mesh and 200 mesh in powder and divide Number respectively accounts for 50%.Taken various powder are inserted in mixed powder machine, mix 40 minutes, then mixed-powder is added the 21 of U-shaped In the H08A carbon steel steel band groove of × 0.5mm, filling rate is 57%.Again U-lag is healed up, make medicated powder wrap up wherein.Then it is made Respectively by one or more in the wire drawing die of a diameter of 4.2mm, 3.8mm, 3.5mm, 3.2mm, 2.8mm, by road drawing, subtract Footpath, finally obtains the product of a diameter of 2.8~4.2mm.Welding current is 280~420A, and weldingvoltage is 30~42V, welding Speed is 0.4m/min, and interlayer temperature controls at 150~250 DEG C, built-up welding 3 layers.Deposited metal hardness and wearability are shown in Table 1.
Embodiment 4
A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, including mild-carbon steel strip and medicated core, flux cored filler in In steel band, drug core component is prepared by following quality: the 80 mesh high carbon ferro-chromes of 60g, the 80 mesh electrolytic manganese powders of 18g, the stone of 2g Ink, the ferro-boron of 8g, the 60 mesh almags of 3g, the ferrosilicon of 5g, the 80 mesh iron powders of 4g, wherein, graphite, ferro-boron, almag and Ferrosilicon all adds with 60 mesh and two kinds of granularities of 200 mesh, and it is equal each of to be added the mass fraction of 60 mesh and 200 mesh in powder Respectively account for 50%.Taken various powder are inserted in mixed powder machine, mix 40 minutes, then mixed-powder add U-shaped 21 × In the H08A carbon steel steel band groove of 0.5mm, filling rate is 58%.Again U-lag is healed up, make medicated powder wrap up wherein.Then its point is made Not Tong Guo one or more in the wire drawing die of a diameter of 4.2mm, 3.8mm, 3.5mm, 3.2mm, 2.8mm, by road drawing, subtract Footpath, finally obtains the product of a diameter of 2.8~4.2mm.Welding current is 280~420A, and weldingvoltage is 30~42V, welding Speed is 0.4m/min, and interlayer temperature controls at 150~250 DEG C, built-up welding 3 layers.Deposited metal hardness and wearability are shown in Table 1.
The beaten hardness of table 1 uses HR-150A Rockwell apparatus, load 150Kg, and each test specimens takes 5 point hardnesses, meter Calculate average hardness value.
Wear test uses MLS-225 type wet type rubber wheel abrasion tester.
The overlay cladding of each embodiment is cut five a size of 57 × 25 × 6mm Wear specimens.Wear test parameter is as follows: Rubber wheel diameter: 178mm, rubber wheel rotating speed: 240 revs/min, rubber wheel hardness: 70 (Shao Er hardness), load: 10Kg, rubber wheel Revolution: pre-grinding 1000 turns, formal test turns 1000 turns, abrasive material: the quartz sand of 40~70 mesh.The anti-wear performance of deposited metal is with just The weight loss of formula abrasion is weighed.Sample is inserted in the beaker filling acetone soln every time experiment is forward and backward, clear at ultrasound wave Wash in instrument and clean 3~5 minutes, record of weighing after dry.Experiment Q235 steel sample as a comparison, contrast piece weight loss and measuring piece Relative wear resistance ε being used for built-up welding sample of weight loss.
Table 1 each embodiment deposited metal hardness and wear resistance
The present invention is by with the addition of more large content of Mn element in medicated core, and on the one hand it effectively facilitate " Binder Phase " Ovshinsky The formation of soma, effectively improves the toughness of hardfacing alloy, thus improves its crack resistance.On the other hand, it is solid-solution in due to Mn M7C3Among, further increase M7C3Hardness.The comprehensive function of two aspects so that rich chromium cast iron hardfacing alloy wear-resisting Property is effectively improved.Additionally, control the new approaches of chemical metallurgy reactivity also by component particle size, group respectively in medicated core Close and add 200 superfine mesh and thicker 60 mesh graphite, ferro-boron, almag and ferrosilicon, be effectively ensured be heated at whole welding wire, Fusing, formation molten drop, droplet transfer, formation molten bath the Welding Metallurgy whole process starting to solidify are provided with good self-shield effect Really, it is achieved thereby that this welding wire is not in the case of adding any mineral powder slag former, remain able to possess good welding Processing performance and welding bead shaping surface.The flux-cored wire welding technological properties of the present invention is good, and alloy structure refinement is obvious, overlay cladding Case hardness is uniform, and toughness is preferable, and average hardness is in 62~66HRC scopes.Wearability is about 30 times of Q235.

Claims (10)

1. a manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, including mild-carbon steel strip and medicated core, flux cored filler is in steel In band, it is characterised in that described drug core component weight/mass percentage composition scope is as follows: 60~the high carbon ferro-chrome of 72%, 12~ The electrolytic manganese powder of 18%, 1~the graphite of 2%, 2~the ferro-boron of 8%, 1~the almag of 4%, 2~the ferrosilicon of 6%, surplus is 80 mesh iron powders, wherein, graphite, ferro-boron, almag and ferrosilicon all add with the mixture of 60 mesh and 200 two kinds of granularities of mesh, its In, medicated core powder accounts for the 54-58% of welding wire gross weight.
Manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire the most according to claim 1, it is characterised in that described High carbon ferro-chrome phosphorus content is 9~10wt%, and chrome content is 60~70wt%, and remaining is ferrum;Described ferrosilicon silicon content be 72~ 80wt%, remaining is ferrum;Described ferro-boron boron content is 19~25wt%, and remaining is ferrum;Described almag aluminum content is 47~53wt%, remaining is magnesium.
The most according to claim 1 containing manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, it is characterised in that no The graphite of one-size: the graphite of 60 mesh and the graphite of 200 mesh, and add in the way of mass ratio 1:1 combination.
The most according to claim 1 containing manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, it is characterised in that no The ferro-boron of one-size: the ferro-boron of 60 mesh and the ferro-boron of 200 mesh, and add in the way of mass ratio 1:1 combination.
The most according to claim 1 containing manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, it is characterised in that no Almag with particle diameter: the almag of 60 mesh and the almag of 200 mesh, and add in the way of mass ratio 1:1 combination.
The most according to claim 1 containing manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, it is characterised in that no Manganese powder with particle diameter: the ferrosilicon of 60 mesh and the ferrosilicon of 200 mesh, and add in the way of mass ratio 1:1 combination.
The most according to claim 1 containing manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, it is characterised in that institute The particle diameter stating the high carbon ferro-chrome in medicated core, manganese powder and iron powder component is equal to 80 mesh.
The most according to claim 1 containing manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, it is characterised in that institute Stating mild-carbon steel strip thickness × width is 0.5 × 21mm.
The most according to claim 1 containing manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire, it is characterised in that institute State in a diameter of 2.8mm, 3.2mm, 3.5mm, 3.8mm and 4.2mm of welding wire any one.
10. the preparation method containing manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire described in claim 1, its feature It is, comprises the steps:
(1) utilize molding roller that mild steel steel band is rolled into U-shaped, then by dust feeder, the medicated core powder of the present invention is pressed weldering The 54-58% of silk gross weight joins in U-lag;
(2) U-lag is healed up, make medicated core wrap up wherein, by wire drawing die, by road drawing, tube reducing, finally make its diameter reach 2.8~4.2mm, obtain final products.
CN201610607718.6A 2016-07-28 2016-07-28 A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire and preparation method thereof Active CN106112304B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610607718.6A CN106112304B (en) 2016-07-28 2016-07-28 A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610607718.6A CN106112304B (en) 2016-07-28 2016-07-28 A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106112304A true CN106112304A (en) 2016-11-16
CN106112304B CN106112304B (en) 2018-07-27

Family

ID=57254144

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610607718.6A Active CN106112304B (en) 2016-07-28 2016-07-28 A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106112304B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113146094A (en) * 2021-02-04 2021-07-23 苏州鑫之泰焊接材料有限公司 High-hardness crack-free boron-containing hardfacing flux-cored wire

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60162594A (en) * 1984-02-02 1985-08-24 Fuji Kogyosho:Kk High-hardness submerged arc welding material
CN103753053A (en) * 2014-01-23 2014-04-30 江苏科技大学 Non-slag self-protection build up welding flux-cored wire with few number of splatter and small size of splashing particles
CN103785971A (en) * 2014-01-23 2014-05-14 江苏科技大学 Non-slag self-protection flux-cored wire with ultra-low stomatal sensitivity for bead weld
CN104708234A (en) * 2013-12-11 2015-06-17 北京有色金属研究总院 Iron-based self-protection flux-cored wire, surfacing alloy manufactured with iron-based self-protection flux-cored wire and method for manufacturing iron-based self-protection flux-cored wire
CN105537797A (en) * 2015-11-27 2016-05-04 湘潭大学 Carbon-controlling and toughening type self-shielded open-arc high-boron surfacing flux-cored wire

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60162594A (en) * 1984-02-02 1985-08-24 Fuji Kogyosho:Kk High-hardness submerged arc welding material
CN104708234A (en) * 2013-12-11 2015-06-17 北京有色金属研究总院 Iron-based self-protection flux-cored wire, surfacing alloy manufactured with iron-based self-protection flux-cored wire and method for manufacturing iron-based self-protection flux-cored wire
CN103753053A (en) * 2014-01-23 2014-04-30 江苏科技大学 Non-slag self-protection build up welding flux-cored wire with few number of splatter and small size of splashing particles
CN103785971A (en) * 2014-01-23 2014-05-14 江苏科技大学 Non-slag self-protection flux-cored wire with ultra-low stomatal sensitivity for bead weld
CN105537797A (en) * 2015-11-27 2016-05-04 湘潭大学 Carbon-controlling and toughening type self-shielded open-arc high-boron surfacing flux-cored wire

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
路德斌: "TiC对高铬堆焊合金层显微组织及耐磨性的影响", 《中国优秀硕士学位论文全文数据库工程科技I辑》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113146094A (en) * 2021-02-04 2021-07-23 苏州鑫之泰焊接材料有限公司 High-hardness crack-free boron-containing hardfacing flux-cored wire
CN113146094B (en) * 2021-02-04 2024-01-09 苏州鑫之泰焊接材料有限公司 High-hardness crack-free boron-containing hardfacing flux-cored wire

Also Published As

Publication number Publication date
CN106112304B (en) 2018-07-27

Similar Documents

Publication Publication Date Title
CN106041356B (en) Good self-protection flux-cored wire of a kind of energy-efficient and overlaying shaping and preparation method thereof
CN106112303B (en) A kind of multicomponent nitride Strengthening and Toughening self protection pile-up welding flux core welding wire and preparation method thereof
CN106001995B (en) A kind of multicomponent nitride and boride collaboration enhancing self protection pile-up welding flux core welding wire
CN106112302A (en) A kind of polynary control amount Dispersed precipitate hard phase strengthens self protection pile-up welding flux core welding wire and preparation method thereof
CN103785967A (en) Slag-free self-protection flux-cored wire for niobium-titanium compound reinforcement hardfacing
CN106141484B (en) A kind of very high content vanadium is modified self-protecting flux-cored wire for overlaying welding and preparation method thereof
CN106141488B (en) A kind of self-protection flux-cored wire for adding more granularity drug core components and preparation method thereof
CN107999999A (en) A kind of abrasive wear resistance flux-cored wire and preparation method for coal-grinding roller
CN106041357B (en) A kind of nickel toughening high-chromium cast iron-type self protection pile-up welding flux core welding wire and preparation method thereof
CN112643244A (en) Self-protection flux-cored wire and preparation method thereof
CN106041358B (en) A kind of fabricated in situ WC and W6C-type carbide enhancing self protection pile-up welding flux core welding wire and preparation method thereof
CN106141495B (en) A kind of polynary boride doping vario-property self-protecting flux-cored wire for hardfacing and preparation method thereof
CN106112304B (en) A kind of manganese Strengthening and Toughening high chromium cast iron self protective build-up welding cored welding wire and preparation method thereof
CN106141483B (en) A kind of spontaneous large volume fraction boron-carbide reinforced wear-resistant built-up welding self-protection flux-cored wire and preparation method thereof
CN106166654B (en) A kind of very high content niobium Strengthening and Toughening self-protecting flux-cored wire for overlaying welding and preparation method thereof
CN107363431B (en) A kind of self-shield open arc built-up welding austenitic matrix flux-cored wire and its application method
CN107962314A (en) A kind of welding wire and its manufacture method
CN114769932B (en) Nickel-based alloy flux-cored wire and preparation method thereof
CN106001994B (en) A kind of flux-cored wire for enhancing the welding continuous self-shield effect of subregion and preparation method thereof
CN106238964B (en) A kind of titanium is modified high-chromium cast iron-type self protection pile-up welding flux core welding wire and preparation method thereof
CN106392361B (en) A kind of silicon toughening High-chromium Cast Iron Flux Cored Wire For Self-shielded and preparation method thereof
CN103785970B (en) A kind of vanadium niobium complex intensifying hardfacing is with without slag self-protection flux-cored wire
CN106112305B (en) A kind of inexpensive self-protection flux-cored wire containing different grain size deoxidier and preparation method thereof
CN109664046B (en) (Ti, Al) N reinforced self-protection flux-cored wire utilizing air to permeate N
CN106001993B (en) A kind of self-fluxing alloyed powder doping vario-property self protection pile-up welding flux core welding wire and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant