CN103464304A - Collector for copper and zinc separating flotation of copper-zinc ore - Google Patents
Collector for copper and zinc separating flotation of copper-zinc ore Download PDFInfo
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- CN103464304A CN103464304A CN201310363872XA CN201310363872A CN103464304A CN 103464304 A CN103464304 A CN 103464304A CN 201310363872X A CN201310363872X A CN 201310363872XA CN 201310363872 A CN201310363872 A CN 201310363872A CN 103464304 A CN103464304 A CN 103464304A
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- copper
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Abstract
The invention provides a collector for copper and zinc separating flotation of copper-zinc ore. The collector is prepared from xanthate, polyoxyethylene-polyoxypropylene oxide glyceryl ether, sodium hydroxide, sodium sulfide, isopropyl ethyl thionocarbamate, copper sulfate, oxalic acid and an activator. The collector has the double properties of collecting and blistering, the copper mineral sulfide selectivity is good, the copper mineral sulfide collecting capacity is strong, the efficient separation of copper and zinc can be realized at the pH value of 7-11, and the grade and recovery rate of copper and zinc concentrates can be increased effectively, so that the copper-zinc ore collector has a wider scope of application.
Description
Technical field
The present invention relates to the copper ore dressing collecting agent, particularly a kind of collecting agent for copper zinc ore copper-zinc separate flotation.
Background technology
At present, China to select smelting copper mineral raw material be mainly chalcopyrite, vitreous copper, bornite, malachite etc.Press the selecting and smelting technology condition, Copper Ores is marked to three natural types with the ratio of cupric oxide and copper sulfide.Be sulfide ore, containing cupric oxide, be less than 10%; Oxidized ore, be greater than 30% containing cupric oxide; Mixed ore, containing cupric oxide 10%～30%.
The collecting agent that occupies leading position in current copper ore floatation technique is the floating agents such as xanthates, thiophosphate and mercaptan, thiamines ester, xanthate, black powder ester, xanthate, but in actual ore dressing, the many requirements that can not reach design of result, copper, sulphur content are from undesirable, in the copper concentrate product, sulfur-bearing exceeds standard, the copper concentrate rate of recovery is on the low side, causes the waste of mining deposits.And other mineral products in ore, as zinc etc. can not separate, cause waste.
Summary of the invention
The collecting agent that the purpose of this invention is to provide a kind of copper zinc ore copper-zinc separate flotation, described collecting agent has collecting and foaming double attribute, selectively good to copper sulfide mineral, collecting ability is strong, can realize the efficient separation of copper, zinc in pH value 7～11 scopes, can effectively improve copper, zinc concentrate grade and the rate of recovery, be a kind of copper zinc ore collecting agent that the wider scope of application is arranged.
Technical scheme of the present invention is as follows:
The collecting agent of this copper zinc ore copper-zinc separate flotation is made by the raw material of following weight portion (kilogram):
Xanthate 34-38, polyoxyethylene polyoxypropylene glycerin ether 2-3, NaOH 1-2, vulcanized sodium 1-2, isopropyl ethyl thiourethane 6-8, copper sulphate 2-3, oxalic acid 2-3, activator 4-5;
Described activator is made by the raw material of following weight portion (kilogram): soybean oil 12-15, sodium lignin sulfonate 2-3, silane resin acceptor kh-550 1-2, rosin acid polyoxyethylene ester 2-3, dimethicone 4-5, fumaric acid 2-3, EDTA5-8; Its preparation method is that soybean oil, sodium lignin sulfonate, silane resin acceptor kh-550, rosin acid polyoxyethylene ester are mixed, and is heated to 60-65 ℃, then adds dimethicone, stir after 20-30 minute, add again residual components, continue to stir 45-60 minute, obtain.
The collecting agent for preparing copper zinc ore copper-zinc separate flotation: other composition except activating agent is mixed, under 40-45 ℃, stir 10-15 minute under 8000-12000 rev/min, then add activator, stir 15-30 minute under 6000-8000 rev/min and get final product.
Collecting agent of the present invention has collecting and foaming double attribute, selectively good to copper sulfide mineral, collecting ability is strong, can realize the efficient separation of copper, zinc in pH value 7～11 scopes, can effectively improve copper, zinc concentrate grade and the rate of recovery, be a kind of copper zinc ore collecting agent that the wider scope of application is arranged.
The specific embodiment
Prepare the raw material of following weight portion (kilogram): xanthate 36, polyoxyethylene polyoxypropylene glycerin ether 3, NaOH 2, vulcanized sodium 2, isopropyl ethyl thiourethane 7, copper sulphate 3, oxalic acid 3, activator 5;
Prepare activator, at first prepare the raw material of following weight portion (kilogram): soybean oil 12, sodium lignin sulfonate 2, silane resin acceptor kh-550 1.5, rosin acid polyoxyethylene ester 2, dimethicone 4, fumaric acid 2, EDTA 7; Its preparation method is that soybean oil, sodium lignin sulfonate, silane resin acceptor kh-550, rosin acid polyoxyethylene ester are mixed, and is heated to 65 ℃, then adds dimethicone, after stirring 25 minutes, then adds residual components, continues to stir 50 minutes, obtains.
The collecting agent for preparing copper zinc ore copper-zinc separate flotation, mix other composition except activating agent, under 40 ℃, stirs 15 minutes under 11000 rev/mins, then add activator, stirs 20 minutes under 8000 rev/mins and get final product.
The present invention is for the flotation of copper zinc ore, and result of the test: the copper productive rate reaches 3.6%, and copper grade reaches 15.1%, and copper recovery reaches 91.3%.
Claims (2)
1. the collecting agent of a copper zinc ore copper-zinc separate flotation is characterized in that it is made by the raw material of following weight portion (kilogram):
Xanthate 34-38, polyoxyethylene polyoxypropylene glycerin ether 2-3, NaOH 1-2, vulcanized sodium 1-2, isopropyl ethyl thiourethane 6-8, copper sulphate 2-3, oxalic acid 2-3, activator 4-5;
Described activator is made by the raw material of following weight portion (kilogram): soybean oil 12-15, sodium lignin sulfonate 2-3, silane resin acceptor kh-550 1-2, rosin acid polyoxyethylene ester 2-3, dimethicone 4-5, fumaric acid 2-3, EDTA5-8; Its preparation method is that soybean oil, sodium lignin sulfonate, silane resin acceptor kh-550, rosin acid polyoxyethylene ester are mixed, and is heated to 60-65 ℃, then adds dimethicone, stir after 20-30 minute, add again residual components, continue to stir 45-60 minute, obtain activator.
2. the preparation method of the collecting agent of copper zinc ore copper-zinc separate flotation according to claim 1, is characterized in that other composition except activating agent is mixed, and stirs 10-15 minute, then add activator, stirs 15-30 minute under 6000-8000 rev/min and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310363872XA CN103464304A (en) | 2013-08-20 | 2013-08-20 | Collector for copper and zinc separating flotation of copper-zinc ore |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310363872XA CN103464304A (en) | 2013-08-20 | 2013-08-20 | Collector for copper and zinc separating flotation of copper-zinc ore |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103464304A true CN103464304A (en) | 2013-12-25 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310363872XA Pending CN103464304A (en) | 2013-08-20 | 2013-08-20 | Collector for copper and zinc separating flotation of copper-zinc ore |
Country Status (1)
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| CN (1) | CN103464304A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104772222A (en) * | 2015-03-11 | 2015-07-15 | 铜陵鑫腾矿业科技有限公司 | Flotation agent for copper-zinc separate flotation of copper-zinc ore |
| CN104815762A (en) * | 2015-05-06 | 2015-08-05 | 广西大学 | Method for preparing tennantite collecting agent |
| CN105013621A (en) * | 2015-07-01 | 2015-11-04 | 中国地质科学院矿产资源研究所 | Oxidized zinc ore flotation reagent and flotation method |
| CN108940604A (en) * | 2018-07-27 | 2018-12-07 | 攀枝花学院 | Marmatite flotation activating and its preparation method and application |
| WO2021141550A1 (en) * | 2020-01-06 | 2021-07-15 | Metal-Ki̇m Metalurji̇ Ve Ki̇mya Tarim San. Ti̇c. Ltd. Şti̇ | Activating reagent for zinc flotation |
| CN114042539A (en) * | 2021-11-17 | 2022-02-15 | 水口山有色金属有限责任公司 | Efficient collecting agent for separating zinc from lead-zinc sulfide ore and zinc separating method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100998963A (en) * | 2006-12-30 | 2007-07-18 | 陈铁 | Beneficiation method of complex copper oxide ore |
| CN102211060A (en) * | 2011-03-23 | 2011-10-12 | 昆明理工大学 | Activation method for flotation process of difficultly processed copper oxide ores |
-
2013
- 2013-08-20 CN CN201310363872XA patent/CN103464304A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100998963A (en) * | 2006-12-30 | 2007-07-18 | 陈铁 | Beneficiation method of complex copper oxide ore |
| CN102211060A (en) * | 2011-03-23 | 2011-10-12 | 昆明理工大学 | Activation method for flotation process of difficultly processed copper oxide ores |
Non-Patent Citations (2)
| Title |
|---|
| 中南工业大学等: "《浮选药剂》", 30 April 1993, 冶金工业出版社 * |
| 刘殿文等: "《氧化铜矿浮选技术》", 31 May 2009, 冶金工业出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104772222A (en) * | 2015-03-11 | 2015-07-15 | 铜陵鑫腾矿业科技有限公司 | Flotation agent for copper-zinc separate flotation of copper-zinc ore |
| CN104815762A (en) * | 2015-05-06 | 2015-08-05 | 广西大学 | Method for preparing tennantite collecting agent |
| CN104815762B (en) * | 2015-05-06 | 2017-03-01 | 广西大学 | A kind of preparation method of tennantite collecting agent |
| CN105013621A (en) * | 2015-07-01 | 2015-11-04 | 中国地质科学院矿产资源研究所 | Oxidized zinc ore flotation reagent and flotation method |
| CN108940604A (en) * | 2018-07-27 | 2018-12-07 | 攀枝花学院 | Marmatite flotation activating and its preparation method and application |
| WO2021141550A1 (en) * | 2020-01-06 | 2021-07-15 | Metal-Ki̇m Metalurji̇ Ve Ki̇mya Tarim San. Ti̇c. Ltd. Şti̇ | Activating reagent for zinc flotation |
| CN114042539A (en) * | 2021-11-17 | 2022-02-15 | 水口山有色金属有限责任公司 | Efficient collecting agent for separating zinc from lead-zinc sulfide ore and zinc separating method thereof |
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| PB01 | Publication | ||
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| C12 | Rejection of a patent application after its publication | ||
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Application publication date: 20131225 |