CN106189392A - A kind of metal Plumbum preparatium epoxy anti-rust paint - Google Patents
A kind of metal Plumbum preparatium epoxy anti-rust paint Download PDFInfo
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- CN106189392A CN106189392A CN201610577926.6A CN201610577926A CN106189392A CN 106189392 A CN106189392 A CN 106189392A CN 201610577926 A CN201610577926 A CN 201610577926A CN 106189392 A CN106189392 A CN 106189392A
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- parts
- plumbum preparatium
- paint
- isocyanates
- benzene
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a kind of metal Plumbum preparatium epoxy anti-rust paint, raw material is: Plumbum preparatium, dimethylbenzene, isocyanates, Pulvis Talci, benzene, ethanol, dibutyl phthalate, zinc oxide, acetone and magnesium oxide;There is excellent rustless property, water resistance, adhesion property and tenacity, solid content 82 86%;Impact 60 80cm, resistance to salt water 20 40d is non-foaming, do not fall off;Surface drying 1 5h, does solid work 16 20h, fineness 10 30 microns, and preparation method is simple, and raw material is simple and easy to get, can be with the widespread production not division of history into periods for current material.
Description
Technical field
The present invention relates to metal field of material technology, particularly relate to a kind of metal Plumbum preparatium epoxy anti-rust paint.
Background technology
Antirust paint is a kind of chemistry protecting metal surfaces from air, sea water etc. or the coating of electrochemical corrosion.Main
Physical property to be divided into and the big class of chemically antirust paint two.The former is by the suitable cooperation of pigment and paint vehicle, formed fine and close paint film with
Stop the intrusion of corrosive substance, such as iron oxide red, aluminium powder, graphite antirust paint etc.;The latter presses down rust effect by the chemistry of rust resisting pigment, as
Plumbum preparatium, zinc chromate anti-rust paint etc..Antirust for metals such as bridge, boats and ships, pipelines.Red lead anti-corrosive paint is one Plumbum preparatium and dryness
The paint that oil mixes.Its permeability, wettability are good, and paint film is soft, attachment is strong, but is dried slower.Additionally, due to Plumbum preparatium ratio
Great, easily precipitate, and stored for a long time can be thickening, brushability is the most poor.
The antirust paint substantially oiliness used and aqueous two kinds.Oily antirust varniss makes the greasy difficulty of removing of material surface,
It is rarely employed.Oily antirust varniss is easy to use, cheap, but because of containing the noxious substance such as nitrite, chromate, to operation
Personnel's harm is relatively big, and country has limited use, and these type of properties of product are single, it is impossible to meets the antirust of magnetic alloy material and wants
Ask.Epoxy anti-rust paint is used for polyamide as firming agent, and bisphenol-A isocyanates is adhesive, and film is good to substrate adhesion,
Workability is good, and paint film flexibility is good, water-fast, oil resistant chemicals-resistant is good.Add different rust resisting pigments, can be configured to not
Same antirust paint, mostly is priming paint.
Water-based metal antirust paint selects metal strength chelating agen inositol hexaphosphate to be main component, with other several aqueouss
Additive compound forms.Inositol hexaphosphate is the Nantural non-toxic Organic chemical products extracted from cereal crops, when it is as magnetic
Property material antirust agent use time, can chelate rapidly with metal on surface, form one layer of fine and close unimolecule complex protecting film, can
Effectively suppress corrosion of metal.Material surface after this product treatment keeps primary colors, it is not necessary to washing can enter under application etc.
Procedure.Conventional epoxy anti-rust paint has epoxy iron red shop antirust paint, Epoxy Aluminum antirust paint, epoxy phosphate zinc antirust paint, epoxy
Micaceous iron oxide rustproof paint and epoxy zinc rich primer etc..
Rust resisting pigment is the important component part of antirust paint. physics rust resisting pigment is that an own chemical property of class is relatively stable
Pigment, they are the physical properties by itself, and stable chemical performance, quality is hard, and granule is trickle, excellent fillibility, carries
The consistency of high paint film, reduces the permeable of paint film thus plays antirust effect. and iron oxide red just belongs to this kind of material. and metal
The rust-preventing characteristic of aluminium powder is owing to aluminium powder has sclay texture, forms paint film tight, also has the energy of stronger uv reflectance light
Power, can improve paint film aging-resistant ability.
The main component of antirust paint is rust resisting pigment and film forming matter.Generally name with the title of rust resisting pigment, such as: red
Red anticorrosive paint, iron oxide red anticorrosive paint etc..If divided with its rust inhibition, it is broadly divided into four big classes: physical action
Anticorrosive paint, chemical action anticorrosive paint, electrochemical action anticorrosive paint, comprehensive function anticorrosive paint.Red lead anti-corrosive paint forms:
By compositions such as modified alkyd resin, rust resisting pigment, extender pigment, drier, organic solvents.Characteristic: adhesive force is good, rustless property
Height, resistance to water is strong, and natural drying is fast at normal temperatures.
It is red that Plumbum preparatium has another name called Plumbum preparatium, lead, molecular formula Pb304.Fresh salmon pink heavy powder.Proportion 9.1, resolves into one at 500 DEG C
Lead oxide and oxygen, water insoluble, it is dissolved in hot alkaline solution.There is Oxidation.It is dissolved in hydrochloric acid generation chlorine.Vitriolization generation oxygen
Gas.For accumulator processed, glass, pottery, enamel, and it is used as rust resisting pigment and the protection surface layer of ironware, and other organic conjunctions
The oxidant become.Obtained by heat-flash lead monoxide in the air stream.
Summary of the invention
The present invention provides the metal Plumbum preparatium epoxy anti-rust paint that a kind of fast drying, impact are good, solves existing metal material
Material is dried the slow and not technical problem such as salt spray resistance.
The present invention is by the following technical solutions: a kind of metal Plumbum preparatium epoxy anti-rust paint, mass fraction proportioning pressed by its raw material
As follows: Plumbum preparatium 100 parts, dimethylbenzene 1-5 part, isocyanates 0.5-4.5 part, Pulvis Talci 8-12 part, benzene 10-30 part, ethanol 5-25
Part, dibutyl phthalate 25-45 part, zinc oxide 15-35 part, acetone 20-40 part, magnesium oxide 4-8 part.
As a preferred technical solution of the present invention: mass fraction pressed by the raw material of described metal Plumbum preparatium epoxy anti-rust paint
Proportioning is as follows: Plumbum preparatium 100 parts, dimethylbenzene 2-4 part, isocyanates 1.5-3.5 part, Pulvis Talci 9-11 part, benzene 15-25 part, ethanol
10-20 part, dibutyl phthalate 30-40 part, zinc oxide 20-30 part, acetone 25-35 part, magnesium oxide 5-7 part.
As a preferred technical solution of the present invention: mass fraction pressed by the raw material of described metal Plumbum preparatium epoxy anti-rust paint
Proportioning is as follows: Plumbum preparatium 100 parts, dimethylbenzene 2 parts, isocyanates 1.5 parts, Pulvis Talci 9 parts, benzene 15 parts, ethanol 10 parts, O-phthalic
Dibutyl phthalate 30 parts, zinc oxide 20 parts, 25 parts of acetone, magnesium oxide 5 parts.
As a preferred technical solution of the present invention: mass fraction pressed by the raw material of described metal Plumbum preparatium epoxy anti-rust paint
Proportioning is as follows: Plumbum preparatium 100 parts, dimethylbenzene 4 parts, isocyanates 3.5 parts, Pulvis Talci 11 parts, benzene 25 parts, ethanol 20 parts, adjacent benzene two
Formic acid dibutyl ester 40 parts, zinc oxide 30 parts, 35 parts of acetone, magnesium oxide 7 parts.
As a preferred technical solution of the present invention: mass fraction pressed by the raw material of described metal Plumbum preparatium epoxy anti-rust paint
Proportioning is as follows: Plumbum preparatium 100 parts, dimethylbenzene 3 parts, isocyanates 2.5 parts, Pulvis Talci 10 parts, benzene 20 parts, ethanol 15 parts, adjacent benzene two
Formic acid dibutyl ester 35 parts, zinc oxide 25 parts, 30 parts of acetone, magnesium oxide 6 parts.
Beneficial effect
A kind of metal Plumbum preparatium epoxy anti-rust paint of the present invention uses above technical scheme compared with prior art, has
Techniques below effect: 1, there is excellent rustless property, water resistance, adhesion property and tenacity, solid content 82-86%;2、
Impact 60-80cm, resistance to salt water 20-40d is non-foaming, do not fall off;3, surface drying 1-5h, does solid work 16-20h, and fineness 10-30 is micro-
Rice, preparation method is simple, and raw material is simple and easy to get, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Below in conjunction with example, the invention will be further described, and embodiment is only used for that the present invention will be described, not
Constituting the restriction to right, other alternative means that it may occur to persons skilled in the art that, all in right of the present invention
In claimed range.
Embodiment 1:
The first step: weigh Plumbum preparatium 100 parts, dimethylbenzene 1 part, isocyanates 0.5 part, Pulvis Talci 8 according to mass fraction proportioning
Part, benzene 10 parts, ethanol 5 parts, dibutyl phthalate 25 parts, zinc oxide 15 parts, 20 parts of acetone, magnesium oxide 4 parts.
Second step: Plumbum preparatium, dimethylbenzene, isocyanates, Pulvis Talci and ethanol are put in reactor, is heated to 140 DEG C, with
400r/min speed stirring 10min.
3rd step: liquid after stirring stands 120min, add benzene, dibutyl phthalate, zinc oxide, two
Toluene and magnesium oxide, put into grinder after 180 DEG C of mix homogeneously and grind 18h, pack after filtration.
There is excellent rustless property, water resistance, adhesion property and tenacity, solid content 82%;Impact 60cm, resistance to
Salt 20d is non-foaming, do not fall off;Surface drying 5h, does solid work 20h, fineness 30 microns, and preparation method is simple, and raw material is simple and easy to get, can
With the widespread production not division of history into periods for current material.
Embodiment 2:
The first step: weigh Plumbum preparatium 100 parts, dimethylbenzene 5 parts, isocyanates 4.5 parts, Pulvis Talci 12 according to mass fraction proportioning
Part, benzene 30 parts, ethanol 25 parts, dibutyl phthalate 45 parts, zinc oxide 35 parts, 40 parts of acetone, magnesium oxide 8 parts.
Second step: Plumbum preparatium, dimethylbenzene, isocyanates, Pulvis Talci and ethanol are put in reactor, is heated to 180 DEG C, with
600r/min speed stirring 50min.
3rd step: liquid after stirring stands 140min, add benzene, dibutyl phthalate, zinc oxide, two
Toluene and magnesium oxide, put into grinder after 200 DEG C of mix homogeneously and grind 22h, pack after filtration.
There is excellent rustless property, water resistance, adhesion property and tenacity, solid content 83%;Impact 65cm, resistance to
Salt 25d is non-foaming, do not fall off;Surface drying 4h, does solid work 19h, fineness 25 microns, and preparation method is simple, and raw material is simple and easy to get, can
With the widespread production not division of history into periods for current material.
Embodiment 3:
The first step: weigh Plumbum preparatium 100 parts, dimethylbenzene 2 parts, isocyanates 1.5 parts, Pulvis Talci 9 according to mass fraction proportioning
Part, benzene 15 parts, ethanol 10 parts, dibutyl phthalate 30 parts, zinc oxide 20 parts, 25 parts of acetone, magnesium oxide 5 parts.
Second step: Plumbum preparatium, dimethylbenzene, isocyanates, Pulvis Talci and ethanol are put in reactor, is heated to 140 DEG C, with
400r/min speed stirring 10min.
3rd step: liquid after stirring stands 120min, add benzene, dibutyl phthalate, zinc oxide, two
Toluene and magnesium oxide, put into grinder after 180 DEG C of mix homogeneously and grind 18h, pack after filtration.
There is excellent rustless property, water resistance, adhesion property and tenacity, solid content 84%;Impact 70cm, resistance to
Salt 30d is non-foaming, do not fall off;Surface drying 3h, does solid work 18h, fineness 20 microns, and preparation method is simple, and raw material is simple and easy to get, can
With the widespread production not division of history into periods for current material.
Embodiment 4:
The first step: weigh Plumbum preparatium 100 parts, dimethylbenzene 4 parts, isocyanates 3.5 parts, Pulvis Talci 11 according to mass fraction proportioning
Part, benzene 25 parts, ethanol 20 parts, dibutyl phthalate 40 parts, zinc oxide 30 parts, 35 parts of acetone, magnesium oxide 7 parts.
Second step: Plumbum preparatium, dimethylbenzene, isocyanates, Pulvis Talci and ethanol are put in reactor, is heated to 180 DEG C, with
600r/min speed stirring 50min.
3rd step: liquid after stirring stands 140min, add benzene, dibutyl phthalate, zinc oxide, two
Toluene and magnesium oxide, put into grinder after 200 DEG C of mix homogeneously and grind 22h, pack after filtration.
There is excellent rustless property, water resistance, adhesion property and tenacity, solid content 85%;Impact 75cm, resistance to
Salt 35d is non-foaming, do not fall off;Surface drying 2h, does solid work 17h, fineness 15 microns, and preparation method is simple, and raw material is simple and easy to get, can
With the widespread production not division of history into periods for current material.
Embodiment 5:
The first step: weigh Plumbum preparatium 100 parts, dimethylbenzene 3 parts, isocyanates 2.5 parts, Pulvis Talci 10 according to mass fraction proportioning
Part, benzene 20 parts, ethanol 15 parts, dibutyl phthalate 35 parts, zinc oxide 25 parts, 30 parts of acetone, magnesium oxide 6 parts.
Second step: Plumbum preparatium, dimethylbenzene, isocyanates, Pulvis Talci and ethanol are put in reactor, is heated to 160 DEG C, with
500r/min speed stirring 30min.
3rd step: liquid after stirring stands 130min, add benzene, dibutyl phthalate, zinc oxide, two
Toluene and magnesium oxide, put into grinder after 190 DEG C of mix homogeneously and grind 20h, pack after filtration.
There is excellent rustless property, water resistance, adhesion property and tenacity, solid content 86%;Impact 80cm, resistance to
Salt 40d is non-foaming, do not fall off;Surface drying 1h, does solid work 16h, fineness 10 microns, and preparation method is simple, and raw material is simple and easy to get, can
With the widespread production not division of history into periods for current material.
Claims (5)
1. a metal Plumbum preparatium epoxy anti-rust paint, it is characterised in that matter pressed by the raw material of described metal Plumbum preparatium epoxy anti-rust paint
Amount number proportioning is as follows: Plumbum preparatium 100 parts, dimethylbenzene 1-5 part, isocyanates 0.5-4.5 part, Pulvis Talci 8-12 part, benzene 10-30
Part, ethanol 5-25 part, dibutyl phthalate 25-45 part, zinc oxide 15-35 part, acetone 20-40 part, magnesium oxide 4-8 part.
A kind of metal Plumbum preparatium epoxy anti-rust paint the most according to claim 1, it is characterised in that described metal Plumbum preparatium ring
It is as follows that mass fraction proportioning pressed by the raw material of oxygen antirust paint: Plumbum preparatium 100 parts, dimethylbenzene 2-4 part, isocyanates 1.5-3.5 part, Talcum
Powder 9-11 part, benzene 15-25 part, ethanol 10-20 part, dibutyl phthalate 30-40 part, zinc oxide 20-30 part, acetone 25-
35 parts, magnesium oxide 5-7 part.
A kind of metal Plumbum preparatium epoxy anti-rust paint the most according to claim 1, it is characterised in that described metal Plumbum preparatium ring
It is as follows that mass fraction proportioning pressed by the raw material of oxygen antirust paint: Plumbum preparatium 100 parts, dimethylbenzene 2 parts, isocyanates 1.5 parts, Pulvis Talci 9 parts,
Benzene 15 parts, ethanol 10 parts, dibutyl phthalate 30 parts, zinc oxide 20 parts, 25 parts of acetone, magnesium oxide 5 parts.
A kind of metal Plumbum preparatium epoxy anti-rust paint the most according to claim 1, it is characterised in that described metal Plumbum preparatium ring
It is as follows that mass fraction proportioning pressed by the raw material of oxygen antirust paint: Plumbum preparatium 100 parts, dimethylbenzene 4 parts, isocyanates 3.5 parts, Pulvis Talci 11
Part, benzene 25 parts, ethanol 20 parts, dibutyl phthalate 40 parts, zinc oxide 30 parts, 35 parts of acetone, magnesium oxide 7 parts.
A kind of metal Plumbum preparatium epoxy anti-rust paint the most according to claim 1, it is characterised in that: described metal Plumbum preparatium ring
It is as follows that mass fraction proportioning pressed by the raw material of oxygen antirust paint: Plumbum preparatium 100 parts, dimethylbenzene 3 parts, isocyanates 2.5 parts, Pulvis Talci 10
Part, benzene 20 parts, ethanol 15 parts, dibutyl phthalate 35 parts, zinc oxide 25 parts, 30 parts of acetone, magnesium oxide 6 parts.
Priority Applications (1)
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CN201610577926.6A CN106189392A (en) | 2016-07-20 | 2016-07-20 | A kind of metal Plumbum preparatium epoxy anti-rust paint |
Applications Claiming Priority (1)
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CN201610577926.6A CN106189392A (en) | 2016-07-20 | 2016-07-20 | A kind of metal Plumbum preparatium epoxy anti-rust paint |
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CN106189392A true CN106189392A (en) | 2016-12-07 |
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CN201610577926.6A Withdrawn CN106189392A (en) | 2016-07-20 | 2016-07-20 | A kind of metal Plumbum preparatium epoxy anti-rust paint |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57187378A (en) * | 1981-05-15 | 1982-11-18 | Tetsuhiko Inoue | Manufacture of adhesive film for coloring and corrosion prevention |
CN103509449A (en) * | 2013-09-10 | 2014-01-15 | 马鞍山市金韩涂料制造有限公司 | Red lead metal anti-rust paint and preparation method thereof |
CN104927582A (en) * | 2015-06-30 | 2015-09-23 | 苏州乔纳森新材料科技有限公司 | Medical red lead epoxy antirust paint and preparation method therefor |
-
2016
- 2016-07-20 CN CN201610577926.6A patent/CN106189392A/en not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57187378A (en) * | 1981-05-15 | 1982-11-18 | Tetsuhiko Inoue | Manufacture of adhesive film for coloring and corrosion prevention |
CN103509449A (en) * | 2013-09-10 | 2014-01-15 | 马鞍山市金韩涂料制造有限公司 | Red lead metal anti-rust paint and preparation method thereof |
CN104927582A (en) * | 2015-06-30 | 2015-09-23 | 苏州乔纳森新材料科技有限公司 | Medical red lead epoxy antirust paint and preparation method therefor |
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Application publication date: 20161207 |