CN101323191A - Transparent anti-ultraviolet heat insulating compound film and method for preparing the same - Google Patents
Transparent anti-ultraviolet heat insulating compound film and method for preparing the same Download PDFInfo
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Abstract
The invention relates to a transparent anti-ultraviolet heat-proof complex film with nanometer oxide and a preparation method thereof, which mainly solves technical problems of high cost, poor quality and the like that existed in the transparent film and film technique of glass surface. Technical proposal of the invention is: the transparent anti-ultraviolet heat-proof complex film, of which, the understratum is the high transparent film or glass base material, and the surface layer is the nanometer transparent heat-proof function photo-cured coating or the nanometer transparent heat-proof function pressure-sensitive adhesive; wherein, the components and parts by weight of the nanometer transparent heat-proof function photo-cured coating or the nanometer transparent heat-proof function pressure-sensitive adhesive are as follows: photo-cured resin or pressure sensitive adhesive: 50-94, nanometer powder: 3-9, surface tension accessory ingredient: 0.2-1.0, thinner: 2.0-35.0, dispersant: 0.8-5.0. The heat-proof complex film of the invention possesses not only the excellent heat isolation performance, ultraviolet radiation absorption performance, but also excellent 'penetrability'. The heat-proof complex film can be extensively used for auto windows, building windows, glass curtain walls and other occasions.
Description
Technical field:
The present invention relates to a kind of thermal isolation film and preparation method thereof, be particularly related to a kind of transparent anti-ultraviolet heat insulating compound film and preparation method who contains nano-oxide, this kind anti-ultraviolet heat insulating film not only has good thermal insulation, absorbs the ultraviolet linearity but also has good " transparency ", can be widely used in occasions such as automotive window, building window, glass curtain wall.
Background technology:
In the prior art, the heat insulation common employing Heat insulation type adhering film of glass or the method for coating film on glass solve, and the Heat insulation type adhering film high comprehensive performance, thereby obtained using comparatively widely.
Show according to data, realize that at glass surface the heat-protecting glass functional film layer all adopts the method for sputter or the method for deposition to realize, its preparation method relative complex, cost height.For example, Chinese patent application 93110358.4 discloses " preparation method of glass transparent insulating film and nozzle specially used ", adopts atmospheric pressure chemical vapor deposition technology to form transparent heat-insulated film at glass surface; Chinese patent application 200310111067.4 discloses a kind of transparent heat-insulated film, the method that it is characterized in that adopting chemical deposition or ultrasonic spray pyrolysis deposition with F, Mn element codope at glass surface depositing nano SnO, thereby obtain transparent heat-insulated film.That Chinese patent application 981 00128.9 discloses is a kind of the preparation method of frost-removing coated glass " heat insulation, ", be splashed to the light transmittance that is heated to 260-350 ℃ greater than 80% glass surface with pluging with molten metal the ashbury metal ceramic target, generate nesa coating (ITO film) through surperficial high-temperature chemical reaction with heat-proof quality.
External product generally all adopts at plastic sheeting surface sputtering metal film and inorganic oxide film and makes on automobile or building glass Heat insulation type adhering film, and this method equipment complexity and equipment and product cost are all very high.
Chinese patent publication number 1951985A is preparation nano transparent heat-insulating functional paint earlier, then coating is coated in the transparent membrane substrate surface by the mode that sprays and brush, and behind the dry solidification, obtains transparent heat-insulating film.Its preparation method is comparatively easy, transparent heat-insulating film with low cost, as to make has the good transparency and excellent effect of heat insulation simultaneously, but product coating process controllable thickness is poor, and the water-base resin of employing solidifies the back and easily dissolves to cause with basement membrane under the water logging bubble and shortcoming such as peel off.
Summary of the invention:
The purpose of this invention is to provide a kind of transparent anti-ultraviolet heat insulating compound film and preparation method, mainly solve cost height that transparent membrane and glass surface film technique exist, technical problem such as of poor quality.The composite membrane that the present invention obtains has excellent thermal insulation, absorbs ultraviolet linearity, the transparency and scratch-resistant performance.
Technical scheme of the present invention is: a kind of transparent anti-ultraviolet heat insulating compound film, be two layers or three-layer composite structure, during two-layer structure, bottom is high transparent membrane or glass baseplate, and the top layer is nano transparent heat-insulating function photocureable coating layer or nano transparent heat-insulating function pressure-sensitive adhesive coating; During three-layer composite structure, bottom is high transparent membrane or glass baseplate, the intermediate layer is nano transparent heat-insulating function photocureable coating layer or nano transparent heat-insulating function pressure-sensitive adhesive coating, the top layer is high transparent membrane or glass baseplate, and the component and the percentage by weight (%) of wherein said nano transparent heat-insulating function photocureable coating layer or nano transparent heat-insulating function pressure-sensitive adhesive coating are as follows:
Light-cured resin (or pressure sensitive adhesive) 50-94
Nano-powder (1-300nm) 3-9
Surface tension auxiliary agent 0.2-1
Diluent 2-35
Dispersant 0.8-5
Light-cured resin is one or several in light-cured acrylic resin, photocuring unsaturated-resin or the light-cured polyurethane resin in the wherein said coating; Pressure sensitive adhesive is pressure-sensitive curing acrylic glue or pressure-sensitive curing polyester glue; Nano-powder is pluged with molten metal in tin (ITO) inorganic oxide one or both with containing infrared semiconductor ceramic powder or oxidation plugs with molten metal tin (ITO) at least for containing infrared semiconductor ceramic powder or oxidation, and tri-iron tetroxide (Fe
3O
4), titanium dioxide (TiO
2), silica (SiO
2) or zinc oxide (ZnO) in any one or the combination of any two kinds of inorganic oxides, particle size range is 1-300nm; It perhaps is the organic nano transparent pigment β-type phthalocyanine blue of 8 grades of weatherabilities; Coating additive comprises a kind of of dispersant, surface tension auxiliary agent, diluent at least.Described dispersant be a kind of polymeric carboxylic polymer (polycarboxylate sodium, HT-5040); The surface tension auxiliary agent be nonionic aggretion type fluorine-containing surfactant (perfluor alkyl ethide sulfonic group salt, FSN-100); Diluent is ethyl acetate (C
2H
4O
2) or absolute ethyl alcohol (C
2H
6O); Coated substrate is transparent PVC, PVB, PC, PE, OPP and PET all types of plastic film or glass.
Transparent heat-insulating film of the present invention can be formed or be made up of two-layer transparent membrane substrate and the heat insulation pressure-sensitive adhesive layer of layer of transparent by layer of transparent film substrate and one deck photocureable coating layer: wherein substrate surface heat insulating coat thickness is that the specific function effect of 1～10 μ m nano particle makes the thermal isolation film make not only reach 85% above transmitance at visible region, and reach more than 60% for the shielding rate of near-infrared region light, ultraviolet light then almost all absorbs shielding.
The preparation method of transparent anti-ultraviolet heat insulating compound film comprises following dual mode:
1, prepares nano transparent heat-insulating function photocureable coating by the method for mechanical blending earlier according to said ratio, method with the anilox roll transfer coated is coated with nano transparent heat-insulating function photocureable coating (also can compoundly go up another floor height transparent membrane or glass formation folder film) at high transparent membrane or glass surface then, uses the ultra violet lamp film-forming again.Make the film of making not only have excellent heat insulation property, and excellent abrasive, can be used for occasions such as vehicle glass, building glass.The base material that is coated with nano transparent heat-insulating function photocureable coating solidifies 1～30s with ultraviolet curing device again at preheating temperature 1～2min of 60～120 ℃.
2, prepare nano transparent heat-insulating function pressure-sensitive adhesive coating or nano transparent heat-insulating function photocureable coating layer by the method for mechanical blending earlier according to said ratio, method with the anilox roll print-on coating is coated with nano transparent heat-insulating function pressure-sensitive adhesive coating or nano transparent heat-insulating function photocureable coating layer at transparent membrane or glass surface then, again with compound another layer transparent membrane or the glass gone up of pressurized after the oven for drying.Oven temperature is controlled at 60～120 ℃, heated volatile solvent 1～2min.
Promptly on high transparent membrane or glass baseplate surface, adopt anilox roll print-on coating nano transparent heat-insulating function photocureable coating or the coating nano transparent heat-insulating function pressure sensitive adhesive mode of laminated film base material again; produce the glass protecting film that has excellent thermal insulation, absorbs ultraviolet linearity, the transparency and scratch-resistant performance, its preparation method is comparatively easy, practical and efficient.Relevant test data shows that the visible light transmissivity of this novel transparent thermal isolation film all can reach more than 85%, and almost all absorbs for ultraviolet ray; For the near infrared light that accounts for sunshine 50%, also can reach the obstruct of 60-80%.
Beneficial effect of the present invention:
1, the present invention has adopted that light-cured resin or pressure sensitive adhesive make that coating has had that wear-resisting wiping significantly improves, the perspective rate is good, adhesive force is good between rete, add the technology that adopts the anilox roll print-on coating and be coated with, make that the coating raw material is saved, film forming evenly reaches speed and significantly improves at transparent membrane or glass surface.
2, transparent heat-insulating film of the present invention not only has excellent heat insulation property, and has good light transmittance at visible region.With reference to the countries concerned's standard, key property to the transparent heat-insulated film of the present invention is measured, the result proves that its visible light transmissivity of transparent heat-insulated film of the present invention all more than 75%, has the near-infrared shielding rate more than 60%, the ultravioletlight screening rate more than 98% simultaneously.Therefore transparent heat-insulating film of the present invention has characteristics such as transparent, shielding ultraviolet rays, shielding infrared ray, wear-resisting wiping, antistatic and anti-glare, its high comprehensive performance.
3, adopt technology increase one deck thermal insulation layer of anilox roll print-on coating to prepare transparent heat-insulated film on the transparent membrane substrate of the present invention, its preparation method is comparatively easy, and cost is low.
Description of drawings:
Fig. 1: be transparent heat-insulating film structural representation of the present invention, wherein 1, nano transparent heat-insulating function light solidifying coating; 2, transparent membrane substrate.
Fig. 2: be transparent heat-insulating film structural representation of the present invention, wherein 1, the transparent membrane substrate; 2, nano transparent heat-insulating function pressure-sensitive adhesive coating; 3, transparent membrane substrate.
Fig. 3: be transparent heat-insulating film structural representation of the present invention, wherein 1, nano transparent heat-insulating function light solidifying coating; 2, transparent glass substrate.
Fig. 4: be transparent heat-insulating film structural representation of the present invention, wherein 1, transparent glass substrate; 2, nano transparent heat-insulating function pressure-sensitive adhesive coating or nano transparent heat-insulating function optic-solidified adhesive; 3, transparent membrane (glass) substrate.
The specific embodiment:
Describe the present invention with relevant chart below in conjunction with embodiment.But the invention is not restricted to given example.
Example 1:PET base transparent heat-insulating film with reference to Fig. 1, is made up of transparent membrane substrate 2 and nano transparent heat-insulating function light solidifying coating 1, and the thickness of coating is 10 μ m.Thermal isolation film is formed and structure sees the following form 1:
Earlier above raw material is stirred by vacuum stirring device froth breaking after the sand mill sand milling disperses the back standby, by special-purpose optics film coated machine the PET film is unreeled tensioning again, dedusting, destatic and sided corona treatment after, through the anilox roll transfer coated transparent heat insulating dope is coated on the PET substrate surface through 100 ℃ of preheating 1min of segmentation baking oven, solidify the nano transparent heat-insulating function photocuring film that 1-30s promptly constitutes the PET base material through ultraviolet curing device again, this thermal isolation film has excellent heat insulation property and visible light transmissivity, reach 80% through dependence test and its light transmittance of calculating, red shielding rate reaches 63%, and uvioresistant reaches 98%.
Example 2:PVC base transparent heat-insulating film with reference to Fig. 1, is made up of transparent membrane substrate 2 and nano transparent heat-insulating function light solidifying coating 1, and the thickness of coating is 10 μ m.Thermal isolation film is formed and structure sees the following form 2:
Earlier above raw material is stirred by vacuum stirring device froth breaking after the sand mill sand milling disperses the back standby, again by special-purpose optics film coated machine with the PVC film unreel tensioning, dedusting, destatic and sided corona treatment after, through the anilox roll transfer coated transparent heat insulating dope is coated on the PVC substrate surface through 100 ℃ of preheating 1.5min of segmentation baking oven, solidify the nano transparent heat-insulating function photocuring film that 15s promptly constitutes the PET base material through ultraviolet curing device again, this thermal isolation film has excellent heat insulation property and visible light transmissivity, reaches 85% through dependence test and its light transmittance of calculating.
Example 3:OPP base transparent heat-insulating film with reference to Fig. 1, is made up of transparent membrane substrate 2 and nano transparent heat-insulating function light solidifying coating 1, and the thickness of coating is 5 μ m.Thermal isolation film is formed and structure sees the following form 3:
Earlier above raw material is stirred by vacuum stirring device froth breaking after the sand mill sand milling disperses the back standby, by special-purpose optics film coated machine the OPP film is unreeled tensioning again, dedusting, destatic and sided corona treatment after, through the anilox roll transfer coated transparent heat insulating dope is coated on the OPP substrate surface through 100 ℃ of preheating 1.3min of segmentation baking oven, solidify the nano transparent heat-insulating function photocuring film that 30s promptly constitutes the PET base material through ultraviolet curing device again, this thermal isolation film has excellent heat insulation property and visible light transmissivity visible region light transmittance can reach 7.8%, the shielding rate of near infrared region light reaches 80%, high comprehensive performance.
Example 4:PVB base transparent heat-insulating film with reference to Fig. 1, is made up of transparent membrane substrate 2 and nano transparent heat-insulating function light solidifying coating 1, and the thickness of coating is 10 μ m.Thermal isolation film is formed and structure sees the following form 4:
Earlier above raw material is stirred by vacuum stirring device froth breaking after the sand mill sand milling disperses the back standby, by special-purpose optics film coated machine the PVB film is unreeled tensioning again, dedusting, destatic and sided corona treatment after, through the anilox roll transfer coated transparent heat insulating dope is coated on the PVB substrate surface through 100 ℃ of preheating 2min of segmentation baking oven, solidify the nano transparent heat-insulating function photocuring film that 10s promptly constitutes the PET base material through ultraviolet curing device again, this thermal isolation film has excellent heat insulation property and visible light transmissivity, can reach 80% through dependence test and its visible region light transmittance of calculating, the shielding rate of near infrared region light reaches 65%, its ultravioletlight screening rate reaches 98%, high comprehensive performance.
Example 5:PET base transparent heat-insulating film with reference to Fig. 2, is composited by transparent membrane substrate 1, nano transparent heat-insulating function pressure-sensitive adhesive coating 2, transparent membrane substrate 3, and the thickness of coating is 10 μ m.Thermal isolation film is formed and structure sees the following form 5:
Earlier above raw material is stirred by vacuum stirring device froth breaking after the sand mill sand milling disperses the back standby, again by special-purpose optics film coated machine with the PET film unreel tensioning, dedusting, destatic and sided corona treatment after, through the anilox roll transfer coated nano transparent heat-insulating function pressure sensitive adhesive is coated on the PET substrate surface, through the temperature heated volatile solvent 15min of segmentation baking oven at 80 ℃, compound upward another layer PET transparent membrane of pressurized or transparent release film constitute nano transparent heat-insulating function composite film more again.This thermal isolation film has excellent heat insulation property and visible light transmissivity, reaches 80% through dependence test and its light transmittance of calculating, and red shielding rate reaches 63%.
Example 6:PE base transparent heat-insulating film with reference to Fig. 1, is made up of transparent membrane substrate 2 and nano transparent heat-insulating function light solidifying coating 1, and the thickness of coating is 5 μ m.Thermal isolation film is formed and structure sees the following form 6:
Earlier above raw material is stirred by vacuum stirring device froth breaking after the sand mill sand milling disperses the back standby, by special-purpose optics film coated machine the PET film is unreeled tensioning again, dedusting, destatic and sided corona treatment after, through the anilox roll transfer coated transparent heat insulating dope is coated on the PET substrate surface through 100 ℃ of preheating 16min of segmentation baking oven, solidify the nano transparent heat-insulating function photocuring film that 20s promptly constitutes the PET base material through ultraviolet curing device again, this thermal isolation film has excellent heat insulation property and visible light transmissivity, can reach 78% through dependence test and its visible region light transmittance of calculating, the shielding rate of near infrared region light reaches 60%, its ultravioletlight screening rate reaches 95%, high comprehensive performance.
Example 7: the clear glass thermal isolation film, with reference to Fig. 3, to form by transparent glass substrate 2 and nano transparent heat-insulating function light solidifying coating 1, the thickness of coating is 5 μ m.Thermal isolation film is formed and structure sees the following form 7:
Earlier above raw material is stirred by vacuum stirring device froth breaking after the sand mill sand milling disperses the back standby, to with the anilox roll transfer coated transparent heat insulating dope be coated on transparent glass substrate 2 surfaces by special-purpose optics coated with glass machine behind the glass cleaning, drying again, and through 100 ℃ of preheating 1min of baking oven, solidify the nano transparent heat-insulating function photocuring film that 25s promptly constitutes glass baseplate with ultraviolet curing device, this thermal isolation film has excellent heat insulation property and visible light transmissivity, can reach 78% through dependence test and its visible region light transmittance of calculating, the shielding rate of near infrared region light reaches 60%, its ultravioletlight screening rate reaches 95%, high comprehensive performance.And all available example of above other Example formulations method of telling is implemented on glass baseplate, no longer detailed here telling.
Example 8: the clear glass thermal isolation film, with reference to Fig. 4, by 3 compound compositions of transparent glass substrate 1, nano transparent heat-insulating function pressure-sensitive adhesive coating 2, transparent membrane (glass) substrate, the thickness of coating is 10 μ m.Thermal isolation film is formed and structure sees the following form 8:
Earlier above raw material is stirred by vacuum stirring device froth breaking after the sand mill sand milling disperses the back standby, again with behind the glass cleaning, drying by special-purpose optics coated with glass machine with the anilox roll transfer coated with nano transparent heat-insulating function pressure-sensitive adhesive coating 2 cloth on transparent glass substrate 1 surface, again through the temperature heated volatile solvent 2min of baking oven at 80 ℃, compound another layer PET transparent membrane of going up of pressurized constitutes nano transparent heat-insulating function composite film again, this thermal isolation film has excellent heat insulation property and visible light transmissivity, can reach 78% through dependence test and its visible region light transmittance of calculating, the shielding rate of near infrared region light reaches 60%, its ultravioletlight screening rate reaches 95%, high comprehensive performance.And all available example of the 1-8 Example formulations method of telling is implemented on glass baseplate, no longer detailed here telling.
Example 9: the clear glass thermal isolation film, with reference to Fig. 4, by 3 compound compositions of transparent glass substrate 1, nano transparent heat-insulating function optic-solidified adhesive 2, transparent membrane (glass) substrate, the thickness of coating is 10 μ m.Thermal isolation film is formed and structure sees the following form 8:
Earlier above raw material is stirred by vacuum stirring device froth breaking after the sand mill sand milling disperses the back standby, again with behind the glass cleaning, drying by special-purpose optics coated with glass machine with the anilox roll transfer coated with nano transparent heat-insulating function optic-solidified adhesive 2 cloth on transparent glass substrate 1 surface, again through the temperature heated volatile solvent 2min of baking oven at 80 ℃, compound another layer PET transparent membrane of going up of pressurized constitutes nano transparent heat-insulating function composite film again, this thermal isolation film has excellent heat insulation property and visible light transmissivity, can reach 78% through dependence test and its visible region light transmittance of calculating, the shielding rate of near infrared region light reaches 60%, its ultravioletlight screening rate reaches 95%, high comprehensive performance.And all available example of the 1-8 Example formulations method of telling is implemented on glass baseplate, no longer detailed here telling.
Claims (10)
1, a kind of transparent anti-ultraviolet heat insulating compound film, it is characterized in that: be two layers or three-layer composite structure, during two-layer structure, bottom is high transparent membrane or glass baseplate, and the top layer is nano transparent heat-insulating function photocureable coating layer or nano transparent heat-insulating function pressure-sensitive adhesive coating; During three-layer composite structure, bottom is high transparent membrane or glass baseplate, the intermediate layer is nano transparent heat-insulating function photocureable coating layer or nano transparent heat-insulating function pressure-sensitive adhesive coating, the top layer is high transparent membrane or glass baseplate, and the component and the percentage by weight % of wherein said nano transparent heat-insulating function photocureable coating layer or nano transparent heat-insulating function pressure-sensitive adhesive coating are as follows:
Light-cured resin or pressure sensitive adhesive: 50.0-94.0
Nano-powder: 3.0-9.0
Surface tension auxiliary agent: 0.2-1.0
Diluent: 2.0-35.0
Dispersant: 0.8-5.0.
2, a kind of transparent anti-ultraviolet heat insulating compound film according to claim 1 is characterized in that: wherein said light-cured resin is a kind of in light-cured acrylic resin, photocuring insatiable hunger or resin or the light-cured polyurethane resin; Pressure sensitive adhesive is pressure-sensitive curing acrylic glue or pressure-sensitive curing polyester glue.
3, a kind of transparent anti-ultraviolet heat insulating compound film according to claim 1, it is characterized in that: nano-powder is
Contain any one or the combination of any two kinds of inorganic oxides in infrared semiconductor ceramic powder and tri-iron tetroxide, titanium dioxide, silica or the zinc oxide;
Or any one or the combination of any two kinds of inorganic oxides in tin inorganic oxide and tri-iron tetroxide, titanium dioxide, silica or the zinc oxide are pluged with molten metal in oxidation;
Or any one or any two kinds of inorganic oxides combination in tin and tri-iron tetroxide, titanium dioxide, silica or the zinc oxide are pluged with molten metal in infrared semiconductor ceramic powder and oxidation;
Or weather-proof eight grades organic nano transparent pigment organic titanium cyanogen orchid.
4, according to claim 1 or 3 described a kind of transparent anti-ultraviolet heat insulating compound films, it is characterized in that: the particle diameter of nanometer powder scope is 1～300nm.
5, a kind of transparent anti-ultraviolet heat insulating compound film according to claim 1 is characterized in that: described dispersant is the polycarboxylate sodium; The surface tension auxiliary agent is a perfluor alkyl ethide sulfonic group salt; Diluent is ethyl acetate or absolute ethyl alcohol.
6, a kind of transparent anti-ultraviolet heat insulating compound film according to claim 1, it is characterized in that: described high transparent membrane is a kind of in transparent PVC, PVB, PC, PE, OPP or the PET plastic sheeting, described heat insulating compound film is made up of layer of transparent film substrate and one deck photocureable coating layer or is made up of two-layer transparent membrane substrate and the heat insulation pressure-sensitive adhesive layer of layer of transparent, and wherein substrate surface heat insulating coat thickness is 1～10 μ m.
7, the preparation method of the described a kind of transparent anti-ultraviolet heat insulating compound film of claim 1, it is characterized in that may further comprise the steps: light-cured resin, nano-powder, surface tension auxiliary agent, diluent and dispersant are prepared nano transparent heat-insulating function photocureable coating by proportioning by the method for mechanical blending, method with the anilox roll transfer coated is coated with nano transparent heat-insulating function photocureable coating at high transparent membrane or glass surface then, uses the ultra violet lamp film-forming again.
8, the preparation method of a kind of transparent anti-ultraviolet heat insulating compound film according to claim 7, the base material that it is characterized in that being coated with nano transparent heat-insulating function photocureable coating solidifies 1～30s with ultraviolet curing device again at preheating temperature 1～2min of 60～120 ℃.
9, the preparation method of the described a kind of transparent anti-ultraviolet heat insulating compound film of claim 1, it is characterized in that may further comprise the steps: with pressure sensitive adhesive or light-cured resin, nano-powder, the surface tension auxiliary agent, diluent and dispersant are prepared nano transparent heat-insulating function pressure-sensitive adhesive coating or nano transparent heat-insulating function photocureable coating layer by proportioning by the method for mechanical blending, method with the anilox roll print-on coating is coated with nano transparent heat-insulating function pressure-sensitive adhesive coating or nano transparent heat-insulating function photocureable coating layer at transparent membrane or glass surface then, again with compound another layer transparent membrane or the glass gone up of pressurized after the oven for drying.
10, the preparation method of a kind of transparent anti-ultraviolet heat insulating compound film according to claim 9 is characterized in that oven temperature is controlled at 60～120 ℃, heated volatile solvent 1～2min.
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2008
- 2008-07-28 CN CNA2008100436706A patent/CN101323191A/en active Pending
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