CN106047041A - Waterborne antirust anti-crush coating for metal - Google Patents
Waterborne antirust anti-crush coating for metal Download PDFInfo
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- CN106047041A CN106047041A CN201610585401.7A CN201610585401A CN106047041A CN 106047041 A CN106047041 A CN 106047041A CN 201610585401 A CN201610585401 A CN 201610585401A CN 106047041 A CN106047041 A CN 106047041A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/18—Condensation polymers of aldehydes or ketones with aromatic hydrocarbons or their halogen derivatives only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1535—Five-membered rings
- C08K5/1539—Cyclic anhydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a waterborne antirust anti-crush coating for metal, made from the materials: water, xylene formaldehyde resin, micaceous iron oxide, titanium dioxide, toluene, methylethylketone, methyl isobutyl ketone, phthalate anhydride, butanol and monoethanolamine; the coating for used as a metal coating layer has deoxidation effect, coating film has smooth and bright appearance, and the coating is 55-57 s in viscosity; the coating has good anti-crush performance, has level one adhesion, can normally tolerate salt spray for 5-25 d, and can tolerate water for 10-30 d without blistering or peeling off; the coating has a surface drying time of 10-30 min and a solid drying time of 1-5 h, the preparation method is simple, the materials are easy to obtain, and the coating is widely producible and can substitute existing materials continuously.
Description
Technical field
The present invention relates to metal field of material technology, particularly relate to a kind of anti-crushing coating of metal waterborne anti-rust.
Background technology
The chemistry of air, sea water etc. or the coating of electrochemical corrosion can be protected metal surfaces from.Coat in metal surface
The direct invasion of various corrosive substances in air can effectively be avoided by antirusting paint so that maximized prolongation metal uses
Time limit.Physical property and the big class of chemically antirust paint two can be divided into.The former, by pigment and the suitable cooperation of paint vehicle, forms fine and close paint
Film is to stop the intrusion of corrosive substance, such as iron oxide red, aluminium powder, graphite antirust paint etc.;The latter presses down rust work by the chemistry of rust resisting pigment
With, such as Plumbum preparatium, zinc chromate anti-rust paint etc..Hydrophobic film is formed in metal surface.
The antirust paint substantially oily antirust varniss used and aqueous antirust paint two kinds.Oily antirust varniss makes material surface greasy
Remove difficulty, be rarely employed.Oily antirust varniss is easy to use, cheap, but because of poisonous containing nitrite, chromate etc.
Material, relatively big to operator's harm, country has limited use, and these type of properties of product are single, it is impossible to meet magnetic alloy material
The antirust requirement of material.It is applicable in the material of all iron content, sprays and impregnate.Without nitrite and nitrate.
The topmost application of metallic paint is automobile industry.Coat the outer surface of automobile of metallic paint, not only can allow
Metal plate part surface after application seems the most glittering moving, and under a different angle, due to the refraction of light, can allow car
Color, even profile all can be varied from.Allowing car load appearance and modeling seem more rich, more interesting, why " metallic paint " this be
One of reason that can be the most universal.
It is the important component part of antirust paint. physics rust resisting pigment is the pigment that an own chemical property of class is relatively stable,
They are the physical properties by itself, stable chemical performance, and quality is hard, and granule is trickle, excellent fillibility, improve paint film
Consistency, reduces the permeable of paint film thus plays antirust effect. and butanol just belongs to this kind of material. and the rust-preventing characteristic of metallic aluminium powder
It is owing to aluminium powder has sclay texture, forms paint film tight, also have the ability of stronger uv reflectance light, paint film can be improved
Aging-resistant ability.There is good stability in hard water energy.Unique gas phase action, protects non-coating or is difficult to the surface touched.
The main film forming substance of the colored varnish is polyurethane resin, after it is applied to coated article surface, can with in air
Moisture content reacts and film-forming, also can baking-curing film forming. and this film has protection against the tide, Defend salt fog, anti-mildew NBC protective performance,
And film transparency, brightness is high, after painting apparent preferably.Antirust paint kind also has a lot, such as barium metaborate antirust paint, zinc gray
Antirust paint, epoxy anti-rust paint, micaceous iron oxide antirust paint, Vinylidene Chloride antirust paint etc..Water solublity, non-combustible, to environment without dirt
Dye, uses safety.Excellent antirust function, can replace antirust oil, fat completely.It is easy to alkalescence cleaning method from metal surface
Dispose.The surface that more than 1:20 diluent processed can directly carry out coating and spray paint.
Water-borne wood coating is in the development experience difficult course in more than 10 years of China, and its Industrialization road is the most distant
Far.China Association of Coatings Industry has held first water-borne wood coating development seminar in Guangzhou, it is intended to promote aqueous wooden ware to be coated with
Expect research and development at home, promotion and application.It is introduced, although employer's organization is devoted to the enthusiasm of water-borne wood coating popularization very
Height, the domestic coatings enterprises attended a meeting is quite a few, but the enterprise looked around is many, and that really wants to set foot in is the most little.This phenomenon is coated with
Material association relevant person is referred to as " industry is hot, market is cold " visually.The popularization of water-borne wood coating is for the Appropriate application of resource
With sanitary improvement, the most highly beneficial.
Summary of the invention
The present invention provides the anti-crushing coating of metal waterborne anti-rust of a kind of fast drying, good salt tolerance, solves existing metal and uses
Material is dried the slow and not technical problem such as salt spray resistance.
The present invention is by the following technical solutions: a kind of anti-crushing coating of metal waterborne anti-rust, its raw material is joined by mass fraction
Ratio is as follows: 100 parts of water, xylene formaldehyde resin 10-30 part, micaceous iron oxide 1-20 part, titanium dioxide 1-5 part, toluene 5-25 part,
Butanone 0.5-4.5 part, methyl iso-butyl ketone (MIBK) 8-12 part, phthalate anhydride 2-8 part, butanol 1-20 part, monoethanolamine 0.1-0.5
Part.
As a preferred technical solution of the present invention: mass parts pressed by the raw material of the described anti-crushing coating of metal waterborne anti-rust
Number proportioning is as follows: 100 parts of water, xylene formaldehyde resin 15-25 part, micaceous iron oxide 5-15 part, titanium dioxide 2-4 part, toluene 10-
20 parts, butanone 1.5-3.5 part, methyl iso-butyl ketone (MIBK) 9-11 part, phthalate anhydride 3-7 part, butanol 5-15 part, monoethanolamine
0.2-0.4 part.
As a preferred technical solution of the present invention: mass parts pressed by the raw material of the described anti-crushing coating of metal waterborne anti-rust
Number proportioning is as follows: 100 parts of water, xylene formaldehyde resin 15 parts, micaceous iron oxide 5 parts, titanium dioxide 2 parts, toluene 10 parts, butanone
1.5 parts, methyl iso-butyl ketone (MIBK) 9 parts, phthalate anhydride 3 parts, 5 parts of butanol, monoethanolamine 0.2 part.
As a preferred technical solution of the present invention: mass parts pressed by the raw material of the described anti-crushing coating of metal waterborne anti-rust
Number proportioning is as follows: 100 parts of water, xylene formaldehyde resin 25 parts, micaceous iron oxide 15 parts, titanium dioxide 4 parts, toluene 20 parts, and first and second
Ketone 3.5 parts, methyl iso-butyl ketone (MIBK) 11 parts, phthalate anhydride 7 parts, 15 parts of butanol, monoethanolamine 0.4 part.
As a preferred technical solution of the present invention: mass parts pressed by the raw material of the described anti-crushing coating of metal waterborne anti-rust
Number proportioning is as follows: 100 parts of water, xylene formaldehyde resin 20 parts, micaceous iron oxide 10 parts, titanium dioxide 3 parts, toluene 15 parts, and first and second
Ketone 2.5 parts, methyl iso-butyl ketone (MIBK) 10 parts, phthalate anhydride 5 parts, 10 parts of butanol, monoethanolamine 0.3 part.
Beneficial effect
A kind of anti-crushing coating of metal waterborne anti-rust of the present invention uses above technical scheme compared with prior art, tool
There is techniques below effect: 1, for metal coating, there is deoxidation, appearance of film smooth, viscosity 55-75s;2, have
Well resistance to chipping, adhesive force one-level, salt spray resistance 5-25d is without exception, and resistance to water 10-30d is non-foaming, do not fall off;3, surface drying
10-30min, does solid work 1-5h, and preparation method is simple, and raw material is simple and easy to get, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Below in conjunction with example, the invention will be further described, and embodiment is only used for that the present invention will be described, not
Constituting the restriction to right, other alternative means that it may occur to persons skilled in the art that, all in right of the present invention
In claimed range.
Embodiment 1:
The first step: weigh 100 parts of water according to mass fraction proportioning, xylene formaldehyde resin 10 parts, micaceous iron oxide 1 part,
Titanium dioxide 1 part, toluene 5 parts, butanone 0.5 part, methyl iso-butyl ketone (MIBK) 8 parts, phthalate anhydride 2 parts, 1 part of butanol, monoethanolamine
0.1 part.
Second step: water, xylene formaldehyde resin, micaceous iron oxide, titanium dioxide and butanone are put in reactor, heating
To 120 DEG C, stir 10min with 200r/min speed.
3rd step: liquid after stirring stands 120min, add toluene, methyl iso-butyl ketone (MIBK), phthalate anhydride,
Butanol and monoethanolamine, put into grinder after 200 DEG C of mix homogeneously and grind 2h, pack after filtration.
For metal coating, there is deoxidation, appearance of film smooth, viscosity 55s;Have the most anti-crushing fall
Property, adhesive force one-level, salt spray resistance 5d is without exception, and resistance to water 10d is non-foaming, do not fall off;Surface drying 30min, does solid work 5h.
Embodiment 2:
The first step: weigh 100 parts of water according to mass fraction proportioning, xylene formaldehyde resin 30 parts, micaceous iron oxide 20 parts,
Titanium dioxide 5 parts, toluene 25 parts, butanone 4.5 parts, methyl iso-butyl ketone (MIBK) 12 parts, phthalate anhydride 8 parts, 20 parts of butanol, an ethanol
Amine 0.5 part.
Second step: water, xylene formaldehyde resin, micaceous iron oxide, titanium dioxide and butanone are put in reactor, heating
To 160 DEG C, stir 50min with 400r/min speed.
3rd step: liquid after stirring stands 160min, add toluene, methyl iso-butyl ketone (MIBK), phthalate anhydride,
Butanol and monoethanolamine, put into grinder after 240 DEG C of mix homogeneously and grind 6h, pack after filtration.
For metal coating, there is deoxidation, appearance of film smooth, viscosity 60s;Have the most anti-crushing fall
Property, adhesive force one-level, salt spray resistance 10d is without exception, and resistance to water 15d is non-foaming, do not fall off;Surface drying 25min, does solid work 4h.
Embodiment 3:
The first step: weigh 100 parts of water according to mass fraction proportioning, xylene formaldehyde resin 15 parts, micaceous iron oxide 5 parts,
Titanium dioxide 2 parts, toluene 10 parts, butanone 1.5 parts, methyl iso-butyl ketone (MIBK) 9 parts, phthalate anhydride 3 parts, 5 parts of butanol, monoethanolamine
0.2 part.
Second step: water, xylene formaldehyde resin, micaceous iron oxide, titanium dioxide and butanone are put in reactor, heating
To 120 DEG C, stir 10min with 200r/min speed.
3rd step: liquid after stirring stands 120min, add toluene, methyl iso-butyl ketone (MIBK), phthalate anhydride,
Butanol and monoethanolamine, put into grinder after 200 DEG C of mix homogeneously and grind 2h, pack after filtration.
For metal coating, there is deoxidation, appearance of film smooth, viscosity 65s;Have the most anti-crushing fall
Property, adhesive force one-level, salt spray resistance 15d is without exception, and resistance to water 20d is non-foaming, do not fall off;Surface drying 20min, does solid work 3h.
Embodiment 4:
The first step: weigh 100 parts of water according to mass fraction proportioning, xylene formaldehyde resin 25 parts, micaceous iron oxide 15 parts,
Titanium dioxide 4 parts, toluene 20 parts, butanone 3.5 parts, methyl iso-butyl ketone (MIBK) 11 parts, phthalate anhydride 7 parts, 15 parts of butanol, an ethanol
Amine 0.4 part.
Second step: water, xylene formaldehyde resin, micaceous iron oxide, titanium dioxide and butanone are put in reactor, heating
To 160 DEG C, stir 50min with 400r/min speed.
3rd step: liquid after stirring stands 160min, add toluene, methyl iso-butyl ketone (MIBK), phthalate anhydride,
Butanol and monoethanolamine, put into grinder after 240 DEG C of mix homogeneously and grind 6h, pack after filtration.
For metal coating, there is deoxidation, appearance of film smooth, viscosity 70s;Have the most anti-crushing fall
Property, adhesive force one-level, salt spray resistance 20d is without exception, and resistance to water 25d is non-foaming, do not fall off;Surface drying 15min, does solid work 2h.
Embodiment 5:
The first step: weigh 100 parts of water according to mass fraction proportioning, xylene formaldehyde resin 20 parts, micaceous iron oxide 10 parts,
Titanium dioxide 3 parts, toluene 15 parts, butanone 2.5 parts, methyl iso-butyl ketone (MIBK) 10 parts, phthalate anhydride 5 parts, 10 parts of butanol, an ethanol
Amine 0.3 part.
Second step: water, xylene formaldehyde resin, micaceous iron oxide, titanium dioxide and butanone are put in reactor, heating
To 140 DEG C, stir 30min with 300r/min speed.
3rd step: liquid after stirring stands 140min, add toluene, methyl iso-butyl ketone (MIBK), phthalate anhydride,
Butanol and monoethanolamine, put into grinder after 220 DEG C of mix homogeneously and grind 4h, pack after filtration.
For metal coating, there is deoxidation, appearance of film smooth, viscosity 75s;Have the most anti-crushing fall
Property, adhesive force one-level, salt spray resistance 25d is without exception, and resistance to water 30d is non-foaming, do not fall off;Surface drying 10min, does solid work 1h.
Claims (5)
1. the anti-crushing coating of metal waterborne anti-rust, it is characterised in that the raw material of the described anti-crushing coating of metal waterborne anti-rust
As follows by mass fraction proportioning: 100 parts of water, xylene formaldehyde resin 10-30 part, micaceous iron oxide 1-20 part, titanium dioxide 1-5
Part, toluene 5-25 part, butanone 0.5-4.5 part, methyl iso-butyl ketone (MIBK) 8-12 part, phthalate anhydride 2-8 part, butanol 1-20 part,
Monoethanolamine 0.1-0.5 part.
A kind of anti-crushing coating of metal waterborne anti-rust the most according to claim 1, it is characterised in that described metal aqueous
It is as follows that mass fraction proportioning pressed by the raw material of antirust anti-crushing coating: 100 parts of water, xylene formaldehyde resin 15-25 part, micaceous iron oxide
5-15 part, titanium dioxide 2-4 part, toluene 10-20 part, butanone 1.5-3.5 part, methyl iso-butyl ketone (MIBK) 9-11 part, phthalate anhydride
3-7 part, butanol 5-15 part, monoethanolamine 0.2-0.4 part.
A kind of anti-crushing coating of metal waterborne anti-rust the most according to claim 1, it is characterised in that described metal aqueous
It is as follows that mass fraction proportioning pressed by the raw material of antirust anti-crushing coating: 100 parts of water, xylene formaldehyde resin 15 parts, micaceous iron oxide 5
Part, titanium dioxide 2 parts, toluene 10 parts, butanone 1.5 parts, methyl iso-butyl ketone (MIBK) 9 parts, phthalate anhydride 3 parts, 5 parts of butanol, a second
Hydramine 0.2 part.
A kind of anti-crushing coating of metal waterborne anti-rust the most according to claim 2, it is characterised in that described metal aqueous
It is as follows that mass fraction proportioning pressed by the raw material of antirust anti-crushing coating: 100 parts of water, xylene formaldehyde resin 25 parts, micaceous iron oxide 15
Part, titanium dioxide 4 parts, toluene 20 parts, butanone 3.5 parts, methyl iso-butyl ketone (MIBK) 11 parts, phthalate anhydride 7 parts, 15 parts of butanol, one
Ethanolamine 0.4 part.
A kind of anti-crushing coating of metal waterborne anti-rust the most according to claim 1, it is characterised in that: described metal aqueous
It is as follows that mass fraction proportioning pressed by the raw material of antirust anti-crushing coating: 100 parts of water, xylene formaldehyde resin 20 parts, micaceous iron oxide 10
Part, titanium dioxide 3 parts, toluene 15 parts, butanone 2.5 parts, methyl iso-butyl ketone (MIBK) 10 parts, phthalate anhydride 5 parts, 10 parts of butanol, one
Ethanolamine 0.3 part.
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CN201610585401.7A CN106047041A (en) | 2016-07-21 | 2016-07-21 | Waterborne antirust anti-crush coating for metal |
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CN201610585401.7A CN106047041A (en) | 2016-07-21 | 2016-07-21 | Waterborne antirust anti-crush coating for metal |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106967339A (en) * | 2017-05-11 | 2017-07-21 | 张维秀 | A kind of anti-corrosion building coating and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004203902A (en) * | 2002-12-20 | 2004-07-22 | Kansai Paint Co Ltd | Coating composition |
CN104087143A (en) * | 2014-07-15 | 2014-10-08 | 沈彩英 | Antirust anti-crush paint |
-
2016
- 2016-07-21 CN CN201610585401.7A patent/CN106047041A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004203902A (en) * | 2002-12-20 | 2004-07-22 | Kansai Paint Co Ltd | Coating composition |
CN104087143A (en) * | 2014-07-15 | 2014-10-08 | 沈彩英 | Antirust anti-crush paint |
Non-Patent Citations (1)
Title |
---|
涂料工艺编委会: "《涂料工艺 下册》", 31 December 1997, 化学工业出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106967339A (en) * | 2017-05-11 | 2017-07-21 | 张维秀 | A kind of anti-corrosion building coating and preparation method thereof |
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Application publication date: 20161026 |