CN106086909A - The wax removing agent of copper piece surface wax dirt after cleaning polishing - Google Patents

The wax removing agent of copper piece surface wax dirt after cleaning polishing Download PDF

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Publication number
CN106086909A
CN106086909A CN201610633708.XA CN201610633708A CN106086909A CN 106086909 A CN106086909 A CN 106086909A CN 201610633708 A CN201610633708 A CN 201610633708A CN 106086909 A CN106086909 A CN 106086909A
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CN
China
Prior art keywords
parts
wax
dirt
wax removing
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610633708.XA
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Chinese (zh)
Inventor
陈腾飞
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GUANGDONG REDSUNSTAR INDUSTRY Co Ltd
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GUANGDONG REDSUNSTAR INDUSTRY Co Ltd
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Application filed by GUANGDONG REDSUNSTAR INDUSTRY Co Ltd filed Critical GUANGDONG REDSUNSTAR INDUSTRY Co Ltd
Priority to CN201610633708.XA priority Critical patent/CN106086909A/en
Publication of CN106086909A publication Critical patent/CN106086909A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/10Other heavy metals
    • C23G1/103Other heavy metals copper or alloys of copper
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel
    • C23G1/088Iron or steel solutions containing organic acids
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/12Light metals
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/12Light metals
    • C23G1/125Light metals aluminium

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention provides a kind of wax removing agent that copper piece surface wax is dirty after cleaning polishing in parts by mass, including following component: triethanolamine 15 20 parts, oleic acid 20 30 parts, a conduit made of long bamboo oil 5 10 parts, anion surfactant 8 12 parts, lauryl diethanolamide 10 15 parts, polypropylene glycol 35 parts, penetrating agent 25 parts, surplus water is supplied, and making gross mass part is 100 parts.Compared with prior art, its component proportion is simple, raw material sources are wide, production cost is relatively low, and the wax removing agent product obtained has good wax removing effect, compared with commercially available main product, there is more preferable wax removing effect, particularly while keeping performance, obtain great price advantage, create great market competition advantage for enterprise product.

Description

The wax removing agent of copper piece surface wax dirt after cleaning polishing
Technical field
The present invention relates to a kind of wax removing agent, a kind of wax removing agent of copper piece surface wax dirt after cleaning polishing, with Time present disclosure additionally applies for rustless steel, ferrum, magnesium, aluminum products surface wax dirt removing.
Background technology
Copper material has excellent physicochemical property and excellent surface treatment properties, applies extremely wide, in order to improve its property Energy and surface smoothness, it can process through surface finish, but must remain in surface of the work to when polishing after a polish Wax dirt carries out wax removing process.
Current pandemic ultrasonic waves for cleaning operation belongs to one of physics (chemical) cleaning method.Its cardinal principle Being: utilize the energy entrained by ultrasound wave, form a number of bubble by surfactant in aqueous cleaning solution, bubble exists Moving in aqueous solution, transmission energy also makes bubbles burst cause " cavitation effect " thus in the moment of bubbles burst, and microcosmic produces The most hundreds of thousands of atmospheric pressure, impact dirt (macroscopical), under the effect of this impulsive force, the dirt on copper piece (metal) surface Dirt departs from, comes off, emulsifying or solubilising, to reach oil removing, wax removing, purpose except Colophonium and resin.But " cavitation effect " is no It is to be the bigger the better, because the biggest corrosion that may cause metal surface, makes cleaned material outward appearance be destroyed.But " cavitation is imitated Should " again can not be the least, the least then cleaning performance is the best, and the non-Ex-all of dirt (dead angle) occurs in local, does not reaches due effect, because of And need the wax removing agent of appropriate mix to can be only achieved preferable effect.
It is said that in general, the dirt of medal polish part attachment, due to the high temperature in time polishing, dirt adhesive force is strong, allows it Come off more difficulty, needs to use organic solvent (such as three vinyl chlorides, trichloroethane, carbon tetrachloride etc.), and at cleaning formulation The middle content needing holding bigger, could remove this type of dirt.But some toxic components contained in this type of wax removing agent, meeting Cause environmental pollution and use healthy problem.Still further aspect, chlorohydrocarbon produces degraded under conditions of photo-thermal, generation Corrosion can be caused in the surface of metal (especially rustless steel, aluminum) by chloride ion (or HCl).And if using oil agent (benzene, first Benzene, gasoline or lower paraffin hydrocarbon etc) replace chlorohydrocarbon be carried out wax removing, then can cause there is inflammable, explosive potential safety hazard. In the past, domestic this special wax removing abluent was all monopolized by imported product, expensive.
Along with the development of domestic enterprise's technology, the common Wax removal water in current market can substantially meet its production requirement, but by In the defect of its component, content and preparation method, still suffer from that wax removing speed is slow, the use cycle is short, and base material is had slight erosion The problem of variable color, not environmentally, there is the problems such as bigger pollution in component to water body environment.
Summary of the invention
For problem above, it is an object of the invention to provide a kind of wax removing of copper piece surface wax dirt after cleaning polishing Agent, component proportion is simple, and raw material sources are wide, and production cost is relatively low, and the wax removing agent product obtained has good wax removing Effect, compared with commercially available main product, has more preferable wax removing effect, creates great market competition advantage for enterprise.
In order to realize the technical purpose of the present invention, the present invention adopts the following technical scheme that.
After cleaning polishing, the wax removing agent of copper piece surface wax dirt is in parts by mass, including following component: triethanolamine 15- 20 parts, oleic acid 20-30 part, a conduit made of long bamboo oil 5-10 part, anion surfactant 8-12 part, lauryl diethanolamide 10-15 part, Polypropylene glycol 3-5 part, penetrating agent 2-5 part, surplus water supplies, and making gross mass part is 100 parts.
Preferably, by mass percentage, the purity of described triethanolamine is not less than 80%, and the purity of oleic acid is not less than 82%, the purity of penetrating agent is not less than 90%.
Preferably, the wax removing agent of copper piece surface wax dirt after cleaning polishing, in parts by mass, including following component: three Ethanolamine 15 parts, oleic acid 20 parts, an a conduit made of long bamboo oil 10 parts, anion surfactant 12 parts, lauryl diethanolamide 15 parts, poly-third Glycol 5 parts, penetrating agent 2 parts, surplus water is supplied, and making gross mass part is 100 parts.
Preferably, the wax removing agent of copper piece surface wax dirt after cleaning polishing, in parts by mass, including following component: three Ethanolamine 18 parts, oleic acid 25 parts, an a conduit made of long bamboo oil 8 parts, anion surfactant 10 parts, lauryl diethanolamide 13 parts, poly-third Glycol 4 parts, penetrating agent 4 parts, surplus water is supplied, and making gross mass part is 100 parts.
Preferably, the wax removing agent of copper piece surface wax dirt after cleaning polishing, in parts by mass, including following component: three Ethanolamine 20 parts, oleic acid 30 parts, a conduit made of long bamboo oil 5 parts, anion surfactant 8 parts, lauryl diethanolamide 10 parts, poly-the third two Alcohol 3 parts, penetrating agent 5 parts, surplus water is supplied, and making gross mass part is 100 parts.
Preferably, at least one during described penetrating agent is fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene.
Preferably, at least one during described anion surfactant is dodecyl sodium sulfate or fatty acid methyl ester.
The invention has the beneficial effects as follows: the invention provides a kind of wax removing of copper piece surface wax dirt after cleaning polishing Agent, compared with prior art, its component proportion is simple, and raw material sources are wide, and production cost is relatively low, and the wax removing agent obtained produces Product have good wax removing effect, compared with commercially available main product, have more preferable wax removing effect, create greatly for enterprise Market competition advantage.
Detailed description of the invention
In order to be better understood from the present invention, below in conjunction with specific embodiment, invention is described in detail.
Embodiment 1
After cleaning polishing, the wax removing agent of copper piece surface wax dirt is in parts by mass, including following component: triethanolamine 15- 20 parts, oleic acid 20-30 part, a conduit made of long bamboo oil 5-10 part, anion surfactant 8-12 part, lauryl diethanolamide 10-15 part, Polypropylene glycol 3-5 part, penetrating agent 2-5 part, surplus water supplies, and making gross mass part is 100 parts.
Embodiment 2
The wax removing agent of copper piece surface wax dirt after cleaning polishing, in parts by mass, including following component: triethanolamine 15 Part, oleic acid 20 parts, a conduit made of long bamboo oil 10 parts, dodecyl sodium sulfate 12 parts, lauryl diethanolamide 15 parts, polypropylene glycol 5 parts, fat Fat polyoxyethylenated alcohol 2 parts, surplus water is supplied, and making gross mass part is 100 parts.
Embodiment 3
The wax removing agent of copper piece surface wax dirt after cleaning polishing, in parts by mass, including following component: triethanolamine 18 Part, oleic acid 25 parts, a conduit made of long bamboo oil 8 parts, dodecyl sodium sulfate 5 parts, fatty acid methyl ester 5 parts, lauryl diethanolamide 13 parts, poly- Propylene glycol 4 parts, alkylphenol polyoxyethylene 4 parts, surplus water is supplied, and making gross mass part is 100 parts.
Embodiment 4
The wax removing agent of copper piece surface wax dirt after cleaning polishing, in parts by mass, including following component: triethanolamine 20 Part, oleic acid 30 parts, a conduit made of long bamboo oil 5 parts, fatty acid methyl ester 8 parts, lauryl diethanolamide 10 parts, polypropylene glycol 3 parts, poly alkyl alcohol Oxygen vinyl Ether 2 parts, alkylphenol polyoxyethylene 3 parts, surplus water is supplied, and making gross mass part is 100 parts.
Water base metal cleaning agent prepared in pending workpiece embodiment 1-4 will carry out wax removing process, to its institute With scavenging period, going the aspect such as wax rate, cleaning cost, compare with commercially available prod, result is as shown in table 1.
Note: above-mentioned raw materials cost is to calculate with 100wt% concentration in embodiment, time actually used, by mass percentage, Antirust agent is diluted to the concentration of 5%, is i.e. watered 95%.
According to upper table data it is apparent that the invention provides a kind of after cleaning polishing copper piece surface wax dirt Wax removing agent, compared with prior art, its component proportion is simple, and raw material sources are wide, and production cost is relatively low, and the wax removing obtained Agent product has good wax removing effect, compared with commercially available main product, has more preferable wax removing effect, particularly at retentivity Obtain great price advantage while energy, create great market competition advantage for enterprise product.
The ultimate principle of the present invention, principal character and advantage have more than been shown and described.The technical staff of the industry should Understanding, above-described embodiment limits the present invention the most in any form, and the mode of all employing equivalents or equivalent transformation is obtained Technical scheme, all falls within protection scope of the present invention.

Claims (6)

1. the wax removing agent of copper piece surface wax dirt after cleaning polishing, it is characterised in that in parts by mass, including following component: Triethanolamine 15-20 part, oleic acid 20-30 part, a conduit made of long bamboo oil 5-10 part, anion surfactant 8-12 part, dodecyl diethanol Amide 10-15 part, polypropylene glycol 3-5 part, penetrating agent 2-5 part, surplus water supplies, and making gross mass part is 100 parts.
The wax removing agent of copper piece surface wax dirt after cleaning polishing the most according to claim 1, it is characterised in that by quality Part meter, including following component: triethanolamine 15 parts, oleic acid 20 parts, a conduit made of long bamboo oil 10 parts, anion surfactant 12 parts, dodecane Base diglycollic amide 15 parts, polypropylene glycol 5 parts, penetrating agent 2 parts, surplus water is supplied, and making gross mass part is 100 parts.
The wax removing agent of copper piece surface wax dirt after cleaning polishing the most according to claim 1, it is characterised in that by quality Part meter, including following component: triethanolamine 18 parts, oleic acid 25 parts, a conduit made of long bamboo oil 8 parts, anion surfactant 10 parts, dodecyl Diglycollic amide 13 parts, polypropylene glycol 4 parts, penetrating agent 4 parts, surplus water is supplied, and making gross mass part is 100 parts.
The wax removing agent of copper piece surface wax dirt after cleaning polishing the most according to claim 1, it is characterised in that by quality Part meter, including following component: triethanolamine 20 parts, oleic acid 30 parts, a conduit made of long bamboo oil 5 parts, anion surfactant 8 parts, dodecyl Diglycollic amide 10 parts, polypropylene glycol 3 parts, penetrating agent 5 parts, surplus water is supplied, and making gross mass part is 100 parts.
5., according to the wax removing agent of the dirt of copper piece surface wax after cleaning polishing described in any one of claim 1-4, its feature exists In: described penetrating agent is at least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene.
The wax removing agent of copper piece surface wax dirt after cleaning polishing the most according to claim 5, it is characterised in that: described the moon Ionic surface active agent is at least one in dodecyl sodium sulfate or fatty acid methyl ester.
CN201610633708.XA 2016-08-03 2016-08-03 The wax removing agent of copper piece surface wax dirt after cleaning polishing Pending CN106086909A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107141852A (en) * 2017-06-12 2017-09-08 上海地宝防滑防护科技有限公司 A kind of floor ceramic tile antilubricant and preparation method thereof
CN107587149A (en) * 2017-11-03 2018-01-16 安徽新合富力科技有限公司 One kind seven is aluminium minute surface wax removing agent
CN107604368A (en) * 2017-07-31 2018-01-19 宁波际超新材料科技有限公司 It is a kind of to be used to clean Wax removal water of steel and iron parts or copper piece and preparation method thereof
EP3354434A1 (en) * 2017-01-30 2018-08-01 Otis Elevator Company Load-bearing member surface treatment
CN108642498A (en) * 2018-06-05 2018-10-12 阳江市伟艺抛磨材料有限公司 A kind of rapid wax removing agent and preparation method thereof
CN113026030A (en) * 2021-03-04 2021-06-25 广东万维创新生物科技有限公司 Wax removing water and preparation method thereof

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CN105755496A (en) * 2014-12-17 2016-07-13 王叶苗 Special dewaxing liquid for cleaning aluminum alloy workpiece
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3354434A1 (en) * 2017-01-30 2018-08-01 Otis Elevator Company Load-bearing member surface treatment
CN108456323A (en) * 2017-01-30 2018-08-28 奥的斯电梯公司 The surface treatment of load carrying component
US10767077B2 (en) 2017-01-30 2020-09-08 Otis Elevator Company Load-bearing member surface treatment
AU2018200593B2 (en) * 2017-01-30 2023-07-27 Otis Elevator Company Load-bearing member surface treatment
CN107141852A (en) * 2017-06-12 2017-09-08 上海地宝防滑防护科技有限公司 A kind of floor ceramic tile antilubricant and preparation method thereof
CN107604368A (en) * 2017-07-31 2018-01-19 宁波际超新材料科技有限公司 It is a kind of to be used to clean Wax removal water of steel and iron parts or copper piece and preparation method thereof
CN107587149A (en) * 2017-11-03 2018-01-16 安徽新合富力科技有限公司 One kind seven is aluminium minute surface wax removing agent
CN108642498A (en) * 2018-06-05 2018-10-12 阳江市伟艺抛磨材料有限公司 A kind of rapid wax removing agent and preparation method thereof
CN113026030A (en) * 2021-03-04 2021-06-25 广东万维创新生物科技有限公司 Wax removing water and preparation method thereof
CN113026030B (en) * 2021-03-04 2023-05-09 广东万维创新生物科技有限公司 Wax removing water and preparation method thereof

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Application publication date: 20161109

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