CN106049695A - Flame-retardant insulation board - Google Patents
Flame-retardant insulation board Download PDFInfo
- Publication number
- CN106049695A CN106049695A CN201610426034.6A CN201610426034A CN106049695A CN 106049695 A CN106049695 A CN 106049695A CN 201610426034 A CN201610426034 A CN 201610426034A CN 106049695 A CN106049695 A CN 106049695A
- Authority
- CN
- China
- Prior art keywords
- parts
- layer
- heat
- insulation layer
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000009413 insulation Methods 0.000 title claims abstract description 92
- 239000003063 flame retardant Substances 0.000 title claims abstract description 26
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract 2
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 238000000576 coating method Methods 0.000 claims abstract description 17
- 238000011049 filling Methods 0.000 claims abstract description 12
- 239000003973 paint Substances 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 34
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 30
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 claims description 23
- 229910021389 graphene Inorganic materials 0.000 claims description 19
- 229910002804 graphite Inorganic materials 0.000 claims description 18
- 239000010439 graphite Substances 0.000 claims description 18
- 239000012766 organic filler Substances 0.000 claims description 18
- 238000010792 warming Methods 0.000 claims description 17
- 239000005995 Aluminium silicate Substances 0.000 claims description 16
- 235000012211 aluminium silicate Nutrition 0.000 claims description 16
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 16
- 239000005711 Benzoic acid Substances 0.000 claims description 15
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 15
- 235000010233 benzoic acid Nutrition 0.000 claims description 15
- 125000005842 heteroatom Chemical group 0.000 claims description 15
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 15
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 14
- 229920002554 vinyl polymer Polymers 0.000 claims description 14
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 claims description 13
- 239000004088 foaming agent Substances 0.000 claims description 13
- 239000004005 microsphere Substances 0.000 claims description 13
- 239000010451 perlite Substances 0.000 claims description 13
- 235000019362 perlite Nutrition 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- 238000007664 blowing Methods 0.000 claims description 12
- OQRWAMBQGTYSRD-UHFFFAOYSA-N dipotassium;oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[K+].[K+].[Ti+4].[Ti+4].[Ti+4].[Ti+4] OQRWAMBQGTYSRD-UHFFFAOYSA-N 0.000 claims description 12
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 12
- 239000010445 mica Substances 0.000 claims description 12
- 229910052618 mica group Inorganic materials 0.000 claims description 12
- 229920001778 nylon Polymers 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- 239000010455 vermiculite Substances 0.000 claims description 12
- 235000019354 vermiculite Nutrition 0.000 claims description 12
- 229910052902 vermiculite Inorganic materials 0.000 claims description 12
- 229960000549 4-dimethylaminophenol Drugs 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- 239000007943 implant Substances 0.000 claims description 7
- 238000010992 reflux Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- WRLRISOTNFYPMU-UHFFFAOYSA-N [S].CC1=CC=CC=C1 Chemical compound [S].CC1=CC=CC=C1 WRLRISOTNFYPMU-UHFFFAOYSA-N 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 4
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims description 2
- 229920001447 polyvinyl benzene Polymers 0.000 claims 1
- 239000010410 layer Substances 0.000 abstract description 123
- 239000000945 filler Substances 0.000 abstract description 2
- 238000005299 abrasion Methods 0.000 abstract 3
- 239000012790 adhesive layer Substances 0.000 abstract 3
- 238000010586 diagram Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 4
- 229940092714 benzenesulfonic acid Drugs 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 229940006460 bromide ion Drugs 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000004079 fireproofing Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ASMQGLCHMVWBQR-UHFFFAOYSA-N Diphenyl phosphate Chemical group C=1C=CC=CC=1OP(=O)(O)OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-N 0.000 description 1
- WBOHXLDSPBIPTP-UHFFFAOYSA-N N,N-dimethyl-1,8-naphthyridin-4-amine Chemical compound CN(C1=CC=NC2=NC=CC=C12)C WBOHXLDSPBIPTP-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/18—Homopolymers or copolymers of aromatic monomers containing elements other than carbon and hydrogen
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/92—Protection against other undesired influences or dangers
- E04B1/94—Protection against other undesired influences or dangers against fire
- E04B1/941—Building elements specially adapted therefor
- E04B1/942—Building elements specially adapted therefor slab-shaped
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Acoustics & Sound (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Fireproofing Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a flame-retardant insulation board which comprises a base layer, a frame layer, an adhesive layer, a waterproof layer, an insulation layer, an elastic buffer layer and an abrasion-resistant coating. The base layer is covered by the frame layer. The frame layer is composed of a plurality of workpieces which are arranged in parallel or in a staggered mode and form filling cavities. The filling cavities are filled with filler. The frame layer is covered by the adhesive layer. The adhesive layer is covered by the waterproof layer. The waterproof layer is covered by the insulation layer. The insulation layer is covered by the elastic buffer layer. The upper surface of the elastic buffer layer is coated with the abrasion-resistant coating made of abrasion-resistant paint.
Description
Technical field
The present invention relates to warming plate technical field, particularly relate to a kind of fire-retardant heat insulation plate.
Background technology
Warming plate say easy-to-understand be exactly insulation to building plank, be with polystyrene resin for raw material plus its
His supplementary material and poly-inclusion, be injected simultaneously into catalyst by adding hot mixing, then extrusion molding extrusion molding and the hard bubble that manufactures
Foam plastic plate, has protection against the tide, water resistance, can make minimizing building envelope thickness, thus increase indoor usable floor area.
Current warming plate heat insulation effect is not the best, simply plays decoration function, once breaking out of fire, and warming plate leads to
Often can not play good fireproofing function.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of fire-retardant heat insulation plate, and heat conductivity is low, toughness
High with intensity, fire protecting performance is excellent, from fire self-extinguishment.
A kind of fire-retardant heat insulation plate that the present invention proposes, including basic unit, ccf layer, tack coat, waterproof layer, heat-insulation layer, elasticity
Cushion and wear-resistant coating；Ccf layer covers above basic unit；Ccf layer by multiple parallel or be staggered and formed filling chamber
Workpiece composition, fill intracavity be filled with implant；Tack coat covers above ccf layer, and waterproof layer covers on tack coat
Side, heat-insulation layer covers above waterproof layer, and elastic cord breaker covers above heat-insulation layer, and elastic cord breaker upper surface is coated with resistance to
Mill coating forms wear-resistant coating.
Preferably, the raw material of heat-insulation layer includes by weight: polyvinyl benzoic acid 70～75 parts, 10-(2,5-dihydroxy benzenes
Base)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide 160～165 parts, dicyclohexylcarbodiimide 132～136 parts, 4-
Dimethylamino naphthyridine 60～65 parts, p-methyl benzenesulfonic acid 82～88 parts, vermiculite power 1～2 parts, Kaolin 2～4 parts, cetyl
Trimethylammonium bromide 1～2 parts, carboxylated graphene oxide 2～2.5 parts, foaming agent 15～20 parts, blowing promotor 6～8 parts, swollen
Swollen graphite 5～6 parts, mica powder 11～14 parts, Inorganic Hollow Microspheres 5～8 parts, expanded perlite 7～10 parts, potassium titanate fibre 1
～2 parts, nylon fiber 13～16 parts, Firebrake ZB 8～12 parts, age resistor 2～3 parts.
Preferably, in the raw material of heat-insulation layer, polyvinyl benzoic acid, 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxygen
Miscellaneous-10-phospho hetero phenanthrene-10-oxide, dicyclohexylcarbodiimide, DMAP, the weight ratio of p-methyl benzenesulfonic acid are
72～73:162～163:134～135:62～63:84～86.
Preferably, in the raw material of heat-insulation layer, vermiculite power, Kaolin, cetyl trimethylammonium bromide, carboxylated oxidation stone
The weight ratio of ink alkene is 1.5～1.8:2.5～3.5:1.3～1.7:2.2～2.4.
Preferably, the preparation method of heat-insulation layer is as follows:
S1, by 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide and polyvinyl benzoic acid
Add mix homogeneously in dichloromethane to obtain, then drip dicyclohexylcarbodiimide, DMAP, to methylbenzene sulphur
Acid, then heats up, backflow, carries out nitrogen protection, then remove impurity in reflux course, and vacuum drying obtains material a；
S2, by vermiculite power and Kaolin mix homogeneously, then carry out hydro-thermal reaction, be washed out, be dried, add cetyl
Trimethylammonium bromide mix homogeneously, heats up, and insulation does not stop stirring in insulating process, stand cooling, wash in filtrate without bromine from
Son, is dried, and grinds and obtains organic filler；
S3, material a is warming up to molten condition, after adding organic filler and carboxylated graphene oxide mix homogeneously, then
Add expanded graphite, mica powder, Inorganic Hollow Microspheres, expanded perlite, potassium titanate fibre, nylon fiber, Firebrake ZB, age resistor
Mix homogeneously, is subsequently adding foaming agent and blowing promotor mix homogeneously, is coated in waterproof layer surface, then heats up, and insulation obtains
Heat-insulation layer.
Preferably, in the S1 of heat-insulation layer preparation method, it is warming up to 40～45 DEG C, backflow 8～9h.
Preferably, in the S2 of heat-insulation layer preparation method, the temperature of hydro-thermal reaction is 180～200 DEG C, the time of hydro-thermal reaction
It is 2～3h.
Preferably, in the S3 of heat-insulation layer preparation method, it is warming up to 40～45 DEG C, is incubated 2～2.5h.
In the heat-insulation layer preparation process of the present invention, use polyvinyl benzoic acid and 10-(2,5-dihydroxy phenyl)-10-
Hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide reacts, and makes 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxa--10-
Phospho hetero phenanthrene-10-oxide is prone to slough chlorine atom, thus is connected on the benzoic phenolic hydroxyl group of polyvinyl, obtains chlorination simultaneously
Hydrogen, adds diethylamine in course of reaction, promotes reaction equation to carry out to the right, improve polyvinyl benzoic acid and 10-(2,5-
Dihydroxy phenyl) response speed of-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide, gained material a contains phosphoric acid hexichol
Ester group.
Vermiculitum and Kaolin are carried out hydro-thermal reaction, gets through Vermiculitum and the micropore that in Kaolin, estrangement is different originally, make micro-
Pore volume increases, and partial pore under high pressure can be made to be expanded into mesopore, causes average pore size to increase, adds cetyl
Trimethylammonium bromide mix homogeneously, is modified Vermiculitum and kaolin surface, it is easy to compatible with material a, improves organic filler
In the scattered uniformity of material a.
Organic filler coordinates carboxylated graphene oxide dispersed at material a, and organic filler is with less sheet layer unit
Being evenly distributed in material a with carboxylated graphene oxide, the sheet layer unit of organic filler and carboxylated graphene oxide are two
Wiener rice corpuscles, interaction force is relatively strong, and material a coordinates its strand to be fettered with the two, and motor capacity declines, and organic
The specific surface area of filler and carboxylated graphene oxide is big, with material a to have contact interface big, the strongest interface interaction, from
And make organic filler and carboxylated graphene oxide play the effect being equivalent to crosslinking points in microstructure, and potassium titanate is fine
Dimension, nylon fiber promote that in macrostructure material a forms three-dimensional crosslinking structure, and above-mentioned five complement each other to form fine and close crosslinking
Network structure, more micro-crack and plastic deformation can be produced when making material be impacted, thus absorb more impact energy,
Improve toughening effect and intensity.
Wherein limit carboxylated graphene oxide and there is high length-diameter ratio, make the network structure formed in composite the thickest
Close, it is possible to effectively to resist mechanical destruction, reduce layer of charcoal alligatoring, form more complete protective layer.
Owing to material a containing diphenyl phosphate group, improve phosphorus atoms content in material a, make the present invention in burning
During, owing to the bond energy of the C-C key bond energy more than C-P wants big, the phosphorus-containing compound of ability of being heated takes the lead in decompositing phosphoric acid
And multiple organic phospho acid plays covering effect, also cause polymer dehydration to form heat insulation, the carbon residue layer of oxygen barrier, stop heat to
Internal delivery.In material a, phenyl ring is as rigid radical, and P-O key compliance is higher, and phenyl ring and P-O key cooperate, and make material
The rigidity of a and flexibility reach balance, on the one hand make material a water-fast, heat-resisting and compression resistant performance is strengthened, improve material a's
Adhesive force, on the other hand makes the impact flexibility of material a be improved, makes material a be adapted as heat-insulation layer.
And organic filler, carboxylated graphene oxide, expanded graphite and Firebrake ZB cooperate, when heat-insulation layer high temperature,
Intercalation compound rapid vaporization produces huge axial thrust to graphite flake layer, makes expanded graphite expand on hundred along c-axis direction
Thousand times, form the graphite worm with level Four pore structure, be combined be collectively forming partition with organic filler, carboxylated graphene oxide
Layer；And Firebrake ZB thermal decomposition, discharge water of crystallization, play the effect of oxygen in heat absorption cooling effect and diluent air, the opposing party
Face, at high temperature Firebrake ZB decomposes generation boron oxide, is attached on the surface of polymer form one layer of glassy state inorganic intumescent layer；
In insulating course, glassy state inorganic intumescent layer, material a, phosphoric acid and multiple organic phospho acid and carbon residue layer cooperate, on the one hand resistance
Only calory burning conducts to matrix, stops matrix decomposes；On the other hand prevention fuel gas is to external diffusion and oxygen mix,
Effectively cut off the transmission channels of combustion system heat and material, interrupted " combustion triangle shape ", made heat-insulation layer meet fire fire-retardant, from fire
Self-extinguishment.
The heat-insulation layer of the present invention uses modified poly ethylene yl benzoic acid as major ingredient, coordinate organic filler, carboxylated oxygen
Functionalized graphene, expanded graphite, Firebrake ZB, make the fireproofing and heat resistant excellent performance of heat-insulation layer, toughness and adhesive force high, adhesive strength
High；Foaming agent, blowing promotor, Inorganic Hollow Microspheres, expanded perlite cooperate, be substantially reduced heat-insulation layer heat conductivity and
Density, improves heat-proof quality of the present invention；And potassium titanate fibre, mica powder, Inorganic Hollow Microspheres, expanded perlite, hydroxide
Magnesium cooperates, and makes heat-insulation layer tenacity excellent, and compression resistant ability is outstanding, can restrict foaming agent simultaneously and excessively foam, and promotes foaming
Hole uniform pore diameter is consistent.
The ccf layer of the present invention is beneficial to alleviate weight due to being provided with of chamber of filling, saves material, the setting of supporting layer
Be conducive to will be spread out on multiple workpiece of ccf layer by galassing, it is to avoid ccf layer due to workpiece discontinuity cause unreliable
Property.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of a kind of fire-retardant heat insulation plate that the present invention proposes.
Fig. 2 is the schematic diagram of a kind of fire-retardant heat insulation plate center rack-layer that the present invention proposes.
Fig. 3 is the schematic diagram of a kind of fire-retardant heat insulation plate center rack-layer that the present invention proposes.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
As Figure 1-3, Fig. 1 is the schematic diagram of a kind of fire-retardant heat insulation plate that the present invention proposes, and Fig. 2 is the one that the present invention proposes
The schematic diagram of fire-retardant heat insulation plate center rack-layer, Fig. 3 is the schematic diagram of a kind of fire-retardant heat insulation plate center rack-layer that the present invention proposes.
With reference to Fig. 1-3, a kind of fire-retardant heat insulation plate that the present invention proposes, including basic unit 1, ccf layer 2, tack coat 3, waterproof layer
4, heat-insulation layer 5, elastic cord breaker 6 and wear-resistant coating 7；Ccf layer 2 covers above basic unit 1；Ccf layer 2 is by multiple parallel or friendship
Staggered arrangement arranges and is formed the workpiece 21 in filling chamber 20 and forms, and is filled with implant in filling chamber 20；Tack coat 3 covers at ccf layer 2
Top, waterproof layer 4 covers above tack coat 3, and heat-insulation layer 5 covers above waterproof layer 4, and elastic cord breaker 6 covers in insulation
Above layer 5, elastic cord breaker 6 upper surface is coated with wear-resistant paint and forms wear-resistant coating 7.
Embodiment 2
A kind of fire-retardant heat insulation plate, including basic unit 1, ccf layer 2, tack coat 3, waterproof layer 4, heat-insulation layer 5, elastic cord breaker 6 and resistance to
Mill coating 7；Ccf layer 2 covers above basic unit 1；Ccf layer 2 by multiple parallel or be staggered and formed fill chamber 20 work
Part 21 forms, and is filled with implant in filling chamber 20；Tack coat 3 covers above ccf layer 2, and waterproof layer 4 covers at tack coat 3
Top, heat-insulation layer 5 covers above waterproof layer 4, and elastic cord breaker 6 covers above heat-insulation layer 5, elastic cord breaker 6 upper surface
It is coated with wear-resistant paint and forms wear-resistant coating 7.
The raw material of heat-insulation layer 5 includes by weight: 70 parts of polyvinyl benzoic acid, 10-(2,5-dihydroxy phenyl)-10-hydrogen-
9-oxa--10-phospho hetero phenanthrene-10-oxide 165 parts, dicyclohexylcarbodiimide 132 parts, DMAP 65 parts, to first
Base benzenesulfonic acid 82 parts, vermiculite power 2 parts, Kaolin 2 parts, cetyl trimethylammonium bromide 2 parts, carboxylated graphene oxide 2 parts,
Foaming agent 20 parts, blowing promotor 6 parts, expanded graphite 6 parts, mica powder 11 parts, Inorganic Hollow Microspheres 8 parts, expanded perlite 7 parts,
Potassium titanate fibre 2 parts, nylon fiber 13 parts, Firebrake ZB 12 parts, 2 parts of age resistor.
Embodiment 3
A kind of fire-retardant heat insulation plate, including basic unit 1, ccf layer 2, tack coat 3, waterproof layer 4, heat-insulation layer 5, elastic cord breaker 6 and resistance to
Mill coating 7；Ccf layer 2 covers above basic unit 1；Ccf layer 2 by multiple parallel or be staggered and formed fill chamber 20 work
Part 21 forms, and is filled with implant in filling chamber 20；Tack coat 3 covers above ccf layer 2, and waterproof layer 4 covers at tack coat 3
Top, heat-insulation layer 5 covers above waterproof layer 4, and elastic cord breaker 6 covers above heat-insulation layer 5, elastic cord breaker 6 upper surface
It is coated with wear-resistant paint and forms wear-resistant coating 7.
The raw material of heat-insulation layer 5 includes by weight: 75 parts of polyvinyl benzoic acid, 10-(2,5-dihydroxy phenyl)-10-hydrogen-
9-oxa--10-phospho hetero phenanthrene-10-oxide 160 parts, dicyclohexylcarbodiimide 136 parts, DMAP 60 parts, to first
Base benzenesulfonic acid 88 parts, vermiculite power 1 part, Kaolin 4 parts, cetyl trimethylammonium bromide 1 part, carboxylated graphene oxide 2.5
Part, foaming agent 15 parts, blowing promotor 8 parts, expanded graphite 5 parts, mica powder 14 parts, Inorganic Hollow Microspheres 5 parts, expanded perlite 10
Part, potassium titanate fibre 1 part, nylon fiber 16 parts, Firebrake ZB 8 parts, 3 parts of age resistor.
The preparation method of heat-insulation layer 5 is as follows:
S1, by 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide and polyvinyl benzoic acid
Add mix homogeneously in dichloromethane to obtain, then drip dicyclohexylcarbodiimide, DMAP, to methylbenzene sulphur
Acid, then heats up, backflow, carries out nitrogen protection, then remove impurity in reflux course, and vacuum drying obtains material a；
S2, by vermiculite power and Kaolin mix homogeneously, then carry out hydro-thermal reaction, be washed out, be dried, add cetyl
Trimethylammonium bromide mix homogeneously, heats up, and insulation does not stop stirring in insulating process, stand cooling, wash in filtrate without bromine from
Son, is dried, and grinds and obtains organic filler；
S3, material a is warming up to molten condition, after adding organic filler and carboxylated graphene oxide mix homogeneously, then
Add expanded graphite, mica powder, Inorganic Hollow Microspheres, expanded perlite, potassium titanate fibre, nylon fiber, Firebrake ZB, age resistor
Mix homogeneously, is subsequently adding foaming agent and blowing promotor mix homogeneously, is coated in waterproof layer 4 surface, then heats up, and insulation obtains
Heat-insulation layer 5.
Embodiment 4
A kind of fire-retardant heat insulation plate, including basic unit 1, ccf layer 2, tack coat 3, waterproof layer 4, heat-insulation layer 5, elastic cord breaker 6 and resistance to
Mill coating 7；Ccf layer 2 covers above basic unit 1；Ccf layer 2 by multiple parallel or be staggered and formed fill chamber 20 work
Part 21 forms, and is filled with implant in filling chamber 20；Tack coat 3 covers above ccf layer 2, and waterproof layer 4 covers at tack coat 3
Top, heat-insulation layer 5 covers above waterproof layer 4, and elastic cord breaker 6 covers above heat-insulation layer 5, elastic cord breaker 6 upper surface
It is coated with wear-resistant paint and forms wear-resistant coating 7.
The raw material of heat-insulation layer 5 includes by weight: 72 parts of polyvinyl benzoic acid, 10-(2,5-dihydroxy phenyl)-10-hydrogen-
9-oxa--10-phospho hetero phenanthrene-10-oxide 163 parts, dicyclohexylcarbodiimide 134 parts, DMAP 63 parts, to first
Base benzenesulfonic acid 84 parts, vermiculite power 1.8 parts, Kaolin 2.5 parts, cetyl trimethylammonium bromide 1.7 parts, carboxylated graphite oxide
2.2 parts of alkene, foaming agent 18 parts, blowing promotor 6.5 parts, expanded graphite 5.6 parts, mica powder 12 parts, Inorganic Hollow Microspheres 7 parts, swollen
Swollen perlite 8 parts, potassium titanate fibre 1.6 parts, nylon fiber 14 parts, Firebrake ZB 11 parts, 2.5 parts of age resistor.
The preparation method of heat-insulation layer 5 is as follows:
S1, by 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide and polyvinyl benzoic acid
Add mix homogeneously in dichloromethane to obtain, then drip dicyclohexylcarbodiimide, DMAP, to methylbenzene sulphur
Acid, is then warming up to 45 DEG C, and reflux 8h, carries out nitrogen protection, then remove impurity in reflux course, and vacuum drying obtains material a；
S2, by vermiculite power and Kaolin mix homogeneously, then carry out hydro-thermal reaction, the temperature of hydro-thermal reaction is 200 DEG C, and hydro-thermal is anti-
The time answered is 2h, is washed out, and is dried, adds cetyl trimethylammonium bromide mix homogeneously, be warming up to 70 DEG C, insulation
2h, does not stop stirring in insulating process, stand cooling, washs to filtrate without bromide ion, is dried, and grinds and obtains organic filler；
S3, material a is warming up to molten condition, after adding organic filler and carboxylated graphene oxide mix homogeneously, then
Add expanded graphite, mica powder, Inorganic Hollow Microspheres, expanded perlite, potassium titanate fibre, nylon fiber, Firebrake ZB, age resistor
Mix homogeneously, is subsequently adding foaming agent and blowing promotor mix homogeneously, is coated in waterproof layer 4 surface, then heats to 45 DEG C, protects
Temperature 2h obtains heat-insulation layer 5.
Embodiment 5
A kind of fire-retardant heat insulation plate, including basic unit 1, ccf layer 2, tack coat 3, waterproof layer 4, heat-insulation layer 5, elastic cord breaker 6 and resistance to
Mill coating 7；Ccf layer 2 covers above basic unit 1；Ccf layer 2 by multiple parallel or be staggered and formed fill chamber 20 work
Part 21 forms, and is filled with implant in filling chamber 20；Tack coat 3 covers above ccf layer 2, and waterproof layer 4 covers at tack coat 3
Top, heat-insulation layer 5 covers above waterproof layer 4, and elastic cord breaker 6 covers above heat-insulation layer 5, elastic cord breaker 6 upper surface
It is coated with wear-resistant paint and forms wear-resistant coating 7.
The raw material of heat-insulation layer 5 includes by weight: 73 parts of polyvinyl benzoic acid, 10-(2,5-dihydroxy phenyl)-10-hydrogen-
9-oxa--10-phospho hetero phenanthrene-10-oxide 162 parts, dicyclohexylcarbodiimide 135 parts, DMAP 62 parts, to first
Base benzenesulfonic acid 86 parts, vermiculite power 1.5 parts, Kaolin 3.5 parts, cetyl trimethylammonium bromide 1.3 parts, carboxylated graphite oxide
2.4 parts of alkene, foaming agent 16 parts, blowing promotor 7.5 parts, expanded graphite 5.2 parts, mica powder 13 parts, Inorganic Hollow Microspheres 6 parts, swollen
Swollen perlite 9 parts, potassium titanate fibre 1.3 parts, nylon fiber 15 parts, Firebrake ZB 10 parts, 2.8 parts of age resistor.
The preparation method of heat-insulation layer 5 is as follows:
S1, by 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide and polyvinyl benzoic acid
Add mix homogeneously in dichloromethane to obtain, then drip dicyclohexylcarbodiimide, DMAP, to methylbenzene sulphur
Acid, is then warming up to 40 DEG C, and reflux 9h, carries out nitrogen protection, then remove impurity in reflux course, and vacuum drying obtains material a；
S2, by vermiculite power and Kaolin mix homogeneously, then carry out hydro-thermal reaction, the temperature of hydro-thermal reaction is 180 DEG C, and hydro-thermal is anti-
The time answered is 3h, is washed out, and is dried, adds cetyl trimethylammonium bromide mix homogeneously, be warming up to 60 DEG C, insulation
3h, does not stop stirring in insulating process, stand cooling, washs to filtrate without bromide ion, is dried, and grinds and obtains organic filler；
S3, material a is warming up to molten condition, after adding organic filler and carboxylated graphene oxide mix homogeneously, then
Add expanded graphite, mica powder, Inorganic Hollow Microspheres, expanded perlite, potassium titanate fibre, nylon fiber, Firebrake ZB, age resistor
Mix homogeneously, is subsequently adding foaming agent and blowing promotor mix homogeneously, is coated in waterproof layer 4 surface, then heats to 40 DEG C, protects
Temperature 2.5h obtains heat-insulation layer 5.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (8)
1. a fire-retardant heat insulation plate, it is characterised in that include basic unit (1), ccf layer (2), tack coat (3), waterproof layer (4), protect
Temperature layer (5), elastic cord breaker (6) and wear-resistant coating (7)；Ccf layer (2) covers in basic unit (1) top；Ccf layer (2) is by multiple
Parallel or be staggered and form workpiece (21) composition filling chamber (20), it is filled with implant in filling chamber (20)；Tack coat
(3) covering in ccf layer (2) top, waterproof layer (4) covers in tack coat (3) top, and heat-insulation layer (5) covers in waterproof layer (4)
Top, elastic cord breaker (6) covers in heat-insulation layer (5) top, and elastic cord breaker (6) upper surface is coated with wear-resistant paint and is formed resistance to
Mill coating (7).
Fire-retardant heat insulation plate the most according to claim 1, it is characterised in that the raw material of heat-insulation layer (5) includes by weight: polyethylene
Yl benzoic acid 70～75 parts, 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide 160～165
Part, dicyclohexylcarbodiimide 132～136 parts, DMAP 60～65 parts, p-methyl benzenesulfonic acid 82～88 parts, trematodiasis
Stone powder 1～2 parts, Kaolin 2～4 parts, cetyl trimethylammonium bromide 1～2 parts, carboxylated graphene oxide 2～2.5 parts,
Foaming agent 15～20 parts, blowing promotor 6～8 parts, expanded graphite 5～6 parts, mica powder 11～14 parts, Inorganic Hollow Microspheres 5～8
Part, expanded perlite 7～10 parts, potassium titanate fibre 1～2 parts, nylon fiber 13～16 parts, Firebrake ZB 8～12 parts, age resistor 2
～3 parts.
Fire-retardant heat insulation plate the most according to claim 2, it is characterised in that the preparation method of heat-insulation layer (5) is as follows:
S1, by 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide and polyvinyl benzoic acid
Add mix homogeneously in dichloromethane to obtain, then drip dicyclohexylcarbodiimide, DMAP, to methylbenzene sulphur
Acid, then heats up, backflow, carries out nitrogen protection, then remove impurity in reflux course, and vacuum drying obtains material a；
S2, by vermiculite power and Kaolin mix homogeneously, then carry out hydro-thermal reaction, be washed out, be dried, add cetyl
Trimethylammonium bromide mix homogeneously, heats up, and insulation does not stop stirring in insulating process, stand cooling, wash in filtrate without bromine from
Son, is dried, and grinds and obtains organic filler；
S3, material a is warming up to molten condition, after adding organic filler and carboxylated graphene oxide mix homogeneously, then
Add expanded graphite, mica powder, Inorganic Hollow Microspheres, expanded perlite, potassium titanate fibre, nylon fiber, Firebrake ZB, age resistor
Mix homogeneously, is subsequently adding foaming agent and blowing promotor mix homogeneously, is coated in waterproof layer (4) surface, then heats up, be incubated
To heat-insulation layer (5).
Fire-retardant heat insulation plate the most according to claim 2, it is characterised in that in the S1 of heat-insulation layer (5) preparation method, be warming up to
40～45 DEG C, backflow 8～9h.
Fire-retardant heat insulation plate the most according to claim 2, it is characterised in that in the S2 of heat-insulation layer (5) preparation method, hydro-thermal reaction
Temperature be 180～200 DEG C, the time of hydro-thermal reaction is 2～3h.
Fire-retardant heat insulation plate the most according to claim 5, it is characterised in that in the S3 of heat-insulation layer (5) preparation method, be warming up to 40
～45 DEG C, it is incubated 2～2.5h.
Fire-retardant heat insulation plate the most according to claim 5, it is characterised in that in the raw material of heat-insulation layer (5), polyvinyl benzene first
Acid, 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide, dicyclohexylcarbodiimide, 4-bis-
Methylamino pyridine, the weight ratio of p-methyl benzenesulfonic acid are 72～73:162～163:134～135:62～63:84～86.
Fire-retardant heat insulation plate the most according to claim 5, it is characterised in that in the raw material of heat-insulation layer (5), vermiculite power, Kaolin,
Cetyl trimethylammonium bromide, the weight ratio of carboxylated graphene oxide are 1.5～1.8:2.5～3.5:1.3～1.7:2.2
～2.4.
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