CN106049695B - A kind of fire-retardant heat insulation plate - Google Patents
A kind of fire-retardant heat insulation plate Download PDFInfo
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- CN106049695B CN106049695B CN201610426034.6A CN201610426034A CN106049695B CN 106049695 B CN106049695 B CN 106049695B CN 201610426034 A CN201610426034 A CN 201610426034A CN 106049695 B CN106049695 B CN 106049695B
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- fire
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- 238000009413 insulation Methods 0.000 title claims abstract description 36
- 239000003063 flame retardant Substances 0.000 title claims abstract description 24
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 238000000576 coating method Methods 0.000 claims abstract description 17
- 239000000945 filler Substances 0.000 claims abstract description 9
- 239000003973 paint Substances 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 32
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 claims description 30
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 28
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 claims description 23
- 229910002804 graphite Inorganic materials 0.000 claims description 19
- 239000010439 graphite Substances 0.000 claims description 19
- 229910021389 graphene Inorganic materials 0.000 claims description 18
- 239000001257 hydrogen Substances 0.000 claims description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- 239000005995 Aluminium silicate Substances 0.000 claims description 16
- 235000012211 aluminium silicate Nutrition 0.000 claims description 16
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 16
- 239000012766 organic filler Substances 0.000 claims description 16
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 15
- 125000005842 heteroatom Chemical group 0.000 claims description 15
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 15
- 239000010455 vermiculite Substances 0.000 claims description 15
- 235000019354 vermiculite Nutrition 0.000 claims description 15
- 229910052902 vermiculite Inorganic materials 0.000 claims description 15
- -1 2,5- dihydroxy phenyl Chemical group 0.000 claims description 13
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 claims description 13
- 239000004088 foaming agent Substances 0.000 claims description 13
- 239000004005 microsphere Substances 0.000 claims description 13
- 239000010451 perlite Substances 0.000 claims description 13
- 235000019362 perlite Nutrition 0.000 claims description 13
- 238000010792 warming Methods 0.000 claims description 13
- 239000005711 Benzoic acid Substances 0.000 claims description 12
- 235000010233 benzoic acid Nutrition 0.000 claims description 12
- 238000007664 blowing Methods 0.000 claims description 12
- OQRWAMBQGTYSRD-UHFFFAOYSA-N dipotassium;oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[K+].[K+].[Ti+4].[Ti+4].[Ti+4].[Ti+4] OQRWAMBQGTYSRD-UHFFFAOYSA-N 0.000 claims description 12
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 12
- 239000010445 mica Substances 0.000 claims description 12
- 229910052618 mica group Inorganic materials 0.000 claims description 12
- 229920001778 nylon Polymers 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- 238000010992 reflux Methods 0.000 claims description 8
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 7
- 230000003078 antioxidant effect Effects 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 229920001447 polyvinyl benzene Polymers 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- 241000545744 Hirudinea Species 0.000 claims 1
- WRLRISOTNFYPMU-UHFFFAOYSA-N [S].CC1=CC=CC=C1 Chemical compound [S].CC1=CC=CC=C1 WRLRISOTNFYPMU-UHFFFAOYSA-N 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 239000010410 layer Substances 0.000 description 112
- 229960004365 benzoic acid Drugs 0.000 description 14
- 238000010586 diagram Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 4
- 229940092714 benzenesulfonic acid Drugs 0.000 description 4
- 229940006460 bromide ion Drugs 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000004079 fireproofing Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- ASMQGLCHMVWBQR-UHFFFAOYSA-N Diphenyl phosphate Chemical group C=1C=CC=CC=1OP(=O)(O)OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-N 0.000 description 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical class OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
- DXRFZHILMCWCNG-UHFFFAOYSA-N N,N-dimethyl-1,8-naphthyridin-2-amine Chemical compound C1=CC=NC2=NC(N(C)C)=CC=C21 DXRFZHILMCWCNG-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/18—Homopolymers or copolymers of aromatic monomers containing elements other than carbon and hydrogen
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/92—Protection against other undesired influences or dangers
- E04B1/94—Protection against other undesired influences or dangers against fire
- E04B1/941—Building elements specially adapted therefor
- E04B1/942—Building elements specially adapted therefor slab-shaped
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of fire-retardant heat insulation plate, including basic unit, ccf layer, tack coat, waterproof layer, insulating layer, elastic cord breaker and wear-resistant coating；Ccf layer is covered in above basic unit；Ccf layer is filled with filler by multiple parallel or be staggered and form the workpiece of filled cavity and form in filled cavity；Tack coat is covered in above ccf layer, and waterproof layer is covered in above tack coat, and insulating layer is covered in above waterproof layer, and elastic cord breaker is covered in above insulating layer, and elastic cord breaker upper surface forms wear-resistant coating coated with wear-resistant paint.
Description
Technical field
The present invention relates to thermal insulation board technical field, more particularly to a kind of fire-retardant heat insulation plate.
Background technology
The easy-to-understand plank exactly to building insulation that thermal insulation board is said, is to add it by raw material of polystyrene resin
His supplementary material and poly- inclusion, by heating mixing injecting catalyst at the same time, then extrusion molding extrusion molding and the hard bubble that manufactures
Foam plastic plate, has moisture-proof, water resistance, can make reduction building envelope thickness, so as to increase indoor usable floor area.
Current thermal insulation board heat insulation effect simply plays decoration function, once fire occurs, thermal insulation board leads to nor very good
Good fireproofing function can not often be played.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of fire-retardant heat insulation plate, and thermal conductivity factor is low, toughness
High with intensity, fire protecting performance is excellent, from fiery self-extinguishment.
A kind of fire-retardant heat insulation plate proposed by the present invention, including basic unit, ccf layer, tack coat, waterproof layer, insulating layer, elasticity
Cushion and wear-resistant coating；Ccf layer is covered in above basic unit；Ccf layer is by multiple parallel or be staggered and form filled cavity
Workpiece composition, is filled with filler in filled cavity；Tack coat is covered in above ccf layer, and waterproof layer is covered on tack coat
Side, insulating layer are covered in above waterproof layer, and elastic cord breaker is covered in above insulating layer, and elastic cord breaker upper surface is coated with resistance to
Grind coating and form wear-resistant coating.
Preferably, the raw material of insulating layer includes by weight：70~75 parts of polyvinyl benzoic acid, 10- (2,5- dihydroxy benzenes
Base) 160~165 parts of -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides, 132~136 parts of dicyclohexylcarbodiimide, 4-
60~65 parts of dimethylamino naphthyridine, 82~88 parts of p-methyl benzenesulfonic acid, 1~2 part of vermiculite power, 2~4 parts of kaolin, cetyl
1~2 part of trimethylammonium bromide, 2~2.5 parts of carboxylated graphene oxide, 15~20 parts of foaming agent, 6~8 parts of blowing promotor are swollen
Swollen 5~6 parts of graphite, 11~14 parts of mica powder, 5~8 parts of Inorganic Hollow Microspheres, 7~10 parts of expanded perlite, potassium titanate fibre 1
~2 parts, 13~16 parts of nylon fiber, 8~12 parts of zinc borate, 2~3 parts of antioxidant.
Preferably, in the raw material of insulating layer, polyvinyl benzoic acid, 10- (2,5- dihydroxy phenyl) -10- hydrogen -9- oxygen
Miscellaneous -10- phospho hetero phenanthrenes -10- oxides, dicyclohexylcarbodiimide, 4-dimethylaminopyridine, the weight ratio of p-methyl benzenesulfonic acid are
72~73：162~163：134~135：62~63：84~86.
Preferably, in the raw material of insulating layer, vermiculite power, kaolin, cetyl trimethylammonium bromide, carboxylated oxidation stone
The weight ratio of black alkene is 1.5~1.8：2.5~3.5：1.3~1.7：2.2~2.4.
Preferably, the preparation method of insulating layer is as follows：
S1, by 10- (2,5- dihydroxy phenyls) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides and polyvinyl benzene
Formic acid is added to be uniformly mixed in dichloromethane and obtained, and dicyclohexylcarbodiimide, 4-dimethylaminopyridine is then added dropwise, to methyl
Benzene sulfonic acid, then heats up, reflux, carries out nitrogen protection in reflux course, then cleans, vacuum drying obtains material a；
Vermiculite power and kaolin, be uniformly mixed by S2, then carries out hydro-thermal reaction, is washed out, dry, adds 16
Alkyl trimethyl ammonium bromide is uniformly mixed, and is heated up, insulation, is not stopped to stir in insulating process, is stood cooling, wash into filtrate nothing
Bromide ion, dry, grinding obtains organic filler；
S3, by material a be warming up to molten condition, adds organic filler and carboxylated graphene oxide after mixing,
It is subsequently added into expanded graphite, mica powder, Inorganic Hollow Microspheres, expanded perlite, potassium titanate fibre, nylon fiber, zinc borate, anti-
Old agent is uniformly mixed, and then adds foaming agent and blowing promotor is uniformly mixed, coated in waterproof layer surface, then heat up, and is kept the temperature
Obtain insulating layer.
Preferably, in the S1 of insulating layer preparation method, 40~45 DEG C are warming up to, flow back 8~9h.
Preferably, in the S2 of insulating layer preparation method, the temperature of hydro-thermal reaction is 180~200 DEG C, the time of hydro-thermal reaction
For 2~3h.
Preferably, in the S3 of insulating layer preparation method, 40~45 DEG C are warming up to, keeps the temperature 2~2.5h.
In the insulating layer preparation process of the present invention, using polyvinyl benzoic acid and 10- (2,5- dihydroxy phenyl) -10-
Hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides are reacted, and make 10- (2,5- dihydroxy phenyl) -10- hydrogen -9- oxa-s -10-
Phospho hetero phenanthrene -10- oxides are easy to slough chlorine atom, so as to be connected on the phenolic hydroxyl group of polyvinyl benzoic acid, while obtain chlorination
Hydrogen, adds diethylamine during the reaction, promotes reaction equation to carry out to the right, improves polyvinyl benzoic acid and 10- (2,5-
Dihydroxy phenyl) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides reaction speed, resulting material a contains phosphoric acid hexichol
Ester group.
Vermiculite and kaolin are subjected to hydro-thermal reaction, the vermiculite micropore different with script estrangement in kaolin is got through, makes micro-
Pore volume increases, and partial pore can be made to be expanded into mesoporous under high pressure, causes average pore size to increase, adds cetyl
Trimethylammonium bromide is uniformly mixed, and vermiculite and kaolin surface are modified, and is easy to compatible with material a, improves organic filler
In the uniformity that material a disperses.
Organic filler cooperation carboxylated graphene oxide is dispersed in material a, and organic filler is with less layer unit
It is evenly distributed on carboxylated graphene oxide in material a, the piece layer unit and carboxylated graphene oxide of organic filler are two
Wiener rice corpuscles, interaction force is stronger, and material a coordinates its strand to be fettered with the two, and locomitivity declines, and organic
The specific surface area of filler and carboxylated graphene oxide is big, the interface interaction big, very strong with contact interface with material a, from
And organic filler and carboxylated graphene oxide is played the role of in microstructure equivalent to crosslinking points, and potassium titanate is fine
Dimension, nylon fiber promote material a to form three-dimensional crosslinking structure in macrostructure, and above-mentioned five complement each other to form fine and close crosslinking
Net structure, material is produced more micro-cracks and plastic deformation when being impacted, so as to absorb more impact energys,
Improve toughening effect and intensity.
Wherein limiting carboxylated graphene oxide has high length-diameter ratio, makes the network structure that is formed in composite material thicker
It is close, mechanical destruction can be effectively resisted, reduces layer of charcoal alligatoring, forms more complete protective layer.
Due to containing diphenyl phosphate group in material a, phosphorus atoms content in material a is improved, the present invention is being burnt
During, since bond energy of the bond energy of C-C keys more than C-P is big, the phosphorus-containing compound of heated energy force difference takes the lead in decompositing phosphoric acid
And a variety of organic phospho acids play the role of covering, also cause polymer to be dehydrated to form heat-insulated, oxygen barrier carbon residue layer, prevent heat to
Transmit inside.Phenyl ring is as rigid radical in material a, and P-O key compliances are higher, and phenyl ring cooperates with P-O keys, makes material
The rigidity and flexibility of a reaches balance, on the one hand enables that material a is water-fast, heat-resisting and resistance against compression is strengthened, and improves material a's
Adhesive force, is on the other hand improved the impact flexibility of material a, material a is adapted as insulating layer.
And organic filler, carboxylated graphene oxide, expanded graphite and zinc borate cooperate, when insulating layer high temperature,
Intercalation compound rapid vaporization produces graphite flake layer huge axial thrust, expanded graphite is expanded into along c-axis direction on hundred
Thousand times, the graphite worm with level Four pore structure is formed, is combined with organic filler, carboxylated graphene oxide and is collectively forming partition
Layer；And zinc borate thermally decomposes, the crystallization water is discharged, plays the role of oxygen in heat absorption cooling effect and diluent air, the opposing party
Face, zinc borate, which decomposes, at high temperature generates boron oxide, is attached to one layer of glassy state inorganic intumescent layer of formation on the surface of polymer；
Phosphoric acid and a variety of organic phospho acids and carbon residue layer cooperate in insulating course, glassy state inorganic intumescent layer, material a, on the one hand hinder
Only calory burning is conducted to matrix, prevents matrix from being thermally decomposed；On the other hand fuel gas is prevented to external diffusion and oxygen mix,
The transmission channels of combustion system heat and material have effectively been cut off, have interrupted " combustion triangle shape ", have met insulating layer fiery fire-retardant, from fire
Self-extinguishment.
Organic filler, carboxylated oxygen are coordinated as major ingredient using modified poly ethylene yl benzoic acid in the insulating layer of the present invention
Graphite alkene, expanded graphite, zinc borate, make the fireproofing and heat resistant excellent performance of insulating layer, toughness and adhesive force are high, adhesive strength
It is high；Foaming agent, blowing promotor, Inorganic Hollow Microspheres, expanded perlite cooperate, substantially reduce insulating layer thermal conductivity factor and
Density, improves heat-proof quality of the present invention；And potassium titanate fibre, mica powder, Inorganic Hollow Microspheres, expanded perlite, hydroxide
Magnesium cooperates, and makes insulating layer tenacity excellent, and compression resistant ability is outstanding, while can restrict foaming agent and excessively foam, and promotes foaming
Hole uniform pore diameter is consistent.
Being provided with beneficial to weight is mitigated due to filled cavity, saves material, the setting of supporting layer in the ccf layer of the present invention
Be conducive to, by by galassing stand to multiple workpiece of ccf layer, avoid ccf layer due to unreliable caused by workpiece discontinuity
Property.
Brief description of the drawings
Fig. 1 is a kind of schematic diagram of fire-retardant heat insulation plate proposed by the present invention.
Fig. 2 is a kind of schematic diagram of fire-retardant heat insulation plate center rack-layer proposed by the present invention.
Fig. 3 is a kind of schematic diagram of fire-retardant heat insulation plate center rack-layer proposed by the present invention.
Embodiment
In the following, technical scheme is described in detail by specific embodiment.
Embodiment 1
As shown in Figs. 1-3, Fig. 1 is a kind of schematic diagram of fire-retardant heat insulation plate proposed by the present invention, and Fig. 2 is proposed by the present invention
A kind of schematic diagram of fire-retardant heat insulation plate center rack-layer, Fig. 3 are a kind of signal of fire-retardant heat insulation plate center rack-layer proposed by the present invention
Figure.
With reference to Fig. 1-3, a kind of fire-retardant heat insulation plate proposed by the present invention, including basic unit 1, ccf layer 2, tack coat 3, waterproof layer
4th, insulating layer 5, elastic cord breaker 6 and wear-resistant coating 7；Ccf layer 2 is covered in the top of basic unit 1；Ccf layer 2 is by multiple parallel or friendship
The wrong workpiece 21 for arranging and forming filled cavity 20 forms, and filler is filled with filled cavity 20；Tack coat 3 is covered in ccf layer 2
Top, waterproof layer 4 are covered in the top of tack coat 3, and insulating layer 5 is covered in the top of waterproof layer 4, and elastic cord breaker 6 is covered in insulation
The top of layer 5,6 upper surface of elastic cord breaker form wear-resistant coating 7 coated with wear-resistant paint.
Embodiment 2
A kind of fire-retardant heat insulation plate, including basic unit 1, ccf layer 2, tack coat 3, waterproof layer 4, insulating layer 5, elastic cord breaker 6
With wear-resistant coating 7；Ccf layer 2 is covered in the top of basic unit 1；Ccf layer 2 is by multiple parallel or be staggered and form filled cavity 20
Workpiece 21 form, is filled with filler in filled cavity 20；Tack coat 3 is covered in the top of ccf layer 2, and waterproof layer 4 is covered in viscous
The top of layer 3 is tied, insulating layer 5 is covered in the top of waterproof layer 4, and elastic cord breaker 6 is covered in above insulating layer 5, on elastic cord breaker 6
Surface forms wear-resistant coating 7 coated with wear-resistant paint.
The raw material of insulating layer 5 includes by weight：70 parts of polyvinyl benzoic acid, 10- (2,5- dihydroxy phenyl) -10- hydrogen -
165 parts of 9- oxa- -10- phospho hetero phenanthrene -10- oxides, 132 parts of dicyclohexylcarbodiimide, 65 parts of 4-dimethylaminopyridine, to first
82 parts of base benzene sulfonic acid, 2 parts of vermiculite power, 2 parts of kaolin, 2 parts of cetyl trimethylammonium bromide, 2 parts of carboxylated graphene oxide,
20 parts of foaming agent, 6 parts of blowing promotor, 6 parts of expanded graphite, 11 parts of mica powder, 8 parts of Inorganic Hollow Microspheres, 7 parts of expanded perlite,
2 parts of potassium titanate fibre, 13 parts of nylon fiber, 12 parts of zinc borate, 2 parts of antioxidant.
Embodiment 3
A kind of fire-retardant heat insulation plate, including basic unit 1, ccf layer 2, tack coat 3, waterproof layer 4, insulating layer 5, elastic cord breaker 6
With wear-resistant coating 7；Ccf layer 2 is covered in the top of basic unit 1；Ccf layer 2 is by multiple parallel or be staggered and form filled cavity 20
Workpiece 21 form, is filled with filler in filled cavity 20；Tack coat 3 is covered in the top of ccf layer 2, and waterproof layer 4 is covered in viscous
The top of layer 3 is tied, insulating layer 5 is covered in the top of waterproof layer 4, and elastic cord breaker 6 is covered in above insulating layer 5, on elastic cord breaker 6
Surface forms wear-resistant coating 7 coated with wear-resistant paint.
The raw material of insulating layer 5 includes by weight：75 parts of polyvinyl benzoic acid, 10- (2,5- dihydroxy phenyl) -10- hydrogen -
160 parts of 9- oxa- -10- phospho hetero phenanthrene -10- oxides, 136 parts of dicyclohexylcarbodiimide, 60 parts of 4-dimethylaminopyridine, to first
88 parts of base benzene sulfonic acid, 1 part of vermiculite power, 4 parts of kaolin, 1 part of cetyl trimethylammonium bromide, carboxylated graphene oxide 2.5
Part, 15 parts of foaming agent, 8 parts of blowing promotor, 5 parts of expanded graphite, 14 parts of mica powder, 5 parts of Inorganic Hollow Microspheres, expanded perlite 10
Part, 1 part of potassium titanate fibre, 16 parts of nylon fiber, 8 parts of zinc borate, 3 parts of antioxidant.
The preparation method of insulating layer 5 is as follows：
S1, by 10- (2,5- dihydroxy phenyls) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides and polyvinyl benzene
Formic acid is added to be uniformly mixed in dichloromethane and obtained, and dicyclohexylcarbodiimide, 4-dimethylaminopyridine is then added dropwise, to methyl
Benzene sulfonic acid, then heats up, reflux, carries out nitrogen protection in reflux course, then cleans, vacuum drying obtains material a；
Vermiculite power and kaolin, be uniformly mixed by S2, then carries out hydro-thermal reaction, is washed out, dry, adds 16
Alkyl trimethyl ammonium bromide is uniformly mixed, and is heated up, insulation, is not stopped to stir in insulating process, is stood cooling, wash into filtrate nothing
Bromide ion, dry, grinding obtains organic filler；
S3, by material a be warming up to molten condition, adds organic filler and carboxylated graphene oxide after mixing,
It is subsequently added into expanded graphite, mica powder, Inorganic Hollow Microspheres, expanded perlite, potassium titanate fibre, nylon fiber, zinc borate, anti-
Old agent is uniformly mixed, and then adds foaming agent and blowing promotor is uniformly mixed, coated in 4 surface of waterproof layer, then heat up, and is kept the temperature
Obtain insulating layer 5.
Embodiment 4
A kind of fire-retardant heat insulation plate, including basic unit 1, ccf layer 2, tack coat 3, waterproof layer 4, insulating layer 5, elastic cord breaker 6
With wear-resistant coating 7；Ccf layer 2 is covered in the top of basic unit 1；Ccf layer 2 is by multiple parallel or be staggered and form filled cavity 20
Workpiece 21 form, is filled with filler in filled cavity 20；Tack coat 3 is covered in the top of ccf layer 2, and waterproof layer 4 is covered in viscous
The top of layer 3 is tied, insulating layer 5 is covered in the top of waterproof layer 4, and elastic cord breaker 6 is covered in above insulating layer 5, on elastic cord breaker 6
Surface forms wear-resistant coating 7 coated with wear-resistant paint.
The raw material of insulating layer 5 includes by weight：72 parts of polyvinyl benzoic acid, 10- (2,5- dihydroxy phenyl) -10- hydrogen -
163 parts of 9- oxa- -10- phospho hetero phenanthrene -10- oxides, 134 parts of dicyclohexylcarbodiimide, 63 parts of 4-dimethylaminopyridine, to first
84 parts of base benzene sulfonic acid, 1.8 parts of vermiculite power, 2.5 parts of kaolin, 1.7 parts of cetyl trimethylammonium bromide, carboxylated graphite oxide
2.2 parts of alkene, 18 parts of foaming agent, 6.5 parts of blowing promotor, 5.6 parts of expanded graphite, 12 parts of mica powder, 7 parts of Inorganic Hollow Microspheres are swollen
Swollen 8 parts of perlite, 1.6 parts of potassium titanate fibre, 14 parts of nylon fiber, 11 parts of zinc borate, 2.5 parts of antioxidant.
The preparation method of insulating layer 5 is as follows：
S1, by 10- (2,5- dihydroxy phenyls) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides and polyvinyl benzene
Formic acid is added to be uniformly mixed in dichloromethane and obtained, and dicyclohexylcarbodiimide, 4-dimethylaminopyridine is then added dropwise, to methyl
Benzene sulfonic acid, is then warming up to 45 DEG C, and flow back 8h, carries out nitrogen protection in reflux course, then cleans, vacuum drying obtains material
a；
Vermiculite power and kaolin, be uniformly mixed by S2, then carries out hydro-thermal reaction, the temperature of hydro-thermal reaction is 200 DEG C, water
The time of thermal response is 2h, is washed out, dry, adds cetyl trimethylammonium bromide and is uniformly mixed, is warming up to 70 DEG C,
2h is kept the temperature, does not stop to stir in insulating process, stands cooling, is washed into filtrate without bromide ion, dry, grinding obtains organic fill out
Material；
S3, by material a be warming up to molten condition, adds organic filler and carboxylated graphene oxide after mixing,
It is subsequently added into expanded graphite, mica powder, Inorganic Hollow Microspheres, expanded perlite, potassium titanate fibre, nylon fiber, zinc borate, anti-
Old agent is uniformly mixed, and then adds foaming agent and blowing promotor is uniformly mixed, coated in 4 surface of waterproof layer, then heat to 45
DEG C, insulation 2h obtains insulating layer 5.
Embodiment 5
A kind of fire-retardant heat insulation plate, including basic unit 1, ccf layer 2, tack coat 3, waterproof layer 4, insulating layer 5, elastic cord breaker 6
With wear-resistant coating 7；Ccf layer 2 is covered in the top of basic unit 1；Ccf layer 2 is by multiple parallel or be staggered and form filled cavity 20
Workpiece 21 form, is filled with filler in filled cavity 20；Tack coat 3 is covered in the top of ccf layer 2, and waterproof layer 4 is covered in viscous
The top of layer 3 is tied, insulating layer 5 is covered in the top of waterproof layer 4, and elastic cord breaker 6 is covered in above insulating layer 5, on elastic cord breaker 6
Surface forms wear-resistant coating 7 coated with wear-resistant paint.
The raw material of insulating layer 5 includes by weight：73 parts of polyvinyl benzoic acid, 10- (2,5- dihydroxy phenyl) -10- hydrogen -
162 parts of 9- oxa- -10- phospho hetero phenanthrene -10- oxides, 135 parts of dicyclohexylcarbodiimide, 62 parts of 4-dimethylaminopyridine, to first
86 parts of base benzene sulfonic acid, 1.5 parts of vermiculite power, 3.5 parts of kaolin, 1.3 parts of cetyl trimethylammonium bromide, carboxylated graphite oxide
2.4 parts of alkene, 16 parts of foaming agent, 7.5 parts of blowing promotor, 5.2 parts of expanded graphite, 13 parts of mica powder, 6 parts of Inorganic Hollow Microspheres are swollen
Swollen 9 parts of perlite, 1.3 parts of potassium titanate fibre, 15 parts of nylon fiber, 10 parts of zinc borate, 2.8 parts of antioxidant.
The preparation method of insulating layer 5 is as follows：
S1, by 10- (2,5- dihydroxy phenyls) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides and polyvinyl benzene
Formic acid is added to be uniformly mixed in dichloromethane and obtained, and dicyclohexylcarbodiimide, 4-dimethylaminopyridine is then added dropwise, to methyl
Benzene sulfonic acid, is then warming up to 40 DEG C, and flow back 9h, carries out nitrogen protection in reflux course, then cleans, vacuum drying obtains material
a；
Vermiculite power and kaolin, be uniformly mixed by S2, then carries out hydro-thermal reaction, the temperature of hydro-thermal reaction is 180 DEG C, water
The time of thermal response is 3h, is washed out, dry, adds cetyl trimethylammonium bromide and is uniformly mixed, is warming up to 60 DEG C,
3h is kept the temperature, does not stop to stir in insulating process, stands cooling, is washed into filtrate without bromide ion, dry, grinding obtains organic fill out
Material；
S3, by material a be warming up to molten condition, adds organic filler and carboxylated graphene oxide after mixing,
It is subsequently added into expanded graphite, mica powder, Inorganic Hollow Microspheres, expanded perlite, potassium titanate fibre, nylon fiber, zinc borate, anti-
Old agent is uniformly mixed, and then adds foaming agent and blowing promotor is uniformly mixed, coated in 4 surface of waterproof layer, then heat to 40
DEG C, insulation 2.5h obtains insulating layer 5.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of fire-retardant heat insulation plate, it is characterised in that including basic unit（1）, ccf layer（2）, tack coat（3）, waterproof layer（4）, protect
Warm layer（5）, elastic cord breaker（6）And wear-resistant coating（7）；Ccf layer（2）It is covered in basic unit（1）Top；Ccf layer（2）By multiple
It is parallel or be staggered and form filled cavity（20）Workpiece（21）Composition, filled cavity（20）It is interior to be filled with filler；Tack coat
（3）It is covered in ccf layer（2）Top, waterproof layer（4）It is covered in tack coat（3）Top, insulating layer（5）It is covered in waterproof layer（4）
Top, elastic cord breaker（6）It is covered in insulating layer（5）Top, elastic cord breaker（6）Upper surface forms resistance to coated with wear-resistant paint
Grind coating（7）；
Insulating layer（5）Preparation method it is as follows：
S1, by 10- (2,5- dihydroxy phenyls) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides and polyvinyl benzoic acid
Add to be uniformly mixed in dichloromethane and obtain, dicyclohexylcarbodiimide, 4-dimethylaminopyridine is then added dropwise, to methylbenzene sulphur
Acid, then heats up, reflux, carries out nitrogen protection in reflux course, then cleans, vacuum drying obtains material a；
Vermiculite power and kaolin, be uniformly mixed by S2, then carries out hydro-thermal reaction, is washed out, dry, adds cetyl
Trimethylammonium bromide is uniformly mixed, and is heated up, and insulation, does not stop to stir in insulating process, stands cooling, wash into filtrate without bromine from
Son, dry, grinding obtains organic filler；
S3, by material a be warming up to molten condition, adds organic filler and carboxylated graphene oxide after mixing, then
Add expanded graphite, mica powder, Inorganic Hollow Microspheres, expanded perlite, potassium titanate fibre, nylon fiber, zinc borate, antioxidant
It is uniformly mixed, then adds foaming agent and blowing promotor is uniformly mixed, coated in waterproof layer（4）Surface, then heats up, and is warming up to
40~45 DEG C, 2~2.5h of insulation obtains insulating layer（5）.
2. fire-retardant heat insulation plate according to claim 1, it is characterised in that insulating layer（5）Raw material include by weight：Polyethylene
70~75 parts of yl benzoic acid, 10- (2,5- dihydroxy phenyl) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides 160~165
Part, 132~136 parts of dicyclohexylcarbodiimide, 60~65 parts of 4-dimethylaminopyridine, 82~88 parts of p-methyl benzenesulfonic acid, leech
1~2 part of mountain flour, 2~4 parts of kaolin, 1~2 part of cetyl trimethylammonium bromide, 2~2.5 parts of carboxylated graphene oxide,
15~20 parts of foaming agent, 6~8 parts of blowing promotor, 5~6 parts of expanded graphite, 11~14 parts of mica powder, Inorganic Hollow Microspheres 5~8
Part, 7~10 parts of expanded perlite, 1~2 part of potassium titanate fibre, 13~16 parts of nylon fiber, 8~12 parts of zinc borate, antioxidant 2
~3 parts.
3. fire-retardant heat insulation plate according to claim 2, it is characterised in that insulating layer（5）In the S1 of preparation method, it is warming up to
40~45 DEG C, flow back 8~9h.
4. fire-retardant heat insulation plate according to claim 2, it is characterised in that insulating layer（5）In the S2 of preparation method, hydro-thermal reaction
Temperature be 180~200 DEG C, the time of hydro-thermal reaction is 2~3h.
5. fire-retardant heat insulation plate according to claim 2, it is characterised in that insulating layer（5）Raw material in, polyvinyl benzene first
Acid, 10- (2,5- dihydroxy phenyls) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides, dicyclohexylcarbodiimide, 4- bis-
Methylamino pyridine, the weight ratio of p-methyl benzenesulfonic acid are 72~73：162~163：134~135：62~63：84~86.
6. fire-retardant heat insulation plate according to claim 2, it is characterised in that insulating layer（5）Raw material in, vermiculite power, kaolin,
Cetyl trimethylammonium bromide, the weight ratio of carboxylated graphene oxide are 1.5~1.8：2.5~3.5：1.3~1.7：2.2
~2.4.
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| CN107602106A (en) * | 2017-10-31 | 2018-01-19 | 广西旭腾实业集团有限公司 | A kind of foamed ceramic heat-insulation wall plate based on graphene and preparation method thereof |
| CN107759243A (en) * | 2017-10-31 | 2018-03-06 | 广西旭腾实业集团有限公司 | One kind is based on graphene and stone material foamed wall slab and preparation method thereof |
| CN107746250A (en) * | 2017-10-31 | 2018-03-02 | 广西旭腾实业集团有限公司 | Based on graphene and nonmetallic tailings foamed wall slab and preparation method thereof |
| CN108393448B (en) * | 2018-02-09 | 2020-05-19 | 天津荣程联合钢铁集团有限公司 | Ladle covering agent and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201420350Y (en) * | 2009-06-05 | 2010-03-10 | 四川威尔达化工有限公司 | Fire retardant and thermal insulation decoration board |
| CN201620486U (en) * | 2010-04-23 | 2010-11-03 | 郎叶龙 | Novel glass micro bead fire-proof and heat-insulation plate |
| KR101303642B1 (en) * | 2012-10-29 | 2013-09-11 | 주식회사 이파엘지종합특수방수 | Insulation waterproof board having image printing layer and construction method for manufacturing the same |
| CN103642364A (en) * | 2013-12-19 | 2014-03-19 | 中国科学院理化技术研究所 | Heat insulation phase change coating and preparation method thereof |
| CN204298973U (en) * | 2014-10-09 | 2015-04-29 | 高惠冰 | A kind of novel building fire-proof board |
| CN105152676A (en) * | 2015-08-06 | 2015-12-16 | 安徽铭源新型建材科技有限公司 | High-performance heat-insulating inner wall board |
| CN105544754A (en) * | 2016-01-31 | 2016-05-04 | 周紫阳 | Flame-retardant curtain wall insulation board |
-
2016
- 2016-06-16 CN CN201610426034.6A patent/CN106049695B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201420350Y (en) * | 2009-06-05 | 2010-03-10 | 四川威尔达化工有限公司 | Fire retardant and thermal insulation decoration board |
| CN201620486U (en) * | 2010-04-23 | 2010-11-03 | 郎叶龙 | Novel glass micro bead fire-proof and heat-insulation plate |
| KR101303642B1 (en) * | 2012-10-29 | 2013-09-11 | 주식회사 이파엘지종합특수방수 | Insulation waterproof board having image printing layer and construction method for manufacturing the same |
| CN103642364A (en) * | 2013-12-19 | 2014-03-19 | 中国科学院理化技术研究所 | Heat insulation phase change coating and preparation method thereof |
| CN204298973U (en) * | 2014-10-09 | 2015-04-29 | 高惠冰 | A kind of novel building fire-proof board |
| CN105152676A (en) * | 2015-08-06 | 2015-12-16 | 安徽铭源新型建材科技有限公司 | High-performance heat-insulating inner wall board |
| CN105544754A (en) * | 2016-01-31 | 2016-05-04 | 周紫阳 | Flame-retardant curtain wall insulation board |
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