CN106111348A - A kind of modified model flotation agent - Google Patents
A kind of modified model flotation agent Download PDFInfo
- Publication number
- CN106111348A CN106111348A CN201610716203.XA CN201610716203A CN106111348A CN 106111348 A CN106111348 A CN 106111348A CN 201610716203 A CN201610716203 A CN 201610716203A CN 106111348 A CN106111348 A CN 106111348A
- Authority
- CN
- China
- Prior art keywords
- parts
- flotation agent
- modified model
- polyethylene
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000008396 flotation agent Substances 0.000 title claims abstract description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- -1 polyethylene Polymers 0.000 claims abstract description 14
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 claims abstract description 7
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004698 Polyethylene Substances 0.000 claims abstract description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 7
- HQABUPZFAYXKJW-UHFFFAOYSA-O butylazanium Chemical compound CCCC[NH3+] HQABUPZFAYXKJW-UHFFFAOYSA-O 0.000 claims abstract description 7
- 239000007822 coupling agent Substances 0.000 claims abstract description 7
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 claims abstract description 7
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 7
- 239000011976 maleic acid Substances 0.000 claims abstract description 7
- 229920000573 polyethylene Polymers 0.000 claims abstract description 7
- 229920000151 polyglycol Polymers 0.000 claims abstract description 7
- 239000010695 polyglycol Substances 0.000 claims abstract description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical compound CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 claims abstract description 6
- OXVXWUDYARFPLN-UHFFFAOYSA-N ethylazanium;hydron;sulfate Chemical compound CC[NH3+].OS([O-])(=O)=O OXVXWUDYARFPLN-UHFFFAOYSA-N 0.000 claims abstract description 6
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 claims abstract description 6
- 229920001684 low density polyethylene Polymers 0.000 claims description 4
- 239000004702 low-density polyethylene Substances 0.000 claims description 4
- 229940079593 drug Drugs 0.000 claims 1
- 239000003814 drug Substances 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052802 copper Inorganic materials 0.000 abstract description 5
- 239000010949 copper Substances 0.000 abstract description 5
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract description 3
- 229910052951 chalcopyrite Inorganic materials 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 2
- 238000005188 flotation Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009867 copper metallurgy Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/018—Mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/005—Dispersants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physical Water Treatments (AREA)
Abstract
The present invention proposes a kind of modified model flotation agent, and described flotation agent is by butyl xanthate, butyl ammonium aerofloat, ethyl ammonia sulfate, erucic acid, maleic acid, polyethylene, alkyl phenol polyglycol ether, ethanol, dodecylbenzene sodium sulfonate, coupling agent KH550 forms with water, the dispersion of described modified model flotation agent and collecting effect are good especially, and selectivity is good, it is possible to floatingly select the copper in low-grade chalcopyrite efficiently.
Description
Technical field
The present invention relates to flotation agent field, particularly to Chalkopyrite flotation agent field.
Background technology
Chalkopyrite is mainly copper iron sulfide, wherein possibly together with materials such as trace gold, silver, is to be distributed the widest copper mine class
Type, is also the topmost raw material of copper metallurgy, has the distribution of concentration at Sichuan and Yunnan area, the most relatively becomes the extraction of copper in general Chalkopyrite
Technology ripe, stable, efficient, but prior art still suffers from bigger improvement about fully extracting of copper in low-grade Chalkopyrite
Space.
Summary of the invention
It is an object of the invention to propose a kind of improved, dispersion and collecting effect is good especially, selectivity is good,
Flotation agent particular for low-grade chalcopyrite flotation.
Technical scheme is as follows:
A kind of modified model flotation agent, composed of the following components: butyl xanthate, butyl ammonium aerofloat, ethyl ammonia sulfate, erucic acid, maleic acid,
Polyethylene, alkyl phenol polyglycol ether, ethanol, dodecylbenzene sodium sulfonate, coupling agent KH550 and water, described polyethylene is low
Density polyethylene, molecular weight is 500～2000.
Preferably: by mass parts, described modified model flotation agent includes butyl xanthate 8～10 parts, butyl ammonium aerofloat 8～10 parts,
Ethyl ammonia sulfate 1～3 parts, erucic acid 1～5 parts, maleic acid 1～5 parts, polyethylene 2～10 parts, alkyl phenol polyglycol ether 10～15
Part, ethanol 5～10 parts, dodecylbenzene sodium sulfonate 1～5 parts, coupling agent KH5501～3 parts, water 30～50 parts.
The dispersion of the present invention and collecting effect are good especially, and selectivity is good, it is possible to floatingly select low-grade pyrite efficiently
Copper in ore deposit.
Detailed description of the invention
Embodiment 1
By butyl xanthate 8 parts, butyl ammonium aerofloat 8 parts, ethyl ammonia sulfate 1 part, erucic acid 1 part, maleic acid 1 part, molecular weight be 500 low
Density polyethylene 2 parts, alkyl phenol polyglycol ether 10 parts, stir after ethanol 5 parts mixing, then by dodecylbenzene sodium sulfonate
1 part, coupling agent KH5501 part is added thereto with 30 parts of water, i.e. obtains described modified model flotation after stirring 30min at 40 DEG C
Agent.
Embodiment 2
By butyl xanthate 10 parts, butyl ammonium aerofloat 10 parts, ethyl ammonia sulfate 3 parts, erucic acid 5 parts, maleic acid 5 parts, molecular weight is 2000
Low Density Polyethylene 10 parts, alkyl phenol polyglycol ether 15 parts, stir, then by detergent alkylate after ethanol 10 parts mixing
Sodium sulfonate 5 parts, coupling agent KH5503 part is added thereto with 50 parts of water, i.e. obtains described improvement after stirring 10min at 50 DEG C
Type flotation agent.
Claims (2)
1. a modified model flotation agent, it is characterised in that: described flotation agent is composed of the following components: butyl xanthate, butyl ammonium aerofloat, second
Thiourethane, erucic acid, maleic acid, polyethylene, alkyl phenol polyglycol ether, ethanol, dodecylbenzene sodium sulfonate, coupling agent KH550
With water, described polyethylene is Low Density Polyethylene, and molecular weight is 500～2000.
Modified model flotation agent the most according to claim 1, it is characterised in that: by mass parts, described flotation agent includes that fourth is yellow
Medicine 8～10 parts, butyl ammonium aerofloat 8～10 parts, ethyl ammonia sulfate 1～3 parts, erucic acid 1～5 parts, maleic acid 1～5 parts, polyethylene 2～10
Part, alkyl phenol polyglycol ether 10～15 parts, ethanol 5～10 parts, dodecylbenzene sodium sulfonate 1～5 parts, coupling agent KH5501～
3 parts, water 30～50 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610716203.XA CN106111348A (en) | 2016-08-24 | 2016-08-24 | A kind of modified model flotation agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610716203.XA CN106111348A (en) | 2016-08-24 | 2016-08-24 | A kind of modified model flotation agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106111348A true CN106111348A (en) | 2016-11-16 |
Family
ID=57275600
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610716203.XA Withdrawn CN106111348A (en) | 2016-08-24 | 2016-08-24 | A kind of modified model flotation agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106111348A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107520060A (en) * | 2017-09-30 | 2017-12-29 | 徐州中泰能源科技有限公司 | A kind of modified copper ore floatation agent |
| CN111672635A (en) * | 2020-05-25 | 2020-09-18 | 西部矿业股份有限公司 | Efficient collecting agent for collecting copper and gold from copper smelting slag and preparation method thereof |
-
2016
- 2016-08-24 CN CN201610716203.XA patent/CN106111348A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107520060A (en) * | 2017-09-30 | 2017-12-29 | 徐州中泰能源科技有限公司 | A kind of modified copper ore floatation agent |
| CN111672635A (en) * | 2020-05-25 | 2020-09-18 | 西部矿业股份有限公司 | Efficient collecting agent for collecting copper and gold from copper smelting slag and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101293221B (en) | Inhibition reelection and separation method for bulk concentrate floatation of plumbum-zincium, plumbum-zincium-copper or plumbum-copper | |
| CN102302981B (en) | Beneficiation reagent and method for separating copper-molybdenum mixed concentrates | |
| CN103350036B (en) | Collecting agent for refractory gold ores | |
| CN104646188A (en) | Cassiterite flotation agent composition | |
| CN105289834A (en) | Zinc and sulfur separation beneficiation method for pyrrhotite-rich zinc sulfide ore | |
| CN103386359A (en) | Beneficiation method for copper oxide cobalt ores | |
| CN106111348A (en) | A kind of modified model flotation agent | |
| CN109821659A (en) | The preparation and its application of copper-sulphide ores high efficiency composition collecting agent | |
| CN110787911A (en) | Flotation method for low-grade copper ore and associated gold and silver | |
| CN105562214A (en) | Low-grade copper sulphide ore collecting agent and preparation method thereof | |
| CN105750074A (en) | Beneficiation method for improving zinc flotation index of lead-zinc polymetallic sulfide ore | |
| CN103464304A (en) | Collector for copper and zinc separating flotation of copper-zinc ore | |
| CN101559423B (en) | Technology for secondarily recovering iron middlings | |
| CN106140484A (en) | A kind of modified model low-grade chalcopyrite flotation agent | |
| CN106000624B (en) | A kind of method of gold tailings waste residue multielement recovery | |
| CN106269285A (en) | A kind of modified model Chalkopyrite flotation agent | |
| CN103831172B (en) | Method for improving antimony, lead and associated silver flotation recovery rate by adopting combination collecting agent | |
| CN105233999A (en) | Chalcopyrite flotation agent | |
| CN106140487A (en) | A kind of modified mineral flotation agent | |
| CN106583057B (en) | A kind of preparation and application vulcanizing copper-molybdenum separating flotation inhibitor | |
| CN106238221A (en) | A kind of modified model copper ore floatation agent | |
| CN106269280A (en) | A kind of preparation method of modified model Chalkopyrite flotation agent | |
| CN204051919U (en) | The device of objectionable impurities is removed before a kind of cyanidation tailings flotation of high-grade iron concentrate | |
| CN106269284A (en) | A kind of preparation method of modified mineral flotation agent | |
| CN105195333A (en) | Mineral floatation agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20161116 |