CN106085073A - A kind of afforestation environmental protection insect paint and preparation method thereof - Google Patents

A kind of afforestation environmental protection insect paint and preparation method thereof Download PDF

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Publication number
CN106085073A
CN106085073A CN201610740373.1A CN201610740373A CN106085073A CN 106085073 A CN106085073 A CN 106085073A CN 201610740373 A CN201610740373 A CN 201610740373A CN 106085073 A CN106085073 A CN 106085073A
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CN
China
Prior art keywords
parts
environmental protection
insect paint
protection insect
isothiazolone
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Pending
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CN201610740373.1A
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Chinese (zh)
Inventor
宋群库
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Individual
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Individual
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Priority to CN201610740373.1A priority Critical patent/CN106085073A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of afforestation environmental protection insect paint and preparation method thereof, described afforestation environmental protection insect paint, according to the component of weight portion be: polymethyl methacrylate resin 30 40 parts, isothiazolone 5 15 parts, polyoxyethylene lauryl ether 12 18 parts, Tissuemat E 8 10 parts, diisocyanate 46 parts, antimony oxide 26 parts, Pulvis Talci 14 parts.Using the environmental protection insect paint that this formula is made, be directly brushed on the trunk of trees, be coated with after brushing, resistance to sunlight irradiates, difficult drop-off, and vermins-proof effect is good, and all material is environment-friendly materials, to person poultry harmless.

Description

A kind of afforestation environmental protection insect paint and preparation method thereof
Technical field
The present invention relates to a kind of paint field, specifically a kind of afforestation environmental protection insect paint and preparation method thereof.
Background technology
Trees are indispensable plants during people live, and it is possible not only to city, decoration, also can purifying city sky Bacterial number in gas, absorption dust, reduction air, so the greening vegetation planned a city can be agreed to by gardens department.Work as temperature During reduction, in order to ensure that trees can normally survive the winter and prevent the infringement of pest and disease damage, people can brush on the trunk of trees Protective layer, relatively often uses three-in-one coating, i.e. lime water in tradition, it has certain vermins-proof effect, but insect protected is limited in scope, And easily come off, rotten bark can be invaded simultaneously, the growth to trees has certain retroaction, and heat insulation effect is not fine.People Through research, some producer develops the coating having environmental protection, using long feature of waiting so long, but its using effect need to increase By force.
Summary of the invention
It is an object of the invention to provide a kind of afforestation environmental protection insect paint and preparation method thereof, above-mentioned to solve The problem proposed in background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of afforestation environmental protection insect paint, according to the primary raw material of weight portion be: polymethyl methacrylate resin 30-40 part, isothiazolone 5-15 part, polyoxyethylene lauryl ether 12-18 part, Tissuemat E 8-10 part, diisocyanate 4-6 Part, antimony oxide 2-6 part, Pulvis Talci 1-4 part.
Further scheme as the present invention: described afforestation environmental protection insect paint, the most former according to weight portion Material is: polymethyl methacrylate resin 33-37 part, isothiazolone 8-11 part, polyoxyethylene lauryl ether 13-15 part, poly-second Alkene wax 8-10 part, diisocyanate 4-6 part, antimony oxide 2-6 part, Pulvis Talci 1-4 part.
Further scheme as the present invention: described afforestation environmental protection insect paint, the most former according to weight portion Material is: polymethyl methacrylate resin 35 parts, isothiazolone 10 parts, polyoxyethylene lauryl ether 14 parts, Tissuemat E 9 parts, Diisocyanate 5 parts, antimony oxide 4 parts, Pulvis Talci 3 parts.
Further scheme as the present invention: the purity of described isothiazolone is more than 99.9%.
Further scheme as the present invention: the purity of described polyoxyethylene lauryl ether is more than 99.9%.
Further scheme as the present invention: the mesh number of described antimony oxide is 1200 mesh.
The preparation method of a kind of afforestation environmental protection insect paint, concretely comprises the following steps:
(1) first, polymethyl methacrylate resin is entered with isothiazolone, polyoxyethylene lauryl ether, Tissuemat E Row stirring, adds diisocyanate under nitrogen protection, stirs 30min-60min at 110 DEG C-120 DEG C, and pressure is 1.0MPa-1.6MPa, makes semi-finished product;
(2) last, semi-finished product and antimony oxide, Pulvis Talci are carried out mixing stirring, speed of agitator is 320r/min, stirs The time of mixing is 30min, then centrifuge washing, vacuum lyophilization at a temperature of being subsequently placed at 4 DEG C, to obtain final product.
Further scheme as the present invention: stirring 45min in step (1) at 115 DEG C, pressure is 1.3MPa.
Compared with prior art, the invention has the beneficial effects as follows:
Use the environmental protection insect paint that this formula is made, be directly brushed on the trunk of trees, be coated with after brushing, resistance to sun Light irradiates, difficult drop-off, and vermins-proof effect is good, and all material is environment-friendly materials, to person poultry harmless.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under not making creative work premise, all Belong to the scope of protection of the invention.
Embodiment 1
A kind of afforestation environmental protection insect paint, according to the primary raw material of weight portion be: polymethyl methacrylate resin 30 parts, isothiazolone 5 parts, polyoxyethylene lauryl ether 12 parts, Tissuemat E 8 parts, diisocyanate 4 parts, antimony oxide 2 Part, Pulvis Talci 1 part;The purity of described isothiazolone is more than 99.9%;The purity of described polyoxyethylene lauryl ether is More than 99.9%;The mesh number of described antimony oxide is 1200 mesh.
The preparation method of a kind of afforestation environmental protection insect paint, concretely comprises the following steps:
(1) first, polymethyl methacrylate resin is entered with isothiazolone, polyoxyethylene lauryl ether, Tissuemat E Row stirring, adds diisocyanate under nitrogen protection, stirs 30min at 110 DEG C, and pressure is 1.0MPa, makes semi-finished product;
(2) last, semi-finished product and antimony oxide, Pulvis Talci are carried out mixing stirring, speed of agitator is 320r/min, stirs The time of mixing is 30min, then centrifuge washing, vacuum lyophilization at a temperature of being subsequently placed at 4 DEG C, to obtain final product.
Embodiment 2
A kind of afforestation environmental protection insect paint, according to the primary raw material of weight portion be: polymethyl methacrylate resin 33 parts, isothiazolone 8 parts, polyoxyethylene lauryl ether 13 parts, Tissuemat E 8 parts, diisocyanate 4 parts, antimony oxide 2 Part, Pulvis Talci 1 part;The purity of described isothiazolone is more than 99.9%;The purity of described polyoxyethylene lauryl ether is More than 99.9%;The mesh number of described antimony oxide is 1200 mesh.
The preparation method of a kind of afforestation environmental protection insect paint, concretely comprises the following steps:
(1) first, polymethyl methacrylate resin is entered with isothiazolone, polyoxyethylene lauryl ether, Tissuemat E Row stirring, adds diisocyanate under nitrogen protection, stirs 30min at 110 DEG C, and pressure is 1.0MPa, makes semi-finished product;
(2) last, semi-finished product and antimony oxide, Pulvis Talci are carried out mixing stirring, speed of agitator is 320r/min, stirs The time of mixing is 30min, then centrifuge washing, vacuum lyophilization at a temperature of being subsequently placed at 4 DEG C, to obtain final product.
Embodiment 3
A kind of afforestation environmental protection insect paint, according to the primary raw material of weight portion be: polymethyl methacrylate resin 35 parts, isothiazolone 10 parts, polyoxyethylene lauryl ether 14 parts, Tissuemat E 9 parts, diisocyanate 5 parts, antimony oxide 4 parts, Pulvis Talci 3 parts;The purity of described isothiazolone is more than 99.9%;The purity of described polyoxyethylene lauryl ether is More than 99.9%;The mesh number of described antimony oxide is 1200 mesh.
The preparation method of a kind of afforestation environmental protection insect paint, concretely comprises the following steps:
(1) first, polymethyl methacrylate resin is entered with isothiazolone, polyoxyethylene lauryl ether, Tissuemat E Row stirring, adds diisocyanate under nitrogen protection, stirs 45min at 115 DEG C, and pressure is 1.3MPa, makes semi-finished product;
(2) last, semi-finished product and antimony oxide, Pulvis Talci are carried out mixing stirring, speed of agitator is 320r/min, stirs The time of mixing is 30min, then centrifuge washing, vacuum lyophilization at a temperature of being subsequently placed at 4 DEG C, to obtain final product.
Embodiment 4
A kind of afforestation environmental protection insect paint, according to the primary raw material of weight portion be: polymethyl methacrylate resin 37 parts, isothiazolone 11 parts, polyoxyethylene lauryl ether 15 parts, Tissuemat E 10 parts, diisocyanate 6 parts, three oxidation two 6 parts of antimony, Pulvis Talci 4 parts;The purity of described isothiazolone is more than 99.9%;The purity of described polyoxyethylene lauryl ether is More than 99.9%;The mesh number of described antimony oxide is 1200 mesh.
The preparation method of a kind of afforestation environmental protection insect paint, concretely comprises the following steps:
(1) first, polymethyl methacrylate resin is entered with isothiazolone, polyoxyethylene lauryl ether, Tissuemat E Row stirring, adds diisocyanate under nitrogen protection, stirs 60min at 120 DEG C, and pressure is 1.6MPa, makes semi-finished product;
(2) last, semi-finished product and antimony oxide, Pulvis Talci are carried out mixing stirring, speed of agitator is 320r/min, stirs The time of mixing is 30min, then centrifuge washing, vacuum lyophilization at a temperature of being subsequently placed at 4 DEG C, to obtain final product.
Embodiment 5
A kind of afforestation environmental protection insect paint, according to the primary raw material of weight portion be: polymethyl methacrylate resin 40 parts, isothiazolone 15 parts, polyoxyethylene lauryl ether 18 parts, Tissuemat E 10 parts, diisocyanate 6 parts, three oxidation two 6 parts of antimony, Pulvis Talci 4 parts;The purity of described isothiazolone is more than 99.9%;The purity of described polyoxyethylene lauryl ether is More than 99.9%;The mesh number of described antimony oxide is 1200 mesh.
The preparation method of a kind of afforestation environmental protection insect paint, concretely comprises the following steps:
(1) first, polymethyl methacrylate resin is entered with isothiazolone, polyoxyethylene lauryl ether, Tissuemat E Row stirring, adds diisocyanate under nitrogen protection, stirs 60min at 120 DEG C, and pressure is 1.6MPa, makes semi-finished product;
(2) last, semi-finished product and antimony oxide, Pulvis Talci are carried out mixing stirring, speed of agitator is 320r/min, stirs The time of mixing is 30min, then centrifuge washing, vacuum lyophilization at a temperature of being subsequently placed at 4 DEG C, to obtain final product.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of the spirit or essential attributes of the present invention, it is possible to realize the present invention in other specific forms.Therefore, no matter From the point of view of which point, all should regard embodiment as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all by fall in the implication of equivalency and scope of claim Change is included in the present invention.
Although moreover, it will be appreciated that this specification is been described by according to embodiment, but the most each embodiment only wraps Containing an independent technical scheme, this narrating mode of description is only that for clarity sake those skilled in the art should Description can also be formed those skilled in the art through appropriately combined as an entirety, the technical scheme in each embodiment May be appreciated other embodiments.

Claims (8)

1. an afforestation environmental protection insect paint, it is characterised in that according to the primary raw material of weight portion be: methacrylic acid Late resin 30-40 part, isothiazolone 5-15 part, polyoxyethylene lauryl ether 12-18 part, Tissuemat E 8-10 part, two different Cyanate 4-6 part, antimony oxide 2-6 part, Pulvis Talci 1-4 part.
Afforestation environmental protection insect paint the most according to claim 1, it is characterised in that described afforestation environmental protection Insect paint, according to the primary raw material of weight portion be: polymethyl methacrylate resin 33-37 part, isothiazolone 8-11 part, the moon Cinnamic alcohol polyoxyethylene ether 13-15 part, Tissuemat E 8-10 part, diisocyanate 4-6 part, antimony oxide 2-6 part, Pulvis Talci 1- 4 parts.
Afforestation environmental protection insect paint the most according to claim 1 and 2, it is characterised in that described afforestation is used Environmental protection insect paint, according to the primary raw material of weight portion be: polymethyl methacrylate resin 35 parts, isothiazolone 10 part, month Cinnamic alcohol polyoxyethylene ether 14 parts, Tissuemat E 9 parts, diisocyanate 5 parts, antimony oxide 4 parts, Pulvis Talci 3 parts.
Afforestation environmental protection insect paint the most according to claim 3, it is characterised in that described isothiazolone pure Degree is more than 99.9%.
Afforestation environmental protection insect paint the most according to claim 4, it is characterised in that described lauryl alcohol polyethylene glycol oxide The purity of ether is more than 99.9%.
Afforestation environmental protection insect paint the most according to claim 5, it is characterised in that the mesh of described antimony oxide Number is 1200 mesh.
7. the preparation method of the afforestation environmental protection insect paint as described in claim 1-6 is arbitrary, it is characterised in that Concretely comprise the following steps:
(1) first, polymethyl methacrylate resin is stirred with isothiazolone, polyoxyethylene lauryl ether, Tissuemat E Mixing, add diisocyanate under nitrogen protection, stir 30min-60min at 110 DEG C-120 DEG C, pressure is 1.0MPa- 1.6MPa, makes semi-finished product;
(2) last, semi-finished product and antimony oxide, Pulvis Talci are carried out mixing stirring, speed of agitator is 320r/min, during stirring Between be 30min, then centrifuge washing, vacuum lyophilization at a temperature of being subsequently placed at 4 DEG C, to obtain final product.
The preparation method of afforestation environmental protection insect paint the most according to claim 7, it is characterised in that step (1) In at 115 DEG C stir 45min, pressure is 1.3MPa.
CN201610740373.1A 2016-08-26 2016-08-26 A kind of afforestation environmental protection insect paint and preparation method thereof Pending CN106085073A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610740373.1A CN106085073A (en) 2016-08-26 2016-08-26 A kind of afforestation environmental protection insect paint and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610740373.1A CN106085073A (en) 2016-08-26 2016-08-26 A kind of afforestation environmental protection insect paint and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106700804A (en) * 2016-12-05 2017-05-24 钦州市钦南区生产力促进中心 Insect repelling coating for greening and preparation method thereof
CN108300075A (en) * 2017-09-15 2018-07-20 南通盛赫园林古建筑工程有限公司 A kind of environmentally friendly insect paint of afforestation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106700804A (en) * 2016-12-05 2017-05-24 钦州市钦南区生产力促进中心 Insect repelling coating for greening and preparation method thereof
CN108300075A (en) * 2017-09-15 2018-07-20 南通盛赫园林古建筑工程有限公司 A kind of environmentally friendly insect paint of afforestation

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Application publication date: 20161109

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