CN105886877A - Wear-resistant anti-oxidation nickel-copper alloy material and preparation method thereof - Google Patents
Wear-resistant anti-oxidation nickel-copper alloy material and preparation method thereof Download PDFInfo
- Publication number
- CN105886877A CN105886877A CN201610474300.2A CN201610474300A CN105886877A CN 105886877 A CN105886877 A CN 105886877A CN 201610474300 A CN201610474300 A CN 201610474300A CN 105886877 A CN105886877 A CN 105886877A
- Authority
- CN
- China
- Prior art keywords
- parts
- alloy material
- nickel
- powder
- copper alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/02—Alloys containing less than 50% by weight of each constituent containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
- C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0005—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with at least one oxide and at least one of carbides, nitrides, borides or silicides as the main non-metallic constituents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
Abstract
The invention discloses a wear-resistant anti-oxidation nickel-copper alloy material and a preparation method thereof. The wear-resistant anti-oxidation nickel-copper alloy material is prepared from, by weight, 45-55 parts of nickel powder, 40-50 parts of copper powder, 3-10 parts of zirconium carbide, 40-50 parts of silica, 10-14 parts of asbestos powder, 3-8 parts of manganese sulfide powder, 4-9 parts of barite powder, 6-8 parts of germanium dioxide, 2-5 parts of tin trioxide, 6-7 parts of cadmium selenide and 11-15 parts of paraffin. The wear-resistant anti-oxidation nickel-copper alloy material prepared by the method has high wear resistance and excellent anti-oxidation performance, and is simple in preparation process, low in processing cost, easy in parameter control, safe and environment-friendly in the production process and suitable for large-scale industrial production.
Description
Technical field
Present invention relates particularly to a kind of wear-resisting antioxidation nickel-copper alloy material and preparation method thereof.
Background technology
Metal material refers to metal or alloy as matrix, and with fiber, whisker, granule etc. is
The composite of reinforcement.By the difference of parent metal used, use temperature range be 350～
1200℃.Its feature is laterally and shear strength is higher in terms of mechanics, and toughness and fatigue etc. are combined
Make a concerted effort to learn better performances, the most also have heat conduction, conduction, wear-resisting, thermal coefficient of expansion is little, resistance
The advantages such as Buddhist nun's property is good, non-hygroscopic, the most aging and pollution-free.Metal-base composites can play
The respective advantage of group element material, it is achieved the optimal allocation of each group element material resource, saves valuable gold
Belong to material, it is achieved the unappeasable performance requirement of single metal, have good economic benefit and
Social benefit.
Monel is a kind of to add other elements such as copper, ferrum, manganese with metallic nickel for matrix and form
Alloy, be silvery white in color, there is the corrosive power of more excellent reducing resistance medium, at hydrogen fluorine
In many corrosive mediums such as acid, alkali, sea water, organic acid, stability is preferable, especially at hydrogen fluorine
Stability in bronsted lowry acids and bases bronsted lowry solution is the most prominent, only than platinum, silver this alloy inferior highly concentrated
The saltwater environment of degree show splendid.Monel has a long history on engineer applied.
Alloy has the features such as easy-formation, easy soldering, Cutting free, the most also has high intensity with hard
Degree and excellent heat-resisting, decay resistance.Therefore it is widely used in aviation, navigation, change
Work, atomic energy, etc. field.
Along with modern science and technology globalization high speed development, the competition between Global Regional presents multiplex
With the trend complicated, the mechanical property of alloy material is had higher requirement.And it is current
Domestic alloy is mainly used in low-end product market, this mainly due to China's high performance alloys with
And the research and development of advanced person's metallurgical technology is the most backward, the material property therefore produced is the highest,
The requirement of high-performance metallurgical product cannot be met.Currently on the market for having wear-resisting antioxidation nickel
Cu alloy material demand the most all increases, but does not has corresponding premium quality product the most corresponding.State
The high performance alloys sold on interior market is substantially imported product, the market share of home products
Rate is less.To this end, we set about from formula and the technique of product, develop new high performance material,
A kind of wear-resisting antioxidation nickel-copper alloy material and preparation method thereof is provided.
Summary of the invention
To achieve these goals, the invention provides a kind of wear-resisting antioxidation nickel-copper alloy material
And preparation method thereof.
It is an object of the invention to be achieved through the following technical solutions:
A kind of wear-resisting antioxidation nickel-copper alloy material, is prepared by the raw materials in: nikel powder
45-55 part, copper powder 40-50 part, zirconium carbide 3-10 part, silicon oxide 40-50 part, asbestos
Powder 10-14 part, sulfuration manganese powder 3-8 part, blanc fixe 4-9 part, germanium dioxide 6-8 part,
Three oxidation two stannum 2-5 parts, cadmium selenide 6-7 part, paraffin 11-15 parts.
Described wear-resisting antioxidation nickel-copper alloy material is prepared by the raw materials in: nikel powder
45 parts, copper powder 40 parts, zirconium carbide 3 parts, silicon oxide 40 parts, flake asbestos 10 parts, sulfuration
Manganese powder 3 parts, blanc fixe 4 parts, germanium dioxide 6 parts, three oxidation 2 parts of two stannum, cadmium selenides
6 parts, 11 parts of paraffin.
Described wear-resisting antioxidation nickel-copper alloy material is prepared by the raw materials in: nikel powder
55 parts, copper powder 50 parts, zirconium carbide 10 parts, silicon oxide 50 parts, flake asbestos 14 parts, sulfur
Change manganese powder 8 parts, blanc fixe 9 parts, germanium dioxide 8 parts, three oxidation 5 parts of two stannum, selenizings
Cadmium 7 parts, 15 parts of paraffin.
Described wear-resisting antioxidation nickel-copper alloy material is prepared by the raw materials in: nikel powder
49 parts, copper powder 46 parts, zirconium carbide 6 parts, silicon oxide 45 parts, flake asbestos 12 parts, sulfuration
Manganese powder 5 parts, blanc fixe 6 parts, germanium dioxide 7 parts, three oxidation 3 parts of two stannum, cadmium selenides
6 parts, 13 parts of paraffin.
The preparation method of described wear-resisting antioxidation nickel-copper alloy material, the method preparation process is such as
Under: first each raw material is joined and batch mixer carries out batch mixing, the batch mixing of mix homogeneously is joined
In press equipment, carrying out extrusion forming, pressure is 400-600MPa, pressurize 10-30min,
Then being sintered in sintering furnace by the sample suppressed, preheating temperature is 250-300 DEG C,
Preheating 1h, sintering temperature is 1000-1100 DEG C, and sintering time is 10-30min, then exists
10-20min, cancellation, finally insulation tempering at 150-180 DEG C it is incubated at 250-350 DEG C
1h,.
Beneficial effect: the wear-resisting antioxidation nickel-copper alloy material that the inventive method prepares has
Higher wearability and superior non-oxidizability, preparation technology is simple, processing cost is low, ginseng
Number is easily-controllable, production process safety and environmental protection, is suitable for large-scale industrial production.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention,
Although the present invention being described in detail with reference to previous embodiment, for the technology of this area
For personnel, the technical scheme described in foregoing embodiments still can be modified by it,
Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it
In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention
Within the scope of.
Embodiment 1
A kind of wear-resisting antioxidation nickel-copper alloy material, is prepared by the raw materials in: nikel powder
45 parts, copper powder 40 parts, zirconium carbide 3 parts, silicon oxide 40 parts, flake asbestos 10 parts, sulfuration
Manganese powder 3 parts, blanc fixe 4 parts, germanium dioxide 6 parts, three oxidation 2 parts of two stannum, cadmium selenides
6 parts, 11 parts of paraffin.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, will
The batch mixing of mix homogeneously joins in press equipment, carries out extrusion forming, pressure
For 400-600MPa, pressurize 10-30min, then the sample suppressed is entered in sintering furnace
Row sintering, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C,
Sintering time is 10-30min, then insulation 10-20min at 250-350 DEG C, cancellation,
Last insulation tempering 1h at 150-180 DEG C,.
Embodiment 2
A kind of wear-resisting antioxidation nickel-copper alloy material, is prepared by the raw materials in: nikel powder
55 parts, copper powder 50 parts, zirconium carbide 10 parts, silicon oxide 50 parts, flake asbestos 14 parts, sulfur
Change manganese powder 8 parts, blanc fixe 9 parts, germanium dioxide 8 parts, three oxidation 5 parts of two stannum, selenizings
Cadmium 7 parts, 15 parts of paraffin.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, will
The batch mixing of mix homogeneously joins in press equipment, carries out extrusion forming, pressure
For 400-600MPa, pressurize 10-30min, then the sample suppressed is entered in sintering furnace
Row sintering, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C,
Sintering time is 10-30min, then insulation 10-20min at 250-350 DEG C, cancellation,
Last insulation tempering 1h at 150-180 DEG C,.
Embodiment 3
A kind of wear-resisting antioxidation nickel-copper alloy material, is prepared by the raw materials in: nikel powder
49 parts, copper powder 46 parts, zirconium carbide 6 parts, silicon oxide 45 parts, flake asbestos 12 parts, sulfuration
Manganese powder 5 parts, blanc fixe 6 parts, germanium dioxide 7 parts, three oxidation 3 parts of two stannum, cadmium selenides
6 parts, 13 parts of paraffin.
Its preparation methods steps is as follows: is first joined by each raw material and carries out batch mixing in batch mixer, will
The batch mixing of mix homogeneously joins in press equipment, carries out extrusion forming, pressure
For 400-600MPa, pressurize 10-30min, then the sample suppressed is entered in sintering furnace
Row sintering, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is 1000-1100 DEG C,
Sintering time is 10-30min, then insulation 10-20min at 250-350 DEG C, cancellation,
Last insulation tempering 1h at 150-180 DEG C,.
Claims (5)
1. a wear-resisting antioxidation nickel-copper alloy material, it is characterised in that described wear-resisting antioxygen
Change nickel-copper alloy material to be prepared by the raw materials in: nikel powder 45-55 part, copper powder 40-50
Part, zirconium carbide 3-10 part, silicon oxide 40-50 part, flake asbestos 10-14 part, sulfuration manganese powder
3-8 part, blanc fixe 4-9 part, germanium dioxide 6-8 part, three oxidation two stannum 2-5 parts, selenium
Cadmium 6-7 part, paraffin 11-15 part.
A kind of wear-resisting antioxidation nickel-copper alloy material, its feature
Being, described wear-resisting antioxidation nickel-copper alloy material is prepared by the raw materials in: nikel powder
45 parts, copper powder 40 parts, zirconium carbide 3 parts, silicon oxide 40 parts, flake asbestos 10 parts, sulfuration
Manganese powder 3 parts, blanc fixe 4 parts, germanium dioxide 6 parts, three oxidation 2 parts of two stannum, cadmium selenides
6 parts, 11 parts of paraffin.
A kind of wear-resisting antioxidation nickel-copper alloy material, its feature
Being, described wear-resisting antioxidation nickel-copper alloy material is prepared by the raw materials in: nikel powder
55 parts, copper powder 50 parts, zirconium carbide 10 parts, silicon oxide 50 parts, flake asbestos 14 parts, sulfur
Change manganese powder 8 parts, blanc fixe 9 parts, germanium dioxide 8 parts, three oxidation 5 parts of two stannum, selenizings
Cadmium 7 parts, 15 parts of paraffin.
A kind of wear-resisting antioxidation nickel-copper alloy material, its feature
Being, described wear-resisting antioxidation nickel-copper alloy material is prepared by the raw materials in: nikel powder
49 parts, copper powder 46 parts, zirconium carbide 6 parts, silicon oxide 45 parts, flake asbestos 12 parts, sulfuration
Manganese powder 5 parts, blanc fixe 6 parts, germanium dioxide 7 parts, three oxidation 3 parts of two stannum, cadmium selenides
6 parts, 13 parts of paraffin.
5. the system of the wear-resisting antioxidation nickel-copper alloy material according to any one of claim 1-4
Preparation Method, it is characterised in that the method preparation process is as follows: first each raw material is joined batch mixing
Machine carries out batch mixing, the batch mixing of mix homogeneously is joined in press equipment, carry out adding being pressed into
Type, pressure is 400-600MPa, pressurize 10-30min, is then being burnt by the sample suppressed
Being sintered in freezing of a furnace, preheating temperature is 250-300 DEG C, preheats 1h, and sintering temperature is
1000-1100 DEG C, sintering time is 10-30min, is then incubated at 250-350 DEG C
10-20min, cancellation, finally insulation tempering 1h at 150-180 DEG C,.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610474300.2A CN105886877A (en) | 2016-06-22 | 2016-06-22 | Wear-resistant anti-oxidation nickel-copper alloy material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610474300.2A CN105886877A (en) | 2016-06-22 | 2016-06-22 | Wear-resistant anti-oxidation nickel-copper alloy material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105886877A true CN105886877A (en) | 2016-08-24 |
Family
ID=56718979
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610474300.2A Pending CN105886877A (en) | 2016-06-22 | 2016-06-22 | Wear-resistant anti-oxidation nickel-copper alloy material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105886877A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106782749A (en) * | 2016-12-22 | 2017-05-31 | 苏州缔绿电子科技有限公司 | A kind of corrosion-resistant composite of high connductivity and preparation method thereof |
| CN109604583A (en) * | 2018-11-16 | 2019-04-12 | 马鞍山市诺尔达数控模具制造有限公司 | A kind of processing technology of shear machine knife blade |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102275139A (en) * | 2011-08-18 | 2011-12-14 | 江苏神龙光电科技有限公司 | Special grinding wheel for photovoltaic glass and processing method thereof |
| CN104889405A (en) * | 2015-06-23 | 2015-09-09 | 江苏鹰球集团有限公司 | Ceramimetallurgical high-nickel alloy bearing material |
| CN105215363A (en) * | 2015-10-14 | 2016-01-06 | 东睦新材料集团股份有限公司 | A kind of preparation method with the copper-base powder metallurgy part of densified surface |
-
2016
- 2016-06-22 CN CN201610474300.2A patent/CN105886877A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102275139A (en) * | 2011-08-18 | 2011-12-14 | 江苏神龙光电科技有限公司 | Special grinding wheel for photovoltaic glass and processing method thereof |
| CN104889405A (en) * | 2015-06-23 | 2015-09-09 | 江苏鹰球集团有限公司 | Ceramimetallurgical high-nickel alloy bearing material |
| CN105215363A (en) * | 2015-10-14 | 2016-01-06 | 东睦新材料集团股份有限公司 | A kind of preparation method with the copper-base powder metallurgy part of densified surface |
Non-Patent Citations (2)
| Title |
|---|
| 李石等: "粉末冶金的特点", 《电子设备结构材料》 * |
| 申小平等: "易切削添加剂", 《粉末冶金制造工程》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106782749A (en) * | 2016-12-22 | 2017-05-31 | 苏州缔绿电子科技有限公司 | A kind of corrosion-resistant composite of high connductivity and preparation method thereof |
| CN106782749B (en) * | 2016-12-22 | 2018-07-17 | 苏州缔绿电子科技有限公司 | A kind of highly conductive corrosion-resistant composite material and preparation method |
| CN109604583A (en) * | 2018-11-16 | 2019-04-12 | 马鞍山市诺尔达数控模具制造有限公司 | A kind of processing technology of shear machine knife blade |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104480407A (en) | Copper/cerium-containing antimicrobial stainless steel and preparation method thereof | |
| CN106086679B (en) | Steel material for high-speed train forged steel brake disc and forging process of forging of steel material | |
| CN105886877A (en) | Wear-resistant anti-oxidation nickel-copper alloy material and preparation method thereof | |
| CN101519746B (en) | Molybdenum-base compound material and preparation method thereof | |
| CN103484713B (en) | High-strength wear-resistant complex complex brass alloy extrudes bar and manufacture craft thereof | |
| CN103849934A (en) | Preparation method of nano Cr3C2 crystal whisker | |
| CN100451147C (en) | High-strength simple-cutting zine-base alloy and preparation process thereof | |
| CN104084587A (en) | Manufacturing method of powder metallurgical hub bearing unit | |
| CN103725918A (en) | Rare earth copper alloy wire and preparation method thereof | |
| CN103352142A (en) | High-strength high-heat resistance aluminum alloy wire rod and preparation method thereof | |
| CN106119666A (en) | A kind of high-strength nickel Cu alloy material and preparation method thereof | |
| CN104032162A (en) | Nickel-aluminum bronze alloy material and preparation method thereof | |
| CN105886876A (en) | High-heat-resistance titanium-magnesium alloy material and preparation method thereof | |
| CN106011587A (en) | Corrosion-resistant titanium aluminum alloy material and preparation method thereof | |
| CN101429600A (en) | Production technology for tellurium copper bar, plate, stick or pipe | |
| CN104387083B (en) | A kind of aluminum-nitride-based cutting tool pottery and preparation method thereof | |
| CN101435046A (en) | Heat resisting magnesium alloy | |
| CN107663599A (en) | A kind of tin bronze for possessing high malleable performance | |
| CN105861910A (en) | High-strength titanium-aluminum alloy material and preparation method thereof | |
| CN105886878A (en) | Corrosion-resistant magnesium alloy material and preparation method thereof | |
| CN105256192A (en) | Aluminium alloy panel and preparation method thereof | |
| CN112322925B (en) | Antioxidant cable conductor material and preparation method and application thereof | |
| CN106011707A (en) | Nickel-copper alloy material with high wear resistance and preparation method thereof | |
| CN101831572A (en) | Seawater corrosion resistant drawn aluminum bronze tube and production process thereof | |
| CN105886969A (en) | Corrosion-resistant nickel-copper alloy material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160824 |
|
| RJ01 | Rejection of invention patent application after publication |