CN106082803A - A kind of materials for wall of energy-conserving and environment-protective and preparation method thereof - Google Patents
A kind of materials for wall of energy-conserving and environment-protective and preparation method thereof Download PDFInfo
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- CN106082803A CN106082803A CN201610407084.XA CN201610407084A CN106082803A CN 106082803 A CN106082803 A CN 106082803A CN 201610407084 A CN201610407084 A CN 201610407084A CN 106082803 A CN106082803 A CN 106082803A
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- tetramethylolmethane
- sulfide isobutene
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/001—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/18—Waste materials; Refuse organic
- C04B18/24—Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
- C04B18/248—Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork from specific plants, e.g. hemp fibres
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00008—Obtaining or using nanotechnology related materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Civil Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Botany (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses materials for wall of a kind of energy-conserving and environment-protective and preparation method thereof, be prepared from by the raw material of following weight portion: precipitated calcium carbonate, 15～25 parts；Bentonite, 25～35 parts；Kaolin, 5～15 parts；Silicon ash, 5～15 parts；Triethanolamine, 3～5 parts；Cotton stalk, 20～30 parts；Polyethylene Glycol, 6～8 parts；Aluminum isopropylate., 2～4 parts；Nano silicon, 7～9 parts；Tetramethylolmethane and sulfide isobutene totally 6～8 parts, the weight ratio of tetramethylolmethane and sulfide isobutene is 5～7:1.The materials for wall that the present invention provides uses the raw materials such as straw to be prepared from, energy-conserving and environment-protective, and insulation, soundproof effect are the best.This technique effect is relevant with the weight ratio of tetramethylolmethane in raw material and sulfide isobutene, the best performance when weight ratio of tetramethylolmethane and sulfide isobutene is 5～7:1.
Description
Technical field
The present invention relates to environment-friendly materials, be specifically related to materials for wall of a kind of energy-conserving and environment-protective and preparation method thereof.
Background technology
A large amount of cotton straws produced by a large amount of Fructus Citri tangerinae bars, particularly Cotton in China producing region produced by agricultural production at present,
One be chopping and returning as fertilizer, but the life-time service of this kind of processing method, can increase crop pest occur possibility, its profit
Value relatively low；Two is as fuel, and its value utilized is greatly lowered, and also have is then as offal treatment, as
Burning disposal, had both caused the waste of resource, had polluted again environment.
At present, the research that use straw prepares energy-conservation environmental protection wall material is less, the heat insulation property of made materials for wall
Can be poor.
Summary of the invention
It is an object of the invention to provide materials for wall of a kind of energy-conserving and environment-protective and preparation method thereof.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
The materials for wall of a kind of energy-conserving and environment-protective, is prepared from by the raw material of following weight portion: precipitated calcium carbonate, 15～25
Part；Bentonite, 25～35 parts；Kaolin, 5～15 parts；Silicon ash, 5～15 parts；Triethanolamine, 3～5 parts；Cotton stalk, 20～
30 parts；Polyethylene Glycol, 6～8 parts；Aluminum isopropylate., 2～4 parts；Nano silicon, 7～9 parts；Tetramethylolmethane and sulfide isobutene
Totally 6～8 parts, the weight ratio of tetramethylolmethane and sulfide isobutene is 5～7:1.
Further, described materials for wall is prepared from by the raw material of following weight portion: precipitated calcium carbonate, 20 parts；
Bentonite, 30 parts；Kaolin, 10 parts；Silicon ash, 10 parts；Triethanolamine, 4 parts；Cotton stalk, 25 parts；Polyethylene Glycol, 7 parts；Different
Aluminum tripropoxide, 3 parts；Nano silicon, 8 parts；Tetramethylolmethane and sulfide isobutene totally 7 parts, tetramethylolmethane and sulfide isobutene
Weight ratio is 6:1.
Further, described materials for wall is prepared from by the raw material of following weight portion: precipitated calcium carbonate, 15 parts；
Bentonite, 25 parts；Kaolin, 5 parts；Silicon ash, 5 parts；Triethanolamine, 3 parts；Cotton stalk, 20 parts；Polyethylene Glycol, 6 parts；Isopropyl
Aluminium alcoholates, 2 parts；Nano silicon, 7 parts；Tetramethylolmethane and sulfide isobutene totally 6 parts, tetramethylolmethane and the weight of sulfide isobutene
The ratio of amount part is 5:1.
Further, described materials for wall is prepared from by the raw material of following weight portion: precipitated calcium carbonate, 25 parts；
Bentonite, 35 parts；Kaolin, 15 parts；Silicon ash, 15 parts；Triethanolamine, 5 parts；Cotton stalk, 30 parts；Polyethylene Glycol, 8 parts；Different
Aluminum tripropoxide, 4 parts；Nano silicon, 9 parts；Tetramethylolmethane and sulfide isobutene totally 8 parts, tetramethylolmethane and sulfide isobutene
Weight ratio is 7:1.
The preparation method of above-mentioned materials for wall, comprises the steps:
Step S1, is ground into the cotton stalk powder of 700～900 μm particle diameters by dry cotton stalk；
Step S2, by cotton stalk powder and precipitated calcium carbonate, bentonite, Kaolin, silicon ash, aluminum isopropylate., nano-silica
SiClx mixes, and stir to obtain mixed-powder；
Step S3, adds triethanolamine, Polyethylene Glycol, tetramethylolmethane and sulfide isobutene in mixed-powder, inserts crowded
Pressing machine is extruded and get final product under 10～14Mpa pressure.
Advantages of the present invention:
The materials for wall that the present invention provides uses the raw materials such as straw to be prepared from, energy-conserving and environment-protective, and insulation, sound insulation
Effect is the best.This technique effect is relevant with the weight ratio of tetramethylolmethane in raw material and sulfide isobutene, Ji Wusi
The best performance when weight ratio of alcohol and sulfide isobutene is 5～7:1.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit the present invention with this and protect model
Enclose.Although the present invention being explained in detail with reference to preferred embodiment, it will be understood by those within the art that, can be right
Technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: the preparation of energy-conservation environmental protection wall material
Parts by weight of raw materials compares:
Precipitated calcium carbonate, 20 parts；Bentonite, 30 parts；Kaolin, 10 parts；Silicon ash, 10 parts；Triethanolamine, 4 parts；Cotton Gossypii straw
Stalk, 25 parts；Polyethylene Glycol, 7 parts；Aluminum isopropylate., 3 parts；Nano silicon, 8 parts；Tetramethylolmethane and sulfide isobutene totally 7 parts,
The weight ratio of tetramethylolmethane and sulfide isobutene is 6:1.
Preparation method:
Step S1, is ground into the cotton stalk powder of 700～900 μm particle diameters by dry cotton stalk；
Step S2, by cotton stalk powder and precipitated calcium carbonate, bentonite, Kaolin, silicon ash, aluminum isopropylate., nano-silica
SiClx mixes, and stir to obtain mixed-powder；
Step S3, adds triethanolamine, Polyethylene Glycol, tetramethylolmethane and sulfide isobutene in mixed-powder, inserts crowded
Pressing machine is extruded and get final product under 12Mpa pressure.
Embodiment 2: the preparation of energy-conservation environmental protection wall material
Parts by weight of raw materials compares:
Precipitated calcium carbonate, 15 parts；Bentonite, 25 parts；Kaolin, 5 parts；Silicon ash, 5 parts；Triethanolamine, 3 parts；Cotton Gossypii straw
Stalk, 20 parts；Polyethylene Glycol, 6 parts；Aluminum isopropylate., 2 parts；Nano silicon, 7 parts；Tetramethylolmethane and sulfide isobutene totally 6 parts,
The weight ratio of tetramethylolmethane and sulfide isobutene is 5:1.
Preparation method:
Step S1, is ground into the cotton stalk powder of 700～900 μm particle diameters by dry cotton stalk；
Step S2, by cotton stalk powder and precipitated calcium carbonate, bentonite, Kaolin, silicon ash, aluminum isopropylate., nano-silica
SiClx mixes, and stir to obtain mixed-powder；
Step S3, adds triethanolamine, Polyethylene Glycol, tetramethylolmethane and sulfide isobutene in mixed-powder, inserts crowded
Pressing machine is extruded and get final product under 12Mpa pressure.
Embodiment 3: the preparation of energy-conservation environmental protection wall material
Parts by weight of raw materials compares:
Precipitated calcium carbonate, 25 parts；Bentonite, 35 parts；Kaolin, 15 parts；Silicon ash, 15 parts；Triethanolamine, 5 parts；Cotton Gossypii straw
Stalk, 30 parts；Polyethylene Glycol, 8 parts；Aluminum isopropylate., 4 parts；Nano silicon, 9 parts；Tetramethylolmethane and sulfide isobutene totally 8 parts,
The weight ratio of tetramethylolmethane and sulfide isobutene is 7:1.
Preparation method:
Step S1, is ground into the cotton stalk powder of 700～900 μm particle diameters by dry cotton stalk；
Step S2, by cotton stalk powder and precipitated calcium carbonate, bentonite, Kaolin, silicon ash, aluminum isopropylate., nano-silica
SiClx mixes, and stir to obtain mixed-powder；
Step S3, adds triethanolamine, Polyethylene Glycol, tetramethylolmethane and sulfide isobutene in mixed-powder, inserts crowded
Pressing machine is extruded and get final product under 12Mpa pressure.
Embodiment 4: the preparation of energy-conservation environmental protection wall material
Parts by weight of raw materials compares:
Precipitated calcium carbonate, 20 parts；Bentonite, 30 parts；Kaolin, 10 parts；Silicon ash, 10 parts；Triethanolamine, 4 parts；Cotton Gossypii straw
Stalk, 25 parts；Polyethylene Glycol, 7 parts；Aluminum isopropylate., 3 parts；Nano silicon, 8 parts；Tetramethylolmethane and sulfide isobutene totally 7 parts,
The weight ratio of tetramethylolmethane and sulfide isobutene is 5:1.
Preparation method:
Step S1, is ground into the cotton stalk powder of 700～900 μm particle diameters by dry cotton stalk；
Step S2, by cotton stalk powder and precipitated calcium carbonate, bentonite, Kaolin, silicon ash, aluminum isopropylate., nano-silica
SiClx mixes, and stir to obtain mixed-powder；
Step S3, adds triethanolamine, Polyethylene Glycol, tetramethylolmethane and sulfide isobutene in mixed-powder, inserts crowded
Pressing machine is extruded and get final product under 12Mpa pressure.
Embodiment 5: the preparation of energy-conservation environmental protection wall material
Parts by weight of raw materials compares:
Precipitated calcium carbonate, 20 parts；Bentonite, 30 parts；Kaolin, 10 parts；Silicon ash, 10 parts；Triethanolamine, 4 parts；Cotton Gossypii straw
Stalk, 25 parts；Polyethylene Glycol, 7 parts；Aluminum isopropylate., 3 parts；Nano silicon, 8 parts；Tetramethylolmethane and sulfide isobutene totally 7 parts,
The weight ratio of tetramethylolmethane and sulfide isobutene is 7:1.
Preparation method:
Step S1, is ground into the cotton stalk powder of 700～900 μm particle diameters by dry cotton stalk；
Step S2, by cotton stalk powder and precipitated calcium carbonate, bentonite, Kaolin, silicon ash, aluminum isopropylate., nano-silica
SiClx mixes, and stir to obtain mixed-powder；
Step S3, adds triethanolamine, Polyethylene Glycol, tetramethylolmethane and sulfide isobutene in mixed-powder, inserts crowded
Pressing machine is extruded and get final product under 12Mpa pressure.
The weight ratio of embodiment 6: comparative example, tetramethylolmethane and sulfide isobutene is 4:1
Parts by weight of raw materials compares:
Precipitated calcium carbonate, 20 parts；Bentonite, 30 parts；Kaolin, 10 parts；Silicon ash, 10 parts；Triethanolamine, 4 parts；Cotton Gossypii straw
Stalk, 25 parts；Polyethylene Glycol, 7 parts；Aluminum isopropylate., 3 parts；Nano silicon, 8 parts；Tetramethylolmethane and sulfide isobutene totally 7 parts,
The weight ratio of tetramethylolmethane and sulfide isobutene is 4:1.
Preparation method:
Step S1, is ground into the cotton stalk powder of 700～900 μm particle diameters by dry cotton stalk；
Step S2, by cotton stalk powder and precipitated calcium carbonate, bentonite, Kaolin, silicon ash, aluminum isopropylate., nano-silica
SiClx mixes, and stir to obtain mixed-powder；
Step S3, adds triethanolamine, Polyethylene Glycol, tetramethylolmethane and sulfide isobutene in mixed-powder, inserts crowded
Pressing machine is extruded and get final product under 12Mpa pressure.
The weight ratio of embodiment 7: comparative example, tetramethylolmethane and sulfide isobutene is 8:1
Parts by weight of raw materials compares:
Precipitated calcium carbonate, 20 parts；Bentonite, 30 parts；Kaolin, 10 parts；Silicon ash, 10 parts；Triethanolamine, 4 parts；Cotton Gossypii straw
Stalk, 25 parts；Polyethylene Glycol, 7 parts；Aluminum isopropylate., 3 parts；Nano silicon, 8 parts；Tetramethylolmethane and sulfide isobutene totally 7 parts,
The weight ratio of tetramethylolmethane and sulfide isobutene is 8:1.
Preparation method:
Step S1, is ground into the cotton stalk powder of 700～900 μm particle diameters by dry cotton stalk；
Step S2, by cotton stalk powder and precipitated calcium carbonate, bentonite, Kaolin, silicon ash, aluminum isopropylate., nano-silica
SiClx mixes, and stir to obtain mixed-powder；
Step S3, adds triethanolamine, Polyethylene Glycol, tetramethylolmethane and sulfide isobutene in mixed-powder, inserts crowded
Pressing machine is extruded and get final product under 12Mpa pressure.
Embodiment 8: effect example
The heat conductivity of the material of testing example 1～7 preparation and sound insulation value.
Result is as follows:
| Test sample | Heat conductivity (W/m k) | Sound insulation coefficient (frequency of sound wave is 5KHz) |
| Embodiment 1 | 0.030 | 1.89 |
| Embodiment 4 | 0.035 | 1.83 |
| Embodiment 5 | 0.034 | 1.85 |
| Embodiment 6 | 0.099 | 0.92 |
| Embodiment 7 | 0.096 | 0.94 |
Embodiment 2,3 test result is basically identical with embodiment 4,5.
Heat preserving and insulating material is divided into by heat conductivity: adiabator (heat conductivity λ ＜ 0.23W/m k)；Insulation material
(heat conductivity λ ＜ 0.14W/m k)；Thermal insulation material (heat conductivity λ≤0.05W/m k).
The above results shows, the materials for wall that the present invention provides uses the raw materials such as straw to be prepared from, energy-conserving and environment-protective, and
Insulation, soundproof effect are the best.In this technique effect and raw material the weight portion of tetramethylolmethane and sulfide isobutene it
Ratio is relevant, the best performance when weight ratio of tetramethylolmethane and sulfide isobutene is 5～7:1.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit the protection of the present invention with this
Scope.It will be understood by those within the art that, technical scheme can be modified or equivalent,
Essence and protection domain without deviating from technical solution of the present invention.
Claims (5)
1. the materials for wall of energy-conserving and environment-protective, it is characterised in that be prepared from by the raw material of following weight portion: lightweight carbonic acid
Calcium, 15～25 parts；Bentonite, 25～35 parts；Kaolin, 5～15 parts；Silicon ash, 5～15 parts；Triethanolamine, 3～5 parts；Cotton Gossypii
Straw, 20～30 parts；Polyethylene Glycol, 6～8 parts；Aluminum isopropylate., 2～4 parts；Nano silicon, 7～9 parts；Tetramethylolmethane and
Sulfide isobutene totally 6～8 parts, the weight ratio of tetramethylolmethane and sulfide isobutene is 5～7:1.
Materials for wall the most according to claim 1, it is characterised in that be prepared from by the raw material of following weight portion: light
Matter calcium carbonate, 20 parts；Bentonite, 30 parts；Kaolin, 10 parts；Silicon ash, 10 parts；Triethanolamine, 4 parts；Cotton stalk, 25 parts；Poly-
Ethylene glycol, 7 parts；Aluminum isopropylate., 3 parts；Nano silicon, 8 parts；Tetramethylolmethane and sulfide isobutene totally 7 parts, tetramethylolmethane and
The weight ratio of sulfide isobutene is 6:1.
Materials for wall the most according to claim 1, it is characterised in that be prepared from by the raw material of following weight portion: light
Matter calcium carbonate, 15 parts；Bentonite, 25 parts；Kaolin, 5 parts；Silicon ash, 5 parts；Triethanolamine, 3 parts；Cotton stalk, 20 parts；Poly-second
Glycol, 6 parts；Aluminum isopropylate., 2 parts；Nano silicon, 7 parts；Tetramethylolmethane and sulfide isobutene totally 6 parts, tetramethylolmethane and sulfur
The weight ratio changing isobutene. is 5:1.
Materials for wall the most according to claim 1, it is characterised in that be prepared from by the raw material of following weight portion: light
Matter calcium carbonate, 25 parts；Bentonite, 35 parts；Kaolin, 15 parts；Silicon ash, 15 parts；Triethanolamine, 5 parts；Cotton stalk, 30 parts；Poly-
Ethylene glycol, 8 parts；Aluminum isopropylate., 4 parts；Nano silicon, 9 parts；Tetramethylolmethane and sulfide isobutene totally 8 parts, tetramethylolmethane and
The weight ratio of sulfide isobutene is 7:1.
5. the preparation method of the arbitrary described materials for wall of Claims 1 to 4, it is characterised in that comprise the steps:
Step S1, is ground into the cotton stalk powder of 700～900 μm particle diameters by dry cotton stalk；
Step S2, by cotton stalk powder and precipitated calcium carbonate, bentonite, Kaolin, silicon ash, aluminum isopropylate., nano silicon
Mixing, stir to obtain mixed-powder；
Step S3, adds triethanolamine, Polyethylene Glycol, tetramethylolmethane and sulfide isobutene in mixed-powder, inserts and be squeezed into
Type machine is extruded and get final product under 10～14Mpa pressure.
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| WO2015130311A1 (en) * | 2014-02-28 | 2015-09-03 | Halliburton Energy Services, Inc. | Tunable control of pozzolan-lime cement compositions |
| CN104909605A (en) * | 2015-05-25 | 2015-09-16 | 重庆市建筑科学研究院 | Composite admixture for high strength concrete and preparation method thereof |
| CN105198370A (en) * | 2015-09-16 | 2015-12-30 | 安徽省中正农业科技开发有限公司 | High-strength biomass wall and production process thereof |
-
2016
- 2016-06-08 CN CN201610407084.XA patent/CN106082803A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102225861A (en) * | 2011-03-18 | 2011-10-26 | 余建国 | Baking-free plant straw building wall material and production method thereof |
| CN103509226A (en) * | 2013-09-24 | 2014-01-15 | 安徽省三乐门窗幕墙工程有限公司 | Wood-plastic composite material and preparation method thereof |
| CN103602234A (en) * | 2013-10-28 | 2014-02-26 | 安徽祈艾特电子科技有限公司 | Alkyd resin waterproof paint |
| WO2015130311A1 (en) * | 2014-02-28 | 2015-09-03 | Halliburton Energy Services, Inc. | Tunable control of pozzolan-lime cement compositions |
| CN104909605A (en) * | 2015-05-25 | 2015-09-16 | 重庆市建筑科学研究院 | Composite admixture for high strength concrete and preparation method thereof |
| CN105198370A (en) * | 2015-09-16 | 2015-12-30 | 安徽省中正农业科技开发有限公司 | High-strength biomass wall and production process thereof |
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Application publication date: 20161109 |