CN105968977A - Quick-drying water-based antirust paint for metals - Google Patents
Quick-drying water-based antirust paint for metals Download PDFInfo
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- CN105968977A CN105968977A CN201610579879.9A CN201610579879A CN105968977A CN 105968977 A CN105968977 A CN 105968977A CN 201610579879 A CN201610579879 A CN 201610579879A CN 105968977 A CN105968977 A CN 105968977A
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- parts
- paint
- fast
- deionized water
- calcium carbonate
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a quick-drying water-based antirust paint for metals. The paint is prepared from deionized water, ethyl phosphate, zinc oxide, ethyl cellosolve, a polystyrene resin, sodium metaborate, light calcium carbonate, barium sulfate, a diphenyl ether resin and phosphoric acid. The pencil hardness is HB; the paint film is smooth; the viscosity is 60-80s; and the hardness is 3-5. dhesion is Grade 1; the paint can resist water for 15-35 days without abnormity; and the impact strength is 500-700N/cm. The paint can be immersed in a 3% sodium chloride water solution at 25 DEG C for 10-30 days without discoloring or blistering. The surface drying time is 10-30 minutes, and the solid drying time is 2-6 hours. The paint has dvantages of simple preparation method and simple and accessible raw materials, and can be widely produced and continuously substituted for the existing materials.
Description
Technical field
The present invention relates to metal field of material technology, particularly relate to a kind of metal with fast-drying aqueous
Antirusting paint.
Background technology
Air, the chemistry of sea deionized water etc. or electrochemical corrosion can be protected metal surfaces from
Coating.Coat antirusting paint in metal surface and can effectively avoid various corrosive goodses in air
The directly invasion of matter so that maximized prolongation metal useful life.Physical property and change can be divided into
The property the learned big class of antirust paint two.The former, by pigment and the suitable cooperation of paint vehicle, forms fine and close paint film
To stop the intrusion of corrosive substance, such as iron oxide red, aluminium powder, graphite antirust paint etc.;The latter is by anti-
The chemistry of rust pigment presses down rust effect, such as Plumbum preparatium, zinc chromate anti-rust paint etc..For bridge, boats and ships,
The metals such as pipeline antirust.It is applicable to kitchen, toilet, balcony, basement, deionized water
Pond, balcony swimming pool, warehouse, tunnel, timber floor be moistureproof and ground warms up anti-deionized water with
With the Imitation Rock Porcelain Tiles of various suction amount of deionized water and the stickup floor wall of deionization cement basic layer and
The floor anti-deionized water of specialty processes.Diluting with tap water, construction tool, equipment, container are also
Clean with tap water, greatly reduce painting cost.
The antirust paint substantially oily antirust varniss used and deionization aqueous antirust paint two kinds.Oiliness
Antirust paint makes material surface greasy removal difficulty, is rarely employed.Oily antirust varniss is easy to use,
Cheap, but because containing the noxious substance such as nitrite, chromate, operator being endangered
Relatively big, country has limited use, and these type of properties of product are single, it is impossible to meet magnetic alloy material
The antirust requirement of material.It is applicable to the antirust of ferrous and nonferrous metals.Aqueous antirust paint is to do with water
For disperse medium, utilize the multiple rust-proof mechanism such as physics, chemistry, according to chemical conversion, network and
The principles of chemistry such as reaction are formulated.It it is the optimal regeneration product of tradition anti-corrosive primer.Extensively should
For various automobiles, boats and ships, rack, machine-building, container, railway, bridge, boiler,
The anti-corrosion protection such as steel construction, petrochemical equipment, is that solvent-based paints is incomparable.
Metallic paint refers to a kind of air-curing coatings in paint base added with fine metal particle, is
Currently a popular a kind of automobile finish.Added with fine aluminum shot in its paint base, light is mapped to
After on aluminum shot, again by aluminum shot through paint film reflection out.Material surface after this product treatment
Keep primary colors, it is not necessary to deionization washing can enter the next procedures such as application.It is applicable to outdoor have
Under covering and indoor conditions, metal is antirust.Nontoxic, tasteless, pollution-free, health is not had
There are any harm, environmental protection.
The important component part of antirust paint. physics rust resisting pigment be an own chemical property of class relatively
For stable pigment, they are the physical properties by itself, stable chemical performance, and quality is hard,
Granule is trickle, excellent fillibility, improve paint film consistency, reduce paint film permeable thus
Playing antirust effect. diphenyl ether just belongs to this kind of material. and the rust-preventing characteristic of metallic aluminium powder is
Owing to aluminium powder has sclay texture, form paint film tight, also have stronger uv reflectance light
Ability, paint film aging-resistant ability can be improved.Deionized water dissolubility, non-combustible, to environment
Pollution-free, use safety.Excellent antirust function, can replace antirust oil, fat completely.It is dried
Time is fast, improves work efficiency, reduces labour cost.
The main film forming substance of the colored varnish is polyurethane resin, after it is applied to coated article surface,
Can react and film-forming with the deionization moisture content in air, also can baking-curing film forming. this
Plant film and there is protection against the tide, Defend salt fog, anti-mildew NBC protective performance, and film transparency, light
Degree height, after painting apparent preferably.Nonflammable non-explosive, it is simple to transport.Dilute at more than 1:20
Can directly carry out coating on the surface that liquid processed and spray paint.
Summary of the invention
The present invention provides a kind of fast drying, the fast-drying aqueous antirusting paint of the metal of good salt tolerance,
Solve existing metal material and be dried the slow and not technical problem such as salt spray resistance.
The present invention is by the following technical solutions: a kind of fast-drying aqueous antirusting paint of metal, it is former
It is as follows that mass fraction proportioning pressed by material: deionized water 100 parts, etherophosphoric acid 30-50 part, oxidation
Zinc 0.5-2.5 part, ethyl cellosolve 15-35 part, polystyrene resin 25-45 part, inclined boron
Acid sodium 1-5 part, precipitated calcium carbonate 15-55 part, barium sulfate 8-12 part, diphenyl ether 10-30
Part, phosphoric acid 5-25 part.
As a preferred technical solution of the present invention: the fast-drying aqueous antirusting paint of described metal
Raw material to press mass fraction proportioning as follows: deionized water 100 parts, etherophosphoric acid 35-45 part,
Zinc oxide 1-2 part, ethyl cellosolve 20-30 part, polystyrene resin 30-40 part, inclined boron
Acid sodium 2-4 part, precipitated calcium carbonate 25-45 part, barium sulfate 9-11 part, diphenyl ether 15-25
Part, phosphatase 11 0-20 part.
As a preferred technical solution of the present invention: the fast-drying aqueous antirusting paint of described metal
Raw material to press mass fraction proportioning as follows: deionized water 100 parts, etherophosphoric acid 45 parts, oxygen
2 parts of zinc of change, ethyl cellosolve 30 parts, polystyrene resin 40 parts, sodium metaborate 4 parts,
Precipitated calcium carbonate 45 parts, 11 parts of barium sulfate, diphenyl ether 25 parts, phosphoric acid 20 parts.
As a preferred technical solution of the present invention: the fast-drying aqueous antirusting paint of described metal
Raw material to press mass fraction proportioning as follows: deionized water 100 parts, etherophosphoric acid 35 parts, oxygen
1 part of zinc of change, ethyl cellosolve 20 parts, polystyrene resin 30 parts, sodium metaborate 2 parts,
Precipitated calcium carbonate 25 parts, 9 parts of barium sulfate, diphenyl ether 15 parts, phosphatase 11 0 part.
As a preferred technical solution of the present invention: the fast-drying aqueous antirusting paint of described metal
Raw material to press mass fraction proportioning as follows: deionized water 100 parts, etherophosphoric acid 40 parts, oxygen
1.5 parts of zinc of change, ethyl cellosolve 25 parts, polystyrene resin 35 parts, sodium metaborate 3 parts,
Precipitated calcium carbonate 35 parts, 10 parts of barium sulfate, diphenyl ether 20 parts, phosphatase 11 5 parts.
Beneficial effect: a kind of metal of the present invention uses above skill with fast-drying aqueous antirusting paint
Art scheme compared with prior art, has following technical effect that 1, pencil hardness HB, film
Smooth, viscosity 60-80s, hardness 3-5;2, adhesive force one-level, resistance to water 15-35d is as good as
Often, impact strength 500-700N/cm;3, salt tolerance 25 DEG C, soak in 3% sodium-chloride water solution
Bubble 10-30d invariant color is non-foaming, and surface drying 10-30min does solid work 2-6h, and preparation method is simple,
Raw material is simple and easy to get, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Below in conjunction with example, the invention will be further described, and embodiment is only used for the present invention
Illustrating, be not intended that the restriction to right, those skilled in the art can think
Other alternative means arrived, the most within the scope of the invention as claimed.
Embodiment 1:
The first step: weigh deionized water 100 parts, etherophosphoric acid 30 according to mass fraction proportioning
Part, zinc oxide 0.5 part, ethyl cellosolve 15 parts, polystyrene resin 25 parts, metaboric acid
1 part of sodium, precipitated calcium carbonate 15 parts, 8 parts of barium sulfate, diphenyl ether 10 parts, phosphoric acid 5
Part.
Second step: by deionized water, etherophosphoric acid, zinc oxide, ethyl cellosolve and metaboric acid
Sodium puts in reactor, is heated to 55 DEG C, stirs 40min with 200r/min speed.
3rd step: liquid after stirring stands 8h, adds polystyrene resin, light
Matter calcium carbonate, barium sulfate, diphenyl ether and phosphoric acid, put into after 80 DEG C of mix homogeneously and grind
Grinding machine grinds 4h, packs after filtration.
Pencil hardness HB, smooth coating, viscosity 60s, hardness 3;Adhesive force one-level, water-fast
15d is without exception for property, impact strength 500N/cm;Salt tolerance 25 DEG C, in 3% sodium-chloride water solution
Soak 10d invariant color non-foaming, surface drying 10min, does solid work 2h.
Embodiment 2:
The first step: weigh deionized water 100 parts, etherophosphoric acid 50 according to mass fraction proportioning
Part, zinc oxide 2.5 parts, ethyl cellosolve 35 parts, polystyrene resin 45 parts, metaboric acid
5 parts of sodium, precipitated calcium carbonate 55 parts, 12 parts of barium sulfate, diphenyl ether 30 parts, phosphoric acid
25 parts.
Second step: by deionized water, etherophosphoric acid, zinc oxide, ethyl cellosolve and metaboric acid
Sodium puts in reactor, is heated to 75 DEG C, stirs 80min with 400r/min speed.
3rd step: liquid after stirring stands 12h, adds polystyrene resin, light
Matter calcium carbonate, barium sulfate, diphenyl ether and phosphoric acid, put into after 120 DEG C of mix homogeneously and grind
Grinding machine grinds 6h, packs after filtration.
Pencil hardness HB, smooth coating, viscosity 65s, hardness 3.5;Adhesive force one-level, resistance to
Aqueous 20d is without exception, impact strength 550N/cm;Salt tolerance 25 DEG C, 3% sodium-chloride water solution
Middle immersion 15d invariant color is non-foaming, and surface drying 25min does solid work 5h.
Embodiment 3:
The first step: weigh deionized water 100 parts, etherophosphoric acid 45 according to mass fraction proportioning
Part, zinc oxide 2 parts, ethyl cellosolve 30 parts, polystyrene resin 40 parts, sodium metaborate
4 parts, precipitated calcium carbonate 45 parts, 11 parts of barium sulfate, diphenyl ether 25 parts, phosphoric acid 20
Part.
Second step: by deionized water, etherophosphoric acid, zinc oxide, ethyl cellosolve and metaboric acid
Sodium puts in reactor, is heated to 55 DEG C, stirs 40min with 200r/min speed.
3rd step: liquid after stirring stands 8h, adds polystyrene resin, light
Matter calcium carbonate, barium sulfate, diphenyl ether and phosphoric acid, put into after 80 DEG C of mix homogeneously and grind
Grinding machine grinds 4h, packs after filtration.
Pencil hardness HB, smooth coating, viscosity 70s, hardness 4;Adhesive force one-level, water-fast
25d is without exception for property, impact strength 600N/cm;Salt tolerance 25 DEG C, in 3% sodium-chloride water solution
Soak 20d invariant color non-foaming, surface drying 20min, does solid work 4h.
Embodiment 4:
The first step: weigh deionized water 100 parts, etherophosphoric acid 35 according to mass fraction proportioning
Part, zinc oxide 1 part, ethyl cellosolve 20 parts, polystyrene resin 30 parts, sodium metaborate
2 parts, precipitated calcium carbonate 25 parts, 9 parts of barium sulfate, diphenyl ether 15 parts, phosphatase 11 0
Part.
Second step: by deionized water, etherophosphoric acid, zinc oxide, ethyl cellosolve and metaboric acid
Sodium puts in reactor, is heated to 75 DEG C, stirs 80min with 400r/min speed.
3rd step: liquid after stirring stands 12h, adds polystyrene resin, light
Matter calcium carbonate, barium sulfate, diphenyl ether and phosphoric acid, put into after 120 DEG C of mix homogeneously and grind
Grinding machine grinds 6h, packs after filtration.
Pencil hardness HB, smooth coating, viscosity 80s, hardness 5;Adhesive force one-level, water-fast
30d is without exception for property, impact strength 650N/cm;Salt tolerance 25 DEG C, in 3% sodium-chloride water solution
Soak 25d invariant color non-foaming, surface drying 15min, does solid work 3h.
Embodiment 5:
The first step: weigh deionized water 100 parts, etherophosphoric acid 40 according to mass fraction proportioning
Part, zinc oxide 1.5 parts, ethyl cellosolve 25 parts, polystyrene resin 35 parts, metaboric acid
3 parts of sodium, precipitated calcium carbonate 35 parts, 10 parts of barium sulfate, diphenyl ether 20 parts, phosphoric acid
15 parts.
Second step: by deionized water, etherophosphoric acid, zinc oxide, ethyl cellosolve and metaboric acid
Sodium puts in reactor, is heated to 65 DEG C, stirs 60min with 300r/min speed.
3rd step: liquid after stirring stands 10h, adds polystyrene resin, light
Matter calcium carbonate, barium sulfate, diphenyl ether and phosphoric acid, put into after 100 DEG C of mix homogeneously and grind
Grinding machine grinds 5h, packs after filtration.
Pencil hardness HB, smooth coating, viscosity 80s, hardness 5;Adhesive force one-level, water-fast
35d is without exception for property, impact strength 700N/cm;Salt tolerance 25 DEG C, in 3% sodium-chloride water solution
Soak 30d invariant color non-foaming, surface drying 10min, does solid work 2h.
Claims (5)
1. the fast-drying aqueous antirusting paint of metal, it is characterised in that described metal is with fast
It is as follows that mass fraction proportioning pressed by the raw material of dry aqueous rust-proof coatings: deionized water 100 parts, phosphoric acid
Ethyl ester 30-50 part, zinc oxide 0.5-2.5 part, ethyl cellosolve 15-35 part, polystyrene
Resin 25-45 part, sodium metaborate 1-5 part, precipitated calcium carbonate 15-55 part, barium sulfate 8-12
Part, diphenyl ether 10-30 part, phosphoric acid 5-25 part.
A kind of fast-drying aqueous antirusting paint of metal the most according to claim 1, it is special
Levying and be, it is as follows that described metal presses mass fraction proportioning with the raw material of fast-drying aqueous antirusting paint:
Deionized water 100 parts, etherophosphoric acid 35-45 part, zinc oxide 1-2 part, ethyl cellosolve
20-30 part, polystyrene resin 30-40 part, sodium metaborate 2-4 part, precipitated calcium carbonate 25-45
Part, barium sulfate 9-11 part, diphenyl ether 15-25 part, phosphatase 11 0-20 part.
A kind of fast-drying aqueous antirusting paint of metal the most according to claim 1, it is special
Levying and be, it is as follows that described metal presses mass fraction proportioning with the raw material of fast-drying aqueous antirusting paint:
Deionized water 100 parts, etherophosphoric acid 45 parts, zinc oxide 2 parts, ethyl cellosolve 30 parts,
Polystyrene resin 40 parts, sodium metaborate 4 parts, precipitated calcium carbonate 45 parts, barium sulfate 11
Part, diphenyl ether 25 parts, phosphoric acid 20 parts.
A kind of fast-drying aqueous antirusting paint of metal the most according to claim 1, it is special
Levying and be, it is as follows that described metal presses mass fraction proportioning with the raw material of fast-drying aqueous antirusting paint:
Deionized water 100 parts, etherophosphoric acid 35 parts, zinc oxide 1 part, ethyl cellosolve 20 parts,
Polystyrene resin 30 parts, sodium metaborate 2 parts, precipitated calcium carbonate 25 parts, 9 parts of barium sulfate,
Diphenyl ether 15 parts, phosphatase 11 0 part.
A kind of fast-drying aqueous antirusting paint of metal the most according to claim 1, it is special
Levy and be: the raw material of the fast-drying aqueous antirusting paint of described metal is as follows by mass fraction proportioning:
Deionized water 100 parts, etherophosphoric acid 40 parts, zinc oxide 1.5 parts, ethyl cellosolve 25 parts,
Polystyrene resin 35 parts, sodium metaborate 3 parts, precipitated calcium carbonate 35 parts, barium sulfate 10
Part, diphenyl ether 20 parts, phosphatase 11 5 parts.
Priority Applications (1)
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CN201610579879.9A CN105968977A (en) | 2016-07-19 | 2016-07-19 | Quick-drying water-based antirust paint for metals |
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CN201610579879.9A CN105968977A (en) | 2016-07-19 | 2016-07-19 | Quick-drying water-based antirust paint for metals |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106590422A (en) * | 2016-12-13 | 2017-04-26 | 南京悠谷知识产权服务有限公司 | Antirust high-temperature-resistant paint for aeronautical materials and preparation method of antirust high-temperature-resistant paint |
Citations (2)
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CN102925011A (en) * | 2012-11-30 | 2013-02-13 | 康力电梯股份有限公司 | Antirust coating material for staircase |
CN104877486A (en) * | 2015-05-20 | 2015-09-02 | 苏州市贝克生物科技有限公司 | Medical quick-drying water-based antirust paint and preparation method thereof |
-
2016
- 2016-07-19 CN CN201610579879.9A patent/CN105968977A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102925011A (en) * | 2012-11-30 | 2013-02-13 | 康力电梯股份有限公司 | Antirust coating material for staircase |
CN104877486A (en) * | 2015-05-20 | 2015-09-02 | 苏州市贝克生物科技有限公司 | Medical quick-drying water-based antirust paint and preparation method thereof |
Non-Patent Citations (3)
Title |
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《自行车制造工艺学》编写组: "《自行车制造工艺学》", 30 June 1987, 轻工业出版社 * |
俞志明: "《中国化学商品大全1995年版 第一卷》", 31 January 1996, 中国物资出版社 * |
曹备等: "《防腐蚀监理工程师应用手册》", 31 August 2011, 中国石化出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106590422A (en) * | 2016-12-13 | 2017-04-26 | 南京悠谷知识产权服务有限公司 | Antirust high-temperature-resistant paint for aeronautical materials and preparation method of antirust high-temperature-resistant paint |
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