CN106064897A - A kind of ecological Binder Materials - Google Patents

A kind of ecological Binder Materials Download PDF

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Publication number
CN106064897A
CN106064897A CN201610364449.5A CN201610364449A CN106064897A CN 106064897 A CN106064897 A CN 106064897A CN 201610364449 A CN201610364449 A CN 201610364449A CN 106064897 A CN106064897 A CN 106064897A
Authority
CN
China
Prior art keywords
clay brick
binder materials
brick
powder
clay
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610364449.5A
Other languages
Chinese (zh)
Inventor
徐德龙
朱建辉
张伟
刘文欢
钱长联
徐德虎
马立全
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gansu Delong Ecological Building Material Co Ltd
Original Assignee
Gansu Delong Ecological Building Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gansu Delong Ecological Building Material Co Ltd filed Critical Gansu Delong Ecological Building Material Co Ltd
Priority to CN201610364449.5A priority Critical patent/CN106064897A/en
Publication of CN106064897A publication Critical patent/CN106064897A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/24Cements from oil shales, residues or waste other than slag
    • C04B7/246Cements from oil shales, residues or waste other than slag from waste building materials, e.g. waste asbestos-cement products, demolition waste
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/38Preparing or treating the raw materials individually or as batches, e.g. mixing with fuel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of ecological Binder Materials, including clay brick powder, account for clay brick opaque amount 0~the slag micropowder of 40%, and chemical activator, wherein chemical activator is one or more of Gypsum Fibrosum, Calx, triisopropanolamine and diethanol monoisopropanolamine, and corresponding content is: Calx 1.5~5%, Gypsum Fibrosum 4~6%, triisopropanolamine 0.015~0.03%, diethanol monoisopropanolamine 0.015~0.03%, it is the percentage by weight of clay brick powder;The present invention uses the ecological Binder Materials of construction waste clay brick preparation, turns waste into wealth, has the social benefit of notable resource, energy conservation and environmental conservation, and the ecological Binder Materials activity of preparation is high, added value is high, steady quality, can large-scale popularization use.

Description

A kind of ecological Binder Materials
Technical field
The present invention relates to resources circulation and building material technical field, particularly to a kind of ecological Binder Materials.
Background technology
Cement as tradition Binder Materials, use wide, consumption big, have the title of " grain of building industry ", China is water Mud big producing country, since 1985, China's cement output keeps the first in the world year after year, and China's cement output in 2014 is up to 24.76 hundred million tons.The fast development of cement industry, while promoting national economic development, uplifting the people's living standard, also brings Substantial amounts of resource and energy resource consumption, create substantial amounts of environmental problem.The most in recent years, it is correlated with environmental protection law along with country Regulation increasingly strict, and the change of energy resource situation both at home and abroad, cause the constraint of its resource environment day by day to highlight, need one badly Plant ecological Binder Materials and substitute cement in order to part, alleviate resource environmental pressure.
Meanwhile, China's annual building waste generation amount is up to 1,000,000,000 tons, and its resource utilization rate is less than 5%.Build In building refuse, maximum with the proportion shared by useless brick, according to statistics, in the building waste of reconstruction of the old city town, useless brick accounts for 50%~60%, builds Build useless brick in the building waste of construction and account for 30%~50%.Discarded clay brick is pozzolanic materials, containing active mineral composition, Wherein silicon dioxide and alumina content are higher.By rational preparation technology, can use as Binder Materials, have and make profits again By value.
Therefore, probe into rational physics and chemical activation approach, excite discarded clay brick lateral reactivity, produce ecology gelling Material substitutes cement in order to part, for alleviating resource environmental pressure and the construction waste clay brick in tradition Binder Materials field The environmental problem brought has important practical significance.
Summary of the invention
In order to overcome the shortcoming of above-mentioned prior art, it is an object of the invention to provide a kind of ecological Binder Materials, with useless Abandoning clay brick is primary raw material, by rational physics and chemical activation approach, excites discarded clay brick lateral reactivity, and and ore deposit Slag micropowder is combined, and produces ecological Binder Materials.
To achieve these goals, the technical solution used in the present invention is:
A kind of ecological Binder Materials, including: clay brick powder, account for clay brick opaque amount 0~the slag micropowder of 40%, Yi Jihua Learning exciting agent, wherein chemical activator is Gypsum Fibrosum, Calx, triisopropanolamine and the one of diethanol monoisopropanolamine or several Kind, corresponding content is: Calx 1.5~5%, Gypsum Fibrosum 4~6%, triisopropanolamine 0.015~0.03%, diethanol list isopropyl Hydramine 0.015~0.03%, is the percentage by weight of clay brick powder.
Described clay brick powder obtains in the following manner:
Step 1, one-level separates except ferrum and light materials: before the construction waste clay brick material sub-elected enters disintegrating machine, pass through magnetic Screening device and light materials sorting unit remove irony material and light materials;
Step 2, broken: the discarded clay brick material after step 1 separates is crushed by disintegrating apparatus, prepared size≤ The block brick material of 50mm;
Step 3, two grades are removed ferrum: by concentration equipment, step 2 gained bulk brick material is removed irony material further;
Step 4, grinding: through step 3 except the block brick material of ferrum is by milling equipment grinding, prepared specific surface area >= 500m2The fine powder of/kg, i.e. clay brick powder.
In described step 1, construction waste clay brick material obtains from building waste in the following way:
By loader, building waste is fed apron feeder, and building waste is sent into separator by apron feeder, profit Sand discarded in building waste, discarded clay brick, discarded concrete being separated by volumetric method, formation construction waste sand material, building are useless Abandon clay brick material and three kinds of primary product of construction waste concrete material;Wherein, the main component of described construction waste clay brick material For discarded clay solid brick, also comprise very small amount particle diameter≤70mm concrete block.
In described step 1, also include except ferrum, light materials separate, before feed of crusher, by concentration equipment and light materials Sorting unit removes irony material and light materials.
Described chemical activator is to add in the step 4 grinding stage.
Specific surface area >=the 450m of described slag micropowder2/kg。
Compared with prior art, the invention has the beneficial effects as follows:
(1) present invention utilizes discarded clay brick to produce ecological Binder Materials and substitutes cement in order to part, for alleviating tradition The environmental problem that the resource environmental pressure in Binder Materials field and construction waste clay brick bring has important practical significance.
(2) the ecological Binder Materials activity prepared by the present invention is high, added value is high, steady quality, can large-scale popularization use.
Detailed description of the invention
Example below describes embodiments of the present invention in detail.
Embodiment 1:
A kind of ecological Binder Materials: clay brick powder 100 mass parts, Calx 3 mass parts, the ecological Binder Materials of preparation, press GB/T 2847-2005 " pozzolana mixed material in cement " detects, and ecological Binder Materials 28d compressive strength rate is 85%.
Described clay brick powder obtains in the following manner:
Step 1, one-level separates except ferrum and light materials: before the construction waste clay brick material sub-elected enters disintegrating machine, by electricity Deironing device, belt feeder electromagnetic cylinder and light materials sorting unit remove irony material and light materials;
Step 2, broken: the discarded clay brick material through step 1 crushes through fine jaw-crusher, prepares size≤50mm Block brick material;
Step 3, two grades are removed ferrum: before block brick material enters Vertical Mill, further by electric magnetic iron remover and belt feeder electromagnetic cylinder Remove irony material;
Step 4, grinding: the block brick material through step 3 passes through vertical mill grinding, prepares specific surface area 650m2/ kg's is thin Powder, for clay brick powder.
Embodiment 2:
A kind of ecological Binder Materials: clay brick powder 100 mass parts, (specific surface area is 450m to slag micropowder2/ kg) 40 mass Part, triisopropanolamine 0.03 mass parts, through batch mixer mix homogeneously, prepare ecological Binder Materials, " use by GB/T 2847-2005 Pozzolana mixed material in cement " detection, ecological Binder Materials 28d compressive strength rate is 97%.
Described clay brick powder obtains mode with embodiment 1.
Embodiment 3:
A kind of ecological Binder Materials: clay brick powder 100 mass parts, (specific surface area is 450m to slag micropowder2/ kg) 35 mass Part, diethanol monoisopropanolamine 0.025 mass parts, through batch mixer mix homogeneously, prepare ecological Binder Materials, by GB/T 2847- 2005 " pozzolana mixed material in cement " detects, and ecological Binder Materials 28d compressive strength rate is 95%.
Described clay brick powder obtains mode with embodiment 1.
Embodiment 4:
A kind of ecological Binder Materials: clay brick powder 100 mass parts, (specific surface area is 450m to slag micropowder2/ kg) 30 mass Part, Gypsum Fibrosum 5 mass parts, diethanol monoisopropanolamine 0.02 mass parts, through batch mixer mix homogeneously, prepare ecological Binder Materials, Detect by GB/T 2847-2005 " pozzolana mixed material in cement ", ecological Binder Materials 28d compressive strength rate It is 98%.
Described clay brick powder obtains mode with embodiment 1.

Claims (4)

1. an ecological Binder Materials, it is characterised in that including: clay brick powder, account for clay brick opaque amount 0~40% slag micro- Powder, and chemical activator, wherein chemical activator is Gypsum Fibrosum, Calx, triisopropanolamine and diethanol monoisopropanolamine One or more, corresponding content is: Calx 1.5~5%, Gypsum Fibrosum 4~6%, triisopropanolamine 0.015~0.03%, diethyl Alcohol monoisopropanolamine 0.015~0.03%, is the percentage by weight of clay brick powder.
A kind of ecological Binder Materials, it is characterised in that described clay brick powder obtains in the following manner Take:
Step 1, one-level separates except ferrum and light materials: before the construction waste clay brick material sub-elected enters disintegrating machine, filled by magnetic separation Put and remove irony material and light materials with light materials sorting unit;
Step 2, broken: the discarded clay brick material after step 1 separates is crushed by disintegrating apparatus, prepare size≤50mm Block brick material;
Step 3, two grades are removed ferrum: by concentration equipment, step 2 gained bulk brick material is removed irony material further;
Step 4, grinding: through step 3 except the block brick material of ferrum is by milling equipment grinding, prepare specific surface area >=500m2/kg Fine powder, i.e. clay brick powder.
3. according to ecological Binder Materials a kind of described in claim 1,2, it is characterised in that it is characterized in that, in described step 1, Construction waste clay brick obtains from building waste in the following way:
By loader, building waste is fed apron feeder, and building waste is sent into separator, is utilized body by apron feeder Sand discarded in building waste, discarded clay brick, discarded concrete are separated by area method, and formation construction waste sand material, construction waste glue Cob brick material and three kinds of primary product of construction waste concrete material;Wherein, described construction waste clay brick material be mainly composed of useless Abandon clay solid brick, also comprise very small amount particle diameter≤70mm concrete block.
A kind of ecological Binder Materials, it is characterised in that the specific surface area of described slag micropowder >= 450m2/kg。
CN201610364449.5A 2016-05-26 2016-05-26 A kind of ecological Binder Materials Pending CN106064897A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107253834A (en) * 2017-07-26 2017-10-17 厦门天润锦龙建材有限公司 A kind of regenerating and modifying slurry composition and preparation method thereof
CN111517707A (en) * 2020-03-30 2020-08-11 杨辉 Ecological slope protection concrete and construction method thereof
CN111662021A (en) * 2020-06-04 2020-09-15 东南大学 Cement-based composite cementing material containing waste clay brick powder and limestone powder
CN111747666A (en) * 2020-06-04 2020-10-09 东南大学 Low-carbon cementing material prepared from waste clay brick powder and slag
CN112573853A (en) * 2020-12-25 2021-03-30 山东众森科技股份有限公司 Titanium gypsum-based full-solid waste cementing material excitant and preparation method thereof
CN113636768A (en) * 2021-07-17 2021-11-12 北京城建华晟交通建设有限公司 Excited clay brick micro powder and preparation method thereof, cementing material and regenerated brick

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102515588A (en) * 2011-12-20 2012-06-27 河北科技大学 Ecotypic cementing material
CN103183485A (en) * 2011-12-27 2013-07-03 上海德滨环保科技有限公司 Environmentally-friendly micro-powder
CN103183483A (en) * 2011-12-27 2013-07-03 上海德滨环保科技有限公司 Environmental-friendly supplementary cementious material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102515588A (en) * 2011-12-20 2012-06-27 河北科技大学 Ecotypic cementing material
CN103183485A (en) * 2011-12-27 2013-07-03 上海德滨环保科技有限公司 Environmentally-friendly micro-powder
CN103183483A (en) * 2011-12-27 2013-07-03 上海德滨环保科技有限公司 Environmental-friendly supplementary cementious material and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107253834A (en) * 2017-07-26 2017-10-17 厦门天润锦龙建材有限公司 A kind of regenerating and modifying slurry composition and preparation method thereof
CN107253834B (en) * 2017-07-26 2019-09-06 厦门天润锦龙建材有限公司 A kind of regenerating and modifying slurry composition and preparation method thereof
CN111517707A (en) * 2020-03-30 2020-08-11 杨辉 Ecological slope protection concrete and construction method thereof
CN111662021A (en) * 2020-06-04 2020-09-15 东南大学 Cement-based composite cementing material containing waste clay brick powder and limestone powder
CN111747666A (en) * 2020-06-04 2020-10-09 东南大学 Low-carbon cementing material prepared from waste clay brick powder and slag
CN112573853A (en) * 2020-12-25 2021-03-30 山东众森科技股份有限公司 Titanium gypsum-based full-solid waste cementing material excitant and preparation method thereof
CN113636768A (en) * 2021-07-17 2021-11-12 北京城建华晟交通建设有限公司 Excited clay brick micro powder and preparation method thereof, cementing material and regenerated brick

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Application publication date: 20161102