CN105886876A - High-heat-resistance titanium-magnesium alloy material and preparation method thereof - Google Patents

High-heat-resistance titanium-magnesium alloy material and preparation method thereof Download PDF

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CN105886876A
CN105886876A CN201610473755.2A CN201610473755A CN105886876A CN 105886876 A CN105886876 A CN 105886876A CN 201610473755 A CN201610473755 A CN 201610473755A CN 105886876 A CN105886876 A CN 105886876A
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parts
powder
titanium
alloy material
magnesium alloy
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陆志强
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/05Mixtures of metal powder with non-metallic powder
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/10Alloys containing non-metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C14/00Alloys based on titanium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0089Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with other, not previously mentioned inorganic compounds as the main non-metallic constituent, e.g. sulfides, glass
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C47/00Making alloys containing metallic or non-metallic fibres or filaments
    • C22C47/14Making alloys containing metallic or non-metallic fibres or filaments by powder metallurgy, i.e. by processing mixtures of metal powder and fibres or filaments
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/02Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/02Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
    • C22C49/10Refractory metals
    • C22C49/11Titanium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/14Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Powder Metallurgy (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

The invention discloses high-heat-resistance titanium-magnesium alloy material and a preparation method thereof. The high-heat-resistance titanium-magnesium alloy material is made from the following materials according to parts by weight: 60-70 parts of titanium powder, 45-55 parts of magnesium powder, 14-20 parts of silicon oxide, 2-9 parts of realgar powder, 10-20 parts of nickel oxide powder, 6-14 parts of carbon fiber, 3-11 parts of pyrrhotite powder, 3-8 parts of graphene, 2-6 parts of iron citrate, 10-15 parts of glass fiber, and 12-16 parts of synthetic wax. The high-heat-resistance titanium-magnesium alloy material prepared by the method has high strength and hardness, excellent properties, wear resistance and good heat resistance, may operate under strict conditions such as high load and high temperature, and is suitable for large-scale production and worthy of popularization.

Description

A kind of high heat-resisting Titanium-magnesium alloy material and preparation method thereof
Technical field
Present invention relates particularly to a kind of high heat-resisting Titanium-magnesium alloy material and preparation method thereof.
Background technology
Metal material refers to metal or alloy as matrix, and with fiber, whisker, particle etc. is The composite of reinforcement.By the difference of parent metal used, use temperature range be 350~ 1200℃.Its feature is laterally and shear strength is higher in terms of mechanics, and toughness and fatigue etc. are combined Make a concerted effort to learn better performances, the most also have heat conduction, conduction, wear-resisting, thermal coefficient of expansion is little, resistance The advantages such as Buddhist nun's property is good, non-hygroscopic, the most aging and pollution-free.Metal-base composites can play The respective advantage of group element material, it is achieved the allocation optimum of each group element material resource, saves valuable gold Belong to material, it is achieved the unappeasable performance requirement of single metal, have good economic benefit and Social benefit.
Titanium-magnesium alloy material, is employed for space material at the beginning, and density is low, processing performance good, There is superior protection against the tide, anticorrosion, insect protected, the feature such as durable.On civilian, as novel Building materials, Titanium-magnesium alloy material is the most extensively favored by consumer once appearance, is mainly applied and building Build the reprocessing of material, such as products such as titanium magnesium alloy door, titanium magnesium alloy decoration door tracery.Titanium magnesium Alloy profile Main Ingredients and Appearance is titanium, and the content of magnesium is many, and intensity is high and density is little, mechanical performance Good, toughness and etch resistant properties are fine.Titanium magnesium alloy section bar has sturdy and durable, moistureproof anti-corrosion Characteristic, fashionable generous with its product manufactured, the lines flow smoothly, bright and lustrous, texture from The most clear, outward appearance elegant, a great variety of models.
Along with modern science and technology globalization high speed development, the competition between Global Regional presents multiplex With the trend complicated, the mechanical property of alloy material is had higher requirement.And it is current Domestic alloy is mainly used in low-end product market, this mainly due to China's high performance alloys with And the research and development of advanced person's metallurgical technology is the most backward, the material property therefore produced is the highest, The requirement of high-performance metallurgical product cannot be met.Currently on the market for having the conjunction of high heat-resisting titanium magnesium Gold copper-base alloy demand the most all increases, but does not has corresponding premium quality product the most corresponding.Domestic city The high performance alloys sold on field is substantially imported product, and the occupation rate of market of home products is more Few.To this end, we set about from formula and the technique of product, develop new high performance material, carry For a kind of high heat-resisting Titanium-magnesium alloy material and preparation method thereof.
Summary of the invention
To achieve these goals, the invention provides a kind of high heat-resisting Titanium-magnesium alloy material and Preparation method.
It is an object of the invention to be achieved through the following technical solutions:
A kind of high heat-resisting Titanium-magnesium alloy material, is prepared by the raw materials in: titanium valve 60-70 Part, magnesium powder 45-55 part, silica 14-20 part, realgar powder 2-9 part, nickel oxide powder 10-20 Part, carbon fiber 6-14 part, magnetic iron ore powder 3-11 part, Graphene 3-8 part, ironic citrate 2-6 part, glass fibre 10-15 part, synthetic wax 12-16 part.
The heat-resisting Titanium-magnesium alloy material of described height is prepared by the raw materials in: titanium valve 60 parts, 45 parts of magnesium powder, silica 14 parts, realgar powder 2 parts, nickel oxide powder 10 parts, carbon fiber 6 Part, 3 parts of magnetic iron ore powder, Graphene 3 parts, ironic citrate 2 parts, 10 parts of glass fibre, Synthetic wax 12 parts.
The heat-resisting Titanium-magnesium alloy material of described height is prepared by the raw materials in: titanium valve 70 parts, 55 parts of magnesium powder, silica 20 parts, realgar powder 9 parts, nickel oxide powder 20 parts, carbon fiber 14 Part, 11 parts of magnetic iron ore powder, Graphene 8 parts, ironic citrate 6 parts, 15 parts of glass fibre, Synthetic wax 16 parts.
The heat-resisting Titanium-magnesium alloy material of described height is prepared by the raw materials in: titanium valve 65 parts, 50 parts of magnesium powder, silica 17 parts, realgar powder 6 parts, nickel oxide powder 15 parts, carbon fiber 10 Part, 7 parts of magnetic iron ore powder, Graphene 6 parts, ironic citrate 4 parts, 13 parts of glass fibre, Synthetic wax 14 parts.
The preparation method of the heat-resisting Titanium-magnesium alloy material of described height, the method preparation process is as follows: first Each raw material is joined in batch mixer and carry out batch mixing, the batch mixing mixed is joined forcing press In equipment, carrying out extrusion forming, pressure is 400-600MPa, pressurize 10-30min, then Being sintered in sintering furnace by the sample suppressed, preheating temperature is 250-300 DEG C, preheating 1h, sintering temperature is 1000-1100 DEG C, and sintering time is 10-30min, then exists 10-20min, cancellation, finally insulation tempering at 150-180 DEG C it is incubated at 250-350 DEG C 1h,.
Beneficial effect: the heat-resisting Titanium-magnesium alloy material of height that the inventive method prepares has preferably By force, hardness, excellent performance, wear-resistant, heat resistance good, can be in high load capacity, hot conditions Work Deng under exacting terms, can be mass-produced, be worthy to be popularized.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention, Although the present invention being described in detail with reference to previous embodiment, for the technology of this area For personnel, the technical scheme described in foregoing embodiments still can be modified by it, Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention Within the scope of.
Embodiment 1
A kind of high heat-resisting Titanium-magnesium alloy material, is prepared by the raw materials in: titanium valve 60 Part, 45 parts of magnesium powder, silica 14 parts, realgar powder 2 parts, nickel oxide powder 10 parts, carbon fibre Tie up 6 parts, 3 parts of magnetic iron ore powder, Graphene 3 parts, ironic citrate 2 parts, glass fibre 10 parts, synthetic wax 12 parts.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, will The batch mixing mixed joins in press equipment, carries out extrusion forming, pressure For 400-600MPa, pressurize 10-30min, then the sample suppressed is entered in sintering furnace Row sintering, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, Sintering time is 10-30min, then insulation 10-20min at 250-350 DEG C, cancellation, Last insulation tempering 1h at 150-180 DEG C,.
Embodiment 2
A kind of high heat-resisting Titanium-magnesium alloy material, is prepared by the raw materials in: titanium valve 70 Part, 55 parts of magnesium powder, silica 20 parts, realgar powder 9 parts, nickel oxide powder 20 parts, carbon fibre Tie up 14 parts, 11 parts of magnetic iron ore powder, Graphene 8 parts, ironic citrate 6 parts, glass fibre 15 parts, synthetic wax 16 parts.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, will The batch mixing mixed joins in press equipment, carries out extrusion forming, pressure For 400-600MPa, pressurize 10-30min, then the sample suppressed is entered in sintering furnace Row sintering, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, Sintering time is 10-30min, then insulation 10-20min at 250-350 DEG C, cancellation, Last insulation tempering 1h at 150-180 DEG C,.
Embodiment 3
A kind of high heat-resisting Titanium-magnesium alloy material, is prepared by the raw materials in: titanium valve 65 Part, 50 parts of magnesium powder, silica 17 parts, realgar powder 6 parts, nickel oxide powder 15 parts, carbon fibre Tie up 10 parts, 7 parts of magnetic iron ore powder, Graphene 6 parts, ironic citrate 4 parts, glass fibre 13 parts, synthetic wax 14 parts.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, will The batch mixing mixed joins in press equipment, carries out extrusion forming, pressure For 400-600MPa, pressurize 10-30min, then the sample suppressed is entered in sintering furnace Row sintering, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, Sintering time is 10-30min, then insulation 10-20min at 250-350 DEG C, cancellation, Last insulation tempering 1h at 150-180 DEG C,.

Claims (5)

1. one kind high heat-resisting Titanium-magnesium alloy material, it is characterised in that described height heat-resisting titanium magnesium closes Gold copper-base alloy is prepared by the raw materials in: titanium valve 60-70 part, magnesium powder 45-55 part, oxygen SiClx 14-20 part, realgar powder 2-9 part, nickel oxide powder 10-20 part, carbon fiber 6-14 part, Magnetic iron ore powder 3-11 part, Graphene 3-8 part, ironic citrate 2-6 part, glass fibre 10-15 Part, synthetic wax 12-16 part.
A kind of high heat-resisting Titanium-magnesium alloy material, it is characterised in that The heat-resisting Titanium-magnesium alloy material of described height is prepared by the raw materials in: titanium valve 60 parts, magnesium 45 parts of powder, silica 14 parts, realgar powder 2 parts, nickel oxide powder 10 parts, 6 parts of carbon fiber, 3 parts of magnetic iron ore powder, Graphene 3 parts, ironic citrate 2 parts, 10 parts of glass fibre, conjunction Become 12 parts of wax.
A kind of high heat-resisting Titanium-magnesium alloy material, it is characterised in that The heat-resisting Titanium-magnesium alloy material of described height is prepared by the raw materials in: titanium valve 70 parts, magnesium 55 parts of powder, silica 20 parts, realgar powder 9 parts, nickel oxide powder 20 parts, 14 parts of carbon fiber, 11 parts of magnetic iron ore powder, Graphene 8 parts, ironic citrate 6 parts, 15 parts of glass fibre, conjunction Become 16 parts of wax.
A kind of high heat-resisting Titanium-magnesium alloy material, it is characterised in that The heat-resisting Titanium-magnesium alloy material of described height is prepared by the raw materials in: titanium valve 65 parts, magnesium 50 parts of powder, silica 17 parts, realgar powder 6 parts, nickel oxide powder 15 parts, 10 parts of carbon fiber, 7 parts of magnetic iron ore powder, Graphene 6 parts, ironic citrate 4 parts, 13 parts of glass fibre, conjunction Become 14 parts of wax.
5. the preparation side of the heat-resisting Titanium-magnesium alloy material of height according to any one of claim 1-4 Method, it is characterised in that the method preparation process is as follows: first each raw material is joined in batch mixer Carry out batch mixing, the batch mixing mixed joined in press equipment, carry out extrusion forming, Pressure is 400-600MPa, pressurize 10-30min, then by the sample that suppresses at sintering furnace Inside being sintered, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, sintering time is 10-30min, is then incubated at 250-350 DEG C 10-20min, cancellation, finally insulation tempering 1h at 150-180 DEG C,.
CN201610473755.2A 2016-06-22 2016-06-22 High-heat-resistance titanium-magnesium alloy material and preparation method thereof Pending CN105886876A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106367650A (en) * 2016-08-29 2017-02-01 桂林新艺制冷设备有限责任公司 Wear-resisting material for slag hole of gasifier
CN107338386A (en) * 2017-06-16 2017-11-10 苏州莱特复合材料有限公司 A kind of preparation method of aluminium lithium alloy material
CN109082569A (en) * 2018-09-13 2018-12-25 太原理工大学 A kind of preparation method of nano silica/Fe 3 O 4 magnetic radiography particulate reinforcement biology magnesium-based composite material

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104372234A (en) * 2014-10-29 2015-02-25 苏州莱特复合材料有限公司 High-wear-resistance titanium-copper nickel-silicon alloy composite material and preparation method thereof
CN104372254A (en) * 2014-10-29 2015-02-25 苏州莱特复合材料有限公司 Silicon-carbide-particle-reinforced iron-base composite material and preparation method thereof
CN104388760A (en) * 2014-10-29 2015-03-04 苏州莱特复合材料有限公司 Boron oxide particle blended titanium-aluminum-based powder metallurgical material and application thereof
CN105108136A (en) * 2015-09-23 2015-12-02 徐�明 High-temperature alloy fiber powder metallurgy material and preparing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104372234A (en) * 2014-10-29 2015-02-25 苏州莱特复合材料有限公司 High-wear-resistance titanium-copper nickel-silicon alloy composite material and preparation method thereof
CN104372254A (en) * 2014-10-29 2015-02-25 苏州莱特复合材料有限公司 Silicon-carbide-particle-reinforced iron-base composite material and preparation method thereof
CN104388760A (en) * 2014-10-29 2015-03-04 苏州莱特复合材料有限公司 Boron oxide particle blended titanium-aluminum-based powder metallurgical material and application thereof
CN105108136A (en) * 2015-09-23 2015-12-02 徐�明 High-temperature alloy fiber powder metallurgy material and preparing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106367650A (en) * 2016-08-29 2017-02-01 桂林新艺制冷设备有限责任公司 Wear-resisting material for slag hole of gasifier
CN107338386A (en) * 2017-06-16 2017-11-10 苏州莱特复合材料有限公司 A kind of preparation method of aluminium lithium alloy material
CN109082569A (en) * 2018-09-13 2018-12-25 太原理工大学 A kind of preparation method of nano silica/Fe 3 O 4 magnetic radiography particulate reinforcement biology magnesium-based composite material
CN109082569B (en) * 2018-09-13 2020-04-21 太原理工大学 Preparation method of nano silicon dioxide/ferroferric oxide magnetic contrast particle enhanced biological magnesium-based composite material

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