CN105886973A - Wear-resistant anti-oxidation magnesium alloy material and preparation method thereof - Google Patents

Wear-resistant anti-oxidation magnesium alloy material and preparation method thereof Download PDF

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Publication number
CN105886973A
CN105886973A CN201610473805.7A CN201610473805A CN105886973A CN 105886973 A CN105886973 A CN 105886973A CN 201610473805 A CN201610473805 A CN 201610473805A CN 105886973 A CN105886973 A CN 105886973A
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magnesium alloy
wear
powder
alloy materials
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陈林美
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/02Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C47/00Making alloys containing metallic or non-metallic fibres or filaments
    • C22C47/14Making alloys containing metallic or non-metallic fibres or filaments by powder metallurgy, i.e. by processing mixtures of metal powder and fibres or filaments
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/14Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention discloses a wear-resistant anti-oxidation magnesium alloy material and a preparation method thereof. The wear-resistant anti-oxidation magnesium alloy material is prepared from, by weight, 20-30 parts of magnesium powder, 60-70 parts of tungsten boride, 20-30 parts of silicon oxide, 2-8 parts of tin powder, 12-15 parts of asbestos powder, 6-14 parts of carbon fiber, 5-9 parts of silicon nitride, 10-15 parts of magnesium chloride powder, 3-8 parts of graphene, 3-6 parts of potassium oxide, 3-11 parts of stainless steel powder and 3-5 parts of oleic acid. The wear-resistant anti-oxidation magnesium alloy material prepared by the method has high wear resistance and excellent anti-oxidation performance, and is simple in preparation process, low in processing cost, easy in parameter control, safe and environment-friendly in the production process and suitable for large-scale industrial production.

Description

A kind of wear-resisting anti-oxidant magnesium alloy materials and preparation method thereof
Technical field
Present invention relates particularly to a kind of wear-resisting anti-oxidant magnesium alloy materials and preparation method thereof.
Background technology
Metal material refers to metal or alloy as matrix, and with fiber, whisker, particle etc. is The composite of reinforcement.By the difference of parent metal used, use temperature range be 350~ 1200℃.Its feature is laterally and shear strength is higher in terms of mechanics, and toughness and fatigue etc. are combined Make a concerted effort to learn better performances, the most also have heat conduction, conduction, wear-resisting, thermal coefficient of expansion is little, resistance The advantages such as Buddhist nun's property is good, non-hygroscopic, the most aging and pollution-free.Metal-base composites can play The respective advantage of group element material, it is achieved the allocation optimum of each group element material resource, saves valuable gold Belong to material, it is achieved the unappeasable performance requirement of single metal, have good economic benefit and Social benefit.
Magnesium alloy is in all structural metallic materials having now been found that, the light structures that density is minimum Material, compares with other similar metal material, magnesium alloy materials have specific strength and specific stiffness high, Damping capacity is good, casting character is good, electromagnetic wave shielding is high, be easily recycled, dimensionally stable Property is high.Owing to magnesium alloy materials has the performance of above-mentioned excellence so that it is automobile, electronics, Before there is in the industry field such as space flight, aviation extremely important using value and wide application Scape, therefore magnesium alloy materials is also had most the metal structure of " development prospect " by praise for this century Material.
Along with modern science and technology globalization high speed development, the competition between Global Regional presents multiplex With the trend complicated, the mechanical property of alloy material is had higher requirement.And it is current Domestic alloy is mainly used in low-end product market, this mainly due to China's high performance alloys with And the research and development of advanced person's metallurgical technology is the most backward, the material property therefore produced is the highest, The requirement of high-performance metallurgical product cannot be met.Currently on the market for having wear-resisting anti-oxidant magnesium Alloy material demand the most all increases, but does not has corresponding premium quality product the most corresponding.Domestic The high performance alloys sold on market is substantially imported product, the occupation rate of market of home products Less.To this end, we set about from formula and the technique of product, develop new high performance material, A kind of wear-resisting anti-oxidant magnesium alloy materials and preparation method thereof is provided.
Summary of the invention
To achieve these goals, the invention provides a kind of wear-resisting anti-oxidant magnesium alloy materials and Its preparation method.
It is an object of the invention to be achieved through the following technical solutions:
A kind of wear-resisting anti-oxidant magnesium alloy materials, is prepared by the raw materials in: magnesium powder 20-30 part, tungsten boride 60-70 part, silica 20-30 part, glass putty 2-8 part, flake asbestos 12-15 part, carbon fiber 6-14 part, silicon nitride 5-9 part, magnesium chloride powder 10-15 part, stone Ink alkene 3-8 part, potassium oxide 3-6 part, powder of stainless steel 3-11 part, oleic acid 3-5 part.
Described wear-resisting anti-oxidant magnesium alloy materials is prepared by the raw materials in: magnesium powder 20 Part, tungsten boride 60 parts, silica 20 parts, glass putty 2 parts, flake asbestos 12 parts, carbon fiber 6 parts, silicon nitride 5 parts, magnesium chloride powder 10 parts, Graphene 3 parts, potassium oxide 3 parts, no Rust powdered steel 3 parts, oleic acid 3 parts.
Described wear-resisting anti-oxidant magnesium alloy materials is prepared by the raw materials in: magnesium powder 30 Part, tungsten boride 70 parts, silica 30 parts, glass putty 8 parts, flake asbestos 15 parts, carbon fiber 14 parts, silicon nitride 9 parts, magnesium chloride powder 15 parts, Graphene 8 parts, potassium oxide 6 parts, no Rust powdered steel 11 parts, oleic acid 5 parts.
Described wear-resisting anti-oxidant magnesium alloy materials is prepared by the raw materials in: magnesium powder 25 Part, tungsten boride 65 parts, silica 25 parts, glass putty 5 parts, flake asbestos 13 parts, carbon fiber 10 parts, silicon nitride 7 parts, magnesium chloride powder 13 parts, Graphene 5 parts, potassium oxide 4 parts, no Rust powdered steel 7 parts, oleic acid 4 parts.
The preparation method of described wear-resisting anti-oxidant magnesium alloy materials, the method preparation process is as follows: First each raw material is joined and batch mixer carries out batch mixing, the batch mixing mixed is joined pressure In machine equipment, carrying out extrusion forming, pressure is 400-600MPa, pressurize 10-30min, so After the sample suppressed is sintered in sintering furnace, preheating temperature be 250-300 DEG C, in advance Hot 1h, sintering temperature is 1000-1100 DEG C, and sintering time is 10-30min, then exists 10-20min, cancellation, finally insulation tempering at 150-180 DEG C it is incubated at 250-350 DEG C 1h,.
Beneficial effect: the wear-resisting anti-oxidant magnesium alloy materials that the inventive method prepares has relatively High wearability and superior non-oxidizability, preparation technology is simple, processing cost is low, parameter Easily-controllable, production process safety and environmental protection, it is suitable for large-scale industrial production.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention, Although the present invention being described in detail with reference to previous embodiment, for the technology of this area For personnel, the technical scheme described in foregoing embodiments still can be modified by it, Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention Within the scope of.
Embodiment 1
A kind of wear-resisting anti-oxidant magnesium alloy materials, is prepared by the raw materials in: magnesium powder 20 Part, tungsten boride 60 parts, silica 20 parts, glass putty 2 parts, flake asbestos 12 parts, carbon fiber 6 parts, silicon nitride 5 parts, magnesium chloride powder 10 parts, Graphene 3 parts, potassium oxide 3 parts, no Rust powdered steel 3 parts, oleic acid 3 parts.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, will The batch mixing mixed joins in press equipment, carries out extrusion forming, pressure For 400-600MPa, pressurize 10-30min, then the sample suppressed is entered in sintering furnace Row sintering, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, Sintering time is 10-30min, then insulation 10-20min at 250-350 DEG C, cancellation, Last insulation tempering 1h at 150-180 DEG C,.
Embodiment 2
A kind of wear-resisting anti-oxidant magnesium alloy materials, is prepared by the raw materials in: magnesium powder 30 parts, tungsten boride 70 parts, silica 30 parts, glass putty 8 parts, flake asbestos 15 parts, carbon fine Tie up 14 parts, silicon nitride 9 parts, magnesium chloride powder 15 parts, Graphene 8 parts, potassium oxide 6 parts, Powder of stainless steel 11 parts, oleic acid 5 parts.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, will The batch mixing mixed joins in press equipment, carries out extrusion forming, pressure For 400-600MPa, pressurize 10-30min, then the sample suppressed is entered in sintering furnace Row sintering, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, Sintering time is 10-30min, then insulation 10-20min at 250-350 DEG C, cancellation, Last insulation tempering 1h at 150-180 DEG C,.
Embodiment 3
A kind of wear-resisting anti-oxidant magnesium alloy materials, is prepared by the raw materials in: magnesium powder 25 parts, tungsten boride 65 parts, silica 25 parts, glass putty 5 parts, flake asbestos 13 parts, carbon fine Tie up 10 parts, silicon nitride 7 parts, magnesium chloride powder 13 parts, Graphene 5 parts, potassium oxide 4 parts, Powder of stainless steel 7 parts, oleic acid 4 parts.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, will The batch mixing mixed joins in press equipment, carries out extrusion forming, pressure For 400-600MPa, pressurize 10-30min, then the sample suppressed is entered in sintering furnace Row sintering, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, Sintering time is 10-30min, then insulation 10-20min at 250-350 DEG C, cancellation, Last insulation tempering 1h at 150-180 DEG C,.

Claims (5)

1. a wear-resisting anti-oxidant magnesium alloy materials, it is characterised in that described wear-resisting anti-oxidant Magnesium alloy materials is prepared by the raw materials in: magnesium powder 20-30 part, tungsten boride 60-70 Part, silica 20-30 part, glass putty 2-8 part, flake asbestos 12-15 part, carbon fiber 6-14 Part, silicon nitride 5-9 part, magnesium chloride powder 10-15 part, Graphene 3-8 part, potassium oxide 3-6 Part, powder of stainless steel 3-11 part, oleic acid 3-5 part.
A kind of wear-resisting anti-oxidant magnesium alloy materials, its feature exists In, described wear-resisting anti-oxidant magnesium alloy materials is prepared by the raw materials in: magnesium powder 20 Part, tungsten boride 60 parts, silica 20 parts, glass putty 2 parts, flake asbestos 12 parts, carbon fiber 6 parts, silicon nitride 5 parts, magnesium chloride powder 10 parts, Graphene 3 parts, potassium oxide 3 parts, no Rust powdered steel 3 parts, oleic acid 3 parts.
A kind of wear-resisting anti-oxidant magnesium alloy materials, its feature exists In, described wear-resisting anti-oxidant magnesium alloy materials is prepared by the raw materials in: magnesium powder 30 Part, tungsten boride 70 parts, silica 30 parts, glass putty 8 parts, flake asbestos 15 parts, carbon fiber 14 parts, silicon nitride 9 parts, magnesium chloride powder 15 parts, Graphene 8 parts, potassium oxide 6 parts, no Rust powdered steel 11 parts, oleic acid 5 parts.
A kind of wear-resisting anti-oxidant magnesium alloy materials, its feature exists In, described wear-resisting anti-oxidant magnesium alloy materials is prepared by the raw materials in: magnesium powder 25 Part, tungsten boride 65 parts, silica 25 parts, glass putty 5 parts, flake asbestos 13 parts, carbon fiber 10 parts, silicon nitride 7 parts, magnesium chloride powder 13 parts, Graphene 5 parts, potassium oxide 4 parts, no Rust powdered steel 7 parts, oleic acid 4 parts.
5. the preparation of the wear-resisting anti-oxidant magnesium alloy materials according to any one of claim 1-4 Method, it is characterised in that the method preparation process is as follows: first each raw material is joined batch mixer In carry out batch mixing, the batch mixing mixed is joined in press equipment, carries out extrusion forming, Pressure is 400-600MPa, pressurize 10-30min, then by the sample that suppresses at sintering furnace Inside being sintered, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C, sintering time is 10-30min, is then incubated at 250-350 DEG C 10-20min, cancellation, finally insulation tempering 1h at 150-180 DEG C,.
CN201610473805.7A 2016-06-22 2016-06-22 Wear-resistant anti-oxidation magnesium alloy material and preparation method thereof Pending CN105886973A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109207878A (en) * 2017-06-30 2019-01-15 宜兴市韦德同机械科技有限公司 A kind of particle emission device nut stem material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105112749A (en) * 2015-08-28 2015-12-02 苏州莱特复合材料有限公司 Magnesium-based composite material containing silicon carbon particles and preparation method of magnesium-based composite material
CN105154704A (en) * 2015-08-31 2015-12-16 苏州莱特复合材料有限公司 Preparation method of high-temperature-resistant magnesium alloy material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105112749A (en) * 2015-08-28 2015-12-02 苏州莱特复合材料有限公司 Magnesium-based composite material containing silicon carbon particles and preparation method of magnesium-based composite material
CN105154704A (en) * 2015-08-31 2015-12-16 苏州莱特复合材料有限公司 Preparation method of high-temperature-resistant magnesium alloy material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109207878A (en) * 2017-06-30 2019-01-15 宜兴市韦德同机械科技有限公司 A kind of particle emission device nut stem material

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