CN106103807A - Process from electrolysis for production groove gas for produce aluminum device - Google Patents

Process from electrolysis for production groove gas for produce aluminum device Download PDF

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Publication number
CN106103807A
CN106103807A CN201580004608.4A CN201580004608A CN106103807A CN 106103807 A CN106103807 A CN 106103807A CN 201580004608 A CN201580004608 A CN 201580004608A CN 106103807 A CN106103807 A CN 106103807A
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China
Prior art keywords
exchanger
gas
heat exchanger
group
pipe
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Granted
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CN201580004608.4A
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Chinese (zh)
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CN106103807B (en
CN106103807A8 (en
Inventor
西埃里·马拉德
埃尔哈尼·鲍哈比拉
安托伊内·昆廷德格罗马德
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Fives Solios SA
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Fives Solios SA
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Publication of CN106103807A publication Critical patent/CN106103807A/en
Publication of CN106103807A8 publication Critical patent/CN106103807A8/en
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Expired - Fee Related legal-status Critical Current
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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/22Collecting emitted gases

Abstract

nullA kind of gas processed from electrolysis for production groove (2) is to produce the device of aluminum,Described smelting groove is positioned in two parallel queues (3),This device is included near electrolysis for production groove (2) for capturing the device (1) of gas、It is collected in the collecting pipe (5) of the gas of capture near electrolysis for production groove (2)、Gas band at least one conduit (7) of gas treatment centre (8) and the heat exchanger (9) that was cooled to before gas enters gas treatment centre (8),Described exchanger (9) be placed in parallel gas band at least one conduit (7) of gas treatment centre (8),Wherein,Each heat exchanger (9) can run independent of other heat exchanger,And there is isolating device (16) at exchanger (9) either side,And,Wherein gas is assigned in all or part of heat exchanger (9) by house steward (13),Focus on the most after cooling in another house steward (14).

Description

Process from electrolysis for production groove gas for produce aluminum device
Technical field
The present invention relates to process the gas from electrolysis for production groove for the device of the production of aluminum.More specifically, relate to And place the heat exchanger for cooling down gas everywhere before process gases.
Background technology
A usual gas treatment centre (GTC) has multiple heat exchanger, because the heap(ed) capacity of exchanger is manufactured Restriction with treatment conditions.Therefore, an extremely large number (usual GTC correspondence 2,000,000N m is processed3/ h) gas flow Typically require and expand to 4 to 32 exchangers.
Now there is various configurations.File WO 2012/007809A1 discloses the layout of a kind of heat exchanger, these exchanges Device is placed directly in below the filter near reactor.By this configuration, the exchanger of minification can be used for each mistake Filter.It is then able to while guard filter, isolates described exchanger.This configuration increases the quantity of equipment (generally It is 2,000,000N m for treating capacity3For one GTC of/h, need 16 to 32 filters and as many exchange Device), especially in the case of reducing defecator size, all the more so, it is therefore desirable to increase cooling circuit and attended operation. Exchanger is placed on below filter and makes described exchanger separate with electrolysis for production groove, it is possible to by along piping network Convection action make gas cool down.If it is intended to utilize the energy reclaimed from gas, then so cooling reduces exchanger The efficiency of middle recuperation of heat.Such as, this energy can be cycled to used in power generation, city or local heat supply, cooling, sea water by ORC Desalination or other industrial use any.
File EP2431499A1 describes exchanger and is positioned at a kind of configuration in electrolysis for production groove exit.Because reclaiming dress Put closest to thermal source, so the maximum temperature reclaimed, but (generally, treating capacity is 2,000,000N because of each smelting groove m3One GTC of/h needs 190 electrolysis for production grooves and the exchanger assembly of equal number) there are a kind of such configuration, institute Its quantity with increment.But, this requires that each smelting groove has a cooling circuit, and needs substantial amounts of attended operation.? On one exchanger, operation needs interim stopping to supply gas to involved smelting groove.This patent also describes on each smelting groove A kind of bypath system, due to it is necessary to have extra pipeline and valve group (each smelting groove three groups), so it is a kind of cost The highest solution.
Present invention especially provides the solution of these problems.
Summary of the invention
The present invention relates to process from electrolysis for production groove gas for produce aluminum a kind of device, including at least one receive Collector, at least one air induction conduit and multiple heat exchanger, described collecting pipe collects the gas from electrolysis for production groove, described Air induction conduit brings gas treatment centre into gas, and described heat exchanger is placed at least one collecting pipe and gas is brought into gas Between at least one air induction conduit of body processing center.Each heat exchanger can run independent of other heat exchanger, and Isolating device is had in exchanger both sides.Pass through exchanger, it is possible to be cooled to before gas enters gas treatment centre.Heat Exchanger is placed in parallel at least one air induction conduit gas being brought into gas treatment centre.This device additionally includes at least One inlet manifold and at least one house steward that gives vent to anger, described inlet manifold is connected to heat exchanger at least one collecting pipe Entrance, in order to distribute air in all or part of heat exchanger, at least one house steward going out heat exchanger of giving vent to anger described Mouth is connected to gas to bring at least one air induction conduit of gas treatment centre.
In some embodiments, described device additionally include individually using or adopt according to all possible technical combinations Following feature in one or more features:
Described device includes multiple collecting pipe, and connecting tube provides collecting pipe to each other at least one to connect, wherein said Connecting tube is connected to the entrance of inlet manifold.Such as, the length of a length of electrolysis for production slot queue of collecting pipe, the work of connecting tube With being the gas mixing and smelting groove from each row;
One group of heat exchanger is positioned in each connecting tube;
One group of heat exchanger is generally made up of 2 to 12 heat exchangers;
Advantageously, heat exchanger is tubular-type, makes gas to be cooled in pipe outer circulation, makes coolant in described pipe Circulation;
One group of exchanger joint between collecting pipe and connecting tube;
~ mono-group of exchanger joint between connecting tube and air induction conduit;
~ described device further includes at the intermediate conductor of the joint between connecting tube, makes one group of heat exchanger be positioned at Joint between intermediate conductor and air induction conduit;
~exchanger is positioned near described pipe;
~isolating device is positioned at each exchanger either side;
~an exchanger is in resting state, in order to change the exchanger not run;
~exchanger and the connecting tube that is connected with these exchangers are equipped with oblique flange, on it, the end, is than lower bottom width;
~a gantry equipped with lifting device is placed on exchanger, to assist the attended operation of exchanger;
~exchanger is substituted by the conduit portion with same size and load loss coefficient.
Accompanying drawing explanation
In addition to regulation discussed above, the present invention includes some other regulations, the enforcement being the most just described with reference to the accompanying figures These regulations are more clearly illustrated by example, but described embodiment being in no way intended to limit property embodiment.In the drawings:
. Fig. 1 is the top view of the aluminum production plant according to prior art;
. Fig. 2 is the perspective view of one group of four exchanger of placement according to first embodiment of the invention;
. Fig. 3 is the front view of the embodiment shown in Fig. 2;
. Fig. 4 is the perspective view of one group of four exchanger of placement according to second embodiment of the invention;And,
. Fig. 5 is the front view of the embodiment implemented according to one variant of the present invention.
Detailed description of the invention
With reference to Fig. 1, it is shown that a kind of for processing the gas from electrolysis for production groove 2 for producing the device of aluminum, described Smelt groove to be positioned in two parallel queues 3.It is provided with the device for capturing gas, is used for extracting all gas or selection Property ground extract from the gas of electrolysis for production groove 2.The length of a length of electrolysis for production groove of collecting pipe 5, and it is collected in smelting groove The gas of neighbouring capture.Two connecting tubes 6 provide the connection between collecting pipe 5, a length of smelting groove 2 of described collecting pipe 5 Length, and its position crosses each other.The two connecting tube 6 is connected to gas takes to gas treatment centre (GTC) 8 together Air induction conduit 7.
Hereinafter, these words using " upstream ", " entrance ", " before ", " downstream ", " outlet " and " afterwards " are bases For gas is recycled to the usual direction of GTC 8 from electrolysis for production groove 2.
With reference to Fig. 2, it can be seen that concentrate, according to what first embodiment of the invention was shown, the one group of exchanger 9 placed, In this embodiment, this group exchanger is placed on the joint between connecting tube 6 and air induction conduit 7.Often group exchanger 9 all includes parallel Place multiple heat exchangers 9 and be connected with inlet manifold 13 and the house steward 14 that gives vent to anger.This group heat exchanger 9 includes N number of quantity Heat exchanger 9, N is preferably ranged between two to ten two.According to example, the exchanger 9 from this group is placed near connecting tube 6, Imply that just after the abutment between two connecting tubes 6 of catcher.More specifically, two connecting tubes 6 are together Enter the inlet manifold 13 shared, be connected respectively to N number of upstream exchanger tube 15 of heat exchanger 9 entrance from described inlet manifold 13 isolate.Outlet from each exchanger 9 of this group is all connected to downstream exchanger tube 17, and the house steward 14 that gives vent to anger Reclaim the exit gas of all coolings from N number of downstream exchanger tube 17, be then attached to the air induction conduit 7 of GTC8.
As a variant, one group of exchanger 9 can be placed in each connecting tube 6, or be even placed on collecting pipe 5 and connect Each abutment between adapter 6, or even after the combined spot of the connecting tube 6 in intermediate conductor 6 or abutment, imply that Between this intermediate conductor and air induction conduit 7.Therefore, this device can include respectively with inlet manifold 13 and give vent to anger what house steward 14 was connected Many group exchangers 9.
Each exchanger 9 combines with the isolating device at upstream and downstream, such as block valve 16 such that it is able to completely Isolated.More specifically, a block valve 16 is placed on the upstream exchanger tube 15 of exchanger 9 entrance, and One block valve 16 is placed on the downstream exchanger tube 17 of exchanger 9 near exit.So configured advantage is if keeped in repair Exchanger, it is possible to use block valve 16 is isolated, then this group exchanger is run by N-1 exchanger 9.Devise aerofluxus Fan and GTC 8, in order to when this group is run by N-1 exchanger 9, using the teaching of the invention it is possible to provide suction flow.Advantageously, according to this Bright, this device includes the additional exchanger of standby 9, implies that it does not run.Therefore, remain on during attended operation The quantity of exchanger.Actually, if it is necessary to change an exchanger 9, then standby additional exchanger 9 is put into operation, Always there to be N-1 exchanger 9 running.Run by N-1 exchanger, be then the standard ruuning situation of this device.
According to another embodiment, the standard ruuning situation of described device is to be run by all N number of exchangers 9.Relatively Cold period carries out attended operation, in order to during whole maintenance, is to connect by the operation of N-1 exchanger 9 for this device It is subject to.In order to limit the time run by N-1 exchanger 9, the exchanger of needs maintenance can be replaced with back-up exchanger.
An enforcement variant according to the present invention shown in Fig. 5, exchanges at corresponding upstream exchanger tube 15 and downstream Changed the exchanger 9 needed repairing, described pipe section 19 by pipe section (duct segment) 19 between device pipe 17 Size identical with the exchanger 9 changed with load loss coefficient.By so configured, can be cold during exchanger 9 is safeguarded But a part (N-1)/N gas, and do not change the operation of remaining N-1 exchanger.Preferably at the gas cooling requirement of exchanger When being not the highest with operation, the most not in hot period, the most in the winter time, so run by N-1 exchanger 9.
In order to more easily control process and dismantle exchanger 9, can be alignd and be put on the ground, as shown in Figure 3.Permissible One gantry 11 equipped with lifting device, such as, winding type lifting device 12 are installed on described exchanger 9, with The most once it is truncated valve 16 before an exchanger 9 to isolate, just can have been dismantled.
According to one embodiment of present invention, block valve 16, described gantry 11 are controlled by gantry 11 Running on N number of intermediate conductor 15, heat exchanger is positioned among described N number of intermediate conductor 15, so as to be vertically movable Block valve 16, to stop or to remove corresponding pipe.
According to another embodiment, control block valve 16 He below upstream exchanger tube 15 and downstream exchanger tube 17 Exchanger 9, exchanger 9 is placed between described upstream exchanger tube 15 and downstream exchanger tube 17.Exchanger 9 to be isolated, cuts Disconnected valve 16 vertical ascent, and in an open position, and described valve is by the ground.
Enforcement example according to the present invention shown in Fig. 3, the parting flange 18 between upstream exchanger tube 15 and exchanger 9 It is to tilt, as the parting flange 18 between exchanger 9 with downstream exchanger tube 17, thus the ratio of the upper end of exchanger 9 Lower bottom width.According to the shape of exchanger, place exchanger 9 and the most therefore become easier to from run location dismounting exchanger 9. Therefore, if in order to safeguard dismounting exchanger 9, comparing other direction, a disassembly direction is more preferable.Equally, the most more When changing exchanger, along preferred moving direction, heat exchanger 9 is parked in its run location.
Such as, presenting a heat exchanger 9 with the form of one group of pipeline, gas to be cooled is worn between described pipeline Cross.The quantity of pipeline changes according to the parameters of this device, amount of gas the most to be cooled, flow, coverage etc.. Certainly, by convention, a heat exchanger 9 includes 500 to 1500 pipelines.The coolant of a kind of such as water circulates in pipe, So as the gas cooling made and contact outside pipeline.Coolant circulates in a heat exchanger 9 and can be advantageously independent of together Other exchanger 9 in group.More precisely, in an exchanger 9 coolant of circulation neither directly from another Exchanger 9, is also not injected into another exchanger 9.Therefore, easily each heat exchanger can be manufactured independent of other heat exchanger 9, it is not necessary to change the cooling fluid supply loop of this group exchanger 9.Additionally, so make maintenance be easier to.
The heat exchanger 9 of same group is preferably identical, particularly the quantity of pipe and equivalently-sized.
By house steward 13, the speed that the gas in upstream exchanger tube 15 injects exchanger 9 is the most uniform, permanent Fixed, do not affected by the quantity constituting this group exchanger 9.Even if it is therefoie, for example, an exchanger 9 is due to attended operation not Time available, inlet manifold 13 makes gas distribute in the porch of the heat exchanger 9 remained on.In the exit of exchanger 9, under Trip exchanger tube 17 leads to, towards the pipeline 7 gas being brought into gas treatment centre 8, the house steward 14 that gives vent to anger.
The most as we have seen, present invention particularly includes to enter in the downstream of the pipeline 5 collecting gas from smelting groove 2 and GTC Between two supervisors 13,14 of the upstream of airway 7, it is placed in parallel exchanger 9, in order to make gas entering at these exchangers Well distribution at Kou.Advantageously, make exchanger 9 from electrolysis for production groove 2 very close to, in order to if it is intended to utilize reclaim heat Amount, increases organic efficiency by hotter gas.In the case of not according to smelting the quantity of groove 12 or filter, this method Also it is feasible for selecting the quantity of exchanger 9.With the exchanger 9 in group, there is indivedual character further, especially because The existence of isolating device 16, thus described exchanger can be isolated from each other, in order to carry out safeguarding, N-1 operation, detection, by it Dismounting or be unlikely to is closed any other of GTC 8 and is processed and ensure good in porch of the exchanger 9 of each operation Distribution.

Claims (12)

1. processing the gas from electrolysis for production groove (2) for producing the device of aluminum, it includes at least one collecting pipe (5), extremely A few air induction conduit (7) and least one set heat exchanger (9), described collecting pipe collects the gas from electrolysis for production groove (2) Body, described air induction conduit brings gas treatment centre (8) into gas, and described exchanger (9) is for entering gas treatment at gas Gas is cooled down, it is characterised in that the heat exchanger (9) in least one set heat exchanger (9) is placed in parallel, often before center (8) Individual exchanger (9) has the isolating device (16) being contained in exchanger (9) either side, so as to independent independent of other exchanger Running, and this device also includes at least one inlet manifold (13) and at least one house steward that gives vent to anger (14), described air inlet is total Pipe is supplied by the gas from least one collecting pipe (5), and is connected to the entrance of this group heat exchanger (9), in order to Gas is assigned to this and organizes in all or part of heat exchanger, and at least one house steward that gives vent to anger described is connected to this group heat exchanger (9) outlet, and gas is brought at least one air induction conduit (7).
Device the most according to claim 1, it is characterised in that include multiple collecting pipe (5), connecting tube (6) provides collects Pipe (5) each other at least one connects, and wherein connecting tube (6) is connected to air induction conduit (7).
Device the most according to claim 2, it is characterised in that one group of heat exchanger (9) be positioned at each connecting tube (6) it On.
4. according to the device described in Claims 2 or 3, it is characterised in that one group of exchanger (9) is positioned at collecting pipe (5) and is connected Joint between pipe (6).
5. according to the device according to any one of claim 2 to 4, it is characterised in that one group of exchanger (9) is positioned at connecting tube (6) joint and between air induction conduit (7).
6. according to the device according to any one of aforementioned claim 2 to 5, it is characterised in that described device further includes at The intermediate conductor of the joint between connecting tube (6), wherein, one group of heat exchanger (9) is positioned at intermediate conductor and air induction conduit (7) Between joint.
7. according to device in any one of the preceding claims wherein, it is characterised in that described least one set heat exchanger (9) is led to Often include 2 to 12 heat exchangers (9).
8. according to device in any one of the preceding claims wherein, it is characterised in that exchanger (9) is tubular-type, wherein, treats The gas of cooling is in pipe outer circulation, and coolant circulates in described pipe.
9. according to device in any one of the preceding claims wherein, it is characterised in that there is standby supplementary exchanger (9), To change the exchanger not run.
10. according to device in any one of the preceding claims wherein, it is characterised in that exchanger (9) is equipped with the flange tilted (18), on it end than lower bottom width.
11. according to device in any one of the preceding claims wherein, it is characterised in that the gantry equipped with lifting device (12) is risen Heavy-duty machine (11) is placed on exchanger (9), to assist the attended operation of exchanger.
12. according to device in any one of the preceding claims wherein, it is characterised in that exchanger (9) is had same size Substitute with the conduit portion (19) of load loss coefficient.
CN201580004608.4A 2014-03-21 2015-03-06 The gas from electrolysis for production slot is handled for producing the device of aluminium Expired - Fee Related CN106103807B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1452416 2014-03-21
FR1452416A FR3018826A1 (en) 2014-03-21 2014-03-21 GAS TREATMENT FACILITY FOR ELECTROLYTIC TANKS FOR THE PRODUCTION OF ALUMINUM
PCT/FR2015/050554 WO2015140445A1 (en) 2014-03-21 2015-03-06 Apparatus for treating gases from electrolytic cells for the production of aluminium

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CN106103807A true CN106103807A (en) 2016-11-09
CN106103807A8 CN106103807A8 (en) 2017-03-01
CN106103807B CN106103807B (en) 2019-04-19

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CN201580004608.4A Expired - Fee Related CN106103807B (en) 2014-03-21 2015-03-06 The gas from electrolysis for production slot is handled for producing the device of aluminium

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EP (1) EP3119927B1 (en)
CN (1) CN106103807B (en)
CA (1) CA2937667A1 (en)
FR (1) FR3018826A1 (en)
NO (1) NO3119927T3 (en)
WO (1) WO2015140445A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3112842A1 (en) * 2020-07-24 2022-01-28 Reel Alesa DEVICE FOR COOLING GAS EFFLUENTS FROM AN INSTALLATION FOR THE PRODUCTION OF ALUMINUM BY IGNITE ELECTROLYSIS

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DE19845258C1 (en) * 1998-10-01 2000-03-16 Hamburger Aluminium Werk Gmbh Installation for sucking away waste gases and using their heat for aluminum multi cell electrolysis plant comprises waste gas collector hoods and suction ducts for each electrolysis cell of the plant
CN1520501A (en) * 2001-06-25 2004-08-11 ����˹��ķ(��ʿ)���޹�˾ Process and device for transport of gas
US20080302520A1 (en) * 2007-06-06 2008-12-11 Alcoa Inc. Heat Exchanger
CN101641462A (en) * 2007-03-22 2010-02-03 阿尔斯托姆科技有限公司 Flue gas cooling and cleaning system
CN201473610U (en) * 2009-09-10 2010-05-19 沈阳铝镁设计研究院 System for lowering temperature of electrolysis smoke
CN102373486A (en) * 2010-08-26 2012-03-14 沈阳铝镁设计研究院有限公司 Aluminum electrolysis anode scrap cooling system and method
CN102817046A (en) * 2012-07-27 2012-12-12 中国铝业股份有限公司 Method for treating volatile smoke gas of aluminum electrolysis cell
CN103201414A (en) * 2010-09-17 2013-07-10 阿尔斯通技术有限公司 Pot heat exchanger
CN103261487A (en) * 2010-09-17 2013-08-21 阿尔斯通技术有限公司 Raw gas collection system

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EP2407228B1 (en) 2010-07-14 2016-09-07 General Electric Technology GmbH Gas cleaning unit and method for cleaning gas

Patent Citations (9)

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Publication number Priority date Publication date Assignee Title
DE19845258C1 (en) * 1998-10-01 2000-03-16 Hamburger Aluminium Werk Gmbh Installation for sucking away waste gases and using their heat for aluminum multi cell electrolysis plant comprises waste gas collector hoods and suction ducts for each electrolysis cell of the plant
CN1520501A (en) * 2001-06-25 2004-08-11 ����˹��ķ(��ʿ)���޹�˾ Process and device for transport of gas
CN101641462A (en) * 2007-03-22 2010-02-03 阿尔斯托姆科技有限公司 Flue gas cooling and cleaning system
US20080302520A1 (en) * 2007-06-06 2008-12-11 Alcoa Inc. Heat Exchanger
CN201473610U (en) * 2009-09-10 2010-05-19 沈阳铝镁设计研究院 System for lowering temperature of electrolysis smoke
CN102373486A (en) * 2010-08-26 2012-03-14 沈阳铝镁设计研究院有限公司 Aluminum electrolysis anode scrap cooling system and method
CN103201414A (en) * 2010-09-17 2013-07-10 阿尔斯通技术有限公司 Pot heat exchanger
CN103261487A (en) * 2010-09-17 2013-08-21 阿尔斯通技术有限公司 Raw gas collection system
CN102817046A (en) * 2012-07-27 2012-12-12 中国铝业股份有限公司 Method for treating volatile smoke gas of aluminum electrolysis cell

Also Published As

Publication number Publication date
CN106103807B (en) 2019-04-19
EP3119927A1 (en) 2017-01-25
WO2015140445A1 (en) 2015-09-24
EP3119927B1 (en) 2018-01-24
NO3119927T3 (en) 2018-06-23
CN106103807A8 (en) 2017-03-01
FR3018826A1 (en) 2015-09-25
CA2937667A1 (en) 2015-09-24

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