CN106047146A - Anticorrosion and antirust paint for metal - Google Patents
Anticorrosion and antirust paint for metal Download PDFInfo
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- CN106047146A CN106047146A CN201610570374.6A CN201610570374A CN106047146A CN 106047146 A CN106047146 A CN 106047146A CN 201610570374 A CN201610570374 A CN 201610570374A CN 106047146 A CN106047146 A CN 106047146A
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- paint
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- naphthenate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C09D179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an anticorrosion and antirust paint for metal. The anticorrosion and antirust paint is prepared from polyamideimide, phenoxy resin, talcum powder, lead oxide, manganese naphthenate, lead naphthenate, tung oil, silicon carbide, antimonous oxide and dibasic lead phosphate. The paint is used for preventing the surface of the metal from being rusted and corroded, and has the viscosity of 110 to 130 s; the corrosion resistance is high, and the impact performance is 55 to 75 cm; the salt water resistance is 15 to 35 d; the paint is free of blistering and falling; the surface can be dried after 8 to 12 h, and the paint is actually dried after 16 to 20 h. The preparation method is simple, and the raw materials are simple and readily available; the anticorrosion and antirust paint can be widely produced and continuously replace the conventional material.
Description
Technical field
The present invention relates to metal anti-corrosion material technical field, particularly relate to a kind of antiseptic and rustproof paint of metal.
Background technology
Antirust paint is a kind of chemistry protecting metal surfaces from air, sea water etc. or the coating of electrochemical corrosion.Main
Physical property to be divided into and the big class of chemically antirust paint two.The former is by the suitable cooperation of pigment and paint vehicle, formed fine and close paint film with
Stop the intrusion of corrosive substance, such as iron oxide red, aluminium powder, graphite antirust paint etc.；The latter presses down rust effect by the chemistry of rust resisting pigment, as
Polyamidoimide, zinc chromate anti-rust paint etc..Antirust for metals such as bridge, boats and ships, pipelines.Polyamidoimide antirust paint is
The paint that a kind of polyamidoimide and drying oil mix.Its permeability, wettability are good, and paint film is soft, attachment is strong, but
It is dried slower.Great additionally, due to polyamidoimide ratio, easily precipitate, and stored for a long time can be thickening, brushability is the most poor.
The antirust paint substantially oiliness used and aqueous two kinds.Oily antirust varniss makes the greasy difficulty of removing of material surface,
It is rarely employed.Oily antirust varniss is easy to use, cheap, but because of containing the noxious substance such as nitrite, chromate, to operation
Personnel's harm is relatively big, and country has limited use, and these type of properties of product are single, it is impossible to meets the antirust of magnetic alloy material and wants
Ask.Epoxy anti-rust paint is used for polyamide as firming agent, and bisphenol-A Pulvis Talci is adhesive, and film is good to substrate adhesion, executes
Work is functional, and paint film flexibility is good, water-fast, oil resistant chemicals-resistant is good.Add different rust resisting pigments, difference can be configured to
Antirust paint, mostly be priming paint.
Water-based metal antirust paint selects metal strength chelating agen inositol hexaphosphate to be main component, with other several aqueouss
Additive compound forms.Inositol hexaphosphate is the Nantural non-toxic Organic chemical products extracted from cereal crops, when it is as magnetic
Property material antirust agent use time, can chelate rapidly with metal on surface, form one layer of fine and close unimolecule complex protecting film, can
Effectively suppress corrosion of metal.Material surface after this product treatment keeps primary colors, it is not necessary to washing can enter under application etc.
Procedure.Conventional epoxy anti-rust paint has epoxy iron red shop antirust paint, Epoxy Aluminum antirust paint, epoxy manganese naphthenate antirust paint, ring
Oxygen antirust paint and epoxy zinc rich primer etc..
Rust resisting pigment is the important component part of antirust paint. physics rust resisting pigment is that an own chemical property of class is relatively stable
Pigment, they are the physical properties by itself, and stable chemical performance, quality is hard, and granule is trickle, excellent fillibility, carries
The consistency of high paint film, reduces the permeable of paint film thus plays antirust effect. and iron oxide red just belongs to this kind of material. and metal
The rust-preventing characteristic of aluminium powder is owing to aluminium powder has sclay texture, forms paint film tight, also has the energy of stronger uv reflectance light
Power, can improve paint film aging-resistant ability.Epoxy iron red shop, Epoxy Aluminum and epoxy manganese naphthenate antirust paint iron oxide red are epoxies
The rust resisting pigment that antirust paint is conventional, if adding aluminium powder, then can strengthen its rustless property, containing manganese naphthenate and iron oxide red
The epoxy manganese naphthenate antirust paint of rust resisting pigment, antirust except for steel surface, also it is especially possible for the anti-of galvanized part
Rust.Should be noted that and be, owing to manganese naphthenate is slightly soluble in water, although so the antirust paint rustless property containing manganese naphthenate pigment is wanted
It is better than comprising only the antirust paint of iron oxide red, but it is not recommended for a long time for underwater sites, otherwise can produce the problems such as foaming.
The main component of antirust paint is rust resisting pigment and film forming matter.Generally name with the title of rust resisting pigment, such as: poly-
Amide imide anticorrosive paint, iron oxide red anticorrosive paint etc..If divided with its rust inhibition, it is broadly divided into four big classes:
Physical action anticorrosive paint, chemical action anticorrosive paint, electrochemical action anticorrosive paint, comprehensive function anticorrosive paint.Polyamide
Acid imide antirust paint forms: by compositions such as modified alkyd resin, rust resisting pigment, extender pigment, drier, organic solvents.Characteristic:
Adhesive force is good, and rustless property is high, and resistance to water is strong, and natural drying is fast at normal temperatures.Some anticorrosive paints are with trickle flakey material
Material is main pigments.Physical action rust resisting pigment mainly has: iron oxide red, natural iron oxide red, micaceous iron oxide, aluminium powder, graphite powder and thin
Micro-sheet glass etc..
Anticorrosive paint, is generally divided into conventional anticorrosive paint and anticorrosive paint, is requisite one in paint
Coating.Conventional anticorrosive paint is under general condition, and metal etc. plays etch-proof effect, the longevity that protection non-ferrous metal uses
Life；For anticorrosive paint refers to relatively conventional anticorrosive paint, can apply in relatively harsh corrosive environment, and have and can reach
The one class anticorrosive paint of protection period more longer than conventional anticorrosive paint.
Summary of the invention
The present invention provides a kind of fast drying, the anti-corrosive properties antiseptic and rustproof paint of good metal, solves existing metal preserving timber
Material is dried the technical problems such as slow and antiseptic property is poor.
The present invention is by the following technical solutions: a kind of antiseptic and rustproof paint of metal, and it is as follows that mass fraction proportioning pressed by its raw material:
Polyamidoimide 100 parts, phenoxy resin 5-25 part, Pulvis Talci 10-30 part, lead oxide 15-35 part, manganese naphthenate 0.2-0.6
Part, lead naphthenate 0.5-4.5 part, Oleum Verniciae fordii 2-8 part, carborundum 4-8 part, antimony oxide 2-6 part, dibasic lead phosphite 3-7
Part.
As a preferred technical solution of the present invention: mass fraction proportioning pressed by the described metal raw material of antiseptic and rustproof paint
As follows: polyamidoimide 100 parts, phenoxy resin 10-20 part, Pulvis Talci 15-25 part, lead oxide 20-30 part, manganese naphthenate
0.3-0.5 part, lead naphthenate 1.5-3.5 part, Oleum Verniciae fordii 3-7 part, carborundum 5-7 part, antimony oxide 3-5 part, two alkali formula phosphorous
Lead plumbate 4-6 part.
As a preferred technical solution of the present invention: mass fraction proportioning pressed by the described metal raw material of antiseptic and rustproof paint
As follows: polyamidoimide 100 parts, phenoxy resin 10 parts, Pulvis Talci 15 parts, 20 parts of lead oxide, manganese naphthenate 0.3 part, cycloalkanes
Lead plumbate 1.5 parts, Oleum Verniciae fordii 3 parts, carborundum 5 parts, antimony oxide 3 parts, dibasic lead phosphite 4 parts.
As a preferred technical solution of the present invention: mass fraction proportioning pressed by the described metal raw material of antiseptic and rustproof paint
As follows: polyamidoimide 100 parts, phenoxy resin 20 parts, Pulvis Talci 25 parts, 30 parts of lead oxide, manganese naphthenate 0.5 part, cycloalkanes
Lead plumbate 3.5 parts, Oleum Verniciae fordii 7 parts, carborundum 7 parts, antimony oxide 5 parts, dibasic lead phosphite 6 parts.
As a preferred technical solution of the present invention: mass fraction proportioning pressed by the described metal raw material of antiseptic and rustproof paint
As follows: polyamidoimide 100 parts, phenoxy resin 15 parts, Pulvis Talci 20 parts, 25 parts of lead oxide, manganese naphthenate 0.4 part, cycloalkanes
Lead plumbate 2.5 parts, Oleum Verniciae fordii 5 parts, carborundum 6 parts, antimony oxide 4 parts, dibasic lead phosphite 5 parts.
Beneficial effect
A kind of metal of the present invention uses above technical scheme compared with prior art with antiseptic and rustproof paint, has following
Technique effect: 1, anticorrosion antirust for metal surface, viscosity 110-130s；2, antiseptic property is good, impact 55-75cm, salt tolerant
Aqueous 15-35d is non-foaming, do not fall off；3, surface drying 8-12h, does solid work 16-20h, and preparation method is simple, and raw material is simple and easy to get, permissible
Current material is replaced in the widespread production not division of history into periods.
Detailed description of the invention
Below in conjunction with example, the invention will be further described, and embodiment is only used for that the present invention will be described, not
Constituting the restriction to right, other alternative means that it may occur to persons skilled in the art that, all in right of the present invention
In claimed range.
Embodiment 1:
The first step: weigh polyamidoimide 100 parts according to mass fraction proportioning, phenoxy resin 5 parts, Pulvis Talci 10 parts,
15 parts of lead oxide, manganese naphthenate 0.2 part, lead naphthenate 0.5 part, Oleum Verniciae fordii 2 parts, carborundum 4 parts, antimony oxide 2 parts, two alkali formulas
Lead phosphite 3 parts.
Second step: polyamidoimide, phenoxy resin, Pulvis Talci, lead oxide and lead naphthenate are put in reactor, adds
Heat, to 140 DEG C, stirs 20min with 200r/min speed.
3rd step: liquid after stirring stands 90min, add manganese naphthenate, Oleum Verniciae fordii, polyamidoimide, three
Aoxidize two antimony and dibasic lead phosphite, after 180 DEG C of mix homogeneously, put into grinder grind 10h, pack after filtration.
, anticorrosion antirust for metal surface, viscosity 110s；Antiseptic property is good, impact 55cm, and resistance to salt water 15d does not rises
Steep, do not fall off；Surface drying 12h, does solid work 20h, and preparation method is simple, and raw material is simple and easy to get, can be with the widespread production not division of history into periods for existing
There is material.
Embodiment 2:
The first step: weigh polyamidoimide 100 parts according to mass fraction proportioning, phenoxy resin 25 parts, Pulvis Talci 30 parts,
35 parts of lead oxide, manganese naphthenate 0.6 part, lead naphthenate 4.5 parts, Oleum Verniciae fordii 8 parts, carborundum 8 parts, antimony oxide 6 parts, two alkali formulas
Lead phosphite 7 parts.
Second step: polyamidoimide, phenoxy resin, Pulvis Talci, lead oxide and lead naphthenate are put in reactor, adds
Heat, to 160 DEG C, stirs 40min with 400r/min speed.
3rd step: liquid after stirring stands 130min, add manganese naphthenate, Oleum Verniciae fordii, polyamidoimide, three
Aoxidize two antimony and dibasic lead phosphite, after 220 DEG C of mix homogeneously, put into grinder grind 14h, pack after filtration.
, anticorrosion antirust for metal surface, viscosity 115s；Antiseptic property is good, impact 60cm, and resistance to salt water 20d does not rises
Steep, do not fall off；Surface drying 11h, does solid work 19h, and preparation method is simple, and raw material is simple and easy to get, can be with the widespread production not division of history into periods for existing
There is material.
Embodiment 3:
The first step: weigh polyamidoimide 100 parts according to mass fraction proportioning, phenoxy resin 10 parts, Pulvis Talci 15 parts,
20 parts of lead oxide, manganese naphthenate 0.3 part, lead naphthenate 1.5 parts, Oleum Verniciae fordii 3 parts, carborundum 5 parts, antimony oxide 3 parts, two alkali formulas
Lead phosphite 4 parts.
Second step: polyamidoimide, phenoxy resin, Pulvis Talci, lead oxide and lead naphthenate are put in reactor, adds
Heat, to 140 DEG C, stirs 20min with 200r/min speed.
3rd step: liquid after stirring stands 90min, add manganese naphthenate, Oleum Verniciae fordii, polyamidoimide, three
Aoxidize two antimony and dibasic lead phosphite, after 180 DEG C of mix homogeneously, put into grinder grind 10h, pack after filtration.
, anticorrosion antirust for metal surface, viscosity 120s；Antiseptic property is good, impact 65cm, and resistance to salt water 25d does not rises
Steep, do not fall off；Surface drying 10h, does solid work 18h, and preparation method is simple, and raw material is simple and easy to get, can be with the widespread production not division of history into periods for existing
There is material.
Embodiment 4:
The first step: weigh polyamidoimide 100 parts according to mass fraction proportioning, phenoxy resin 20 parts, Pulvis Talci 25 parts,
30 parts of lead oxide, manganese naphthenate 0.5 part, lead naphthenate 3.5 parts, Oleum Verniciae fordii 7 parts, carborundum 7 parts, antimony oxide 5 parts, two alkali formulas
Lead phosphite 6 parts.
Second step: polyamidoimide, phenoxy resin, Pulvis Talci, lead oxide and lead naphthenate are put in reactor, adds
Heat, to 160 DEG C, stirs 40min with 400r/min speed.
3rd step: liquid after stirring stands 130min, add manganese naphthenate, Oleum Verniciae fordii, polyamidoimide, three
Aoxidize two antimony and dibasic lead phosphite, after 220 DEG C of mix homogeneously, put into grinder grind 14h, pack after filtration.
, anticorrosion antirust for metal surface, viscosity 125s；Antiseptic property is good, impact 70cm, and resistance to salt water 30d does not rises
Steep, do not fall off；Surface drying 9h, does solid work 17h, and preparation method is simple, and raw material is simple and easy to get, can be with the widespread production not division of history into periods for existing
Material.
Embodiment 5:
The first step: weigh polyamidoimide 100 parts according to mass fraction proportioning, phenoxy resin 15 parts, Pulvis Talci 20 parts,
25 parts of lead oxide, manganese naphthenate 0.4 part, lead naphthenate 2.5 parts, Oleum Verniciae fordii 5 parts, carborundum 6 parts, antimony oxide 4 parts, two alkali formulas
Lead phosphite 5 parts.
Second step: polyamidoimide, phenoxy resin, Pulvis Talci, lead oxide and lead naphthenate are put in reactor, adds
Heat, to 150 DEG C, stirs 30min with 300r/min speed.
3rd step: liquid after stirring stands 110min, add manganese naphthenate, Oleum Verniciae fordii, polyamidoimide, three
Aoxidize two antimony and dibasic lead phosphite, after 200 DEG C of mix homogeneously, put into grinder grind 12h, pack after filtration.
, anticorrosion antirust for metal surface, viscosity 130s；Antiseptic property is good, impact 75cm, and resistance to salt water 35d does not rises
Steep, do not fall off；Surface drying 8h, does solid work 16h, and preparation method is simple, and raw material is simple and easy to get, can be with the widespread production not division of history into periods for existing
Material.
Claims (5)
1. the antiseptic and rustproof paint of metal, it is characterised in that the described metal raw material of antiseptic and rustproof paint is joined by mass fraction
Ratio is as follows: polyamidoimide 100 parts, phenoxy resin 5-25 part, Pulvis Talci 10-30 part, lead oxide 15-35 part, manganese naphthenate
0.2-0.6 part, lead naphthenate 0.5-4.5 part, Oleum Verniciae fordii 2-8 part, carborundum 4-8 part, antimony oxide 2-6 part, two alkali formula phosphorous
Lead plumbate 3-7 part.
A kind of antiseptic and rustproof paint of metal the most according to claim 1, it is characterised in that the antiseptic and rustproof paint of described metal
Raw material to press mass fraction proportioning as follows: polyamidoimide 100 parts, phenoxy resin 10-20 part, Pulvis Talci 15-25 part, oxidation
Lead 20-30 part, manganese naphthenate 0.3-0.5 part, lead naphthenate 1.5-3.5 part, Oleum Verniciae fordii 3-7 part, carborundum 5-7 part, three oxidations two
Antimony 3-5 part, dibasic lead phosphite 4-6 part.
A kind of antiseptic and rustproof paint of metal the most according to claim 1, it is characterised in that the antiseptic and rustproof paint of described metal
Raw material to press mass fraction proportioning as follows: polyamidoimide 100 parts, phenoxy resin 10 parts, Pulvis Talci 15 parts, lead oxide 20
Part, manganese naphthenate 0.3 part, lead naphthenate 1.5 parts, Oleum Verniciae fordii 3 parts, carborundum 5 parts, antimony oxide 3 parts, dibasic lead phosphite
4 parts.
A kind of antiseptic and rustproof paint of metal the most according to claim 2, it is characterised in that the antiseptic and rustproof paint of described metal
Raw material to press mass fraction proportioning as follows: polyamidoimide 100 parts, phenoxy resin 20 parts, Pulvis Talci 25 parts, lead oxide 30
Part, manganese naphthenate 0.5 part, lead naphthenate 3.5 parts, Oleum Verniciae fordii 7 parts, carborundum 7 parts, antimony oxide 5 parts, dibasic lead phosphite
6 parts.
A kind of antiseptic and rustproof paint of metal the most according to claim 1, it is characterised in that: the antiseptic and rustproof paint of described metal
Raw material to press mass fraction proportioning as follows: polyamidoimide 100 parts, phenoxy resin 15 parts, Pulvis Talci 20 parts, lead oxide 25
Part, manganese naphthenate 0.4 part, lead naphthenate 2.5 parts, Oleum Verniciae fordii 5 parts, carborundum 6 parts, antimony oxide 4 parts, dibasic lead phosphite
5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610570374.6A CN106047146A (en) | 2016-07-19 | 2016-07-19 | Anticorrosion and antirust paint for metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610570374.6A CN106047146A (en) | 2016-07-19 | 2016-07-19 | Anticorrosion and antirust paint for metal |
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| CN106047146A true CN106047146A (en) | 2016-10-26 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4530975A (en) * | 1980-09-12 | 1985-07-23 | Hitachi Chemical Company, Ltd. | Polyamide-imide resin composition |
| CN1097444A (en) * | 1993-07-15 | 1995-01-18 | 中国科学院兰州化学物理研究所 | Protective system |
| CN103045143A (en) * | 2012-11-14 | 2013-04-17 | 浙江华正新材料股份有限公司 | Halogen-free epoxy adhesive and cover film prepared by using halogen-free epoxy adhesive |
| CN105017927A (en) * | 2015-06-30 | 2015-11-04 | 苏州乔纳森新材料科技有限公司 | Medical magnetic red lead antirust paint and preparation method thereof |
| CN105555866A (en) * | 2013-09-30 | 2016-05-04 | 新日铁住金化学株式会社 | Phosphorus-containing epoxy resin composition and cured article |
-
2016
- 2016-07-19 CN CN201610570374.6A patent/CN106047146A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4530975A (en) * | 1980-09-12 | 1985-07-23 | Hitachi Chemical Company, Ltd. | Polyamide-imide resin composition |
| CN1097444A (en) * | 1993-07-15 | 1995-01-18 | 中国科学院兰州化学物理研究所 | Protective system |
| CN103045143A (en) * | 2012-11-14 | 2013-04-17 | 浙江华正新材料股份有限公司 | Halogen-free epoxy adhesive and cover film prepared by using halogen-free epoxy adhesive |
| CN105555866A (en) * | 2013-09-30 | 2016-05-04 | 新日铁住金化学株式会社 | Phosphorus-containing epoxy resin composition and cured article |
| CN105017927A (en) * | 2015-06-30 | 2015-11-04 | 苏州乔纳森新材料科技有限公司 | Medical magnetic red lead antirust paint and preparation method thereof |
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Application publication date: 20161026 |