CN106048477A - High-wear-resisting titanium-magnesium alloy material and preparation method thereof - Google Patents

High-wear-resisting titanium-magnesium alloy material and preparation method thereof Download PDF

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Publication number
CN106048477A
CN106048477A CN201610617508.5A CN201610617508A CN106048477A CN 106048477 A CN106048477 A CN 106048477A CN 201610617508 A CN201610617508 A CN 201610617508A CN 106048477 A CN106048477 A CN 106048477A
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parts
powder
titanium
magnesium alloy
alloy material
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吴国庆
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/02Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
    • C22C49/10Refractory metals
    • C22C49/11Titanium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C47/00Making alloys containing metallic or non-metallic fibres or filaments
    • C22C47/14Making alloys containing metallic or non-metallic fibres or filaments by powder metallurgy, i.e. by processing mixtures of metal powder and fibres or filaments

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention discloses a high-wear-resisting titanium-magnesium alloy material and a preparation method thereof. The high-wear-resisting titanium-magnesium alloy material is prepared from the following raw materials in parts by weight: 50 to 60 parts of titanium powder, 20 to 30 parts of magnesium powder, 10 to 15 parts of aluminum powder, 10 to 20 parts of zirconium carbide, 4 to 9 parts of asbestos powder, 4 to 9 parts of silicon carbide, 3 to 8 parts of jarosite powder, 6 to 8 parts of germanium dioxide, 6 to 8 parts of nano boron fibers, 4 to 8 parts of yttrium oxide and 3 to 5 parts of oleic acid. The high-wear-resisting titanium-magnesium alloy material prepared by the method has relatively good strength and hardness, wearing resistance and long service life; the raw materials are easy to obtain and the processing cost is low; a preparation process is simple and parameters are easy to control; a production process is safe and environment-friendly and is suitable for large-scale industrial production.

Description

A kind of high abrasion Titanium-magnesium alloy material and preparation method thereof
Technical field
Present invention relates particularly to a kind of high abrasion Titanium-magnesium alloy material and preparation method thereof.
Background technology
Metal material refers to metal or alloy as matrix, and with fiber, whisker, the composite wood that granule etc. is reinforcement Material.By the difference of parent metal used, using temperature range is 350~1200 DEG C.Its feature terms of mechanics be laterally and Shear strength is higher, and the comprehensive mechanical property such as toughness and fatigue is preferable, the most also has heat conduction, conduction, wear-resisting, thermal coefficient of expansion Little, damping and amortization good, the advantage such as non-hygroscopic, the most aging and pollution-free.It is respective that metal-base composites can play group element material Advantage, it is achieved the optimal allocation of each group element material resource, saves precious metal material, it is achieved the unappeasable performance of single metal Requirement, has good economic benefit and social benefit.
Titanium-magnesium alloy material, is employed for space material at the beginning, and density is low, processing performance good, have superior protection against the tide, Anticorrosion, insect protected, the feature such as durable.On civilian, as novel building materials, Titanium-magnesium alloy material is once occurring the most extensively by consumer Favor, mainly apply the reprocessing at construction material, such as products such as titanium magnesium alloy door, titanium magnesium alloy decoration door tracery.Titanium Magnesium alloy profiles Main Ingredients and Appearance is titanium, and the content of magnesium is many, and intensity is high and density is little, good mechanical property, toughness and etch resistant properties Very well.Titanium magnesium alloy section bar has sturdy and durable, moistureproof anti-corrosion characteristic, fashionable generous with its product manufactured, lines Smooth, bright and lustrous, texture is naturally clear, outward appearance elegant, a great variety of models.
Along with modern science and technology globalizes high speed development, the competition between Global Regional presents becoming of multiplex and complication Gesture, has higher requirement to the mechanical property of alloy material.And the most domestic alloy is mainly used in low-end product market, This is the most backward mainly due to the research and development of China's high performance alloys and advanced metallurgical technology, the material therefore produced Material performance is the highest, cannot meet the requirement of high-performance metallurgical product.Currently on the market for having high abrasion Titanium-magnesium alloy material Demand the most all increases, but does not has corresponding premium quality product the most corresponding.The high performance alloys sold on domestic market is basic Being all imported product, the market share of home products is less.To this end, we set about from formula and the technique of product, exploitation is new High performance material, it is provided that a kind of high abrasion Titanium-magnesium alloy material and preparation method thereof.
Summary of the invention
To achieve these goals, the invention provides a kind of high abrasion Titanium-magnesium alloy material and preparation method thereof.
It is an object of the invention to be achieved through the following technical solutions:
A kind of high abrasion Titanium-magnesium alloy material, is prepared by the raw materials in: titanium valve 50-60 part, magnesium powder 20-30 Part, aluminium powder 10-15 part, zirconium carbide 10-20 part, flake asbestos 4-9 part, carborundum 4-9 part, autunezite powder 3-8 part, germanium dioxide 6-8 part, nanometer boron fibre 6-8 part, yittrium oxide 4-8 part, oleic acid 3-5 part.
Described high abrasion Titanium-magnesium alloy material is prepared by the raw materials in: titanium valve 50 parts, magnesium powder 20 parts, aluminium powder 10 Part, zirconium carbide 10 parts, flake asbestos 4 parts, carborundum 4 parts, 3 parts of autunezite powder, germanium dioxide 6 parts, nanometer boron fibre 6 parts, oxygen Change yttrium 4 parts, oleic acid 3 parts.
Described high abrasion Titanium-magnesium alloy material is prepared by the raw materials in: titanium valve 60 parts, magnesium powder 30 parts, aluminium powder 15 Part, zirconium carbide 20 parts, flake asbestos 9 parts, carborundum 9 parts, 8 parts of autunezite powder, germanium dioxide 8 parts, nanometer boron fibre 8 parts, oxygen Change yttrium 4-8 part, oleic acid 3-5 part.
Described high abrasion Titanium-magnesium alloy material is prepared by the raw materials in: titanium valve 55 parts, magnesium powder 25 parts, aluminium powder 13 Part, zirconium carbide 15 parts, flake asbestos 6 parts, carborundum 7 parts, 6 parts of autunezite powder, germanium dioxide 7 parts, nanometer boron fibre 7 parts, oxygen Change yttrium 6 parts, oleic acid 4 parts.
The preparation method of described high abrasion Titanium-magnesium alloy material, the method preparation process is as follows: first joined by each raw material Carrying out batch mixing in batch mixer, join in press equipment by the batch mixing of mix homogeneously, carry out extrusion forming, pressure is 400- 600MPa, pressurize 10-30min, be then sintered the sample suppressed in sintering furnace, and preheating temperature is 250-300 DEG C, Preheating 1h, sintering temperature is 1000-1100 DEG C, and sintering time is 10-30min, is then incubated 10-at 250-350 DEG C 20min, cancellation, finally insulation tempering 1h at 150-180 DEG C,.
Beneficial effect: the high abrasion Titanium-magnesium alloy material that the inventive method prepares has more eager to do well in everything, hardness, wear-resistant Damaging, service life is long;And raw material is easy to get, processing cost is low, preparation technology is simple, parameter is easily-controllable, production process safety and environmental protection, suitable Close large-scale industrial production.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention, although with reference to aforementioned reality Executing example to be described in detail the present invention, for a person skilled in the art, it still can be to aforementioned each enforcement Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent.All essences in the present invention Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Embodiment 1
A kind of high abrasion Titanium-magnesium alloy material, is prepared by the raw materials in: titanium valve 50 parts, magnesium powder 20 parts, aluminium powder 10 parts, zirconium carbide 10 parts, flake asbestos 4 parts, carborundum 4 parts, 3 parts of autunezite powder, germanium dioxide 6 parts, nanometer boron fibre 6 parts, Yittrium oxide 4 parts, oleic acid 3 parts.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, by the batch mixing of mix homogeneously Join in press equipment, carry out extrusion forming, pressure is 400-600MPa, pressurize 10-30min, then will suppress Sample is sintered in sintering furnace, and preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, sintering Time is 10-30min, is then incubated 10-20min, cancellation, finally insulation tempering at 150-180 DEG C at 250-350 DEG C 1h,.
Embodiment 2
A kind of high abrasion Titanium-magnesium alloy material, is prepared by the raw materials in: titanium valve 60 parts, magnesium powder 30 parts, aluminium powder 15 parts, zirconium carbide 20 parts, flake asbestos 9 parts, carborundum 9 parts, 8 parts of autunezite powder, germanium dioxide 8 parts, nanometer boron fibre 8 parts, Yittrium oxide 4-8 part, oleic acid 3-5 part.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, by the batch mixing of mix homogeneously Join in press equipment, carry out extrusion forming, pressure is 400-600MPa, pressurize 10-30min, then will suppress Sample is sintered in sintering furnace, and preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, sintering Time is 10-30min, is then incubated 10-20min, cancellation, finally insulation tempering at 150-180 DEG C at 250-350 DEG C 1h,.
Embodiment 3
A kind of high abrasion Titanium-magnesium alloy material, is prepared by the raw materials in: titanium valve 55 parts, magnesium powder 25 parts, aluminium powder 13 parts, zirconium carbide 15 parts, flake asbestos 6 parts, carborundum 7 parts, 6 parts of autunezite powder, germanium dioxide 7 parts, nanometer boron fibre 7 parts, Yittrium oxide 6 parts, oleic acid 4 parts.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, by the batch mixing of mix homogeneously Join in press equipment, carry out extrusion forming, pressure is 400-600MPa, pressurize 10-30min, then will suppress Sample is sintered in sintering furnace, and preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, sintering Time is 10-30min, is then incubated 10-20min, cancellation, finally insulation tempering at 150-180 DEG C at 250-350 DEG C 1h,.

Claims (5)

1. a high abrasion Titanium-magnesium alloy material, it is characterised in that described high abrasion Titanium-magnesium alloy material is by following weight portion Raw material is made: titanium valve 50-60 part, magnesium powder 20-30 part, aluminium powder 10-15 part, zirconium carbide 10-20 part, flake asbestos 4-9 part, carborundum 4-9 part, autunezite powder 3-8 part, germanium dioxide 6-8 part, nanometer boron fibre 6-8 part, yittrium oxide 4-8 part, oleic acid 3-5 part.
A kind of high abrasion Titanium-magnesium alloy material, it is characterised in that described high abrasion titanium magnesium alloy material Material is prepared by the raw materials in: titanium valve 50 parts, magnesium powder 20 parts, aluminium powder 10 parts, zirconium carbide 10 parts, flake asbestos 4 parts, carbonization Silicon 4 parts, 3 parts of autunezite powder, germanium dioxide 6 parts, nanometer boron fibre 6 parts, yittrium oxide 4 parts, oleic acid 3 parts.
A kind of high abrasion Titanium-magnesium alloy material, it is characterised in that described high abrasion titanium magnesium alloy material Material is prepared by the raw materials in: titanium valve 60 parts, magnesium powder 30 parts, aluminium powder 15 parts, zirconium carbide 20 parts, flake asbestos 9 parts, carbonization Silicon 9 parts, 8 parts of autunezite powder, germanium dioxide 8 parts, nanometer boron fibre 8 parts, yittrium oxide 4-8 part, oleic acid 3-5 part.
A kind of high abrasion Titanium-magnesium alloy material, it is characterised in that described high abrasion titanium magnesium alloy material Material is prepared by the raw materials in: titanium valve 55 parts, magnesium powder 25 parts, aluminium powder 13 parts, zirconium carbide 15 parts, flake asbestos 6 parts, carbonization Silicon 7 parts, 6 parts of autunezite powder, germanium dioxide 7 parts, nanometer boron fibre 7 parts, yittrium oxide 6 parts, oleic acid 4 parts.
5. one kind according to the preparation method of high abrasion Titanium-magnesium alloy material described in claim 1-4, it is characterised in that the party's legal system Standby step is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, the batch mixing of mix homogeneously is joined press equipment In, carrying out extrusion forming, pressure is 400-600MPa, and then the sample suppressed is entered in sintering furnace by pressurize 10-30min Row sintering, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, and sintering time is 10-30min, so After at 250-350 DEG C be incubated 10-20min, cancellation, finally at 150-180 DEG C insulation tempering 1h,.
CN201610617508.5A 2016-07-28 2016-07-28 High-wear-resisting titanium-magnesium alloy material and preparation method thereof Pending CN106048477A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111485183A (en) * 2020-05-19 2020-08-04 上海叁健新材料科技有限公司 Gradient nano-structure titanium alloy and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104372234A (en) * 2014-10-29 2015-02-25 苏州莱特复合材料有限公司 High-wear-resistance titanium-copper nickel-silicon alloy composite material and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104372234A (en) * 2014-10-29 2015-02-25 苏州莱特复合材料有限公司 High-wear-resistance titanium-copper nickel-silicon alloy composite material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111485183A (en) * 2020-05-19 2020-08-04 上海叁健新材料科技有限公司 Gradient nano-structure titanium alloy and preparation method thereof

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Application publication date: 20161026