CN106087391A - Crease-resistant flexible, breathable, the preparation method of free of contamination composite functional fabric - Google Patents

Crease-resistant flexible, breathable, the preparation method of free of contamination composite functional fabric Download PDF

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Publication number
CN106087391A
CN106087391A CN201610429549.1A CN201610429549A CN106087391A CN 106087391 A CN106087391 A CN 106087391A CN 201610429549 A CN201610429549 A CN 201610429549A CN 106087391 A CN106087391 A CN 106087391A
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fabric
5min
preparation
titanium oxide
nano titanium
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CN106087391B (en
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张瑞萍
李胜臻
郭桂萍
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XINJIE LINING CLOTH CO Ltd JIANGSU
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Nantong University
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192Polycarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses a kind of crease-resistant flexible, breathable, the preparation method of free of contamination composite functional fabric, including preparation activation modification treatment fluid, preparation of nano titanium oxide dispersion, activation modification treatment fluid to the process of fabric, nano titanium oxide dispersion to steps such as the process of fabric.After present invention arrangement, the UPF value of fabric is 100+, is 50+ after 10 home washings.After arrangement, the smelly eliminating rate of fabric is more than 95%, and after 10 home washings, smelly eliminating rate (including ammonia, formaldehyde, acetaldehyde, hydrogen sulfide, nicotine, trimethylamine) is more than 90%.Fabric after arrangement is 96.7% to the catalytic self-cleaning rate of fading of chilli oil, is 93.9% after 10 home washings.Bacteriostasis rate (golden staphylococci) 98.6%, is 95.8% after 10 home washings.

Description

Crease-resistant flexible, breathable, the preparation method of free of contamination composite functional fabric
The application is application number: " antibacterial uvioresistant smelly eliminating is certainly for 201410556751.1, the applying date: 2014-10-20, title The preparation method of clean composite functional fabric " divisional application.
Technical field
The present invention relates to the preparation method of a kind of composite functional fabric.
Background technology
Along with growth in the living standard, people become more concerned with health and cleaning problems, for textile requirement the most not It is limited only to dress decoration again, the demand of the functions such as hygiene health care is improved constantly.
General antibacterial deodourizing product mainly reaches the purpose preventing stink from producing by antibacterial bacteria growing inhibiting. But the volatile organic matter produced in the unhappy stink with perspiration existed in daily life, body odor, cigarette stink, new house finishing is different Taste, severe contamination pure and fresh air, have impact on living environment and the physical and mental health of people, particularly with aging society Arriving, the aged person of bed increases, and the requirement to preventing stench measure is increased the most therewith, and these all promote the fast of smelly eliminating arrangement Speed development.It addition, textile is during dress, using, imprudence can stain stain, these dirts not only affect making of people With, also it is the good environment of microbial reproduction.Along with the quickening of people's rhythm of life, and the requirement of pursuit high-quality life, The textile with antibacterial and deodorizing automatically cleaning ability arises at the historic moment.
At present, mainly having two kinds of approach can develop the textile with deodorization functions, one is directly to send to have deodorization The fiber of function;Two is that textile is carried out deodorization arrangement.The deodorization of textile arrange refer to by deodorizer by dipping absorption, The modes such as chemical reaction, resin set, coating arrange on textile.The research and development of deodorization functions fiber and production cost are higher, work Industryization application is restricted.Method and mechanism that textile deodorization arranges mainly have: sensation deodorization process (encapsulation method), physical deodorization Method (absorption method), chemical deodorizing method, biological odor removal method etc..The adsorptivity deodorant such as activated carbon in the market, at absorption foul smell In can not decompose destruction foul smell, it is necessary to be desorbed in time, otherwise easily resolve to cause environment is repeated several times pollution.Many deodorization are whole Reason also exists deodorizer coloring, deodorizing capability persistence is poor, affect the problem such as physical property and dyeability of textile.
The latest development technology is nano material photocatalysis technology, uses nanometer Ti02 to carry out photocatalysis, directly utilizes bag Including sunlight at interior various light sources, degrade various pollutant at normal temperatures, advantage is that energy consumption is low, simple to operate, nothing Secondary pollution.Nano titanium oxide is a kind of N-type semiconductor, and particle size is little, and specific surface area is big, surface can and surface tension with The decline of particle diameter is increased dramatically.Nano material has quantum size effect, small-size effect, skin effect and macroscopic quantum tunneling Effects etc. are different from the new features of Conventional solid.Owing to crystalline field environment and combination at surface atom can be different from interior atoms, There is many dangling bonds in nano TiO 2 particles, has unsaturation, have the highest reactivity;It is nonpoisonous and tasteless, do not burn, with Time also there is the strongest photocatalysis, antibacterial and ultraviolet screener performance.The nano titanium oxide Final finishing of general textile Being on the surface of fiber by its physical absorption, adhesion is less, easily comes off;If using binding agent to be glued by nano titanium oxide Be combined in surface of cotton fabric, then after arranging, fabric breathability is poor, and affects feel.
Summary of the invention
It is an object of the invention to provide a kind of antibacterial uvioresistant deodorization good, soft ventilative, method simplicity The preparation method of the antibacterial self-cleaning composite functional fabric of uvioresistant smelly eliminating.
The technical solution of the present invention is:
The preparation method of a kind of antibacterial self-cleaning composite functional fabric of uvioresistant smelly eliminating, is characterized in that: comprise the following steps:
(1) preparation activation modification treatment fluid:
Following component is mixed activation modification treatment fluid:
Polybasic carboxylic acid consumption 20-60g/L
Cyclodextrin 20-80 g/L
Catalyst 5-50 g/L
Polyamino terminated polymer 2-20 g/L
Water surplus;
(2) preparation of nano titanium oxide dispersion:
Weigh nano titanium oxide and add deionized water, mechanical agitation 15 minutes, sonic oscillation 10 minutes, add dispersant 0.1-1 g/ L sonic oscillation 10 minutes, then mechanical agitation 5 minutes, obtain stable nano titanium oxide dispersion, nano titanium oxide consumption 1-10g/L;Dispersant is SDS, sodium hexameta phosphate, sodium polyphosphate or ethylene glycol;
(3) the activation modification treatment fluid process to fabric:
Process technique employing infusion process or padding method:
A: infusion process: bath raio 50:1-20:1,40-80 DEG C processes 30-90min, is dehydrated, 80 DEG C of drying and processing 5min of dehydrator, 1-5min is baked at pressing machine 150 DEG C-180 DEG C;
B: padding method: two leachings two are rolled, liquid carrying rate 70%-100%, dries 5min for 80 DEG C, and 150 DEG C-180 DEG C bake 1-5min;
(4) nano titanium oxide dispersion process to fabric:
A: infusion process: bath raio 50:1-20:1,40-80 DEG C processes 30-90min, dehydration, 80 DEG C of drying and processings of dehydrator 5min, bakes 1-5min at pressing machine 150 DEG C-180 DEG C, 5min is dried in ultrasonic wave water washing 5min → 80 DEG C.
B: padding method: two leachings two are rolled, pick-up 70%-100% → 80 DEG C preliminary drying 5min → 150-180 DEG C bakes 1-5min 5min is dried in → ultrasonic wave water washing 5min → 80 DEG C.
Described polyprotic acid is citric acid, 1,2,3,4-BTCA, malic acid, maleic acid, polymaleic anhydride, 2,4-bis- Methyl-pentane-1,2,3,3,4,5-hexacarboxylic acid.
Described cyclodextrin is beta-schardinger dextrin-or hydroxypropylβ-cyclodextrin.
Described catalyst is sodium hypophosphite, nano titanium oxide, nano silicon or nano zine oxide.
Described fabric is cotton, fiber crops, viscose glue, real silk, Pilus Caprae seu Ovis, chinlon and the fabric of terylene, or the blending of above-mentioned fiber is fine Dimension, the thread knitted fabric of yarn or woven fabric.
After arrangement, the UPF value of fabric is 100+, is 50+ after 10 home washings.After arrangement, the smelly eliminating rate of fabric (includes ammonia Gas, formaldehyde, acetaldehyde, hydrogen sulfide, nicotine, trimethylamine) more than 95%, smelly eliminating rate after 10 home washings (include ammonia, formaldehyde, Acetaldehyde, hydrogen sulfide, nicotine, trimethylamine) more than 90%.The catalytic self-cleaning rate of fading of chilli oil is by the fabric after arrangement 96.7%, it is 93.9% after 10 home washings.Bacteriostasis rate (golden staphylococci) 99.6%, is 95.8% after 10 home washings.
Testing standard
Uvioresistant: GB/T 18830-2002 " evaluation of textile UV resistance performance "
Smelly eliminating: Japan (1 society) estimation of fibres technological associations SEK mark fibre certification benchmark 21. smelly eliminating test (gas Detection tube method), test period 2h, foul smell initial concentration: foul smell 100ppm.
Antibiotic property: GB/T 20944.3 2008 " the evaluation Part III of antibacterial textile performance: succusion ".
Washability: measure according to " AATCC 61-2003 domestic and commercial washing color fastness ".Wash temperature is 40 DEG C, mark Quasi-detergent concentration is 0.37%, steel ball number 10, wash time 45min.
Owing in nano titanium oxide, Ti-O bond polarity is relatively big, the water of surface adsorption dissociates because of polarization, easy shape One-tenth-OH.The present invention uses polybasic carboxylic acid that fabric is carried out activation modification pre-treatment so that part COOH and fiber in polybasic carboxylic acid Upper-OH crosslinks modification, and the free carboxyl group-OH again with nano titanium oxide that remains on polybasic carboxylic acid modified fabric occurs ester Change reaction, be connected with covalent bond between three, form staggered network structure, strengthen and improve nano titanium oxide and fabric Adhesion and load capacity, decompose foul smell by the photocatalysis of nano titanium oxide;Additionally add in polybasic carboxylic acid modification There is the cyclodextrin of adsorptivity deodorizing function, make the part-COOH in polybasic carboxylic acid also esterification can be occurred anti-with cyclodextrin-OH Should, the cyclodextrin with cavity structure is anchored on fiber, utilizes the clathration absorption foul smell of cyclodextrin;And on fiber The cyclodextrin of anchoring can improve the photocatalysis effect of nano titanium oxide.
The present invention is that to use polybasic carboxylic acid be cross-linking agent, and cyclodextrin and nano titanium oxide are anchored at fiber surface, logical Cross the inclusion of cyclodextrin and the compound action of the photocatalysis Decomposition of nano titanium oxide, fabric is carried out antibacterial uvioresistant smelly eliminating certainly Clean complex function arranges, and prepares the antibacterial self-cleaning composite functional fabric of uvioresistant smelly eliminating, and the wrinkle resistance of fabric is also improved, hands Sense softness, wash resistant, do not affect permeability, non-environmental-pollution.
Below in conjunction with embodiment, the invention will be further described.
Detailed description of the invention
The preparation method of a kind of antibacterial self-cleaning composite functional fabric of uvioresistant smelly eliminating, is characterized in that: comprise the following steps:
(1) preparation activation modification treatment fluid:
Following component is mixed activation modification treatment fluid:
Polybasic carboxylic acid consumption 20-60g/L (example 20 g/L, 40 g/L, 60 g/L)
Cyclodextrin 20-80 g/L(example 20 g/L, 50 g/L, 80 g/L)
Catalyst 5-50 g/L(example 5 g/L, 30 g/L, 50 g/L)
Polyamino terminated polymer 2-20 g/L(example 2g/L, 10 g/L, 20 g/L)
Water surplus;
(2) preparation of nano titanium oxide dispersion:
Weigh nano titanium oxide and add deionized water, mechanical agitation 15 minutes, sonic oscillation 10 minutes, add dispersant 0.1-1 g/ L(example 0.1g/L, 0.5g/L, 1g/L) sonic oscillation 10 minutes, then mechanical agitation 5 minutes, obtain stable nano titanium oxide Dispersion liquid, nano titanium oxide consumption 1-10g/L(example 1 g/L, 5 g/L, 10 g/L);Dispersant is SDS, sodium hexameta phosphate, Sodium polyphosphate or ethylene glycol;
(3) the activation modification treatment fluid process to fabric:
Process technique employing infusion process or padding method:
A: infusion process: bath raio (g/ml) 50:1-20:1(example 50:1,35:1,20:1), 40-80 DEG C (example 40 DEG C, 60 DEG C, 80 DEG C) Process 30-90min(example 30 minutes, 60 minutes, 90 minutes), dehydration, 80 DEG C of drying and processing 5min of dehydrator, pressing machine 150 1-5min is baked under DEG C-180 DEG C (examples 150 DEG C, 165 DEG C, 180 DEG C);
B: padding method: two leachings two are rolled, liquid carrying rate 70%-100%, dries 5min for 80 DEG C, 150 DEG C-180 DEG C (example 150 DEG C, 165 DEG C, 180 DEG C) bake 1-5min(example 1 minute, 3 minutes, 5 minutes);
(4) nano titanium oxide dispersion process to fabric: use infusion process or padding method;
A: infusion process: bath raio (g/ml) 50:1-20:1(example 50:1,35:1,20:1), 40-80 DEG C (example 40 DEG C, 60 DEG C, 80 DEG C) process 30-90min(example 30 minutes, 60 minutes, 90 minutes), dehydration, 80 DEG C of drying and processing 5min of dehydrator, pressing machine Baking 1-5min under 150 DEG C-180 DEG C (examples 150 DEG C, 165 DEG C, 180 DEG C), 5min is dried in ultrasonic wave water washing 5min → 80 DEG C.
B: padding method: two leachings two are rolled, pick-up 70%-100% → 80 DEG C preliminary drying 5min → 150-180 DEG C bakes 1-5min 5min is dried in → ultrasonic wave water washing 5min → 80 DEG C.
Described polyprotic acid is citric acid, 1,2,3,4-BTCA, malic acid, maleic acid, polymaleic anhydride, 2,4-bis- Methyl-pentane-1,2,3,3,4,5-hexacarboxylic acid.
Described cyclodextrin is beta-schardinger dextrin-or hydroxypropylβ-cyclodextrin.
Described catalyst is sodium hypophosphite, nano titanium oxide, nano silicon or nano zine oxide.
Described fabric is cotton, fiber crops, viscose glue, real silk, Pilus Caprae seu Ovis, chinlon and the fabric of terylene, or the blending of above-mentioned fiber is fine Dimension, the thread knitted fabric of yarn or woven fabric.
Polybasic carboxylic acid processes as activation modification and the nano titanium oxide dispersion two-step method of cross-linking agent, it is also possible to polynary Carboxylic acid activated modification and nano titanium oxide dispersion one-step method process.

Claims (4)

1. crease-resistant flexible, breathable, a preparation method for free of contamination composite functional fabric, is characterized in that: comprise the following steps:
(1) preparation activation modification treatment fluid:
Following component is mixed activation modification treatment fluid:
Polybasic carboxylic acid consumption 20-60g/L
Cyclodextrin 20-80 g/L
Catalyst 5-50 g/L
Polyamino terminated polymer 2-20 g/L
Water surplus;
(2) preparation of nano titanium oxide dispersion:
Weigh nano titanium oxide and add deionized water, mechanical agitation 15 minutes, sonic oscillation 10 minutes, add dispersant 0.1-1 g/ L sonic oscillation 10 minutes, then mechanical agitation 5 minutes, obtain stable nano titanium oxide dispersion, nano titanium oxide consumption 1-10g/L;Dispersant is SDS, sodium hexameta phosphate, sodium polyphosphate or ethylene glycol;
(3) the activation modification treatment fluid process to fabric:
Process technique employing infusion process or padding method:
A: infusion process: bath raio 50:1-20:1,40-80 DEG C processes 30-90min, is dehydrated, 80 DEG C of drying and processing 5min of dehydrator, 1-5min is baked at pressing machine 150 DEG C-180 DEG C;
B: padding method: two leachings two are rolled, liquid carrying rate 70%-100%, dries 5min for 80 DEG C, and 150 DEG C-180 DEG C bake 1-5min;
(4) nano titanium oxide dispersion process to fabric:
A: infusion process: bath raio 50:1-20:1,40-80 DEG C processes 30-90min, dehydration, 80 DEG C of drying and processings of dehydrator 5min, bakes 1-5min at pressing machine 150 DEG C-180 DEG C, 5min is dried in ultrasonic wave water washing 5min → 80 DEG C;
B: padding method: two leachings two are rolled, pick-up 70%-100% → 80 DEG C preliminary drying 5min → 150-180 DEG C bakes 1-5min → super 5min is dried in sound wave washing 5min → 80 DEG C;
Described polyprotic acid is citric acid, 1,2,3,4-BTCA, malic acid, maleic acid, polymaleic anhydride or 2,4-diformazan Base-pentane-1,2,3,3,4,5-hexacarboxylic acid etc..
Crease-resistant flexible, breathable the most according to claim 1, the preparation method of free of contamination composite functional fabric, its feature It is: described fabric is cotton, numb fabric.
Crease-resistant flexible, breathable the most according to claim 1, the preparation method of free of contamination composite functional fabric, its feature It is: described fabric is the fabric of viscose glue, real silk.
Crease-resistant flexible, breathable the most according to claim 1, the preparation method of free of contamination composite functional fabric, its feature It is: described fabric is the fabric of Pilus Caprae seu Ovis, chinlon and terylene.
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