CN101289718A - Metallic glass material synthesized from metallic elements - Google Patents
Metallic glass material synthesized from metallic elements Download PDFInfo
- Publication number
- CN101289718A CN101289718A CNA2007101718476A CN200710171847A CN101289718A CN 101289718 A CN101289718 A CN 101289718A CN A2007101718476 A CNA2007101718476 A CN A2007101718476A CN 200710171847 A CN200710171847 A CN 200710171847A CN 101289718 A CN101289718 A CN 101289718A
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- Prior art keywords
- metallic
- glass material
- elements
- metallic elements
- material synthesized
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 title claims abstract description 28
- 239000005300 metallic glass Substances 0.000 title claims abstract description 13
- 229910052742 iron Inorganic materials 0.000 claims abstract description 7
- 229910052796 boron Inorganic materials 0.000 claims abstract description 6
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 6
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 6
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 6
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 6
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 6
- 239000007769 metal material Substances 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 4
- 239000011521 glass Substances 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 4
- 101100055224 Anemone leveillei AL10 gene Proteins 0.000 claims description 3
- 238000003723 Smelting Methods 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 3
- 238000002425 crystallisation Methods 0.000 claims description 3
- 230000008025 crystallization Effects 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000005491 wire drawing Methods 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001315 Tool steel Inorganic materials 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Sliding Valves (AREA)
- Glass Compositions (AREA)
Abstract
The invention provides metallic glass materials synthesized by metallic elements. The materials consist of the following elements: Fe, Zr, Ni, Cu, be, Ti, Al, Co, Y, Cr, B, p, Nb, w, Mn, Mo and C. The metallic glass materials synthesized by the metallic elements have the advantages of corrosion resistance, high temperature resistance, service life being 2 to 5 times longer and light weight being three fifths to one half lighter than those of the prior metallic materials,, low cost and high use value, so that the metallic glass materials are particularly suitable for special industrial fields.
Description
Affiliated technical field:
The present invention relates to a kind of metal glass material, particularly a kind of metallic glass material synthesized from metallic elements belongs to metallic substance practical technique field.
Background technology:
Because traditional metal materials is normal because of resisting the abominable performance of medium in special industry uses, and can not improve production output and reduce cost, the chemical metallization material began to obtain to pay attention to and research from nineteen nineties, and particularly metal glass material at home and abroad is applied in the military aerospace field.But industries such as chemical industry, metallurgy, mine are not also found the applied metal glass material at home at present.
Summary of the invention:
The object of the present invention is to provide a kind of metallic glass material synthesized from metallic elements with high strength, snappiness, high tenacity and high corrosion resistance.
Another object of the present invention is to provide the preparation method of this metallic glass material synthesized from metallic elements.
A kind of metallic element synthetic glass material of the present invention is characterized in that the component of this glass material synthesized from metallic is: Fe, Zr, Ni, Cu, be, Ti, AL, Co, Y, Cr, B, p, Nb, w, Mn, Mo, C.
The preparation method of the synthetic metallic glass of this metallic element is as follows:
Fe, Zr, Ni, Cu, be, Ti, AL, Co, Y, Cr, B, p, Nb, w, Mn, Mo, C are prepared according to the atomic percent (seeing following eight examples) of defined, mix and put into the stove melting together, 1650 ℃～1750 ℃ of smelting temperatures, be smelted into mother alloy to all metallic elements, then according to the requirement of material requested, casting and wire-drawing shape are more earlier after 850 ℃ of coring of high temperature and 750 ℃ of crystallization of high temperature make each metallic element crystallite evenly separate out growth at last.Can change each metallic element component content according to the difference of materials used performance, be cast into required Industrial Metal glass material.
Example 1:Zr58%, Cu20%, Ni10%, Ti5%, be5%, C2%
Example 2:Zr55%, Ni10%, Cu17%, AL10%, Nb4%, be2%, Ti2%, C1.5%
Example 3:ni40%, Cu18%, Zr33%, Ti4%, Nb5%
Example 4:ni50%, mo25%, nb5%, Cr15%, p10%
Example 5:Fe45%, Cr5%, Co5%, Mo12.5%, Mn11%, C14%, B6%, Y1.5%
Example 6:Fe68%, Cr11%, p15%, C6%
Example 7:Fe60%, Co2%, Zr20%, Mo8%, w4%, B5%
Example 8:Fe50%, Ni30%, Co2%, Mo8%, w4%, Zr6%
The present invention has following conspicuous outstanding feature and advantage compared with prior art: a kind of metallic glass material synthesized from metallic elements of the present invention, and its breaking tenacity reaches 3500mpa, and is higher 6 times than the intensity of general steel; Elasticity is also good than common metal, and crooked deformation can reach more than 50%; Has high toughness simultaneously, when breaking tenacity is 2600mpa, still can carry out the cold-rolled steel processing of deformation 30%-50%, when vickers hardness hv can reach 1000mpa, be equivalent to high rigidity tool steel level, its corrosion resistance of iron based metallic glass that contains Cr in addition is better than stainless material.Therefore, a kind of metallic element synthetic glass material of the present invention not only has the characteristics of corrosion-resistant, high temperature resistant, wear-resistant and high strength, low heat expansion, and work-ing life than the high 2-5 of existing metallic substance doubly, 3/5-1/2 in light weight, price is low, the use value height is specially adapted to the special industry field.
Embodiment
Metallic element atomic percents (seeing following eight examples) according to the rules such as Fe, Zr, Ni, Cu, be, Ti, AL, Co, Y, Cr, B, p, Nb, w, Mn, Mo, C are prepared, mix and put into the stove melting together, 1650 ℃～1750 ℃ of smelting temperatures, be smelted into mother alloy to all metallic elements, then according to the requirement of material requested, casting and wire-drawing shape are more earlier after 850 ℃ of coring of high temperature and 750 ℃ of crystallization of high temperature make each metallic element crystallite evenly separate out growth at last.Can change each metallic element component content according to the difference of materials used performance.
Example 1:Zr58%, Cu20%, Ni10%, Ti5%, be5%, C2%
Example 2:Zr55%, Ni10%, Cu17%, AL10%, Nb4%, be2%, Ti2%, C1.5%
Example 3:ni40%, Cu18%, Zr33%, Ti4%, Nb5%
Example 4:ni50%, mo25%, nb5%, Cr15%, p10%
Example 5:Fe45%, Cr5%, Co5%, Mo12.5%, Mn11%, C14%, B6%, Y1.5%
Example 6:Fe68%, Cr11%, p15%, C6%
Example 7:Fe60%, Co2%, Zr20%, Mo8%, w4%, B5%
Example 8:Fe50%, Ni30%, Co2%, Mo8%, w4%, Zr6%
Claims (3)
1, a kind of metallic glass material synthesized from metallic elements is characterized in that, the component of this metal glass material is: Fe, Zr, Ni, Cu, be, Ti, AL, Co, Y, Cr, B, p, Nb, w, Mn, Mo, C.
2, a kind of metallic glass material synthesized from metallic elements according to claim 1 is characterized in that, the component of this metal glass material and content (atomic percent) are following eight examples:
Example 1:Zr58%, Cu20%, Ni10%, Ti5%, be5%, C2%
Example 2:Zr55%, Ni10%, Cu17%, AL10%, Nb4%, be2%, Ti2%, C1.5%
Example 3:ni40%, Cu18%, Zr33%, Ti4%, Nb5%
Example 4:ni50%, mo25%, nb5%, Cr15%, p10%
Example 5:Fe45%, Cr5%, Co5%, Mo12.5%, Mn11%, C14%, B6%, Y1.5%
Example 6:Fe68%, Cr11%, p15%, C6%
Example 7:Fe60%, Co2%, Zr20%, Mo8%, w4%, B5%
Example 8:Fe50%, Ni30%, Co2%, Mo8%, w4%, Zr6%
3, the preparation method of the synthetic metallic substance of a kind of metallic element, it is characterized in that, its preparation method is as follows: with Fe, Zr, Ni, Cu, be, Ti, AL, Co, Y, Cr, B, p, Nb, w, Mn, Mo, metallic elements such as C atomic percent according to the rules prepares, mix and put into the stove melting together, 1650 ℃～1750 ℃ of smelting temperatures, be smelted into mother alloy to all metallic elements, then according to the requirement of material requested, casting and wire-drawing shape, again earlier after 850 ℃ of coring of high temperature and 750 ℃ of crystallization of high temperature make each metallic element crystallite evenly separate out growth at last.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101718476A CN101289718A (en) | 2007-12-06 | 2007-12-06 | Metallic glass material synthesized from metallic elements |
| CNA2008101830907A CN101451222A (en) | 2007-12-06 | 2008-12-04 | Metal glass material and valve system using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101718476A CN101289718A (en) | 2007-12-06 | 2007-12-06 | Metallic glass material synthesized from metallic elements |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101289718A true CN101289718A (en) | 2008-10-22 |
Family
ID=40034161
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101718476A Pending CN101289718A (en) | 2007-12-06 | 2007-12-06 | Metallic glass material synthesized from metallic elements |
| CNA2008101830907A Pending CN101451222A (en) | 2007-12-06 | 2008-12-04 | Metal glass material and valve system using the same |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008101830907A Pending CN101451222A (en) | 2007-12-06 | 2008-12-04 | Metal glass material and valve system using the same |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN101289718A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102459680A (en) * | 2009-05-19 | 2012-05-16 | 加州理工学院 | Tough iron-based bulk metallic glass alloys |
| US8911572B2 (en) | 2009-05-19 | 2014-12-16 | California Institute Of Technology | Tough iron-based bulk metallic glass alloys |
| CN105171248A (en) * | 2015-09-06 | 2015-12-23 | 苏州市宝玛数控设备有限公司 | Pressing plate cushion block for cutting machine |
| US9708699B2 (en) | 2013-07-18 | 2017-07-18 | Glassimetal Technology, Inc. | Bulk glass steel with high glass forming ability |
| US11371108B2 (en) | 2019-02-14 | 2022-06-28 | Glassimetal Technology, Inc. | Tough iron-based glasses with high glass forming ability and high thermal stability |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105779911B (en) * | 2014-12-16 | 2017-10-24 | 辽宁工业大学 | A kind of high-intensity high-tenacity dendrite strengthens titanium-based metal glass composite material |
-
2007
- 2007-12-06 CN CNA2007101718476A patent/CN101289718A/en active Pending
-
2008
- 2008-12-04 CN CNA2008101830907A patent/CN101451222A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102459680A (en) * | 2009-05-19 | 2012-05-16 | 加州理工学院 | Tough iron-based bulk metallic glass alloys |
| US8911572B2 (en) | 2009-05-19 | 2014-12-16 | California Institute Of Technology | Tough iron-based bulk metallic glass alloys |
| CN102459680B (en) * | 2009-05-19 | 2015-04-01 | 加州理工学院 | Tough iron-based bulk metallic glass alloys |
| US9359664B2 (en) | 2009-05-19 | 2016-06-07 | California Institute Of Technology | Tough iron-based bulk metallic glass alloys |
| US9708699B2 (en) | 2013-07-18 | 2017-07-18 | Glassimetal Technology, Inc. | Bulk glass steel with high glass forming ability |
| CN105171248A (en) * | 2015-09-06 | 2015-12-23 | 苏州市宝玛数控设备有限公司 | Pressing plate cushion block for cutting machine |
| US11371108B2 (en) | 2019-02-14 | 2022-06-28 | Glassimetal Technology, Inc. | Tough iron-based glasses with high glass forming ability and high thermal stability |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101451222A (en) | 2009-06-10 |
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| WD01 | Invention patent application deemed withdrawn after publication |