CN106048837B - Wallpaper and its manufacturing method - Google Patents

Wallpaper and its manufacturing method Download PDF

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Publication number
CN106048837B
CN106048837B CN201610207728.0A CN201610207728A CN106048837B CN 106048837 B CN106048837 B CN 106048837B CN 201610207728 A CN201610207728 A CN 201610207728A CN 106048837 B CN106048837 B CN 106048837B
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CN
China
Prior art keywords
husks
fabric
wallpaper
mounting system
adhesive
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Expired - Fee Related
Application number
CN201610207728.0A
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Chinese (zh)
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CN106048837A (en
Inventor
武井千秋
小池伸二
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Kojyo Jyo Co Ltd
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Kojyo Jyo Co Ltd
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Publication of CN106048837A publication Critical patent/CN106048837A/en
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Expired - Fee Related legal-status Critical Current
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Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/06—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00—Walls, panels
    • B32B2607/02—Wall papers, wall coverings
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/04—Silk
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D10B2503/04—Floor or wall coverings; Carpets

Abstract

The present invention provides a kind of while with antibiotic property, high flame retardant, the characteristic of this natural fiber of high-hygroscopicity, adsorbs various gases etc. by photochemical catalyst, and have the natural fiber system wallpaper and its manufacturing method with previous entirely different quality.The wallpaper is the wallpaper for having carried out mounting system with pasting to natural fabric, and is coated with the coating agent containing photochemical catalyst.

Description

Wallpaper and its manufacturing method
Technical field
The present invention relates to a kind of wallpaper and its manufacturing methods.
Background technique
In the type of wallpaper, there are paper system wallpaper, fiber system wallpaper, vinyl chloride resin system wallpaper, plastics system wallpapers, nothing Machine matter system wallpaper, the wallpaper for being formed as the structure of the main material for applying surface and pasting are widely used.Such as 1 institute of patent document State, in fiber system wallpaper, also use by as the natural fiber of the silk of fiber, hair, cotton, fiber crops etc., artificial silk, nylon, Non-woven fabrics, the fabric, braided fabric, yarn of the synthetic fibers composition of polyester, acrylic acid etc..Wherein, silk is as antibiotic property, high fire-retardance Property, high-hygroscopicity material and attracted attention.In addition, it is also proposed that multiple schemes for making wallpaper that there are various functions.
Existing technical literature
Patent document
Patent document No. 5354256 bulletins of 1 Japanese Patent Publication No.
Summary of the invention
The problem to be solved in the present invention
But fail to provide using previous natural fiber as while material, pursue functional wallpaper.
The purpose of the present invention is to provide a kind of with antibiotic property, high flame retardant, high-hygroscopicity this natural fiber While characteristic, by various gases of composite functional ceramic adsorbent etc., promote the decomposition of gas etc. by photochemical catalyst, and With the natural fiber system wallpaper and its manufacturing method with previous entirely different quality.
The means solved the problems, such as
Fabric wallpaper according to the present invention is to have carried out the wallpaper of mounting system with pasting to natural fabric, and be coated with Coating agent containing photochemical catalyst.Natural fabric can be made of husks (キ ビ ソ), ko-hemp cloth, fiber crops, paper mulberry etc..In addition, of the invention Related fabric wallpaper, can be with adsorption of nitrogen other than it can adsorb ammonia, formaldehyde, acetaldehyde, styrene, toluene, dimethylbenzene Partial size in oxide, environmental hormone and so-called PM2.5, the particle to swim in an atmosphere is probably in 2.5 μm of substances below.
Invention effect
By using the wallpaper of the function according to the present invention of having both photochemical catalyst while using natural material, energy It is enough to provide while with antibiotic property, high flame retardant, the characteristic of this silk of high-hygroscopicity, fiber it is thicker and have with Toward the natural of entirely different quality and the fiber system wallpaper of the function that has both adsorbed gas etc..
Detailed description of the invention
Fig. 1 is the block diagram for indicating the manufacturing process of wallpaper according to the present invention.
Fig. 2 is the skeleton diagram for indicating the manufacturing process of wallpaper according to the present invention, and (a) is the skeleton diagram of cocoon, is (b) cocoon The skeleton diagram of clothing, (c) be winding after husks skeleton diagram.
Fig. 3 is the skeleton diagram for indicating the manufacturing process of wallpaper according to the present invention, and (a) is the skeleton diagram of husks fabric, (b) be husks fabric and its pasting skeleton diagram.
Fig. 4 is the skeleton diagram for indicating the manufacturing process of wallpaper according to the present invention, and (a) is the outline of husks product finished product Scheme, is (b) skeleton diagram of husks commodity.
What Fig. 5 was indicated is that the three foundation weave i.e. plain weave that indicates the fabric of wallpaper according to the present invention, twill, satin weave are knitted The combined method figure and completion figure of method.
Fig. 6 is the side view of the laminated structure of wallpaper according to the present invention, indicates that (a) fabric, (b) pasting, (c) are being mounted State, (d) on paper after coating adhesive are with adhesive by the state after pasting and fabric bonding and (e) after coating photocatalyst State composition figure.
Fig. 7 is the composition figure of wallpaper according to the present invention.
Symbol description
18 plain weaves
26 twills
30 satin weaves
32 adhesives
34 husks fabrics
36 pastings
Specific embodiment
Next, referring to attached drawing, detailed description of embodiments of the present invention.Further more, attached in whole described below In figure, identical symbol is accompanied by for identical constituent element, and suitably omit the description.
Fig. 1 shows the manufacturing processes of husks fabric wallpaper according to the present invention.
Husks refers in the silk to spue when the silkworm spins its cocoon, the unfixed silk of the thickness initially to spue.It is identical as silk ingredient, Dangerous hazardous substances are entirely free of, extinguishing chemical is also not particularly limited in fire.But two can be generated in burning Carbonoxide, carbon monoxide.Acute toxicity is especially not present.
As design process, design of material process, Color Scheme process (step S4), warp thread latitude shown in implementation steps S2 The each process of yarn density design process (step S6) and tissue, the design process (step S8) being open.
Design of material process (step S2) is the process for determining silk, pasting, adhesive.
Color Scheme process (step S4) is the process for determining the color of silk.Silk color, in addition to carry out silkworm type and Except the decision of the material color of silk itself, the decision of dyed color is also carried out.
Warp thread weft count design process (step S6) specifies the degree of weft yarn, the ratio of heald frame and degree, and pre- prerequisite Surely it is set as the opening of which kind of degree.
The design process (step S8) of tissue, opening, is the process for being decided to become the husks textile design of wallpaper pattern.It is The process for determining jacquard design, line version.
Configurations (step S10) are the steps for determining to seem preferably to configure to the configuration of each pattern in addition to color Suddenly.
Twisted filament process (step 12), twisted filament, which refers to, carries out twisting, the i.e. twisted meaning to silk.Silkworm initially spues when doing cocoon Cocoon exterior portion silk be lower temple, by for protecting pupa to constitute from the crin of bird or the top of pest infestation.This is most First thick silk is referred to as cocoon net (filoplume).The silk to spue after cocoon net is exactly husks.
For example, the silk being scattered from cocoon (Fig. 2 (a)), is difficult with for hairline.Thus it is possible to by by several Silk forms beam, and lightly carries out twisting to the beam, formed a solid synnema come using.If it is weak twist, then for 500T/m is then 500-1000T/m hereinafter, if it is middle twirl, is then 1000-2500T/m if it is heavy twist, pole Heavy twist is 2500T/m or more.
Dyeing process (step S14) carries out the dyeing of wheel plum and mud dye with bundles of state.
Alternatively, in dyeing process (step S14), although dye by pigment and using dyestuff both, But it is preferable to use acid dyes.In acid dyes, levelling type, half fulling milling type, fulling milling type can be applicable in.Specifically, with acid Property dyestuff first with 40 DEG C dyeing 30-60 minutes, later with 80-90 DEG C dyeing 30-45 minutes, which contains 2-3% Ammonium acetate, 1-2% acetic acid, 0.2% for promoting dyestuff to be uniformly distributed, realize levelling and add the levelling in dye bath Agent.
Then, it is divided into the warp thread process (step S16) of manufacture warp thread and manufactures the weft yarn process (step S38) of weft yarn.
Spinning process (step S18) is the husks removed with cocoon beater to be removed from frame, and wind dry husks Process (Fig. 2 (b)).Husks also can be used in warp thread, but uses that the even thickness of fiber, will not to generate tension unbalanced 16, cotton yarn to 50, cotton yarn.Particularly preferably 40 numbers.Furthermore it is also possible to use spun silk yarn.Further more, as partition board material Material is, it is preferable to use 40 numbers can also use husks if using if it is wallpaper in warp thread.
Warping process (step S20) is to carry out twisted filament, dyeing to precursor according to fabric from the process of precursor manufacture warp thread Afterwards, it spins.It is the process for determining radical, the breadth of the yarn after the spinning, and being organized into defined length.Then, standby The radical of warp thread and gathering together, are uniformly wound around on spool (Fig. 2 (c)) for warp thread woven pieces with being rolled up.
In order to keep the shape of husks, preferably without making the uniform twisting of yarn curve shape.
It connects through process (step S22), for that manufactured spool will be erected on loom in warping process (step S20), with First-class warp thread engagement, passes through heald frame for warp thread, completes the upper machine process of shaping.
Drawing-in process (step S24) is to carry out loom movement after upper machine, into the behaviour before normal operation The process of work.
Weaving process (step S26) is the process that weft yarn is woven into warp thread.It is set using the machine that rapier loom is woven into weft yarn Device and by air spray weft yarn machine both.The characteristic of cooperation fabric is used separately.Weave the fabric being made of husks. Further more, using plain weave (Fig. 3 (a)) herein.This is because tension can be prevented unbalanced, and energy by being set as plain weave It is enough fully to play the unique quality of husks.
Inspection operation (step S28) is to check fabric damage, fabric spot by check device after weaving process terminates The process of point.For example, reflecting from it to fabric irradiation light as detection fabric damage, fabric spotting.
Repair procedure (step S30) is the fabric damage for repairing the fabric found in inspection operation, the work of fabric spotting Sequence.
Manufacturing procedure (step S32) processed is mounted, the fabric being made of husks and pasting are bonded by (Fig. 3 (b)) by adhesive.
Pasting is preferably made of the paper pulp that waste paper is 70% or more.
Adhesive is preferably according to the adhesive of JIS standard (Japanese Industrial Standards) A6922 quality qualification or according to this The adhesive of standard.
Finishing process (step S34) is to bond the process made it dry after fabric and pasting made of husks.
Later, photochemical catalyst manufacturing procedure (step S35) is 30g- with the weight after drying on the husks after mounting system 35g/m2Mode be coated with visible light type photocatalytic coating liquid (Wan Chang Industry Co., Ltd manufacture Original complex function The agent of property ceramic coating), obtain photochemical catalyst processing type natural material wallpaper.Visible light type photocatalytic coating liquid by titanium oxide and Composite functional ceramics and adhesive are constituted.At this time, it is preferable that composite functional ceramics and adhesive are flanked with husks one Touching, and titanium oxide is configured above it.
Titanium oxide is light function catalyst.
Composite functional ceramics be the inside of ceramics and area load and acetaldehyde, formaldehyde, ammonia etc. functional group reactions simultaneously Carry out the ceramics of the substance of ion exchange.If ion exchange material is contacted with a part of the functional group of various organic gas, State as the inhaled material in chemical binding state.
By in can be with the functionality of the state of the bound fraction ion exchange of the functional group of various organic gas Ceramics are adjusted, and can suck various organic gas.
Visible light type photocatalytic coating liquid with the function of sucking organic gas in the functionality ceramic and utilizes light Catalyst function decomposes the function of the organic gas of sucking, utilizes the two Function long-term effects as a result, becoming It constitutes.
Adhesive is the material for improving associativity.
In addition, in present invention, due to paying attention to quality, gloss, the texture of silk, if excellent from photochemical catalyst function Project that is first then being in gonorrhoea is set out, and reduces the addition of photochemical catalyst, therefore take the photochemical catalyst function of inhibiting script, and With functionality ceramic come the method that plays effect.
Article process (step S36) is packaging process, is packaged in the product completed in step S36 and to be capable of shipment Mode is packaged.
Weft yarn process (step S38) is the process for manufacturing weft yarn.
Spinning process (step S40) is the husks removed with cocoon beater to be removed from frame, and wind dry blaze silk Process.
On the other hand, in the design of warp thread weft count, including gait process (step S42) and denting process (step S44)。
In process of gaiting (step S42), convenient opening portion is set in order to move up and down warp thread and squeeze into weft yarn.
Then, denting process (step S44), play the role of by determine warp thread arrangement and density shuttle pass through shed open, Play the role of making warp thread simultaneously and weft yarn is closely sealed squeezes into.It is later exactly drawing-in process.
Further more, being exactly to plan to determine jacquard design process (step S46).Jacquard design process is designed in fabric The process of the plan of weave of surface setting.
Further, line version is the cardboard for controlling loom, is that porose cardboard is arranged in cooperation jacquard design.Passing through will This embossing board combines on loom, is able to carry out the weaving of fabric.
Fig. 5 indicates weaving method when weaving with drawing.Instruction number 18 is plain weave, and instruction number 26 is twill, instruction Number 30 is satin weave.Twill is that warp thread and weft yarn is made alternately to drift along fabric tissue woven, simplest.It is warp thread With weft yarn with two warp thread on weft yarn, the fabric tissue that mode of the warp thread under weft yarn weaves across.It is special Sign is that the intertwined point from yarn from the point of view of front in an inclined direction arranges.With the quality softer than plain weave, there is retractility Advantage that is excellent, being difficult to wrinkle etc..Satin weave be by five or more warp thread, weft yarn constitute, one kind of fabric tissue.It is constituted Flotation line for any yarn in warp thread, weft yarn is considerably less, it appears that only warp thread or weft yarn are revealed in surface.Although fabric is close Degree is high, quality is thick, but has more excellent compared with twill flexibility, good luster feature.But there is not rub resistance, hooking Property.
Fig. 6 indicates the side view when manufacture of husks fabric wallpaper according to the present invention.What Fig. 6 (a) was indicated is to cocoon Clothing silk carries out the husks fabric 34 after plain weave.Then, what Fig. 6 (b) was indicated is pasting 36.In Fig. 6 (c), applied in pasting 36 Cloth adhesive 32.In Fig. 6 (d), husks fabric 34 is bonded in the upper surface of the adhesive 32.
<embodiment 1>
Next, illustrating the embodiment of husks fabric wallpaper according to the present invention.By five ages of 2000 or so silkworms The cocoon of larva carries out cocoon cooking in the hot water of boiling, carries out filature after dry, winds the husks of 900g.The husks of winding is carried out Twisted filament.Warping is carried out to the husks after twisted filament, using husks as weft yarn, using the cotton yarn of 40 numbers as warp thread, with loom with plain weave Weave husks fabric.Then, the coating adhesive in preformed pasting.Bond woven husks fabric on it, i.e., it is complete At.
For the husks fabric wallpaper of completion, the dry husks fabric wallpaper on polyethylene board.Then, from obtained husks Constant weight (A) is taken on fabric wallpaper, lighting one end makes its burning, measures the residual of husks fabric wallpaper after a certain period of time After depositing weight, husks fabric wallpaper survival rate (%) is found out by following formula.Numerical value illustrates that anti-flammability is more excellent closer to 100% It is different.Husks fabric wallpaper survival rate (%)=(B/A) × 100.In addition, smoke state when with visual observation burning, and it is following It states and judges benchmark evaluation smokiness.
Judge benchmark
The case where not seeing smoke substantially is indicated with zero, indicates to see moderate smoke with △, with × indicate to see To a large amount of smoke, when the classification as carrying out judges, husks fabric wallpaper is in the state for not seeing smoke substantially.
<embodiment 2>
By 100cm2Sample be put into the bag of 5L, inject the adjusting to the measure object gas of normal concentration of 3L, pass through Detection pipe (manufacture of (strain) GASTEC company) measurement irradiation ultraviolet light (1.0mW/cm2) (ultraviolet light photograph has been defined as after 2 hours Penetrate) gas concentration of sample.As the pretreatment of sample, 3 hours ultraviolet light (1.0mW/cm are irradiated to the surface of sample2)。 The bag used, the Smart Bag PA manufactured using GL Sciences company, and use nitrogen as diluent gas.Ultraviolet light The black light lamp FL20SBLB that irradiation is manufactured using Liang Gen Toshiba.In addition, what ultraviolet ray intensity meter was manufactured using shore pine photonics C9536-01.The gas used, using formaldehyde No.91L, styrene No.124L, toluene No.122L, dimethylbenzene No.122L, second Benzene No.122L is tested.Slip (%) is defined as follows.
Slip (%)=(stink odor concentration-test stink odor concentration of blank test)/blank test it is smelly Gas constituent concentration } × 100
During the relationship of the gas flow sucked when by measurement range and measurement is shown in Table 1 below.
Table 1
Test result is illustrated using table 2 to table 6.The removal capacity evaluation test of the expression formaldehyde gas of table 2.
The removal capacity evaluation test of table 2 (1) formaldehyde gas
As it appears from the above, the slip that the removal capacity of formaldehyde gas is 95%.
What table 3 indicated is the removal capacity evaluation test of styrene gas.
The removal capacity evaluation test of table 3 (2) styrene gas
As it appears from the above, the slip that the removal capacity of styrene gas is 20%.
What table 4 indicated is the removal capacity evaluation test of toluene gas.
The removal capacity evaluation test of table 4 (3) toluene gas
As it appears from the above, the slip that the removal capacity of toluene gas is 14%.
What table 5 indicated is the removal capacity evaluation test of diformazan benzene gas.
The removal capacity evaluation test of table 5 (4) diformazan benzene gas
As it appears from the above, the slip that the removal capacity of diformazan benzene gas is 18%.
The removing performance evaluation test of the expression ethylbenzene gas of table 6.
The removal capacity evaluation test of table 6 (5) ethylbenzene gas
As it appears from the above, the slip that the removal capacity of ethylbenzene gas is 5%.
<embodiment 3>
Further, in the removing performance evaluation test of ammonia and aldehydes gas, it is divided into the bright condition and the filaments of sun of visible light Part is evaluated.That is, irradiating ultraviolet light in the state of having visible light is bright condition, irradiated in the state of no visible light Ultraviolet light is dark condition.
In table 7, the difference of slip of the ammonia under bright condition and dark condition is tested.
The removal capacity evaluation test [first time exposure test] of ammonia under 7 test result of table (1) photochemical catalyst effect
In table 7, it is bright under the conditions of slip it is 1 percentage point lower than the slip under dark condition.
In table 8, second is carried out to the difference of slip of the ammonia under bright condition and dark condition and is tested.
The removal capacity evaluation test [second of exposure test] of ammonia under 8 photochemical catalyst effect of table
In table 8, it is bright under the conditions of slip it is 3 percentage points lower than the slip under dark condition.
In table 9, the difference of slip of the aldehydes gas under bright condition and dark condition is tested.
The removal capacity evaluation test [first time exposure test] of aldehydes gas under table 9 (2) photochemical catalyst effect
In table 9, it is bright under the conditions of slip and the slip under dark condition there is no difference.
In table 10, the difference of slip of the aldehydes gas under bright condition and dark condition is tested.
Table 10
The removal capacity evaluation test [second of exposure test] of aldehydes gas under photochemical catalyst effect
In table 10, it is bright under the conditions of slip it is 4 percentage points lower than the slip under dark condition.

Claims (2)

1. a kind of husks fabric wallpaper is to carry out mounting system to the husks fabric of plain weave with pasting, weft yarn is husks, warp thread For cotton yarn, the number of the cotton yarn is 16-50 branch, and husks fabric and mounting adhesive for paper carry out mounting system, and husks is without twisting Husks fabric wallpaper, which is characterized in that
It, will be by the titanium oxide containing photochemical catalyst and composite functional ceramics and the painting that constitutes of adhesive after the mounting system of progress Layer agent is coated on husks and obtains, and carries out the substance of ion exchange with functional group reactions by loading, sucks ammonia, formaldehyde, second Aldehyde, styrene, toluene, dimethylbenzene, nitrogen oxides, environmental hormone and PM2.5, and make its decomposition.
2. a kind of manufacturing method of husks fabric wallpaper is to carry out mounting system, weft yarn with pasting to the husks fabric of plain weave For husks, warp thread is cotton yarn,
The number of the cotton yarn is 16-50 branch,
Husks fabric and mounting adhesive for paper carry out mounting system,
Manufacturing method of the husks without the husks fabric wallpaper of twisting, which is characterized in that
After the mounting system of progress, the coating agent being made of titanium oxide and composite functional ceramics and adhesive is coated on husks On, the substance of ion exchange is carried out with functional group reactions by loading, sucks ammonia, formaldehyde, acetaldehyde, styrene, toluene, diformazan Benzene, nitrogen oxides, environmental hormone and PM2.5, and make its decomposition.
CN201610207728.0A 2015-04-06 2016-04-06 Wallpaper and its manufacturing method Expired - Fee Related CN106048837B (en)

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CN109248701A (en) * 2018-09-03 2019-01-22 福建工程学院 Modification wallpaper of photocatalytic degradation of indoor toluene gas and its preparation method and application
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CN1489624A (en) * 2000-12-27 2004-04-14 爱斯旺株式会社 Water-based coating composition for wall paper and wall paper thereof
CN2825281Y (en) * 2005-10-11 2006-10-11 郑夕阳 Wall paper with air cleaning function
CN201265127Y (en) * 2008-08-04 2009-07-01 宁波博艺装饰材料有限公司 Function type wallpaper
CN101724208A (en) * 2008-10-28 2010-06-09 陈静 Wallpaper for releasing negative ions and manufacturing method thereof
CN103384738A (en) * 2011-02-10 2013-11-06 公寓专家株式会社 Kibiso wallpaper and method of kibiso wallpaper
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