CN101293221B - Inhibition reelection and separation method for bulk concentrate floatation of plumbum-zincium, plumbum-zincium-copper or plumbum-copper - Google Patents

Inhibition reelection and separation method for bulk concentrate floatation of plumbum-zincium, plumbum-zincium-copper or plumbum-copper Download PDF

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CN101293221B
CN101293221B CN2008100585397A CN200810058539A CN101293221B CN 101293221 B CN101293221 B CN 101293221B CN 2008100585397 A CN2008100585397 A CN 2008100585397A CN 200810058539 A CN200810058539 A CN 200810058539A CN 101293221 B CN101293221 B CN 101293221B
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concentrate
lead
copper
zinc
inhibitor
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CN101293221A (en
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李美平
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Lanping Mineral Waste Recycling Plant
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Abstract

An inhibition gravity treatment separation method for lead-zinc, lead-zinc-copper or lead-copper floatation collective concentrates pertains to the mineral processing technical field. In gravity treatresurgence till the water co$tent reaches 16 percent to 22 percent, the fermentation is carried out for 3 days under the connitions of the temperature of 25`DEG C to 40 DEG C and the humidity of 70 pement separation of the collective concentrates, lead sulphide inhibitor is added. The method includes the following procedures: after lead sulphide inhibitor is added, the collective concentrate is sent to a table concentrator again for gravity treatment separation; after the gravity treatment separation in the table concentrator, the concentrate belt includes lead concentrate and sub-concentrate belt and the tailing zone includes sub-concentrate and gangue containing lead-zinc, lead-zinc-copper or lead-copper; the obtained sub-concentrate and the gangue undergo the gravity treatment separation in the table concentrator again or for a plurality of times, thus finally obtaining lead concentrate, zinc concentrate, zinc-copper concentrate or copper concentrate. Due to the existence of lead sulphide inhibitor, the floatability of the lead sulphide is completely inhibited so as to highlight the high specific gravity feature of the lead sulphide; therefore, the lead sulphide is easily separated from a plurality of metallic collective concentrates by the gravity treatment separation in the table concentrator. The content of the metal elements in the obtained concentrates is mutually low and the major metal concentrate and the attaching metal concentrate can both satisfy the metallurgical standards and requirements, thus having extremely remarkable economic benefits.

Description

The inhibition reelection and separation method of plumbous zinc, plumbous zinc-copper or lead bronze bulk concentrate floatation
Technical field
The invention belongs to the technique of preparing field of nonferrous metals ore, be specifically related to the shaking table gravity separation separation method of inhibiting.
Background technology
No matter Non-ferrous Metallurgy is pyrogenic process or wet method, all must use concentrate.The ore dressing difficulty in plumbous zinc, plumbous zinc-copper or lead bronze mixing ore deposit is very big.Because the control of FLOTATION SEPARATION inhibition point is very difficult, the concentrate metallic element of output usually contains height each other mutually.Because of galena has native floatability, thereby gravity treatment gained concentrate metallic element contains also high each other mutually.Even plumbous zinc, plumbous zinc-copper or lead bronze mixing ore deposit are through flotation-gravity treatment beneficiation combined method, the concentrate metallic element of output contains still high each other mutually.This makes follow-up metallurgical technology both increase cost, the metallurgic product that the purity of having difficult labour out again is high.The metallurgical main metal that obtains contains more mutual containing metal, causes non-main metal recovery to utilize the cost height, and abandon waste big dilemma.If the metallic element of concentrate contains each other mutually exceed standard, then directly cause follow-up metallurgical technology to be difficult to carry out, need do and join ore deposit or other processing, cause unnecessary waste to production to a certain degree.
Summary of the invention
The objective of the invention is to overcome the shortcoming of prior art, the inhibition reelection and separation method of a kind of plumbous zinc, plumbous zinc-copper or lead bronze bulk concentrate floatation is provided, allow plumbous zinc, plumbous zinc-copper or lead bronze bulk concentrate floatation after the inventive method gravity treatment, can obtain metallic element and contain lowly each other mutually, the main metal concentrate and the attached metal concentrate of gained all can satisfy metallurgical standard-required.
The technical scheme of the inventive method is: when the plumbous zinc of flotation gained, plumbous zinc-copper or lead bronze bulk concentrate are carried out gravity treatment, be added with the used vulcanized lead inhibitor of common flotation.
The optimisation technique scheme of the inventive method may further comprise the steps:
1, will send into table concentration again through behind the plumbous zinc of flotation gained, plumbous zinc-copper or the used vulcanized lead inhibitor of the lead bronze bulk concentrate elder generation common flotation of adding,
2, through table concentration, the concentrate band gets lead concentrate, and inferior concentrate band and tailing zone get inferior concentrate, the mine tailing of leaded zinc, plumbous zinc-copper or lead bronze,
3, again or repeatedly with inferior concentrate, the mine tailing of above-mentioned gained, and the dried up shaking table of sending into of branch that contains inhibitor carries out gravity treatment, at last lead concentrate and zinc concentrate, zinc-copper concentrate or copper concentrate.
Said shaking table is preferably the fiberglass shaking table.Preferably will carry out grading earlier through the plumbous zinc of flotation gained, plumbous zinc-copper or lead bronze bulk concentrate, thin to gained respectively again, in, thick varigrained concentrate adds the vulcanized lead inhibitor, plumbous zinc, plumbous zinc-copper or the lead bronze bulk concentrate that maybe will add behind the vulcanized lead inhibitor carry out grading earlier, respectively that gained is thin again, in, thick varigrained concentrate sends into table concentration.
The vulcanized lead inhibitor that said common floatation process is used can be: one or more in bichromate, sodium thiosulfate, sulphite, vulcanized sodium, carboxymethyl cellulose, the humic acid etc., but bichromate preferably.
Because the existence of vulcanized lead inhibitor is fully suppressed the floatability of vulcanized lead, highlights the high specific gravity characteristic of vulcanized lead, thereby in gravity treatment, can easily vulcanized lead be separated from many metal mixed concentrate.The present invention has separated lead effectively, more up hill and dale, has promoted mutual metallic effective richness poly-simultaneously.
Beneficial effect of the present invention: the present invention dexterously in reuse adoption process the lead of bringing Selection In property can float inhibitor, allow copper, zinc keep natural attribute, make plumbous zinc, plumbous zinc-copper or lead bronze bulk concentrate floatation after the inventive method gravity treatment, the metallic element of gained concentrate contains low each other mutually, main metal concentrate and attached metal concentrate all can satisfy metallurgical standard-required, can increase economic efficiency greatly, improve the recovery utilization rate of metallurgic product quality, the attached metal of raising, cut down the consumption of energy, environmental.
The specific embodiment
Embodiment 1: through flotation gained lead bronze bulk concentrate, its leaded weight ratio is 45%, and the cupric weight ratio is 4.5%.Above-mentioned concentrate is put into mixing drum, add the inhibitor sodium dichromate, the pH value of adjusting ore pulp is 7.4~8, stirred 10~30 minutes, send into fiberglass fine ore mud shaking table again and sort, the concentrate band of shaking table gets lead concentrate, and inferior concentrate band and tailing zone must contain inferior concentrate, the mine tailing of lead bronze.The leaded weight ratio of gained lead concentrate is not less than 60.5%, and the cupric weight ratio is lower than 1%.Again repeatedly 4 times with inferior concentrate, the mine tailing of above-mentioned gained and contain the dried up table concentration of sending into of branch of inhibitor, the leaded weight ratio of lead concentrate of each gained all is not less than 60.5%.Last gained copper concentrate cupric weight ratio is 10.2%, and leaded weight ratio is 1.5%.
As a comparison, to equally through flotation gained lead bronze bulk concentrate, unconstrained dose, sending into same shaking table carries out 5 times and sorts, the result can only obtain a spot of leaded weight ratio and be not less than 60.5% lead concentrate, and last gained bulk concentrate cupric weight ratio is lower than 7%, leaded weight ratio is higher than 12%.
Embodiment 2: through flotation gained lead and zinc bulk concentrate, its leaded weight ratio is 45.72%, and containing the zinc weight ratio is 8.62%.Above-mentioned concentrate is put into mixing drum, add inhibitor vulcanized sodium, the pH value of adjusting ore pulp is 9~10, stirs 8~25 minutes, and ore pulp is carried out the high-frequency vibration screening, more respectively with gained carefully, in, thick varigrained concentrate sends into the fiberglass table concentration.The leaded weight ratio of gained lead concentrate is 65%.Again repeatedly 5 times with inferior concentrate, the mine tailing of above-mentioned gained with contain the dried up table concentration of sending into of branch of inhibitor, the leaded weight ratio of lead concentrate of each gained all is not less than 65%, contains the zinc weight ratio and is lower than 1.5%.It is 22.7% that last gained zinc concentrate contains the zinc weight ratio, and leaded weight ratio is lower than 2%.
As a comparison, to equally through flotation gained lead and zinc bulk concentrate, unconstrained dose, sending into same shaking table carries out 6 times and sorts, the result can only obtain a spot of leaded weight ratio and be not less than 65% lead concentrate, and last gained is to contain that the zinc weight ratio is lower than 14%, leaded weight ratio is higher than 7% lead and zinc bulk concentrate.
Embodiment 3: through the plumbous zinc-copper bulk concentrate of flotation gained, its leaded weight ratio is 55.64%, and containing the zinc weight ratio is 6.1%, and the cupric weight ratio is 6.85%.Above-mentioned concentrate is put into mixing drum, add water and become ore pulp, ore pulp per ton adds inhibitor carboxymethyl cellulose 200 grams, after the stirring, send into fiberglass fine ore mud shaking table again and sort, the concentrate band of shaking table gets lead concentrate, and inferior concentrate band and tailing zone get inferior concentrate, the mine tailing of leaded zinc-copper.The leaded weight ratio of gained lead concentrate is 66%, contains zinc and the cupric weight ratio all is lower than 1%.Again repeatedly 6 times with inferior concentrate, the mine tailing of above-mentioned gained with contain the dried up table concentration of sending into of branch of inhibitor, the leaded weight ratio of lead concentrate of each gained all is not less than 66%.Last gained zinc-copper bulk concentrate cupric weight ratio is 14%, and containing the zinc weight ratio is 25%, and leaded weight ratio is lower than 1.8%.
As a comparison, to equally through the plumbous zinc-copper bulk concentrate of flotation gained, unconstrained dose, sending into same shaking table carries out 7 times and sorts, the result can only obtain a small amount of leaded weight ratio and be not less than 66% lead concentrate, last gained is lower than 10%, contains the zinc weight ratio and be lower than 18% for the cupric weight ratio, and leaded weight ratio is higher than 9% plumbous zinc-copper bulk concentrate.
Only the present invention is further illustrated for above embodiment, but it is described to the invention is not restricted to embodiment.

Claims (7)

1. the inhibition reelection and separation method of plumbous zinc, plumbous zinc-copper or lead bronze bulk concentrate floatation is characterized in that:
When the plumbous zinc of flotation gained, plumbous zinc-copper or lead bronze bulk concentrate are carried out gravity treatment, be added with the used vulcanized lead inhibitor of common flotation.
2. as the said inhibition reelection and separation method of claim 1, it is characterized in that:
(1), will add the used vulcanized lead inhibitor of common flotation earlier through the plumbous zinc of flotation gained, plumbous zinc-copper or lead bronze bulk concentrate after, send into table concentration again,
(2), through table concentration, the concentrate band gets lead concentrate, inferior concentrate band and tailing zone get inferior concentrate, the mine tailing of leaded zinc, plumbous zinc-copper or lead bronze,
(3), again or repeatedly with inferior concentrate, the mine tailing of above-mentioned gained, and the dried up shaking table of sending into of branch that contains inhibitor carries out gravity treatment, at last lead concentrate and zinc concentrate, zinc-copper concentrate or copper concentrate.
3. as the said inhibition reelection and separation method of claim 2, it is characterized in that shaking table is the fiberglass shaking table.
4. as the said inhibition reelection and separation method of claim 2, it is characterized in that: will carry out grading earlier through the plumbous zinc of flotation gained, plumbous zinc-copper or lead bronze bulk concentrate, thin to gained respectively again, in, thick varigrained concentrate adds the vulcanized lead inhibitor.
5. as the said inhibition reelection and separation method of claim 2, it is characterized in that: plumbous zinc, plumbous zinc-copper or the lead bronze bulk concentrate that will add behind the vulcanized lead inhibitor carry out grading earlier, respectively that gained is thin again, in, thick varigrained concentrate sends into table concentration.
6. as the said inhibition reelection and separation method of claim 2, it is characterized in that: the vulcanized lead inhibitor is one or more in bichromate, sodium thiosulfate, sulphite, vulcanized sodium, carboxymethyl cellulose, the humic acid.
7. as the said inhibition reelection and separation method of claim 6, it is characterized in that the vulcanized lead inhibitor is a bichromate.
CN2008100585397A 2008-06-16 2008-06-16 Inhibition reelection and separation method for bulk concentrate floatation of plumbum-zincium, plumbum-zincium-copper or plumbum-copper Expired - Fee Related CN101293221B (en)

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CN101486011B (en) * 2009-02-11 2011-07-27 李美平 Gravity separation method with defoaming agent for non-ferrous metal ore capable of being treated with gravity method
CN101690910A (en) * 2009-10-16 2010-04-07 株洲市湘麒科技开发有限公司 Method for separating lead and silver from manganese in anode sludge
CN102049352B (en) * 2009-11-06 2013-10-23 北京有色金属研究总院 Mineral processing technology for polymetallic sulfide ore containing arsenic, copper and zinc
CN101850296A (en) * 2010-06-03 2010-10-06 广西现代职业技术学院 Copper-separating process of high-sulfur copper ore containing higher silicate minerals of speckstone and like
CN102225369A (en) * 2011-05-18 2011-10-26 河南省岩石矿物测试中心 Beneficiation method for separating copper-lead-zinc multi-metal complex ore embedded with fine particles
CN102824954A (en) * 2011-06-14 2012-12-19 北京华夏建龙矿业科技有限公司 Method for separating bright molybdenum and brass in refractory molybdenum copper sulphide ore
CN103240167B (en) * 2013-04-27 2014-12-03 昆明冶金研究院 Lead and zinc separating method for high-oxidation-rate low-grade lead-zinc oxide ores
CN103350033B (en) * 2013-06-29 2016-05-25 西北矿冶研究院 Mineral separation method for separating chalcopyrite from galena, sphalerite and pyrite
WO2015113141A1 (en) 2014-01-31 2015-08-06 Goldcorp Inc. Process for separation of at least one metal sulfide compristng arsenic and/or antimony from a mixed sulfide concentrate
CN104138793B (en) * 2014-08-06 2016-08-17 广西龙胜华美滑石开发有限公司 A kind of gravity treatment impurity-removing method in sulfur-bearing minnesotaite ore deposit
CN106269271A (en) * 2016-11-02 2017-01-04 长春黄金研究院 The composite inhibitor of suppression lead minerals flotation
CN107159444B (en) * 2017-07-12 2019-02-26 湖南有色金属研究院 The ore-dressing technique of Zn content in a kind of reduction lead concentrate
CN107824339A (en) * 2017-11-16 2018-03-23 石义武 The environment-protecting and non-poisonous medicament isolation technics of copper, lead zinc
CN109013049A (en) * 2018-06-21 2018-12-18 中国恩菲工程技术有限公司 The method for handling Pb-Zn deposits
CN109530108B (en) * 2018-12-04 2021-05-07 中国恩菲工程技术有限公司 Separation process of copper-lead bulk concentrate
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