CN106590422A - Antirust high-temperature-resistant paint for aeronautical materials and preparation method of antirust high-temperature-resistant paint - Google Patents

Antirust high-temperature-resistant paint for aeronautical materials and preparation method of antirust high-temperature-resistant paint Download PDF

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CN106590422A
CN106590422A CN201611148936.4A CN201611148936A CN106590422A CN 106590422 A CN106590422 A CN 106590422A CN 201611148936 A CN201611148936 A CN 201611148936A CN 106590422 A CN106590422 A CN 106590422A
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parts
zinc
resisting coating
temperature resisting
temperature
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王维根
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Nanjing Valley Intellectual Property Service Co Ltd
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Nanjing Valley Intellectual Property Service Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D195/00Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
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  • Compositions Of Macromolecular Compounds (AREA)
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Abstract

The invention discloses antirust high-temperature-resistant paint for aeronautical materials and a preparation method of the antirust high-temperature-resistant paint. The antirust high-temperature-resistant paint is prepared from coal tar pitch, zinc yellow, silver paste powder, paratoluensulfonyl chloride, zinc carbonate, titanium dioxide, polystyrene resin, zinc phosphate, glass powder, melamine, diphenyl ether resin, cyclohexanone, potassium dichromate and a drier. A product is in level 1 of adhesion, free of cracking and shedding at a high temperature, quick in drying and 30-70d in salt fog resistance and can be dried only by drying for 80-120min at 200 DEG C; pendulum hardness is 8-10, coating brightness, smoothness and great thermal strength and dielectric properties are realized, and fineness is 20-40micron; shedding is avoided at a high temperature of 1000-1400 DEG C, metal corrosion is avoided, and flexibility is 0.5-2.5mm; coating film firmness is achieved, steel materials are protected from oxidization and decarbonization, and the paint is resistant to water, acids, alkalis and low temperature and unchanged after being soaked in hydrochloric acid, sodium hydroxide and sodium chloride for 4-8 months.

Description

A kind of aeronautical material Rustproof high-temperature resisting coating and preparation method thereof
Technical field
The present invention relates to aircraft coating technical field, more particularly to a kind of aeronautical material Rustproof high-temperature resisting coating and its system Preparation Method.
Background technology
During aeronautical manufacture develops, the update of material presents the change conversion of high speed, material and aircraft Constantly develop in the case where mutually promoting always.One real picture of " generation material, generation aircraft " exactly World Airways development history.
Nineteen sixty-five, in this stage based on synthesis type resin, representative coatings were acrylic resin paints to 1975. The characteristics of this kind of coating is one-component, fast drying, easy construction, coating light and heat stability, with more stable performance but resistance to The poor-performing of oil and resistant to chemical media;Phase early 1980s, begin one's study curable coating.Because this kind of coating is formed Body structure.Its Typical Representative is that double-component solidifies polyurethane paint, and Photochromic Properties are good, and with excellent water-fast, oil resistant, Resistance to mist, wet-heat resisting and anti-chemical mediator performance.
Aircraft coating is for the coating on aircraft.By can be divided into using position:Aircraft skin coating, aircraft cabin are applied Material, aircraft engine coating, airplane component coating, special special coating, including insulating moulding coating, fireproof coating and thermo-color Deng.
By taking aircraft surfaces fuselage coating as an example, fuselage bottom, finish paint are generally epoxypolyamine fat priming paint and polyurethane type finish paint. In addition, also polyurethane primer, wherein epoxy polychlorostyrene fat priming paint has the adhesive force and resistance to abrasion and polyurethane of epoxy Pliability, recoatability, compared with epoxy primer, its advantage is that bi-component pot-life is long, and recoatability is good, dried film thickness 0.4u~ 0.5u, can mitigate the weight of airframe.
Chemical membrane is referred to first by the polymer-coated of solvable (or fusible) low relative molecular mass in substrate surface After, under heating or other conditions, intermolecular reacting and relative molecular mass is further increased or is crosslinked and Into the process of tough and tensile film, this thin film-forming method is the thin film-forming method of thermohardening lacquer.Such as:Drying oil and alkyd resin pass through With the effect film forming of oxygen, the alkyd resin of amino resin and hydroxyl, polyester and acrylic resin by ether exchange reaction into Film, epoxy resin and polyamine crosslinking film forming etc. are all using chemical reaction mode film forming.
The development trend of coating industry is developed in terms of VOC etc. is reduced, domestic traditional solvent Type coating portion starts to reduce, in addition, the development speed of water paint starts to accelerate, is increasingly becoming the coating of great potential Product.The new kind of the quality of raising water paint, exploitation is to consolidate and develop the important step of water paint.
Paint finishing to be constructed and simply complete the first step of coating film forming on coated article part surface, is further continued to be carried out and is become The process of solid-state continuous film, can just complete whole coating film forming procedures.This is usual from the process that " wet film " is changed into " dry film " Referred to as " drying " or " solidification ".This drying and the process for solidifying are the cores of coating film forming procedure.Different shape and composition Coating has respective membrane formation mechanism, and membrane formation mechanism is that the property of the film forming matter used by coating is determined.
Estimated whole world passenger plane quantity average growth rate per annum is 3.6%, by 2029, global passenger plane quantity nearly 35000 framves.Not Carrying out several years Chinese aircraft manufacturing industries will increase rapidly to the demand of aeronautical material.According to China Aviation Industry Corporation I Prediction, by 2025, civil air transportation aircraft owning amount was up to 3900 framves, and wherein airliner will be up to 2000 framves.This will China is set to become the world's second largest air market for being only second to the U.S..
The content of the invention
The present invention provides a kind of aeronautical material Rustproof high-temperature resisting coating and preparation method thereof, solves existing aircraft coating material Material low intensity, tensile strength are low, elongation percentage is low and the low technical problem of hardness.
The present invention is employed the following technical solutions:A kind of aeronautical material Rustproof high-temperature resisting coating, its raw material presses mass fraction Proportioning is as follows:100 parts of coal tar asphalt, zinc yellow 10-30 part, silver paste powder 12-18 parts, paratoluensulfonyl chloride 8-12 parts, zinc carbonate 6-10 parts, titanium dioxide 40-60 parts, polystyrene resin be 15-35 parts, trbasic zinc phosphate 25-65 parts, glass dust 15-55 parts, melamine Amine 18-22 parts, diphenyl ether 3-7 parts, cyclohexanone 25-45 parts, potassium bichromate 0.5-4.5 parts, drier 0.1-2 parts.
As a preferred technical solution of the present invention:The aeronautical material presses quality with the raw material of Rustproof high-temperature resisting coating Number proportioning is as follows:100 parts of coal tar asphalt, 10 parts of zinc yellow, 12 parts of silver paste powder, 8 parts of paratoluensulfonyl chloride, 6 parts of zinc carbonate, titanium 40 parts of white powder, polystyrene resin is 15 parts, 25 parts of trbasic zinc phosphate, 15 parts of glass dust, 18 parts of melamine, 3 parts of diphenyl ether, 25 parts of cyclohexanone, 0.5 part of potassium bichromate, 0.1 part of drier.
As a preferred technical solution of the present invention:The aeronautical material presses quality with the raw material of Rustproof high-temperature resisting coating Number proportioning is as follows:100 parts of coal tar asphalt, 30 parts of zinc yellow, 18 parts of silver paste powder, 12 parts of paratoluensulfonyl chloride, 10 parts of zinc carbonate, 60 parts of titanium dioxide, polystyrene resin is 35 parts, 65 parts of trbasic zinc phosphate, 55 parts of glass dust, 22 parts of melamine, diphenyl ether 7 Part, 45 parts of cyclohexanone, 4.5 parts of potassium bichromate, 2 parts of drier.
As a preferred technical solution of the present invention:The aeronautical material presses quality with the raw material of Rustproof high-temperature resisting coating Number proportioning is as follows:100 parts of coal tar asphalt, 25 parts of zinc yellow, 17 parts of silver paste powder, 11 parts of paratoluensulfonyl chloride, 9 parts of zinc carbonate, 55 parts of titanium dioxide, polystyrene resin is 30 parts, 55 parts of trbasic zinc phosphate, 45 parts of glass dust, 21 parts of melamine, diphenyl ether 6 Part, 40 parts of cyclohexanone, 3.5 parts of potassium bichromate, 1.5 parts of drier.
As a preferred technical solution of the present invention:The aeronautical material presses quality with the raw material of Rustproof high-temperature resisting coating Number proportioning is as follows:100 parts of coal tar asphalt, 15 parts of zinc yellow, 13 parts of silver paste powder, 9 parts of paratoluensulfonyl chloride, 7 parts of zinc carbonate, titanium 45 parts of white powder, polystyrene resin is 20 parts, 35 parts of trbasic zinc phosphate, 25 parts of glass dust, 19 parts of melamine, 4 parts of diphenyl ether, 30 parts of cyclohexanone, 1.5 parts of potassium bichromate, 0.5 part of drier.
As a preferred technical solution of the present invention:The aeronautical material presses quality with the raw material of Rustproof high-temperature resisting coating Number proportioning is as follows:100 parts of coal tar asphalt, 20 parts of zinc yellow, 15 parts of silver paste powder, 10 parts of paratoluensulfonyl chloride, 8 parts of zinc carbonate, 50 parts of titanium dioxide, polystyrene resin is 25 parts, 45 parts of trbasic zinc phosphate, 35 parts of glass dust, 20 parts of melamine, diphenyl ether 5 Part, 35 parts of cyclohexanone, 2.5 parts of potassium bichromate, 1 part of drier.
As a preferred technical solution of the present invention:The drier adopts cobalt naphthenate, manganese naphthenate or aphthenic acids Lead.
A kind of method for preparing described aeronautical material Rustproof high-temperature resisting coating, step is:
The first step:Coal tar asphalt, zinc yellow, silver paste powder, paratoluensulfonyl chloride, zinc carbonate, titanium are weighed according to mass fraction proportioning White powder, polystyrene resin, trbasic zinc phosphate, glass dust, melamine, diphenyl ether, cyclohexanone, potassium bichromate and drier;
Second step:By coal tar asphalt, zinc yellow, silver paste powder, titanium dioxide and potassium bichromate input with thermometer and agitator In reactor, 80-100 DEG C is warming up to, under 300-500r/min rotating speeds 20-40min is stirred;
3rd step:60-70 DEG C is cooled to, paratoluensulfonyl chloride, zinc carbonate and polystyrene resin is added, 2-4h is stirred;
4th step:Surplus stock is added, 190-210 DEG C is warming up to, high-speed stirred 15-35min puts into after being cooled to 20-30 DEG C Barrelling after grinding in ball grinder 44-48h.
As a preferred technical solution of the present invention:The high-speed stirred rotating speed of the 4th step is 500-700r/min.
Beneficial effect
A kind of aeronautical material of the present invention with Rustproof high-temperature resisting coating and preparation method thereof using above technical scheme with it is existing Technology is compared, with following technique effect:1st, product adhesion 1 grade, high temperature is not dry and cracked and comes off, fast drying, is dried at 200 DEG C 80-120min, the corrosion-free 30-70d of salt tolerant;2nd, pendulum-rocker hardness 8-10, coating luminous, flat smooth, with good heat State intensity and dielectric properties, fineness 20-40 μm;3rd, resistance to 1000-1400 DEG C of high temperature does not fall off, and metal is not corroded, pliability 0.5-2.5mm;4th, film firmly, protects steel not aoxidize, not decarburization, water-fast, acid and alkali-resistance and low-temperature resistance, in hydrochloric acid, hydroxide Soak in sodium and sodium chloride 4-8 month it is unchanged, can extensively produce and constantly replace current material.
Specific embodiment
Below in conjunction with example, the invention will be further described, and embodiment is only used for that the present invention will be described, not Constitute restriction to right, it may occur to persons skilled in the art that other alternative means, in right of the present invention In claimed range.
Embodiment 1:
The first step:100 parts of coal tar asphalt, 10 parts of zinc yellow, 12 parts of silver paste powder, tolysulfonyl are weighed according to mass fraction proportioning 8 parts of chlorine, 6 parts of zinc carbonate, 40 parts of titanium dioxide, polystyrene resin is 15 parts, 25 parts of trbasic zinc phosphate, 15 parts of glass dust, melamine 18 parts, 3 parts of diphenyl ether, 25 parts of cyclohexanone, 0.5 part of potassium bichromate, 0.1 part of lead naphthenate.
Second step:By coal tar asphalt, zinc yellow, silver paste powder, titanium dioxide and potassium bichromate input with thermometer and stirring In the reactor of device, 80 DEG C are warming up to, under 300r/min rotating speeds 20min is stirred.
3rd step:60 DEG C are cooled to, paratoluensulfonyl chloride, zinc carbonate and polystyrene resin is added, 2h is stirred;Add surplus Remaining raw material, is warming up to 190 DEG C, and high-speed stirred 15min, speed of agitator is 500r/min, puts in ball mill after being cooled to 20 DEG C Barrelling after grinding 44h.
Product adhesion 1 grade, high temperature is not dry and cracked and comes off, and fast drying is dried 120min at 200 DEG C, salt tolerant is without corruption Erosion 30d;Pendulum-rocker hardness 8, coating luminous, flat smooth, with good hot strength and dielectric properties, 40 μm of fineness;It is resistance to 1000 DEG C of high temperature do not fall off, and metal are not corroded, pliability 0.5mm;Film firmly, protects steel not aoxidize, and not decarburization is resistance to Water, acid and alkali-resistance and low-temperature resistance, soak in hydrochloric acid, NaOH and sodium chloride 4 months it is unchanged, can extensively produce and constantly Replace current material.
Embodiment 2:
The first step:100 parts of coal tar asphalt, 30 parts of zinc yellow, 18 parts of silver paste powder, tolysulfonyl are weighed according to mass fraction proportioning 12 parts of chlorine, 10 parts of zinc carbonate, 60 parts of titanium dioxide, polystyrene resin is 35 parts, 65 parts of trbasic zinc phosphate, 55 parts of glass dust, melamine 22 parts of amine, 7 parts of diphenyl ether, 45 parts of cyclohexanone, 4.5 parts of potassium bichromate, 2 parts of lead naphthenate.
Second step:By coal tar asphalt, zinc yellow, silver paste powder, titanium dioxide and potassium bichromate input with thermometer and stirring In the reactor of device, 100 DEG C are warming up to, under 500r/min rotating speeds 40min is stirred.
3rd step:70 DEG C are cooled to, paratoluensulfonyl chloride, zinc carbonate and polystyrene resin is added, 4h is stirred;Add surplus Remaining raw material, is warming up to 210 DEG C, and high-speed stirred 35min, speed of agitator is 700r/min, puts in ball mill after being cooled to 30 DEG C Barrelling after grinding 48h.
Product adhesion 1 grade, high temperature is not dry and cracked and comes off, and fast drying is dried 110min at 200 DEG C, salt tolerant is without corruption Erosion 40d;Pendulum-rocker hardness 8, coating luminous, flat smooth, with good hot strength and dielectric properties, 35 μm of fineness;It is resistance to 1100 DEG C of high temperature do not fall off, and metal are not corroded, pliability 1mm;Film firmly, protects steel not aoxidize, not decarburization, water-fast, Acid and alkali-resistance and low-temperature resistance, in hydrochloric acid, NaOH and sodium chloride soak 5 months it is unchanged, can extensively produce the not division of history into periods For current material.
Embodiment 3:
The first step:100 parts of coal tar asphalt, 25 parts of zinc yellow, 17 parts of silver paste powder, tolysulfonyl are weighed according to mass fraction proportioning 11 parts of chlorine, 9 parts of zinc carbonate, 55 parts of titanium dioxide, polystyrene resin is 30 parts, 55 parts of trbasic zinc phosphate, 45 parts of glass dust, melamine 21 parts, 6 parts of diphenyl ether, 40 parts of cyclohexanone, 3.5 parts of potassium bichromate, 1.5 parts of manganese naphthenate.
Second step:By coal tar asphalt, zinc yellow, silver paste powder, titanium dioxide and potassium bichromate input with thermometer and stirring In the reactor of device, 80 DEG C are warming up to, under 300r/min rotating speeds 20min is stirred.
3rd step:60 DEG C are cooled to, paratoluensulfonyl chloride, zinc carbonate and polystyrene resin is added, 2h is stirred;Add surplus Remaining raw material, is warming up to 190 DEG C, and high-speed stirred 15min, speed of agitator is 500r/min, puts in ball mill after being cooled to 20 DEG C Barrelling after grinding 44h.
Product adhesion 1 grade, high temperature is not dry and cracked and comes off, and fast drying is dried 100min at 200 DEG C, salt tolerant is without corruption Erosion 50d;Pendulum-rocker hardness 9, coating luminous, flat smooth, with good hot strength and dielectric properties, 30 μm of fineness;It is resistance to 1200 DEG C of high temperature do not fall off, and metal are not corroded, pliability 1.5mm;Film firmly, protects steel not aoxidize, and not decarburization is resistance to Water, acid and alkali-resistance and low-temperature resistance, soak in hydrochloric acid, NaOH and sodium chloride 6 months it is unchanged, can extensively produce and constantly Replace current material.
Embodiment 4:
The first step:100 parts of coal tar asphalt, 15 parts of zinc yellow, 13 parts of silver paste powder, tolysulfonyl are weighed according to mass fraction proportioning 9 parts of chlorine, 7 parts of zinc carbonate, 45 parts of titanium dioxide, polystyrene resin is 20 parts, 35 parts of trbasic zinc phosphate, 25 parts of glass dust, melamine 19 parts, 4 parts of diphenyl ether, 30 parts of cyclohexanone, 1.5 parts of potassium bichromate, 0.5 part of cobalt naphthenate.
Second step:By coal tar asphalt, zinc yellow, silver paste powder, titanium dioxide and potassium bichromate input with thermometer and stirring In the reactor of device, 100 DEG C are warming up to, under 500r/min rotating speeds 40min is stirred.
3rd step:70 DEG C are cooled to, paratoluensulfonyl chloride, zinc carbonate and polystyrene resin is added, 4h is stirred;Add surplus Remaining raw material, is warming up to 210 DEG C, and high-speed stirred 35min, speed of agitator is 700r/min, puts in ball mill after being cooled to 30 DEG C Barrelling after grinding 48h.
Product adhesion 1 grade, high temperature is not dry and cracked and comes off, and fast drying is dried 90min at 200 DEG C, salt tolerant is corrosion-free 60d;Pendulum-rocker hardness 9, coating luminous, flat smooth, with good hot strength and dielectric properties, 25 μm of fineness;Resistance to 1300 DEG C high temperature does not fall off, and metal is not corroded, pliability 2mm;Film firmly, protects steel not aoxidize, and not decarburization is water-fast, acidproof Alkali and low-temperature resistance, in hydrochloric acid, NaOH and sodium chloride soak 7 months it is unchanged, can extensively produce and constantly replace show There is material.
Embodiment 5:
The first step:100 parts of coal tar asphalt, 20 parts of zinc yellow, 15 parts of silver paste powder, tolysulfonyl are weighed according to mass fraction proportioning 10 parts of chlorine, 8 parts of zinc carbonate, 50 parts of titanium dioxide, polystyrene resin is 25 parts, 45 parts of trbasic zinc phosphate, 35 parts of glass dust, melamine 20 parts, 5 parts of diphenyl ether, 35 parts of cyclohexanone, 2.5 parts of potassium bichromate, 1 part of cobalt naphthenate.
Second step:By coal tar asphalt, zinc yellow, silver paste powder, titanium dioxide and potassium bichromate input with thermometer and stirring In the reactor of device, 90 DEG C are warming up to, under 400r/min rotating speeds 30min is stirred.
3rd step:65 DEG C are cooled to, paratoluensulfonyl chloride, zinc carbonate and polystyrene resin is added, 3h is stirred;Add surplus Remaining raw material, is warming up to 200 DEG C, and high-speed stirred 25min, speed of agitator is 600r/min, puts in ball mill after being cooled to 25 DEG C Barrelling after grinding 46h.
Product adhesion 1 grade, high temperature is not dry and cracked and comes off, and fast drying is dried 80min at 200 DEG C, salt tolerant is corrosion-free 70d;Pendulum-rocker hardness 10, coating luminous, flat smooth, with good hot strength and dielectric properties, 20 μm of fineness;Resistance to 1400 DEG C high temperature does not fall off, and metal is not corroded, pliability 2.5mm;Film firmly, protects steel not aoxidize, and not decarburization is water-fast, resistance to Soda acid and low-temperature resistance, in hydrochloric acid, NaOH and sodium chloride soak 8 months it is unchanged, can extensively produce and constantly replace Current material.

Claims (9)

1. a kind of aeronautical material Rustproof high-temperature resisting coating, it is characterised in that aeronautical material Rustproof high-temperature resisting coating It is as follows that raw material presses mass fraction proportioning:100 parts of coal tar asphalt, zinc yellow 10-30 part, silver paste powder 12-18 parts, paratoluensulfonyl chloride 8-12 parts, zinc carbonate 6-10 parts, titanium dioxide 40-60 parts, polystyrene resin be 15-35 parts, trbasic zinc phosphate 25-65 parts, glass dust 15-55 parts, melamine 18-22 parts, diphenyl ether 3-7 parts, cyclohexanone 25-45 parts, potassium bichromate 0.5-4.5 parts urge dry Agent 0.1-2 parts.
2. a kind of aeronautical material Rustproof high-temperature resisting coating according to claim 1, it is characterised in that the aeronautical material It is as follows mass fraction proportioning to be pressed with the raw material of Rustproof high-temperature resisting coating:100 parts of coal tar asphalt, 10 parts of zinc yellow, 12 parts of silver paste powder, 8 parts of paratoluensulfonyl chloride, 6 parts of zinc carbonate, 40 parts of titanium dioxide, polystyrene resin is 15 parts, 25 parts of trbasic zinc phosphate, glass dust 15 Part, 18 parts of melamine, 3 parts of diphenyl ether, 25 parts of cyclohexanone, 0.5 part of potassium bichromate, 0.1 part of drier.
3. a kind of aeronautical material Rustproof high-temperature resisting coating according to claim 1, it is characterised in that:The aeronautical material It is as follows mass fraction proportioning to be pressed with the raw material of Rustproof high-temperature resisting coating:100 parts of coal tar asphalt, 30 parts of zinc yellow, 18 parts of silver paste powder, 12 parts of paratoluensulfonyl chloride, 10 parts of zinc carbonate, 60 parts of titanium dioxide, polystyrene resin is 35 parts, 65 parts of trbasic zinc phosphate, glass dust 55 Part, 22 parts of melamine, 7 parts of diphenyl ether, 45 parts of cyclohexanone, 4.5 parts of potassium bichromate, 2 parts of drier.
4. a kind of aeronautical material Rustproof high-temperature resisting coating according to claim 1, it is characterised in that:The aeronautical material It is as follows mass fraction proportioning to be pressed with the raw material of Rustproof high-temperature resisting coating:100 parts of coal tar asphalt, 25 parts of zinc yellow, 17 parts of silver paste powder, 11 parts of paratoluensulfonyl chloride, 9 parts of zinc carbonate, 55 parts of titanium dioxide, polystyrene resin is 30 parts, 55 parts of trbasic zinc phosphate, glass dust 45 Part, 21 parts of melamine, 6 parts of diphenyl ether, 40 parts of cyclohexanone, 3.5 parts of potassium bichromate, 1.5 parts of drier.
5. a kind of aeronautical material Rustproof high-temperature resisting coating according to claim 1, it is characterised in that:The aeronautical material It is as follows mass fraction proportioning to be pressed with the raw material of Rustproof high-temperature resisting coating:100 parts of coal tar asphalt, 15 parts of zinc yellow, 13 parts of silver paste powder, 9 parts of paratoluensulfonyl chloride, 7 parts of zinc carbonate, 45 parts of titanium dioxide, polystyrene resin is 20 parts, 35 parts of trbasic zinc phosphate, glass dust 25 Part, 19 parts of melamine, 4 parts of diphenyl ether, 30 parts of cyclohexanone, 1.5 parts of potassium bichromate, 0.5 part of drier.
6. a kind of aeronautical material Rustproof high-temperature resisting coating according to claim 1, it is characterised in that:The aeronautical material It is as follows mass fraction proportioning to be pressed with the raw material of Rustproof high-temperature resisting coating:100 parts of coal tar asphalt, 20 parts of zinc yellow, 15 parts of silver paste powder, 10 parts of paratoluensulfonyl chloride, 8 parts of zinc carbonate, 50 parts of titanium dioxide, polystyrene resin is 25 parts, 45 parts of trbasic zinc phosphate, glass dust 35 Part, 20 parts of melamine, 5 parts of diphenyl ether, 35 parts of cyclohexanone, 2.5 parts of potassium bichromate, 1 part of drier.
7. a kind of aeronautical material Rustproof high-temperature resisting coating according to claim 1, it is characterised in that:The drier is adopted With cobalt naphthenate, manganese naphthenate or lead naphthenate.
8. a kind of aeronautical material prepared described in claim 1 method of Rustproof high-temperature resisting coating, it is characterised in that include as Lower step:
The first step:Coal tar asphalt, zinc yellow, silver paste powder, paratoluensulfonyl chloride, zinc carbonate, titanium are weighed according to mass fraction proportioning White powder, polystyrene resin, trbasic zinc phosphate, glass dust, diphenyl ether, cyclohexanone, potassium bichromate and drier;
Second step:By coal tar asphalt, zinc yellow, silver paste powder, titanium dioxide and potassium bichromate input with thermometer and agitator In reactor, 80-100 DEG C is warming up to, under 300-500r/min rotating speeds 20-40min is stirred;
3rd step:60-70 DEG C is cooled to, paratoluensulfonyl chloride, zinc carbonate and polystyrene resin is added, 2-4h is stirred;
4th step:Surplus stock is added, 190-210 DEG C is warming up to, high-speed stirred 15-35min puts into after being cooled to 20-30 DEG C Barrelling after grinding in ball grinder 44-48h.
9. the aeronautical material according to claim 8 method of Rustproof high-temperature resisting coating, it is characterised in that:4th step High-speed stirred rotating speed be 500-700r/min.
CN201611148936.4A 2016-12-13 2016-12-13 Antirust high-temperature-resistant paint for aeronautical materials and preparation method of antirust high-temperature-resistant paint Pending CN106590422A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
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CN107720053A (en) * 2017-09-30 2018-02-23 柳州联海科技有限公司 A kind of antirust and marine garbage gathering device
CN109810600A (en) * 2019-01-25 2019-05-28 万晟建设集团有限公司 Green energy conservation interior wall coating

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CN102925011A (en) * 2012-11-30 2013-02-13 康力电梯股份有限公司 Antirust coating material for staircase
CN104341924A (en) * 2014-11-14 2015-02-11 无锡伊佩克科技有限公司 Water-based antirust and rust removing asphalt ship bottom coating and preparation method for same
CN105968977A (en) * 2016-07-19 2016-09-28 任新根 Quick-drying water-based antirust paint for metals
CN106147591A (en) * 2016-07-19 2016-11-23 任新根 A kind of waterproof antirusting paint of metal
CN106189858A (en) * 2016-07-19 2016-12-07 任新根 A kind of metal antirusting paint

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Publication number Priority date Publication date Assignee Title
CN102925011A (en) * 2012-11-30 2013-02-13 康力电梯股份有限公司 Antirust coating material for staircase
CN104341924A (en) * 2014-11-14 2015-02-11 无锡伊佩克科技有限公司 Water-based antirust and rust removing asphalt ship bottom coating and preparation method for same
CN105968977A (en) * 2016-07-19 2016-09-28 任新根 Quick-drying water-based antirust paint for metals
CN106147591A (en) * 2016-07-19 2016-11-23 任新根 A kind of waterproof antirusting paint of metal
CN106189858A (en) * 2016-07-19 2016-12-07 任新根 A kind of metal antirusting paint

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107720053A (en) * 2017-09-30 2018-02-23 柳州联海科技有限公司 A kind of antirust and marine garbage gathering device
CN109810600A (en) * 2019-01-25 2019-05-28 万晟建设集团有限公司 Green energy conservation interior wall coating

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