CN106057610B - A kind of powder-coating method of straight tube fluorescent tube - Google Patents
A kind of powder-coating method of straight tube fluorescent tube Download PDFInfo
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- CN106057610B CN106057610B CN201610491436.4A CN201610491436A CN106057610B CN 106057610 B CN106057610 B CN 106057610B CN 201610491436 A CN201610491436 A CN 201610491436A CN 106057610 B CN106057610 B CN 106057610B
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- 238000000576 coating method Methods 0.000 title claims abstract description 74
- 239000002002 slurry Substances 0.000 claims abstract description 121
- 239000011521 glass Substances 0.000 claims abstract description 88
- 239000000843 powder Substances 0.000 claims abstract description 69
- 238000010410 dusting Methods 0.000 claims abstract description 55
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000011347 resin Substances 0.000 claims abstract description 30
- 229920005989 resin Polymers 0.000 claims abstract description 30
- 238000010790 dilution Methods 0.000 claims abstract description 29
- 239000012895 dilution Substances 0.000 claims abstract description 29
- 239000003292 glue Substances 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 24
- 239000011265 semifinished product Substances 0.000 claims abstract description 24
- 238000002834 transmittance Methods 0.000 claims abstract description 20
- 239000002270 dispersing agent Substances 0.000 claims abstract description 19
- 239000000243 solution Substances 0.000 claims abstract description 19
- 238000007689 inspection Methods 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 16
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical class C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 claims abstract description 10
- -1 methacryloxy Chemical group 0.000 claims abstract description 10
- 239000004744 fabric Substances 0.000 claims abstract description 9
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000047 product Substances 0.000 claims abstract description 8
- 239000013530 defoamer Substances 0.000 claims abstract description 3
- 239000011248 coating agent Substances 0.000 claims description 46
- 238000007664 blowing Methods 0.000 claims description 38
- 238000001035 drying Methods 0.000 claims description 31
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 21
- 239000011259 mixed solution Substances 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 11
- 238000004140 cleaning Methods 0.000 claims description 8
- 239000011440 grout Substances 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 7
- 229920000178 Acrylic resin Polymers 0.000 claims description 7
- 239000007859 condensation product Substances 0.000 claims description 7
- 159000000000 sodium salts Chemical class 0.000 claims description 7
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 5
- 238000006277 sulfonation reaction Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- 229910002114 biscuit porcelain Inorganic materials 0.000 abstract description 9
- CYIGRWUIQAVBFG-UHFFFAOYSA-N 1,2-bis(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOCCOC=C CYIGRWUIQAVBFG-UHFFFAOYSA-N 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 5
- 230000021615 conjugation Effects 0.000 abstract description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 12
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 6
- 229930185605 Bisphenol Natural products 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical class COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 3
- 238000000016 photochemical curing Methods 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- ZRXADTFMGYNRKV-UHFFFAOYSA-N [S].C1=CC=CC2=CC=CC=C21 Chemical compound [S].C1=CC=CC2=CC=CC=C21 ZRXADTFMGYNRKV-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- RJGDLRCDCYRQOQ-UHFFFAOYSA-N anthrone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3CC2=C1 RJGDLRCDCYRQOQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical class OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/20—Manufacture of screens on or from which an image or pattern is formed, picked up, converted or stored; Applying coatings to the vessel
- H01J9/22—Applying luminescent coatings
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Formation Of Various Coating Films On Cathode Ray Tubes And Lamps (AREA)
Abstract
The present invention relates to tube cell preparing technical field, a kind of powder-coating method of straight tube fluorescent tube is disclosed, including：A, with powder：Weigh resin glue dilution, triethylene glycol divinyl ether, double [2 (methacryloxy) ethyoxyl] dimethylsilanes, isopropyl thioxanthone, levelling agent, dispersant solution, hydrophilizing agent, defoamer, ethanol, water and water-soluble spread powder；After each raw material is mixed, filter cloth obtains slurry, regulation slurry proportion and viscosity, stirs evenly rear stand for standby use；B, dusting：Dusting is carried out to straight tube glass tube；Semi-finished product are made after dusting；C, inspection：Light transmittance inspection is carried out to semi-finished product；D, baking：Choose and examine qualified semi-finished product, finished product after baking.The powder-coating method slurry hardening time of the present invention is short, and operating efficiency is high；Straight tube tube cell made from the inventive method, the caliper uniformity of bisque is good, and each position light transmittance of tube cell is essentially identical.It is difficult for drop-off and the conjugation of bisque and glass tube is good.
Description
Technical field
The present invention relates to tube cell preparing technical field, more particularly to a kind of efficient powder-coating method of straight tube fluorescent tube.
Background technology
The tube cell of LED is in preparation process, it is necessary to carry out dusting to the inwall of glass tube, the quality of dusting is directly affected
To the translucent effect of fluorescent tube.Current coating process, is usually to be poured into slurry from the upper end of glass tube with pump, makes slurry by weight
Power is left, and is flowed out from the lower end of glass tube, after then toasting, and one layer of bisque is thus formed on glass inside pipe wall.
Chinese patent such as Application No. 200910182998.0 discloses a kind of powder coating method of fluorescent lamp tube, including following
Step：(1) washed bright pipe is put on starching machine, is blown into hot blast and dries bright pipe；(2) when bright pipe advances to upper powder position
When, spraying pump pipette tips are inserted to one end mouth of pipe of fluorescent tube, starts pump and carries out the slurry that dusts, when slurry is sprayed onto at the top of fluorescent tube, are stopped
Dust slurry, and removes lance head；(3) pipette tips of air draught pump are inserted to the other end mouth of pipe of fluorescent tube, starts air draught pumping wind, works as powder
When slurry is flowed at the mouth of pipe, then stop air draught, and remove air draught pipette tips；(4) tube cell is dried into drying area.
The powder-coating method of above-mentioned technical proposal, slurry can not rapid curing, hardening time is longer, therefore whole coating process
Working effect it is not high enough.
In addition, after the dusting of above-mentioned technical proposal, it is not equal enough in the powder layer thickness of glass inside pipe wall formation after slurry solidification
One, cause the light transmittance at each position of tube cell different, cause of low quality.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides a kind of efficient powder-coating method of straight tube fluorescent tube.The present invention's
Slurry hardening time is short in powder-coating method, and operating efficiency is high；Straight tube tube cell made from the inventive method, the caliper uniformity of bisque
Good, each position light transmittance of tube cell is essentially identical.It is difficult for drop-off and the conjugation of bisque and glass tube is good.
The present invention concrete technical scheme be：A kind of efficient powder-coating method of straight tube fluorescent tube, comprises the following steps：
A, with powder：The raw material of volumes below part is weighed respectively：550-650 parts of resin glue dilutions, 10-30 parts of triethylene glycols
Divinyl ether, 10-20 parts of double [2- (methacryloxy) ethyoxyl] dimethylsilane, 0.5-1.5 parts of isopropyl thioxanthones
Anthrone, 1-2 part levelling agent, 35-45 parts of dispersant solutions, 35-45 parts of hydrophilizing agents, 2-3 parts of defoamers, 100-200 parts of ethanol,
600-700 parts of water；Weigh the water-soluble spread powder with the resin glue liquid-solid ratio 600mL/1kg；Above-mentioned each raw material is mixed
Afterwards, 250-350 mesh filter clothes are crossed, slurry is obtained, adds water and slurry proportion is adjusted to 1.32-1.34g/cm3, measured with 4 glasss of viscosity are applied
Viscosity is determined for 18-20 seconds, 40-60h is stood after stirring standby.
In the slurry that the present invention matches somebody with somebody, quick-setting light-cured components can be realized containing triethylene glycol divinyl ether,
Rapid curing can be realized during dusting, dusting efficiency is greatly improved.But above-mentioned photocuring material is oily matter, with
Other aqueous materials compatibilities are poor, to overcome this shortcoming, and the present invention is with having selected ethanol as solvent composition and selection
Double [2- (methacryloxy) ethyoxyl] dimethylsilanes can reduce oily matter viscosity as diluent, improve two
Phase compatibility, meanwhile, double [2- (methacryloxy) ethyoxyl] dimethylsilanes itself also have the effect of photocuring, one
Two are lifted to obtain.Pass through the burden control to each raw material, slurry good dispersion produced by the present invention, no large particulate matter, in dusting
Mobility, film-forming are moderate in journey, and thickness is homogeneous after solidification, and light transmittance is more average.
B, dusting：Straight tube glass tube is vertically loaded into powder coating machine, in the slurry bucket that slurry is loaded into powder coating machine, from straight tube glass
Slurry is poured at the upper end of pipe, dusting is carried out to its inwall；Ultraviolet lighting is carried out to straight tube glass inside pipe wall during dusting
Penetrate, make photocuring active material rapid curing, be blowed simultaneously, blowing temperature is 25-75 DEG C；Semi-finished product are made after dusting.
C, inspection：Position each to semi-finished product carries out light transmittance inspection, it is desirable to which light transmittance is controlled in 86-88%.
D, baking：Choose and examine qualified semi-finished product, 8-12min, finished product are toasted at 110-130 DEG C.In baking
During, glass tube is not contacted directly directly with calandria.
Preferably, the order of addition of each raw material is in step a：Water and ethanol are configured to mixed solution, by dispersant
Solution is added in mixed solution；Then water-soluble spread powder is added, 40-80min is stirred；Continue to add resin glue dilution
Liquid, stirs 20-40min；Then surplus stock is added, 10-14h is stirred.
Preferably, the resin glue dilution by S-3501 types water-based acrylic resin and water in equal volume dilution and
Into；The levelling agent is levelling agent 420；The dispersant solution is 8-12wt% FD-40 dispersant solutions；The water solubility
The model S-833 of spread powder；The hydrophilizing agent is 10wt% N-80 hydrophilizing agents；The defoamer is P-76 defoamers.
Preferably, also including naphthalene of the relative molecular mass in 3000-5000 of 4-8 parts by volume in the raw material of the slurry
Sulfonic acid and formaldehyde condensation product sodium salt, and sulfonation degree is more than 80%.For further improve slurry can and stability, in slurry
Middle addition naphthalenesulfonateformaldehyde formaldehyde condensation product sodium salt, it is to avoid split-phase, accumulation sedimentation occur after preparing in slurry.In addition, naphthalene sulphur
Sour formaldehyde condensation products sodium salt can also avoid bubble during the dusting of slurry.
Preferably, also including the focus ratio of 8-12 parts by volume in the raw material of the slurry；The focus ratio
Relative molecular mass in 8-12 ten thousand, solid content is 40-50wt%.Focus ratio is thermosetting resin, can improve slurry with
The tack of glass inside pipe wall, makes slurry difficult for drop-off after solidifying；And focus ratio heat-resisting quantity is preferably, it can prevent solid
The bisque of change is heated and come off under long-time illumination.Focus ratio be able to can also be made by oneself with purchased in market.
Preferably, in step b dustings, straight tube glass tube is done on powder coating machine on the circular motion of individual pen, powder coating machine
It is divided into 1-5 areas by straight tube glass tube movement locus, wherein 1st area blowing speed is 1-3m/s, 50-70 DEG C of temperature of drying；Dry in 2nd area
Speed is 1-3m/s, 55-75 DEG C of temperature of drying；3rd area blowing speed is 3-5m/s, 25-45 DEG C of temperature of drying；4th area blowing speed
For 4-6m/s, 25-45 DEG C of temperature of drying；5th area blowing speed is 4-6m/s, 40-60 DEG C of temperature of drying.Region is carried out to powder coating machine
Divide, according to slurry in the curing degree of glass inside pipe wall, the blowing speed and blowing temperature of regional, energy are set respectively
Enough ensure that thickness of the slurry at each position of glass inside pipe wall is essentially identical.
Preferably, rotating speed of the straight tube glass tube on powder coating machine is 900-960 branch/h.With rotating speed in the prior art
1300-1500 branch/h rotating speed is compared, and dusting efficiency of the invention is obviously improved.
Preferably, during dusting, slurry is recycles, and slurry is collected weight after the outflow of straight tube glass tube
Newly input in the slurry bucket；The charging aperture and grout outlet of slurry bucket are provided with the filter cloth of 150-250 mesh.Circulation profit is carried out to slurry
With cost-effective.Filter cloth is set to the charging aperture and grout outlet of slurry bucket, the glass tube being mixed into during dusting can be filtered out
The impurity such as slag.
Preferably, during dusting, dusting is carried out to position below the upper end mouth of pipe of straight tube glass tube；When straight tube glass
When glass pipe reaches 4 zone position of powder coating machine, ultrasonic wave cleaning is carried out to the lower end mouth of pipe of straight tube glass tube, slurry is washed away.Due to
The two ends mouth of pipe of glass tube is finally to need to assemble, therefore can not have slurry at the mouth of pipe of two ends, in coating, directly to glass
Position below the mouth of pipe of pipe upper end carries out coating, it is ensured that the upper end mouth of pipe is without slurry；Using ultrasonic wave cleaning to lower end during special powder
The mouth of pipe is cleaned, and washes away slurry.The zone position of powder coating machine 4 cleaning, reason be it is substantially stationary in the position slurry, no longer
Flow, will not occur to drip slurry situation.Cleaned using ultrasonic wave, not only cleaning efficiency is high, and will not pollute slurry, makes it
It can recycle.
Preferably, during dusting, the slurry in the slurry bucket is in vacuum environment.Because slurry is circulation profit
, air easily is mixed into cyclic process, so as to produce bubble, is conducive to the row of the air in slurry under vacuum environment
Go out.
It is compared with the prior art, the beneficial effects of the invention are as follows：Slurry hardening time is short in the powder-coating method of the present invention, work
Make efficiency high；Straight tube tube cell made from the inventive method, the caliper uniformity of bisque is good, each basic phase of position light transmittance of tube cell
Together.It is difficult for drop-off and the conjugation of bisque and glass tube is good.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of efficient powder-coating method of straight tube fluorescent tube, comprises the following steps：
A, with powder：Following raw material is weighed respectively：600mL resin glues dilution, 20mL triethylene glycol divinyl ethers, 15mL
Double [2- (methacryloxy) ethyoxyl] dimethylsilanes, 1mL isopropyl thioxanthones, 1.5mL levelling agents 420,40mL
10wt% FD-40 dispersant solutions, 40mL 10wt% N-80 hydrophilizing agents, 2.5mL P-76 defoamers, 150mL ethanol,
650mL water；Weigh the water-soluble spread powders of S-833 with the resin glue liquid-solid ratio 600mL/1kg.The resin glue dilution
By S-3501 types water-based acrylic resin, dilution is formed liquid in equal volume with water.
Water and ethanol are configured to mixed solution, dispersant solution is added in mixed solution；Stir 60min；Continue
Resin glue dilution is added, 30min is stirred；Then surplus stock is added, 12h is stirred.After above-mentioned each raw material is mixed, mistake
300 mesh filter clothes, obtain slurry, add water slurry proportion being adjusted to 1.32-1.34g/cm3, it is with 4 glasss of viscosimeters measure viscosity are applied
18-20 seconds, 50h is stood after stirring standby.
B, dusting：Straight tube glass tube is vertically loaded into powder coating machine, in the slurry bucket that slurry is loaded into powder coating machine, in the slurry bucket
Slurry be in vacuum environment under.Slurry is poured at the upper end of straight tube glass tube, to the upper end mouth of pipe of straight tube glass tube with
Lower position carries out dusting；Straight tube glass tube does the circular motion of individual pen on powder coating machine, in straight tube glass tube during dusting
Wall carries out ultraviolet light, is blowed simultaneously, and semi-finished product are made after dusting.
Wherein, it is divided into 1-5 areas by straight tube glass tube movement locus on powder coating machine,
Wherein 1st area blowing speed is 2m/s, temperature 60 C of drying；2nd area blowing speed is 2m/s, temperature 60 C of drying；3rd area
Blowing speed is 4m/s, 35 DEG C of temperature of drying；4th area blowing speed is 5m/s, 35 DEG C of temperature of drying；5th area blowing speed is 5m/s,
Blowing temperature 50 C.Rotating speed of the straight tube glass tube on powder coating machine is 930/h.When straight tube glass tube reaches 4th area of powder coating machine
During position, ultrasonic wave cleaning is carried out to the lower end mouth of pipe of straight tube glass tube, slurry is washed away.
In addition, during dusting, slurry is recycles, and slurry is collected again defeated after the outflow of straight tube glass tube
Enter in the slurry bucket；The charging aperture and grout outlet of slurry bucket are provided with the filter cloth of 200 mesh.
C, inspection：Position each to semi-finished product carries out light transmittance inspection, it is desirable to which light transmittance is controlled in 86-88%.
D, baking：Choose and examine qualified semi-finished product, 10min, finished product are toasted at 120 DEG C.
Embodiment 2
A kind of efficient powder-coating method of straight tube fluorescent tube, comprises the following steps：
A, with powder：Following raw material is weighed respectively：550mL resin glues dilution, 10mL triethylene glycol divinyl ethers, 10mL
Double [2- (methacryloxy) ethyoxyl] dimethylsilanes, 0.5mL isopropyl thioxanthones, 1mL levelling agents 420,35mL
12wt% FD-40 dispersant solutions, 35mL 10wt% N-80 hydrophilizing agents, 2mL P-76 defoamers, 100mL ethanol, 600mL
Water；Weigh the water-soluble spread powders of S-833 with the resin glue liquid-solid ratio 600mL/1kg.The resin glue dilution by
Dilution is formed S-3501 types water-based acrylic resin in equal volume with water.
Water and ethanol are configured to mixed solution, dispersant solution is added in mixed solution；Stir 40min；Continue
Resin glue dilution is added, 20min is stirred；Then surplus stock is added, 14h is stirred.After above-mentioned each raw material is mixed, mistake
250 mesh filter clothes, obtain slurry, add water slurry proportion being adjusted to 1.32-1.34g/cm3, it is with 4 glasss of viscosimeters measure viscosity are applied
18-20 seconds, 40h is stood after stirring standby.
B, dusting：Straight tube glass tube is vertically loaded into powder coating machine, in the slurry bucket that slurry is loaded into powder coating machine, in the slurry bucket
Slurry be in vacuum environment under.Slurry is poured at the upper end of straight tube glass tube, to the upper end mouth of pipe of straight tube glass tube with
Lower position carries out dusting；Straight tube glass tube does the circular motion of individual pen on powder coating machine, in straight tube glass tube during dusting
Wall carries out ultraviolet light, is blowed simultaneously, and semi-finished product are made after dusting.
Wherein, it is divided into 1-5 areas by straight tube glass tube movement locus on powder coating machine, wherein 1st area blowing speed is 1m/s, blowing
Temperature 50 C；2nd area blowing speed is 1m/s, 55 DEG C of temperature of drying；3rd area blowing speed is 3m/s, 25 DEG C of temperature of drying；4th area blow
Airspeed is 4m/s, 25 DEG C of temperature of drying；5th area blowing speed is 4m/s, 40 DEG C of temperature of drying.Straight tube glass tube is on powder coating machine
Rotating speed be 900/h.When straight tube glass tube reaches 4 zone position of powder coating machine, the lower end mouth of pipe of straight tube glass tube is carried out
Ultrasonic wave is cleaned, and washes away slurry.
In addition, during dusting, slurry is recycles, and slurry is collected again defeated after the outflow of straight tube glass tube
Enter in the slurry bucket；The charging aperture and grout outlet of slurry bucket are provided with the filter cloth of 150 mesh.
C, inspection：Position each to semi-finished product carries out light transmittance inspection, it is desirable to which light transmittance is controlled in 86-88%.
D, baking：Choose and examine qualified semi-finished product, 12min, finished product are toasted at 110 DEG C.
Embodiment 3
A kind of efficient powder-coating method of straight tube fluorescent tube, comprises the following steps：
A, with powder：Following raw material is weighed respectively：650mL resin glues dilution, 30mL triethylene glycol divinyl ethers,
Double [2- (methacryloxy) ethyoxyl] dimethylsilanes of 20mL, 1.5mL isopropyl thioxanthones, 2mL levelling agents 420,
45mL 8wt% FD-40 dispersant solutions, 45mL 10wt% N-80 hydrophilizing agents, 3mL P-76 defoamers, the relative of 8mL are divided
Protonatomic mass is in naphthalenesulfonateformaldehyde formaldehyde condensation product sodium salt more than 80% of 3000-5000, sulfonation degree, 12 mL solid content
The focus ratio, 200mL ethanol, 700mL water of 40wt%, relative molecular mass in 8-12 ten thousand；Weigh and the resin glue aqueous
Gu the water-soluble spread powders of S-833 than 600mL/1kg.The resin glue dilution by S-3501 types water-based acrylic resin with
Dilution is formed water in equal volume.
The preparation method of focus ratio is：By quality than bisphenol A type epoxy resin, bis-phenol base under atmosphere of inert gases
Propane, which is added in reaction vessel, to be well mixed, and bisphenol A type epoxy resin and the total matter of bis-phenol base propane are added into reaction vessel
The methyl phenyl ethers anisole of amount 20%, is warming up to material dissolution.Wherein, the epoxy radicals in bisphenol A type epoxy resin and phenol hydroxyl in bis-phenol base propane
The mol ratio of base is 1.05:1.Urging for bisphenol A type epoxy resin and bis-phenol base propane gross mass 0.15% is added into reaction vessel
Agent, reaction temperature is 160 DEG C, and the reaction time is 24h.When reaction proceeds to 20h, material gross mass in addition reaction vessel
50% butanone, reaction naturally cools to 70 DEG C after terminating, and filtering is carried out after discharging focus ratio is made.
Water and ethanol are configured to mixed solution, dispersant solution is added in mixed solution；Stir 80min；Continue
Resin glue dilution is added, 40min is stirred；Then surplus stock is added, 10h is stirred.After above-mentioned each raw material is mixed, mistake
350 mesh filter clothes, obtain slurry, add water slurry proportion being adjusted to 1.32-1.34g/cm3, it is with 4 glasss of viscosimeters measure viscosity are applied
18-20 seconds, 60h is stood after stirring standby.
B, dusting：Straight tube glass tube is vertically loaded into powder coating machine, in the slurry bucket that slurry is loaded into powder coating machine, in the slurry bucket
Slurry be in vacuum environment under.Slurry is poured at the upper end of straight tube glass tube, to the upper end mouth of pipe of straight tube glass tube with
Lower position carries out dusting；Straight tube glass tube does the circular motion of individual pen on powder coating machine, in straight tube glass tube during dusting
Wall carries out ultraviolet light, is blowed simultaneously, and semi-finished product are made after dusting.
Wherein, it is divided into 1-5 areas by straight tube glass tube movement locus on powder coating machine, wherein 1st area blowing speed is 3m/s, blowing
Temperature 70 C；2nd area blowing speed is 3m/s, 75 DEG C of temperature of drying；3rd area blowing speed is 5m/s, temperature 45 C of drying；4th area blow
Airspeed is 6m/s, temperature 45 C of drying；5th area blowing speed is 6m/s, temperature 60 C of drying.Straight tube glass tube is on powder coating machine
Rotating speed be 960/h.When straight tube glass tube reaches 4 zone position of powder coating machine, the lower end mouth of pipe of straight tube glass tube is carried out
Ultrasonic wave is cleaned, and washes away slurry.
In addition, during dusting, slurry is recycles, and slurry is collected again defeated after the outflow of straight tube glass tube
Enter in the slurry bucket；The charging aperture and grout outlet of slurry bucket are provided with the filter cloth of 250 mesh.
C, inspection：Position each to semi-finished product carries out light transmittance inspection, it is desirable to which light transmittance is controlled in 86-88%.
D, baking：Choose and examine qualified semi-finished product, 8min, finished product are toasted at 130 DEG C.
Embodiment 4
A kind of efficient powder-coating method of straight tube fluorescent tube, comprises the following steps：
A, with powder：Following raw material is weighed respectively：600mL resin glues dilution, 15mL triethylene glycol divinyl ethers, 12mL
Double [2- (methacryloxy) ethyoxyl] dimethylsilanes, 0.5mL isopropyl thioxanthones, 1.5mL levelling agents 420,
40mL 9wt% FD-40 dispersant solutions, 40mL 10wt% N-80 hydrophilizing agents, 2.5mL P-76 defoamers, 6mL it is relative
Molecular mass is in naphthalenesulfonateformaldehyde formaldehyde condensation product sodium salt more than 80% of 3000-5000, sulfonation degree, 10mL solid content
Focus ratio, the 150mL ethanol of 45wt%, relative molecular mass in 8-12 ten thousand.600mL water；Weigh and the resin glue aqueous
Gu the water-soluble spread powders of S-833 than 600mL/1kg.The resin glue dilution by S-3501 types water-based acrylic resin with
Dilution is formed water in equal volume.
Water and ethanol are configured to mixed solution, dispersant solution is added in mixed solution；Stir 50min；Continue
Resin glue dilution is added, 25min is stirred；Then surplus stock is added, 11h is stirred.After above-mentioned each raw material is mixed, mistake
300 mesh filter clothes, obtain slurry, add water slurry proportion being adjusted to 1.32-1.34g/cm3, it is with 4 glasss of viscosimeters measure viscosity are applied
18-20 seconds, 55h is stood after stirring standby.
B, dusting：Straight tube glass tube is vertically loaded into powder coating machine, in the slurry bucket that slurry is loaded into powder coating machine, in the slurry bucket
Slurry be in vacuum environment under.Slurry is poured at the upper end of straight tube glass tube, to the upper end mouth of pipe of straight tube glass tube with
Lower position carries out dusting；Straight tube glass tube does the circular motion of individual pen on powder coating machine, in straight tube glass tube during dusting
Wall carries out ultraviolet light, is blowed simultaneously, and semi-finished product are made after dusting.
Wherein, it is divided into 1-5 areas by straight tube glass tube movement locus on powder coating machine, wherein 1st area blowing speed is 1.5m/s, blows
55 DEG C of air temperature；2nd area blowing speed is 1.5m/s, temperature 60 C of drying；3rd area blowing speed is 3.5m/s, 30 DEG C of temperature of drying；
4th area blowing speed is 4.5m/s, 30 DEG C of temperature of drying；5th area blowing speed is 4.5m/s, temperature 45 C of drying.Straight tube glass tube
Rotating speed on powder coating machine is 950/h.When straight tube glass tube reaches 4 zone position of powder coating machine, under straight tube glass tube
End pipe mouthful carries out ultrasonic wave cleaning, washes away slurry.
In addition, during dusting, slurry is recycles, and slurry is collected again defeated after the outflow of straight tube glass tube
Enter in the slurry bucket；The charging aperture and grout outlet of slurry bucket are provided with the filter cloth of 200 mesh.
C, inspection：Position each to semi-finished product carries out light transmittance inspection, it is desirable to which light transmittance is controlled in 86-88%.
D, baking：Choose and examine qualified semi-finished product, 9min, finished product are toasted at 115 DEG C.
Embodiment 5
A kind of efficient powder-coating method of straight tube fluorescent tube, comprises the following steps：
A, with powder：Following raw material is weighed respectively：550mL resin glues dilution, 25mL triethylene glycol divinyl ethers, 16mL
Double [2- (methacryloxy) ethyoxyl] dimethylsilanes, 1mL isopropyl thioxanthones, 2mL levelling agents 420,40mL
11wt% FD-40 dispersant solutions, 40mL 10wt% N-80 hydrophilizing agents, 2mL P-76 defoamers, 4mL average molecular matter
The solid content measured in naphthalenesulfonateformaldehyde formaldehyde condensation product sodium salt more than 80% of 3000-5000, sulfonation degree, 8mL is 50wt%, relative
Focus ratio, 150mL ethanol, 650mL water of the molecular mass in 8-12 ten thousand；Weigh and the resin glue liquid-solid ratio 600mL/
The water-soluble spread powders of 1kg S-833.The resin glue dilution is dilute in equal volume with water by S-3501 types water-based acrylic resin
Release and form.
Water and ethanol are configured to mixed solution, dispersant solution is added in mixed solution；Stir 65min；Continue
Resin glue dilution is added, 35min is stirred；Then surplus stock is added, 13h is stirred.After above-mentioned each raw material is mixed, mistake
300 mesh filter clothes, obtain slurry, add water slurry proportion being adjusted to 1.32-1.34g/cm3, it is with 4 glasss of viscosimeters measure viscosity are applied
18-20 seconds, 55h is stood after stirring standby.
B, dusting：Straight tube glass tube is vertically loaded into powder coating machine, in the slurry bucket that slurry is loaded into powder coating machine, in the slurry bucket
Slurry be in vacuum environment under.Slurry is poured at the upper end of straight tube glass tube, to the upper end mouth of pipe of straight tube glass tube with
Lower position carries out dusting；Straight tube glass tube does the circular motion of individual pen on powder coating machine, in straight tube glass tube during dusting
Wall carries out ultraviolet light, is blowed simultaneously, and semi-finished product are made after dusting.
Wherein, it is divided into 1-5 areas by straight tube glass tube movement locus on powder coating machine, wherein 1st area blowing speed is 2.5m/s, blows
65 DEG C of air temperature；2nd area blowing speed is 2.5m/s, temperature 70 C of drying；3rd area blowing speed is 4.5m/s, 40 DEG C of temperature of drying；
4th area blowing speed is 5.5m/s, 40 DEG C of temperature of drying；5th area blowing speed is 5.5m/s, 55 DEG C of temperature of drying.Straight tube glass tube
Rotating speed on powder coating machine is 920/h.When straight tube glass tube reaches 4 zone position of powder coating machine, under straight tube glass tube
End pipe mouthful carries out ultrasonic wave cleaning, washes away slurry.
In addition, during dusting, slurry is recycles, and slurry is collected again defeated after the outflow of straight tube glass tube
Enter in the slurry bucket；The charging aperture and grout outlet of slurry bucket are provided with the filter cloth of 200 mesh.
C, inspection：Position each to semi-finished product carries out light transmittance inspection, it is desirable to which light transmittance is controlled in 86-88%.
D, baking：Choose and examine qualified semi-finished product, 10min, finished product are toasted at 125 DEG C.
T8 straight tubes tube cell produced by the present invention, its bisque firmness boils 6h through 100 DEG C of water and not fallen off；100 DEG C of thermostatic roastings are baked
168h non yellowings.
Raw materials used in the present invention, equipment, is the conventional raw material, equipment of this area unless otherwise noted；In the present invention
Method therefor, is the conventional method of this area unless otherwise noted.
It is described above, only it is presently preferred embodiments of the present invention, not the present invention is imposed any restrictions, it is every according to the present invention
Any simple modification, change and equivalent transformation that technical spirit is made to above example, still fall within the technology of the present invention side
The protection domain of case.
Claims (10)
1. a kind of powder-coating method of straight tube fluorescent tube, it is characterised in that comprise the following steps：
A, with powder：The raw material of volumes below part is weighed respectively：550-650 parts of resin glue dilutions, 10-30 parts of triethylene glycol diethyls
Alkene ether, 10-20 parts of double [2- (methacryloxy) ethyoxyl] dimethylsilanes, 0.5-1.5 parts of isopropyl thioxanthones,
1-2 parts of levelling agents, 35-45 parts of dispersant solutions, 35-45 parts of hydrophilizing agents, 2-3 parts of defoamers, 100-200 parts of ethanol, 600-700
Part water；Weigh the water-soluble spread powder with the resin glue dilution liquid-solid ratio 600mL/1kg；Above-mentioned each raw material is mixed equal
After even, 250-350 mesh filter clothes are crossed, slurry is obtained, adds water and slurry proportion is adjusted to 1.32-1.34g/cm3, with 4 glasss of viscosimeters of painting
It is 18-20 seconds to determine viscosity, 40-60h is stood after stirring standby；
B, dusting：Straight tube glass tube is vertically loaded into powder coating machine, in the slurry bucket that slurry is loaded into powder coating machine, from straight tube glass tube
Slurry is poured at upper end, dusting is carried out to its inwall；Ultraviolet light is carried out to straight tube glass inside pipe wall during dusting, together
When be blowed, blowing temperature be 25-75 DEG C；Semi-finished product are made after dusting；
C, inspection：Position each to semi-finished product carries out light transmittance inspection, it is desirable to which light transmittance is controlled in 86-88%；
D, baking：Choose and examine qualified semi-finished product, 8-12min, finished product are toasted at 110-130 DEG C.
2. a kind of powder-coating method of straight tube fluorescent tube as claimed in claim 1, it is characterised in that the addition of each raw material in step a
Sequentially it is：Water and ethanol are configured to mixed solution, dispersant solution is added in mixed solution；Then water-soluble expand is added
Loose powder, stirs 40-80min；Continue to add resin glue dilution, stir 20-40min；Then surplus stock is added, is stirred
10-14h。
3. a kind of powder-coating method of straight tube fluorescent tube as claimed in claim 1 or 2, it is characterised in that the resin glue dilution
By S-3501 types water-based acrylic resin, dilution is formed liquid in equal volume with water；The levelling agent is levelling agent 420；The dispersant
Solution is 8-12wt% FD-40 dispersant solutions；The model S-833 of the water-soluble spread powder；The hydrophilizing agent is
10wt% N-80 hydrophilizing agents；The defoamer is P-76 defoamers.
4. a kind of powder-coating method of straight tube fluorescent tube as claimed in claim 1 or 2, it is characterised in that in the raw material of the slurry
Also include naphthalenesulfonateformaldehyde formaldehyde condensation product sodium salt of the relative molecular mass in 3000-5000 of 4-8 parts by volume, and sulfonation degree exists
More than 80%.
5. a kind of powder-coating method of straight tube fluorescent tube as claimed in claim 1 or 2, it is characterised in that in the raw material of the slurry
Also include the focus ratio of 8-12 parts by volume；The relative molecular mass of the focus ratio is in 8-12 ten thousand, and solid content is 40-
50wt%。
6. a kind of powder-coating method of straight tube fluorescent tube as claimed in claim 1, it is characterised in that in step b dustings, straight tube glass
Glass pipe is done on powder coating machine on the circular motion of individual pen, powder coating machine is divided into 1-5 areas by straight tube glass tube movement locus, wherein 1st area
Blowing speed is 1-3m/s, 50-70 DEG C of temperature of drying；2nd area blowing speed is 1-3m/s, 55-75 DEG C of temperature of drying；Dry in 3rd area
Speed is 3-5m/s, 25-45 DEG C of temperature of drying；4th area blowing speed is 4-6m/s, 25-45 DEG C of temperature of drying；5th area blowing speed
For 4-6m/s, 40-60 DEG C of temperature of drying.
7. a kind of powder-coating method of straight tube fluorescent tube as described in claim 1 or 2 or 6, it is characterised in that the straight tube glass tube
Rotating speed on powder coating machine is 900-960 branch/h.
8. the powder-coating method of a kind of straight tube fluorescent tube as described in claim 1 or 2 or 6, it is characterised in that during dusting,
Slurry is recycles, and slurry is re-entered in the slurry bucket after the outflow of straight tube glass tube by collection；The charging aperture of slurry bucket with
Grout outlet is provided with the filter cloth of 150-250 mesh.
9. the powder-coating method of a kind of straight tube fluorescent tube as described in claim 1 or 2 or 6, it is characterised in that during dusting,
Dusting is carried out to position below the upper end mouth of pipe of straight tube glass tube；When straight tube glass tube reaches 4 zone position of powder coating machine, to straight
The lower end mouth of pipe of pipe glass tube carries out ultrasonic wave cleaning, washes away slurry.
10. the powder-coating method of a kind of straight tube fluorescent tube as described in claim 1 or 2 or 6, it is characterised in that during dusting,
Slurry in the slurry bucket is in vacuum environment.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101290853A (en) * | 2008-02-28 | 2008-10-22 | 江苏宜兴市华宇电光源有限公司 | Novel dusting method of bi-helix fluorescent lamp |
| CN101887830A (en) * | 2009-05-15 | 2010-11-17 | Nec照明株式会社 | Fluorescer coating method |
| CN103560063A (en) * | 2013-10-21 | 2014-02-05 | 徐州锐阳照明电器设备有限公司 | Electrodeless lamp bepowdering technology |
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| JP4401329B2 (en) * | 2005-06-24 | 2010-01-20 | オスラム・メルコ株式会社 | Manufacturing method of fluorescent lamp |
| JP2008041324A (en) * | 2006-08-02 | 2008-02-21 | Matsushita Electric Ind Co Ltd | Phosphor coating liquid and manufacturing method of fluorescent lamp using it |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101290853A (en) * | 2008-02-28 | 2008-10-22 | 江苏宜兴市华宇电光源有限公司 | Novel dusting method of bi-helix fluorescent lamp |
| CN101887830A (en) * | 2009-05-15 | 2010-11-17 | Nec照明株式会社 | Fluorescer coating method |
| CN103560063A (en) * | 2013-10-21 | 2014-02-05 | 徐州锐阳照明电器设备有限公司 | Electrodeless lamp bepowdering technology |
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