CN106009843A - Zinc chrome yellow antirust paint for metals - Google Patents

Zinc chrome yellow antirust paint for metals Download PDF

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Publication number
CN106009843A
CN106009843A CN201610585504.3A CN201610585504A CN106009843A CN 106009843 A CN106009843 A CN 106009843A CN 201610585504 A CN201610585504 A CN 201610585504A CN 106009843 A CN106009843 A CN 106009843A
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parts
antirust paint
zinc
chrome yellow
zinc chrome
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CN201610585504.3A
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沈旭源
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/086Organic or non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses zinc chrome yellow antirust paint for metals. The zinc chrome yellow antirust paint is made of dipentene, zinc chrome yellow, dimethylbenzene, talcum powder, zinc phosphate, manganese naphthenate, butyl acrylate, zinc oxide, stillingia oil and cobalt naphthenate. The zinc chrome yellow antirust paint has the advantages that the solid content of the zinc chrome yellow antirust paint is 83-87%, and the viscosity of the zinc chrome yellow antirust paint is 95-115s; the zinc chrome yellow antirust paint is good in corrosion resistance, the impact strength of the zinc chrome yellow antirust paint is 60-80cm, the salt solution resistance of the zinc chrome yellow antirust paint is 30-50d, and the zinc chrome yellow antirust paint is free of blistering and falling off; the surface of the zinc chrome yellow antirust paint can be dried in 3-7 hours, the zinc chrome yellow antirust paint can be completely dried in 18-22 hours, and the fineness of the zinc chrome yellow antirust paint is 20-40 microns. A preparation method of the zinc chrome yellow antirust paint is simple, simple and easy in raw material obtaining, and capable of achieving wide production to constantly replace existing materials.

Description

A kind of metal zinc yellow antirust paint
Technical field
The present invention relates to metal field of material technology, particularly relate to a kind of metal zinc yellow and prevent Rust paint.
Background technology
Antirust paint is a kind of chemistry protecting metal surfaces from air, sea water etc. or electrochemistry The coating of corrosion.It is broadly divided into physical property and the big class of chemically antirust paint two.The former by pigment and The suitable cooperation of paint vehicle, forms fine and close paint film to stop the intrusion of corrosive substance, as iron oxide red, Aluminium powder, graphite antirust paint etc.;The latter presses down rust effect by the chemistry of rust resisting pigment, as dipentene, Zinc chromate anti-rust paint etc..Antirust for metals such as bridge, boats and ships, pipelines.Dipentene antirust paint It is the paint that mixes with drying oil of a kind of dipentene.Its permeability, wettability are good, paint Film is soft, attachment is strong, but is dried slower.Great additionally, due to dipentene ratio, easily precipitate, And stored for a long time can be thickening, brushability is the most poor.
The antirust paint substantially oiliness used and aqueous two kinds.Oily antirust varniss makes material surface oil Greasy removal difficulty, is rarely employed.Oily antirust varniss is easy to use, cheap, but because containing Having the noxious substance such as nitrite, chromate, relatively big to operator's harm, country limits Use, and these type of properties of product are single, it is impossible to meet the antirust requirement of magnetic alloy material.Ring Oxygen antirust paint is used for polyamide as firming agent, and bisphenol-A dimethylbenzene is adhesive, film pair Substrate adhesion is good, and workability is good, and paint film flexibility is good, water-fast, oil resistant chemicals-resistant Good.Add different rust resisting pigments, different antirust paints can be configured to, mostly be priming paint.
Water-based metal antirust paint selects metal strength chelating agen inositol hexaphosphate to be main component, Compound with other several aqueous promoters and form.Inositol hexaphosphate extracts from cereal crops Nantural non-toxic Organic chemical products, when it uses as magnetic material antirust agent, can be on surface Chelate rapidly with metal, form one layer of fine and close unimolecule complex protecting film, can effectively suppress Corrosion of metal.Material surface after this product treatment keeps primary colors, it is not necessary to washing can be entered Enter the next procedures such as application.Conventional epoxy anti-rust paint has epoxy iron red shop antirust paint, Epoxy Aluminum Antirust paint, epoxy phosphate zinc antirust paint, epoxy zinc yellow antirust paint and epoxy zinc rich primer etc..
Rust resisting pigment is the important component part of antirust paint. physics rust resisting pigment is class ownization Learning the pigment that character is relatively stable, they are the physical properties by itself, stable chemical performance, matter Ground hard, granule is trickle, excellent fillibility, improve paint film consistency, reduce paint film can Oozing property thus play antirust effect. iron oxide red just belongs to this kind of material. and metallic aluminium powder is anti- Rust property is owing to aluminium powder has sclay texture, forms paint film tight, also has stronger reflection purple The ability of outer linear light, can improve paint film aging-resistant ability.Epoxy iron red shop, Epoxy Aluminum and ring Oxygen zinc phosphate antirust paint iron oxide red is the rust resisting pigment that epoxy anti-rust paint is conventional, if added Aluminium powder, then can strengthen its rustless property, containing zinc phosphate and the ring of iron oxide red rust resisting pigment Oxygen zinc phosphate antirust paint, antirust except for steel surface, also it is especially possible for galvanized part Antirust.Should be noted that and be, owing to zinc phosphate is slightly soluble in water, so containing zinc phosphate pigment Although antirust paint rustless property is better than the antirust paint comprising only iron oxide red, but it is not recommended for a long time For underwater sites, the problems such as foaming otherwise can be produced.
The main component of antirust paint is rust resisting pigment and film forming matter.Generally with the name of rust resisting pigment Claim and name, such as: dipentene anticorrosive paint, iron oxide red anticorrosive paint etc..If preventing with it Rust effect divides, and is broadly divided into four big classes: physical action anticorrosive paint, chemical action are antirust Paint, electrochemical action anticorrosive paint, comprehensive function anticorrosive paint.Dipentene antirust paint forms: By compositions such as modified alkyd resin, rust resisting pigment, extender pigment, drier, organic solvents. Characteristic: adhesive force is good, rustless property is high, and resistance to water is strong, and natural drying is fast at normal temperatures.Ring Oxygen zinc yellow antirust paint is extremely important with the epoxy anti-rust paint that dipentene is main rust resisting pigment A kind of heavy-duty antiseptic paint.The appearance of epoxy zinc yellow antirust paint, instead of traditional alkyd and chlorine Change the zinc yellow antirust paints such as rubber, be applied to Modern Heavy anticorrosive steel structure.Now at epoxy On the basis of zinc yellow antirust paint, have developed again the epoxy zinc yellow being provided purely for inter coat Intermediate coat, its rustless property is more weak, but as inter coat, can effectively strengthen whole The antiseptic property of individual coat system.
Summary of the invention
The present invention provides the metal zinc yellow antirust paint that a kind of fast drying, anti-corrosive properties are good, solves Existing metal material is dried the technical problems such as slow and antiseptic property is poor.
The present invention is by the following technical solutions: a kind of metal zinc yellow antirust paint, its raw material is pressed Mass fraction proportioning is as follows: dipentene 100 parts, zinc yellow 65-85 part, dimethylbenzene 25-45 Part, Pulvis Talci 20-40 part, zinc phosphate 15-35 part, manganese naphthenate 1-5 part, acrylic acid fourth Ester 4-8 part, zinc oxide 5-25 part, Chinese tallowtree seed oil 10-30 part, cobalt naphthenate 1-20 part.
As a preferred technical solution of the present invention: described metal zinc yellow antirust paint former It is as follows that mass fraction proportioning pressed by material: dipentene 100 parts, zinc yellow 70-80 part, dimethylbenzene 30-40 part, Pulvis Talci 25-35 part, zinc phosphate 20-30 part, manganese naphthenate 2-4 part, third Olefin(e) acid butyl ester 5-7 part, zinc oxide 10-20 part, Chinese tallowtree seed oil 15-25 part, cobalt naphthenate 5-15 Part.
As a preferred technical solution of the present invention: described metal zinc yellow antirust paint former It is as follows that mass fraction proportioning pressed by material: dipentene 100 parts, zinc yellow 70 parts, dimethylbenzene 30 parts, Pulvis Talci 25 parts, zinc phosphate 20 parts, manganese naphthenate 2 parts, butyl acrylate 5 parts, oxidation 10 parts of zinc, Chinese tallowtree seed oil 15 parts, cobalt naphthenate 5 parts.
As a preferred technical solution of the present invention: described metal zinc yellow antirust paint former It is as follows that mass fraction proportioning pressed by material: dipentene 100 parts, zinc yellow 80 parts, dimethylbenzene 40 parts, Pulvis Talci 35 parts, zinc phosphate 30 parts, manganese naphthenate 4 parts, butyl acrylate 7 parts, oxidation 20 parts of zinc, Chinese tallowtree seed oil 25 parts, cobalt naphthenate 15 parts.
As a preferred technical solution of the present invention: described metal zinc yellow antirust paint former It is as follows that mass fraction proportioning pressed by material: dipentene 100 parts, zinc yellow 75 parts, dimethylbenzene 35 parts, Pulvis Talci 30 parts, zinc phosphate 25 parts, manganese naphthenate 3 parts, butyl acrylate 6 parts, oxidation 15 parts of zinc, Chinese tallowtree seed oil 20 parts, cobalt naphthenate 10 parts.
Beneficial effect
A kind of metal zinc yellow antirust paint of the present invention uses above technical scheme with existing Technology is compared, and has following technical effect that 1, solid content 83-87%, viscosity 95-115s;2、 Antiseptic property is good, impact 60-80cm, and resistance to salt water 30-50d is non-foaming, do not fall off;3、 Surface drying 3-7h, does solid work 18-22h, fineness 20-40 micron, and preparation method is simple, raw material letter Singly it is easy to get, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Below in conjunction with example, the invention will be further described, and embodiment is only used for the present invention Illustrating, be not intended that the restriction to right, those skilled in the art can think Other alternative means arrived, the most within the scope of the invention as claimed.
Embodiment 1:
The first step: weigh dipentene 100 parts according to mass fraction proportioning, zinc yellow 65 parts, Dimethylbenzene 25 parts, Pulvis Talci 20 parts, zinc phosphate 15 parts, manganese naphthenate 1 part, acrylic acid Butyl ester 4 parts, zinc oxide 5 parts, Chinese tallowtree seed oil 10 parts, cobalt naphthenate 1 part.
Second step: dipentene, zinc yellow, dimethylbenzene, Pulvis Talci and manganese naphthenate are put into anti- Answer in still, be heated to 160 DEG C, stir 30min with 300r/min speed.
3rd step: the liquid after stirring stands 100min, adds zinc phosphate, propylene Acid butyl ester, zinc oxide, Chinese tallowtree seed oil and cobalt naphthenate, put into grinder after 200 DEG C of mix homogeneously Grind 12h, pack after filtration.
Solid content 83%, viscosity 95s;Antiseptic property is good, impact 60cm, resistance to salt water 30d Non-foaming, do not fall off;Surface drying 7h, does solid work 22h, fineness 40 microns, and preparation method is simple, Raw material is simple and easy to get, can be with the widespread production not division of history into periods for current material.
Embodiment 2:
The first step: weigh dipentene 100 parts according to mass fraction proportioning, zinc yellow 85 parts, Dimethylbenzene 45 parts, Pulvis Talci 40 parts, zinc phosphate 35 parts, manganese naphthenate 5 parts, acrylic acid Butyl ester 8 parts, zinc oxide 25 parts, Chinese tallowtree seed oil 30 parts, cobalt naphthenate 20 parts.
Second step: dipentene, zinc yellow, dimethylbenzene, Pulvis Talci and manganese naphthenate are put into anti- Answer in still, be heated to 180 DEG C, stir 50min with 500r/min speed.
3rd step: the liquid after stirring stands 140min, adds zinc phosphate, propylene Acid butyl ester, zinc oxide, Chinese tallowtree seed oil and cobalt naphthenate, put into grinder after 240 DEG C of mix homogeneously Grind 18h, pack after filtration.
Solid content 84%, viscosity 100s;Antiseptic property is good, impact 65cm, resistance to salt water 35d is non-foaming, do not fall off;Surface drying 6h, does solid work 21h, fineness 35 microns, preparation method Simply, raw material is simple and easy to get, can be with the widespread production not division of history into periods for current material.
Embodiment 3:
The first step: weigh dipentene 100 parts according to mass fraction proportioning, zinc yellow 70 parts, Dimethylbenzene 30 parts, Pulvis Talci 25 parts, zinc phosphate 20 parts, manganese naphthenate 2 parts, acrylic acid Butyl ester 5 parts, zinc oxide 10 parts, Chinese tallowtree seed oil 15 parts, cobalt naphthenate 5 parts.
Second step: dipentene, zinc yellow, dimethylbenzene, Pulvis Talci and manganese naphthenate are put into anti- Answer in still, be heated to 160 DEG C, stir 30min with 300r/min speed.
3rd step: the liquid after stirring stands 100min, adds zinc phosphate, propylene Acid butyl ester, zinc oxide, Chinese tallowtree seed oil and cobalt naphthenate, put into grinder after 200 DEG C of mix homogeneously Grind 12h, pack after filtration.
Solid content 85%, viscosity 105s;Antiseptic property is good, impact 70cm, resistance to salt water 40d is non-foaming, do not fall off;Surface drying 5h, does solid work 20, and fineness 30 microns, preparation method is simple Single, raw material is simple and easy to get, can be with the widespread production not division of history into periods for current material.
Embodiment 4:
The first step: weigh dipentene 100 parts according to mass fraction proportioning, zinc yellow 80 parts, Dimethylbenzene 40 parts, Pulvis Talci 35 parts, zinc phosphate 30 parts, manganese naphthenate 4 parts, acrylic acid Butyl ester 7 parts, zinc oxide 20 parts, Chinese tallowtree seed oil 25 parts, cobalt naphthenate 15 parts.
Second step: dipentene, zinc yellow, dimethylbenzene, Pulvis Talci and manganese naphthenate are put into anti- Answer in still, be heated to 180 DEG C, stir 50min with 500r/min speed.
3rd step: the liquid after stirring stands 140min, adds zinc phosphate, propylene Acid butyl ester, zinc oxide, Chinese tallowtree seed oil and cobalt naphthenate, put into grinder after 240 DEG C of mix homogeneously Grind 18h, pack after filtration.
Solid content 86%, viscosity 110s;Antiseptic property is good, impact 75cm, resistance to salt water 45d is non-foaming, do not fall off;Surface drying 4h, does solid work 19h, fineness 25 microns, preparation method Simply, raw material is simple and easy to get, can be with the widespread production not division of history into periods for current material.
Embodiment 5:
The first step: weigh dipentene 100 parts according to mass fraction proportioning, zinc yellow 75 parts, Dimethylbenzene 35 parts, Pulvis Talci 30 parts, zinc phosphate 25 parts, manganese naphthenate 3 parts, acrylic acid Butyl ester 6 parts, zinc oxide 15 parts, Chinese tallowtree seed oil 20 parts, cobalt naphthenate 10 parts.
Second step: dipentene, zinc yellow, dimethylbenzene, Pulvis Talci and manganese naphthenate are put into anti- Answer in still, be heated to 170 DEG C, stir 40min with 400r/min speed.
3rd step: the liquid after stirring stands 120min, adds zinc phosphate, propylene Acid butyl ester, zinc oxide, Chinese tallowtree seed oil and cobalt naphthenate, put into grinder after 220 DEG C of mix homogeneously Grind 15h, pack after filtration.
Solid content 87%, viscosity 115s;Antiseptic property is good, impact 80cm, resistance to salt water 50d is non-foaming, do not fall off;Surface drying 3h, does solid work 18h, fineness 20 microns, preparation method Simply, raw material is simple and easy to get, can be with the widespread production not division of history into periods for current material.

Claims (5)

1. a metal zinc yellow antirust paint, it is characterised in that described metal zinc yellow It is as follows that mass fraction proportioning pressed by the raw material of antirust paint: dipentene 100 parts, zinc yellow 65-85 part, Dimethylbenzene 25-45 part, Pulvis Talci 20-40 part, zinc phosphate 15-35 part, manganese naphthenate 1-5 Part, butyl acrylate 4-8 part, zinc oxide 5-25 part, Chinese tallowtree seed oil 10-30 part, cobalt naphthenate 1-20 part.
A kind of metal zinc yellow antirust paint the most according to claim 1, its feature exists In, it is as follows that mass fraction proportioning pressed by the raw material of described metal zinc yellow antirust paint: dipentene 100 parts, zinc yellow 70-80 part, dimethylbenzene 30-40 part, Pulvis Talci 25-35 part, phosphoric acid Zinc 20-30 part, manganese naphthenate 2-4 part, butyl acrylate 5-7 part, zinc oxide 10-20 part, Chinese tallowtree seed oil 15-25 part, cobalt naphthenate 5-15 part.
A kind of metal zinc yellow antirust paint the most according to claim 1, its feature exists In, it is as follows that mass fraction proportioning pressed by the raw material of described metal zinc yellow antirust paint: dipentene 100 parts, zinc yellow 70 parts, dimethylbenzene 30 parts, Pulvis Talci 25 parts, zinc phosphate 20 parts, Manganese naphthenate 2 parts, butyl acrylate 5 parts, zinc oxide 10 parts, Chinese tallowtree seed oil 15 parts, aphthenic acids Cobalt 5 parts.
A kind of metal zinc yellow antirust paint the most according to claim 1, its feature exists In, it is as follows that mass fraction proportioning pressed by the raw material of described metal zinc yellow antirust paint: dipentene 100 parts, zinc yellow 80 parts, dimethylbenzene 40 parts, Pulvis Talci 35 parts, zinc phosphate 30 parts, Manganese naphthenate 4 parts, butyl acrylate 7 parts, zinc oxide 20 parts, Chinese tallowtree seed oil 25 parts, aphthenic acids Cobalt 15 parts.
A kind of metal zinc yellow antirust paint the most according to claim 1, its feature exists In: it is as follows that mass fraction proportioning pressed by the raw material of described metal zinc yellow antirust paint: dipentene 100 parts, zinc yellow 75 parts, dimethylbenzene 35 parts, Pulvis Talci 30 parts, zinc phosphate 25 parts, Manganese naphthenate 3 parts, butyl acrylate 6 parts, zinc oxide 15 parts, Chinese tallowtree seed oil 20 parts, aphthenic acids Cobalt 10 parts.
CN201610585504.3A 2016-07-20 2016-07-20 Zinc chrome yellow antirust paint for metals Pending CN106009843A (en)

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CN201610585504.3A CN106009843A (en) 2016-07-20 2016-07-20 Zinc chrome yellow antirust paint for metals

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Application Number Priority Date Filing Date Title
CN201610585504.3A CN106009843A (en) 2016-07-20 2016-07-20 Zinc chrome yellow antirust paint for metals

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590095A (en) * 2016-12-05 2017-04-26 钦州市钦南区生产力促进中心 Antirust paint and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0657168A (en) * 1992-08-04 1994-03-01 Taihei Kagaku Sangyo Kk Zinc calcium phosphite pigment, and coating material containing the same
CN104877487A (en) * 2015-05-20 2015-09-02 苏州市贝克生物科技有限公司 Medical waterproof corrosion-resistant anti-rusting coating and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0657168A (en) * 1992-08-04 1994-03-01 Taihei Kagaku Sangyo Kk Zinc calcium phosphite pigment, and coating material containing the same
CN104877487A (en) * 2015-05-20 2015-09-02 苏州市贝克生物科技有限公司 Medical waterproof corrosion-resistant anti-rusting coating and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周学良等: "《精细化工产品手册 涂料》", 31 May 2002 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590095A (en) * 2016-12-05 2017-04-26 钦州市钦南区生产力促进中心 Antirust paint and preparation method thereof

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Application publication date: 20161012