CN106079764A - Fenestrated membrane and processing technology thereof - Google Patents

Fenestrated membrane and processing technology thereof Download PDF

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Publication number
CN106079764A
CN106079764A CN201610472999.9A CN201610472999A CN106079764A CN 106079764 A CN106079764 A CN 106079764A CN 201610472999 A CN201610472999 A CN 201610472999A CN 106079764 A CN106079764 A CN 106079764A
Authority
CN
China
Prior art keywords
fenestrated membrane
composite bed
weight
percentage
polyurethane adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610472999.9A
Other languages
Chinese (zh)
Inventor
蔡志强
韩雪云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HAIAN HAOCHI SCIENCE & TECHNOLOGY Co Ltd
Original Assignee
HAIAN HAOCHI SCIENCE & TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HAIAN HAOCHI SCIENCE & TECHNOLOGY Co Ltd filed Critical HAIAN HAOCHI SCIENCE & TECHNOLOGY Co Ltd
Priority to CN201610472999.9A priority Critical patent/CN106079764A/en
Publication of CN106079764A publication Critical patent/CN106079764A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/033 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/40Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/552Fatigue strength

Landscapes

  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of fenestrated membrane and processing technology thereof, fenestrated membrane includes two PET base material layer and composite bed, and composite bed is between two PET base material layer, and wherein composite bed has polyurethane adhesive.Consequently, it is possible to polyurethane adhesive can make there is the most firm bonding between PET base material layer, and significantly extend the service life of fenestrated membrane, and fenestrated membrane appearance looks elegant, without open defects such as any glue stricture of vagina, bubble, Pericarpium Citri tangerinaes.

Description

Fenestrated membrane and processing technology thereof
Technical field
The present invention relates to fenestrated membrane field, particularly one has the ground fenestrated membranes such as preferable temperature resistance, resistance to ag(e)ing, feel fragility And processing technology.
Background technology
Current fenestrated membrane product be all pressure-sensitive acrylate be main, and add the materials such as corresponding dyestuff, auxiliary agent with Manufacture fenestrated membrane product.But, these product loss of properties on agings, feel are the softest, and outward appearance is the most defective, such as Pericarpium Citri tangerinae stricture of vagina, glue Stricture of vagina, bubble etc., thus still greatly improve space.
Therefore, the shortcoming how improving above-mentioned fenestrated membrane, is to solve the technical problem that needed for those skilled in the art.
Summary of the invention
For above-mentioned the deficiencies in the prior art, the invention provides a kind of fenestrated membrane and processing technology thereof, solve Fenestrated membrane loss of properties on aging, feel be the softest and the easy defective problem of outward appearance.
The present invention provides a kind of fenestrated membrane, and fenestrated membrane includes two PET base material layer and composite bed, and composite bed is positioned at two PET base material Between Ceng, wherein composite bed has polyurethane adhesive.
Preferably, polyurethane adhesive includes polyurethane, tungsten trioxide nano particle, dispersant and solvent.
Preferably, the percentage by weight of polyurethane is 2%-5%.
Preferably, the percentage by weight of Tungstic anhydride. is 10%-20%.
Preferably, the percentage by weight of dispersant is 2%-10%.
The present invention also provides for the processing technology of a fenestrated membrane, and processing technology comprises the steps of and composite bed is bonding on two PET Between substrate layer, wherein composite bed has polyurethane adhesive.
Preferably, polyurethane adhesive includes polyurethane, tungsten trioxide nano particle, dispersant and solvent.
Preferably, the percentage by weight of polyurethane is 2%-5%.
Preferably, the percentage by weight of Tungstic anhydride. is 10%-20%.
Preferably, the percentage by weight of dispersant is 2%-10%.
Fenestrated membrane and processing technology thereof that the present invention provides at least have the advantages that
(1) present invention uses polyurethane adhesive can make between PET base material layer the most firm bonding, and significantly extends The service life of fenestrated membrane, and fenestrated membrane appearance looks elegant, without open defects such as any glue stricture of vagina, bubble, Pericarpium Citri tangerinaes.
(2) present invention uses polyurethane adhesive that the composite bed of fenestrated membrane can be made to be fully achieved complete heat cure effect, fenestrated membrane Overall performance more stable, superior.Fenestrated membrane outward appearance is more smooth, clear, transparent, and has superior feel fragility and construction party Just property, has wide market prospect and use value.
Accompanying drawing explanation
Accompanying drawing described herein is used for providing a further understanding of the present invention, constitutes the part of the present invention, this Bright schematic description and description is used for explaining the present invention, is not intended that inappropriate limitation of the present invention.In the accompanying drawings:
Fig. 1 is the structural representation of the fenestrated membrane of the present invention.
Detailed description of the invention
In order to make those skilled in the art be more fully understood that technical scheme, below in conjunction with detailed description of the invention The present invention is described in further detail.
First, the structural representation that Fig. 1, Fig. 1 are the fenestrated membranes of the present invention is referred to.
Fenestrated membrane 1 includes two PET base material layer 11,13 and composite beds 12, composite bed 12 be positioned at two PET base material layer 11,13 it Between.Wherein composite bed 12 has polyurethane adhesive, thereby there to be the most firm bonding between PET base material layer 11,13.
Specifically, PET base material layer 11,13 used in the present invention is the PET base material of optical grade, and polyurethane adhesive Then distinguished for having the high grade of transparency, the performance such as aging Dupont material.
Furthermore, containing urethano (NHCOO) and/or NCO (-NCO) in polyurethane (PU) strand. Wherein NCO and the polarity of urethano, chemism are the strongest, therefore have good chemical adhesion, and have The advantages such as the feel fragility that temperature resistance energy is excellent, resistance to ag(e)ing is high and good.
It is as noted previously, as composite bed 12 and there is polyurethane adhesive, and polyurethane adhesive can strengthen PET base material layer 11, the caking property between 13, thus can significantly extend the service life of fenestrated membrane 1, and fenestrated membrane 1 appearance looks elegant, without any glue stricture of vagina, gas The open defects such as bubble, Pericarpium Citri tangerinae, that is effectively improve fenestrated membrane problem encountered in prior art.
Specifically, polyurethane adhesive includes polyurethane, tungsten trioxide nano particle, dispersant and solvent.At this In embodiment, the dispersant used is sodium polyacrylate, and solvent is ethyl acetate, but the present invention is not limited thereto.Wherein, Tungsten trioxide nano particle can further improve the heat-resisting effect of prepared fenestrated membrane.
In the present embodiment and other embodiments of part, the percentage by weight of polyurethane is 2%-5%, above-mentioned weight percent Ratio is on the basis of the gross weight of solution.The percentage by weight of dispersant is such as 2%, 3%, 4%, 5%.
In the present embodiment and other embodiments of part, the percentage by weight of Tungstic anhydride. is 10%-20%, above-mentioned weight Percentage ratio is on the basis of the gross weight of solution.Specifically, the percentage by weight of Tungstic anhydride. be such as 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18%, 19%, 20%.
In the present embodiment and other embodiments of part, the percentage by weight of dispersant is 2%-10%, above-mentioned weight hundred Proportion by subtraction is on the basis of the gross weight of solution.The percentage by weight of dispersant is such as 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%.
Also please note that, owing to polyurethane, Tungstic anhydride. and dispersant have said ratio relation, thus obtained Nano tungsten trioxide performance more stable.
The processing technology of the fenestrated membrane of the present invention introduced below.Processing technology comprises the steps of and composite bed is bonding on two Between PET base material layer, wherein composite bed has polyurethane adhesive.
Specifically, first the formula of polyurethane adhesive is weighed, feeds, stirs.Operating ambient temperature is 23-25 degree, Humidity is 50-65%.Mixing speed is 500rpm, and the viscosity after stirring is 120cps.Wherein, the formula of polyurethane adhesive is such as Upper described, therefore not repeated description.
Then, use MG coating method, the characteristic of bond material, need to adjust the temperature 50-80 degree of baking oven.Due to coating Very thin thickness (coating thickness 3 microns), the surface levelling to material, coating homogeneity etc. has the highest requirement.
Then, using electrical heating to carry out that composite roll carries out heating compound, heating-up temperature is 50-60 degree, in order to PET film energy Enough sufficiently laminatings.
Then, through curing oven after product coating and compound through precision;It is wound into the semi-finished product of needs.Produce speed Degree is 15-20m/min.
Then carry out ripening, semi-finished product are carried out ripening, so that the most completely crued part of product fully solidifies, reach steady Fixed product quality requirement.
Finally, semi-finished product are carried out the coating of acrylate pressure-sensitive adhesive, and the another side of semi-finished product is carried out UV coating painting Cloth, and carry out UV photocuring.To reach case-hardened purpose.Require that hardness reaches more than 3H.
So, the preparation of the fenestrated membrane product of the present invention is i.e. completed.
Fenestrated membrane and processing technology thereof that the present invention provides at least have the advantages that
(1) present invention uses polyurethane adhesive can make between PET base material layer the most firm bonding, and significantly extends The service life of fenestrated membrane, and fenestrated membrane appearance looks elegant, without open defects such as any glue stricture of vagina, bubble, Pericarpium Citri tangerinaes.
(2) present invention uses polyurethane adhesive that the composite bed of fenestrated membrane can be made to be fully achieved complete heat cure effect, fenestrated membrane Overall performance more stable, superior.Fenestrated membrane outward appearance is more smooth, clear, transparent, and has superior feel fragility and construction party Just property, has wide market prospect and use value.
(3) properties of transparency product is to fenestrated membrane market with revolutionary cognitive experience, is keeping the heat-proof quality that product is good, Intercept outside ultraviolet performance.Improve the outward appearance of fenestrated membrane product completely, it is to avoid the bad defect of outward appearance, apply at the vehicles On, client can be made to have more comfortable visual experience in driving procedure.Additionally, the definition of fenestrated membrane product, ageing-resistant performance etc. Also it is obviously improved, extends service life.Product also has good feel fragility and construction convenience, brings to work progress The biggest convenience.
Principle and the embodiment of the present invention are set forth by specific case used herein, saying of above example The bright core concept being only intended to help to understand the present invention.It should be pointed out that, for those skilled in the art, Under the premise without departing from the principles of the invention, it is also possible to the present invention is carried out some improvement and modification.These improve and modify also Should fall in the protection domain of the claims in the present invention.

Claims (10)

1. a fenestrated membrane, it is characterised in that include that two PET base material layer and composite bed, described composite bed are positioned at described two PET bases Between sheet material layers, wherein said composite bed has polyurethane adhesive.
Fenestrated membrane the most according to claim 1, it is characterised in that described polyurethane adhesive includes polyurethane, Tungstic anhydride. Nanoparticle, dispersant and solvent.
Fenestrated membrane the most according to claim 2, it is characterised in that the percentage by weight of described polyurethane is 2%-5%.
Fenestrated membrane the most according to claim 2, it is characterised in that the percentage by weight of described Tungstic anhydride. is 10%-20%.
Fenestrated membrane the most according to claim 2, it is characterised in that the percentage by weight of described dispersant is 2%-10%.
6. the processing technology of a fenestrated membrane, it is characterised in that described processing technology comprises the steps of and composite bed is bonding on two Between PET base material layer, wherein said composite bed has polyurethane adhesive.
Technique the most according to claim 6, it is characterised in that described polyurethane adhesive includes polyurethane, Tungstic anhydride. Nanoparticle, dispersant and solvent.
Technique the most according to claim 7, it is characterised in that the percentage by weight of described polyurethane is 2%-5%.
Technique the most according to claim 7, it is characterised in that the percentage by weight of described Tungstic anhydride. is 10%-20% Water.
Technique the most according to claim 7, it is characterised in that the percentage by weight of described dispersant is 2%-10%.
CN201610472999.9A 2016-06-24 2016-06-24 Fenestrated membrane and processing technology thereof Pending CN106079764A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610472999.9A CN106079764A (en) 2016-06-24 2016-06-24 Fenestrated membrane and processing technology thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610472999.9A CN106079764A (en) 2016-06-24 2016-06-24 Fenestrated membrane and processing technology thereof

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CN106079764A true CN106079764A (en) 2016-11-09

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109177414A (en) * 2018-07-20 2019-01-11 中国航发北京航空材料研究院 A kind of compound elastomer film and preparation method with heat-proof quality

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008045013A (en) * 2006-08-14 2008-02-28 National Institute Of Advanced Industrial & Technology Light-transmitting flexible heat insulating material and method for producing the same
CN101323191A (en) * 2008-07-28 2008-12-17 金国华 Transparent anti-ultraviolet heat insulating compound film and method for preparing the same
CN102559025A (en) * 2011-11-18 2012-07-11 上海沪正纳米科技有限公司 Preparation method for high-performance transparent glass heat-insulating coating
CN104149431A (en) * 2014-08-08 2014-11-19 常州山由帝杉防护材料制造有限公司 Ultraviolet-blocking colored antifogging and heat-insulating window film
CN104175664A (en) * 2014-08-08 2014-12-03 常州山由帝杉防护材料制造有限公司 Heat insulation window film capable of blocking ultraviolet rays
CN104210197A (en) * 2014-09-25 2014-12-17 海安浩驰科技有限公司 Super-hydrophobic film and preparation method and application thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008045013A (en) * 2006-08-14 2008-02-28 National Institute Of Advanced Industrial & Technology Light-transmitting flexible heat insulating material and method for producing the same
CN101323191A (en) * 2008-07-28 2008-12-17 金国华 Transparent anti-ultraviolet heat insulating compound film and method for preparing the same
CN102559025A (en) * 2011-11-18 2012-07-11 上海沪正纳米科技有限公司 Preparation method for high-performance transparent glass heat-insulating coating
CN104149431A (en) * 2014-08-08 2014-11-19 常州山由帝杉防护材料制造有限公司 Ultraviolet-blocking colored antifogging and heat-insulating window film
CN104175664A (en) * 2014-08-08 2014-12-03 常州山由帝杉防护材料制造有限公司 Heat insulation window film capable of blocking ultraviolet rays
CN104210197A (en) * 2014-09-25 2014-12-17 海安浩驰科技有限公司 Super-hydrophobic film and preparation method and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109177414A (en) * 2018-07-20 2019-01-11 中国航发北京航空材料研究院 A kind of compound elastomer film and preparation method with heat-proof quality

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