CN106046976A - Process for preparing ultraviolet-resistant anionic decorative plate - Google Patents
Process for preparing ultraviolet-resistant anionic decorative plate Download PDFInfo
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- CN106046976A CN106046976A CN201610352442.1A CN201610352442A CN106046976A CN 106046976 A CN106046976 A CN 106046976A CN 201610352442 A CN201610352442 A CN 201610352442A CN 106046976 A CN106046976 A CN 106046976A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
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- Architecture (AREA)
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Abstract
The invention relates to a process for preparing an ultraviolet-resistant anionic decorative plate. The process comprises the steps of firstly, coating a calcium silicate substrate with ultraviolet-resistant seal coat in a rolling-brushing manner, spraying a binder to the seal coat after the seal coat is subjected to ultraviolet lamp irradiating and aeration-drying, covering the binder with a patterned transfer print film, then, irradiating the transfer print film by an ultraviolet lamp so as to carry out cold transfer printing on the transfer print film, spraying finish-coat paint to the calcium silicate substrate, and carrying out film coating and pressing after the finish-coat paint is subjected to ultraviolet lamp irradiating and aeration-drying, thereby obtaining the ultraviolet-resistant anionic decorative plate. According to the process for preparing the ultraviolet-resistant anionic decorative plate, disclosed by the invention, anions with extremely high adsorption and oxidation actions can be generated, and bacteria and viruses in air can be efficiently killed, so that the ultraviolet-resistant anionic decorative plate has a certain health care action on human bodies; an ultraviolet absorbent is added into the seal coat, so that the life span of patterns on the decorative plate under the condition of ultraviolet irradiation is prolonged; and the ultraviolet-resistant anionic decorative plate is in line with the requirements of modern people on green and environment-friendly dwelling environments and is applicable to popularization in building outdoor decorative plate related industries.
Description
Technical field
The invention belongs to environment-friendly building materials preparation field, the preparation technology of a kind of UV resistant anion decorative panel.
Background technology
In the various construction materials of interior decoration, containing various harmful volatile organic matters, these are poisonous
Harmful Organic substance includes halogenated hydrocarbon compound, arene compound, aldehydes, ketone and lipoid substance, to outdoor environment
Cause the biggest pollution with air, human health is constituted potentially hazardous.
Traditional decorative board structure used for building exterior wall and function are more single, easily produce the harmful substances such as formaldehyde, easily
Human body is produced injury, it is impossible to meet modern's requirement to Green environment-friendlyhome home environment.
The charged particle that atom or atomic group are formed after losing or obtain electronics in ion, anion refer to carry one or
The ion of multiple negative charges, also known as " anion ".Negative ions in air is divided into large, medium and small three according to the size of mobility
Plant ion.The anion of small particle has good biological activity, it is easy to through human body blood brain barrier, enters human body and plays it
Biological effect.Effect based on anion, it has again the title of " air vitamin ".Countless clinical researches find, anion is permissible
Improve neurasthenia, insomnia, unobstructed cardiovascular and cerebrovascular vessel, reduce blood viscosity, improve body immunity, to improving insomnia, asthma,
Alleviate the persistent ailment such as hypertension, diabetes and there is significant curative effect, " the modern physics therapeutics " that correlational study is edited at Chen Jingzao with
And Tsing-Hua University's woods gold penetrating judgment awards and has in detail explaination in the works such as " environment, health and the negative oxygen ion " of chief editor.
Needing to accept the irradiation of sunlight when decorative panel uses out of doors, color and pattern on decorative panel can be at ultraviolet
Gradually fading under irradiation, service life is shorter.Therefore, it is badly in need of one can anion releasing and UV resistant irradiate, necessarily
The environment friendly decoration board that will not fade in time.
Summary of the invention
In order to solve the problems referred to above, it is an object of the invention to provide the preparation work of a kind of UV resistant anion decorative panel
Skill, by using the anion paint of safety and environmental protection to replace traditional finish on the basis of traditional decoration plate preparation technology, makes
The anion that produces when in use of decorative panel has extremely strong absorption and Oxidation, it is possible to kill in air efficiently
Antibacterial and virus, human body is had certain health-care effect, possibly together with UV absorbent simultaneously in the seal coat used, makes
The pattern obtained on decorative panel will not fade under ultraviolet irradiation in a short time, meets modern to living environment green ring
The requirement protected.
The present invention is to solve that the technical scheme that the problems referred to above are taked is:
A kind of preparation technology of UV resistant anion decorative panel, the first closing of round brush UV resistant on calcium silicates substrate
Paint, seal coat irradiates and spraying binder after aeration-drying through Burdick lamp, covers patterned transfer film on the adhesive, cover
Using Burdick lamp to irradiate after lid and carry out cold transfer, the pattern on film to be transferred is thrown off at the bottom of transfer film after being transferred on seal coat
Film, coating hood finish paint on calcium silicates substrate, finish uses Burdick lamp to irradiate and carries out overlay film and compacting after aeration-drying
The UV resistant anion decorative panel i.e. obtained, according to weight ratio, described finish preparation process is by 60-80 part emulsion, 10-
16 parts of coloring agent and 0.05-0.13 part preservative dispersed with stirring are uniform, add 1-4 part thickening agent and 2-6 part anion liquid enters
Row stirring, is eventually adding 0.08-0.7 part defoamer and carries out low speed dispersion stirring, use the alkaline solution containing hydroxide ion
Adjustment pH value, to 8.5-10, stands 2h with the nylon net filter of 150 mesh, filtrate, obtains finish after standing 10min；
The Mg dispelling in system is needed while system ensures alkaline environment2+, add the soluble-salt with hydroxide ion
Solution, on the one hand adjusts the pH value of system, on the other hand hydroxide ion and Mg2+Interact reaction, form Mg (OH)2Knot
Crystalline substance, uses nylon wire to carry out filtering to remove bigger crystallization, remains less crystallization and can strengthen the viscosity of finish with steady
Qualitative.
Described emulsion by acrylic emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethyl cellulose according to 40:
The ratio of 10:4:2:1 is sufficiently mixed prepared, wherein the solvent in sodium chloride solution be hardness be the soft water of 4, the quality of solute is divided
Number is 3-5%；
Industry emulsion the most easy-to-use pure water dilution, contributes to the dilution of industry emulsion containing the ion of debita spissitudo in water, but water
In Mg2+And Ca2+Then can impact, therefore the using effect of distilled water and tap water is the most bad, and the present invention selects the hardness to be
The soft water of 4, the Mg being because in soft water2+And Ca2+Concentration is relatively low does not haves the industry uneven feelings that caking occurs of emulsion dilution
Condition.
According to weight ratio, described anion liquid by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part
Former times purine natural gum, 0.05 part of disodiumedetate, 0.3 part of dodecyl sodium sulfate composition, wherein tourmaline powder and wheat meal
The fineness of stone powder is 3000 mesh；
Described defoamer is organic silicon emulsion, and thickening agent is sodium carboxymethyl cellulose, and preservative is Methylisothiazolinone；
The seal coat of described UV resistant is to the addition of UV absorbent in commercially available seal coat, wherein according to volume ratio, and city
The adding proportion selling seal coat and UV absorbent is 30:1；Described UV absorbent include 50 parts of dehydrated alcohol, 3 part two
Titanium oxide, 6 parts of zinc oxide, 5 parts of benzophenone, 2 parts of cinoxates and 1 part of ethylhexyl methoxy cinnamate, preparation process is by 5
Part benzophenone, 2 parts of cinoxates, 1 part of ethylhexyl methoxy cinnamate and 50 parts of dehydrated alcohol are sufficiently mixed, and are subsequently adding 3
Part titanium dioxide and 6 parts of zinc oxide carry out the dispersion stirring 1h that rotating speed is 100 revs/min, use ultrasonic degas, i.e. after stirring
Obtain UV absorbent.
Described UV absorbent have employed physical reflection ultraviolet and chemical absorbing ultraviolet two ways and deposits
Method prevents decorative panel from fading after being irradiated by ultraviolet, wherein benzophenone, cinoxate, methoxy cinnamic acid ethyl hexyl
Ester is the most water insoluble, therefore uses dehydrated alcohol to enter benzophenone, cinoxate, ethylhexyl methoxy cinnamate as solvent
Row dissolves, again because ultraviolet is divided into nearultraviolet rays UVA, far ultraviolet rays UVB and ultrashort ultraviolet (UV) C tri-according to the difference of wavelength
Kind, by benzophenone, cinoxate, ethylhexyl methoxy cinnamate three kinds is used in mixed way can by the ultraviolet of three kinds of wavelength all
It is included in absorption region, in order to reach best ultra-violet absorption effect.
Meanwhile, UV absorbent is also added into titanium dioxide and zinc oxide, belongs to common physical sunscreen agent, energy
The nearultraviolet rays UVA of enough reflection overwhelming majority, and nearultraviolet rays UVA is the main cause causing decorative panel to fade.
According to weight ratio, described finish preparation process is by 70 parts of emulsions, 15 parts of coloring agent and 0.1 part of preservative stirring
It is uniformly dispersed, adds 3 parts of thickening agents and 5 parts of anion liquid are stirred, be eventually adding 0.5 part of defoamer and carry out low speed dispersion
Stirring, to be mixed rear with the nylon net filter of 150 mesh, stand 2h after filtration, obtain finish.
By 60-80 part emulsion, 10-16 part coloring agent and 0.05-0.13 part preservative in described finish preparation process
At 40 DEG C, carry out the high-speed stirred that rotating speed is 1200 revs/min after mixing, stir 30min.
High-speed stirred can use high velocity dispersators, makes mixed liquor in rolling annular flow, produce strong in agitator
Vortex, mixed liquor surface particle drops to bottom eddy current in the shape of a spiral, forms turbulent area at dispersion impeller edge 2.5-5mm, mixed
Close liquid and particle therein by intensive shear and impact；Forming upper and lower two lines outside stirring region, mixed liquor obtains fully
Circulate and stir.By the mixed liquor distributed components that this alr mode is stirred, in stable condition, it is not susceptible to after standing
Layering.
The preparation process of described anion liquid is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06
Part former times purine natural gum at room temperature carries out the stirring that rotating speed is 800 revs/min, and mixing time is 10min, adds 0.05 part of second
Edetate disodium and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasound wave aerofluxus, must bear from
Sub-liquid.
Disodiumedetate is added in the formula of anion liquid use as chelating agent.There is stronger network
Conjunction ability, just can reach the complexation degree needed at the most minimum consumption of less consumption, itself also has dispersion, suspends and make
With, because anion liquid contains the water-fast granule such as tourmaline powder and medical stone powder, layering easily occurs when standing
Situation, therefore adds disodiumedetate and can improve the stability of the suspended state of anion liquid.
Dodecyl sodium sulfate, as a kind of anion surfactant, has stronger emulsification, at anion liquid
Middle use, plays emulsifying and stable effect while not affecting anion release to anion liquid.
Described calcium silicates substrate is through fixed thick sanding to 4cm, and round brush seal coat on sanding face, round brush thickness is for often to put down
40 grams, side.
Beneficial effects of the present invention:
The preparation technology of a kind of UV resistant anion decorative panel of the present invention, by traditional decoration plate preparation technology's
On the basis of employ the anion paint of safety and environmental protection and replace traditional finish, wherein in anion paint, industry emulsion employs molten
Agent is that the sodium chloride solution of soft water is diluted, and has dispelled the calcium ion in solvent and magnesium ion, it is to avoid both examples are with negative
Some element generation combination reactions in ionic liquid thus affect finish and produce the effect of anion, additionally in anion liquid
With the addition of a certain proportion of medical stone powder, Maifanitum to no toxic biological and there is certain biological activity, main component except
Beyond aluminosilicate and some macroelements, possibly together with various trace elements and rare earth element, its rare earth elements and tourmaline
Powder interacts and can significantly improve the anion growing amount of finish；UV absorbent, ultraviolet is with the addition of in seal coat
Light absorbers have employed physical reflection ultraviolet and chemical absorbing ultraviolet two ways the method deposited to prevent decorative panel quilt
Ultraviolet fades after irradiating, respond well.
In sum, the preparation technology of a kind of UV resistant anion decorative panel of the present invention, obtained decoration
Plate can produce the anion with extremely strong absorption and Oxidation during using, it is possible to kills efficiently in air
Antibacterial and virus human body had certain health-care effect, again because preparation process of the present invention successively coats four
Layer paint, and with the addition of Methylisothiazolinone in last finish so that anion decorative panel is bright in luster, and covering power is good,
Scrubbing resistance and mildew-resistant are fungi-proofing, with the addition of UV absorbent in seal coat, extend the upper figure of decorative panel under ultraviolet irradiates
The existence time of case, meet modern's requirement to living environment environmental protection, be suitable to being correlated with at exterior decoration plate for building
Industry is promoted the use of.
Detailed description of the invention
In conjunction with specific examples below, the present invention is described in further detail, and protection scope of the present invention is not limited to
In following example.Implement the process of the present invention, condition, reagent, experimental technique etc., outside the lower content mentioned specially,
Being universal knowledege and the common knowledge of this area, the present invention is not particularly limited content.
The preparation technology of a kind of UV resistant anion decorative panel, the first envelope of round brush UV resistant on calcium silicates substrate
Closing paint, seal coat irradiates and spraying binder after aeration-drying through Burdick lamp, covers patterned transfer film on the adhesive,
Using Burdick lamp to irradiate after covering and carry out cold transfer, the pattern on film to be transferred is thrown off at the bottom of transfer film after being transferred on seal coat
Film, coating hood finish paint on calcium silicates substrate, finish uses Burdick lamp to irradiate and carries out overlay film and compacting after aeration-drying
The UV resistant anion decorative panel i.e. obtained, according to weight ratio, described finish preparation process is by 60-80 part emulsion, 10-
16 parts of coloring agent and 0.05-0.13 part preservative dispersed with stirring are uniform, add 1-4 part thickening agent and 2-6 part anion liquid enters
Row stirring, is eventually adding 0.08-0.7 part defoamer and carries out low speed dispersion stirring, use the alkaline solution containing hydroxide ion
Adjustment pH value, to 8.5-10, stands 2h with the nylon net filter of 150 mesh, filtrate, obtains finish after standing 10min；
The Mg dispelling in system is needed while system ensures alkaline environment2+, add the soluble-salt with hydroxide ion
Solution, on the one hand adjusts the pH value of system, on the other hand hydroxide ion and Mg2+Interact reaction, form Mg (OH)2Knot
Crystalline substance, uses nylon wire to carry out filtering to remove bigger crystallization, remains less crystallization and can strengthen the viscosity of finish with steady
Qualitative.
Described emulsion by acrylic emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethyl cellulose according to 40:
The ratio of 10:4:2:1 is sufficiently mixed prepared, wherein the solvent in sodium chloride solution be hardness be the soft water of 4, the quality of solute is divided
Number is 3-5%；
Industry emulsion the most easy-to-use pure water dilution, contributes to the dilution of industry emulsion containing the ion of debita spissitudo in water, but water
In Mg2+And Ca2+Then can impact, therefore the using effect of distilled water and tap water is the most bad, and the present invention selects the hardness to be
The soft water of 4, the Mg being because in soft water2+And Ca2+Concentration is relatively low does not haves the industry uneven feelings that caking occurs of emulsion dilution
Condition.
According to weight ratio, described anion liquid by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part
Former times purine natural gum, 0.05 part of disodiumedetate, 0.3 part of dodecyl sodium sulfate composition, wherein tourmaline powder and wheat meal
The fineness of stone powder is 3000 mesh；
Described defoamer is organic silicon emulsion, and thickening agent is sodium carboxymethyl cellulose, and preservative is Methylisothiazolinone；
The seal coat of described UV resistant is to the addition of UV absorbent in commercially available seal coat, wherein according to volume ratio, and city
The adding proportion selling seal coat and UV absorbent is 30:1；Described UV absorbent include 50 parts of dehydrated alcohol, 3 part two
Titanium oxide, 6 parts of zinc oxide, 5 parts of benzophenone, 2 parts of cinoxates and 1 part of ethylhexyl methoxy cinnamate, preparation process is by 5
Part benzophenone, 2 parts of cinoxates, 1 part of ethylhexyl methoxy cinnamate and 50 parts of dehydrated alcohol are sufficiently mixed, and are subsequently adding 3
Part titanium dioxide and 6 parts of zinc oxide carry out the dispersion stirring 1h that rotating speed is 100 revs/min, use ultrasonic degas, i.e. after stirring
Obtain UV absorbent.
Described UV absorbent have employed physical reflection ultraviolet and chemical absorbing ultraviolet two ways and deposits
Method prevents decorative panel from fading after being irradiated by ultraviolet, wherein benzophenone, cinoxate, methoxy cinnamic acid ethyl hexyl
Ester is the most water insoluble, therefore uses dehydrated alcohol to enter benzophenone, cinoxate, ethylhexyl methoxy cinnamate as solvent
Row dissolves, again because ultraviolet is divided into nearultraviolet rays UVA, far ultraviolet rays UVB and ultrashort ultraviolet (UV) C tri-according to the difference of wavelength
Kind, by benzophenone, cinoxate, ethylhexyl methoxy cinnamate three kinds is used in mixed way can by the ultraviolet of three kinds of wavelength all
It is included in absorption region, in order to reach best ultra-violet absorption effect.
Meanwhile, UV absorbent is also added into titanium dioxide and zinc oxide, belongs to common physical sunscreen agent, energy
The nearultraviolet rays UVA of enough reflection overwhelming majority, and nearultraviolet rays UVA is the main cause causing decorative panel to fade.
According to weight ratio, described finish preparation process is by 70 parts of emulsions, 15 parts of coloring agent and 0.1 part of preservative stirring
It is uniformly dispersed, adds 3 parts of thickening agents and 5 parts of anion liquid are stirred, be eventually adding 0.5 part of defoamer and carry out low speed dispersion
Stirring, to be mixed rear with the nylon net filter of 150 mesh, stand 2h after filtration, obtain finish.
By 60-80 part emulsion, 10-16 part coloring agent and 0.05-0.13 part preservative in described finish preparation process
At 40 DEG C, carry out the high-speed stirred that rotating speed is 1200 revs/min after mixing, stir 30min.
High-speed stirred can use high velocity dispersators, makes mixed liquor in rolling annular flow, produce strong in agitator
Vortex, mixed liquor surface particle drops to bottom eddy current in the shape of a spiral, forms turbulent area at dispersion impeller edge 2.5-5mm, mixed
Close liquid and particle therein by intensive shear and impact；Forming upper and lower two lines outside stirring region, mixed liquor obtains fully
Circulate and stir.By the mixed liquor distributed components that this alr mode is stirred, in stable condition, it is not susceptible to after standing
Layering.
The preparation process of described anion liquid is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06
Part former times purine natural gum at room temperature carries out the stirring that rotating speed is 800 revs/min, and mixing time is 10min, adds 0.05 part of second
Edetate disodium and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasound wave aerofluxus, must bear from
Sub-liquid.
Disodiumedetate is added in the formula of anion liquid use as chelating agent.There is stronger network
Conjunction ability, just can reach the complexation degree needed at the most minimum consumption of less consumption, itself also has dispersion, suspends and make
With, because anion liquid contains the water-fast granule such as tourmaline powder and medical stone powder, layering easily occurs when standing
Situation, therefore adds disodiumedetate and can improve the stability of the suspended state of anion liquid.
Dodecyl sodium sulfate, as a kind of anion surfactant, has stronger emulsification, at anion liquid
Middle use, plays emulsifying and stable effect while not affecting anion release to anion liquid.
Described calcium silicates substrate is through fixed thick sanding to 4cm, and round brush seal coat on sanding face, round brush thickness is for often to put down
40 grams, side.
Embodiment 1
A kind of preparation technology of UV resistant anion decorative panel, the first closing of round brush UV resistant on calcium silicates substrate
Paint, calcium silicates substrate is through fixed thick sanding to 4cm, and round brush thickness is 40 grams every square, and seal coat irradiates through Burdick lamp and leads to
The dried spraying binder of wind, covers patterned transfer film on the adhesive, uses Burdick lamp irradiation to carry out cold after covering
Transferring, transfer film counterdie thrown off by the pattern on film to be transferred after being transferred on seal coat, coating hood finish paint on calcium silicates substrate,
Finish uses Burdick lamp to irradiate and carries out overlay film after aeration-drying and suppress the UV resistant anion decorative panel i.e. obtained,
According to weight ratio, described finish preparation process is by equal to 60 parts of emulsions, 10 parts of coloring agent and 0.05 part of preservative dispersed with stirring
Even, add 1 part of thickening agent and 2 parts of anion liquid are stirred, be eventually adding 0.08 part of defoamer and carry out low speed dispersion stirring,
The use alkaline solution adjustment pH value containing hydroxide ion is to 8.5, with the nylon net filter of 150 mesh, filtrate after standing 10min
Stand 2h, obtain finish；By carrying out rotating speed at 40 DEG C after 60 parts of emulsions, 10 parts of coloring agent and 0.05 part of preservative mixing it is
The high-speed stirred of 1200 revs/min, stirs 30min.
Described emulsion by acrylic emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethyl cellulose according to 40:
The ratio of 10:4:2:1 is sufficiently mixed prepared, wherein the solvent in sodium chloride solution be hardness be the soft water of 4, the quality of solute is divided
Number is 3%；
According to weight ratio, described anion liquid is fast by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part of former times
Purine natural gum, 0.05 part of disodiumedetate, 0.3 part of dodecyl sodium sulfate composition, wherein tourmaline powder and medical stone powder
Fineness be 3000 mesh；The preparation process of described anion liquid is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distillations
Water and 0.06 part of former times purine natural gum at room temperature carry out the stirring that rotating speed is 800 revs/min, and mixing time is 10min, adds
0.05 part of disodiumedetate and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasound wave aerofluxus,
Obtain anion liquid.
Described defoamer is organic silicon emulsion, and thickening agent is sodium carboxymethyl cellulose, and preservative is Methylisothiazolinone；
The seal coat of described UV resistant is to the addition of UV absorbent in commercially available seal coat, wherein according to volume ratio, and city
The adding proportion selling seal coat and UV absorbent is 30:1；Described UV absorbent include 50 parts of dehydrated alcohol, 3 part two
Titanium oxide, 6 parts of zinc oxide, 5 parts of benzophenone, 2 parts of cinoxates and 1 part of ethylhexyl methoxy cinnamate, preparation process is by 5
Part benzophenone, 2 parts of cinoxates, 1 part of ethylhexyl methoxy cinnamate and 50 parts of dehydrated alcohol are sufficiently mixed, and are subsequently adding 3
Part titanium dioxide and 6 parts of zinc oxide carry out the dispersion stirring 1h that rotating speed is 100 revs/min, use ultrasonic degas, i.e. after stirring
Obtain UV absorbent.
Embodiment 2
A kind of preparation technology of UV resistant anion decorative panel, the first closing of round brush UV resistant on calcium silicates substrate
Paint, calcium silicates substrate is through fixed thick sanding to 4cm, and round brush thickness is 40 grams every square, and seal coat irradiates through Burdick lamp and leads to
The dried spraying binder of wind, covers patterned transfer film on the adhesive, uses Burdick lamp irradiation to carry out cold after covering
Transferring, transfer film counterdie thrown off by the pattern on film to be transferred after being transferred on seal coat, coating hood finish paint on calcium silicates substrate,
Finish uses Burdick lamp to irradiate and carries out overlay film after aeration-drying and suppress the UV resistant anion decorative panel i.e. obtained,
According to weight ratio, described finish preparation process is by equal to 65 parts of emulsions, 12 parts of coloring agent and 0.08 part of preservative dispersed with stirring
Even, add 1.5 parts of thickening agents and 2.5 parts of anion liquid be stirred, be eventually adding 0.2 part of defoamer carry out low speed dispersion stir
Mix, use the alkaline solution adjustment pH value containing hydroxide ion to 9, with the nylon net filter of 150 mesh after standing 10min, filter
Liquid stands 2h, obtains finish；At 40 DEG C, rotating speed is carried out after 65 parts of emulsions, 12 parts of coloring agent and 0.08 part of preservative mixing
It is the high-speed stirred of 1200 revs/min, stirs 30min.
Described emulsion by acrylic emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethyl cellulose according to 40:
The ratio of 10:4:2:1 is sufficiently mixed prepared, wherein the solvent in sodium chloride solution be hardness be the soft water of 4, the quality of solute is divided
Number is 3.5%；
According to weight ratio, described anion liquid is fast by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part of former times
Purine natural gum, 0.05 part of disodiumedetate, 0.3 part of dodecyl sodium sulfate composition, wherein tourmaline powder and medical stone powder
Fineness be 3000 mesh；The preparation process of described anion liquid is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distillations
Water and 0.06 part of former times purine natural gum at room temperature carry out the stirring that rotating speed is 800 revs/min, and mixing time is 10min, adds
0.05 part of disodiumedetate and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasound wave aerofluxus,
Obtain anion liquid.
Described defoamer is organic silicon emulsion, and thickening agent is sodium carboxymethyl cellulose, and preservative is Methylisothiazolinone；
The seal coat of described UV resistant is to the addition of UV absorbent in commercially available seal coat, wherein according to volume ratio, and city
The adding proportion selling seal coat and UV absorbent is 30:1；Described UV absorbent include 50 parts of dehydrated alcohol, 3 part two
Titanium oxide, 6 parts of zinc oxide, 5 parts of benzophenone, 2 parts of cinoxates and 1 part of ethylhexyl methoxy cinnamate, preparation process is by 5
Part benzophenone, 2 parts of cinoxates, 1 part of ethylhexyl methoxy cinnamate and 50 parts of dehydrated alcohol are sufficiently mixed, and are subsequently adding 3
Part titanium dioxide and 6 parts of zinc oxide carry out the dispersion stirring 1h that rotating speed is 100 revs/min, use ultrasonic degas, i.e. after stirring
Obtain UV absorbent.
Embodiment 3
A kind of preparation technology of UV resistant anion decorative panel, the first closing of round brush UV resistant on calcium silicates substrate
Paint, calcium silicates substrate is through fixed thick sanding to 4cm, and round brush thickness is 40 grams every square, and seal coat irradiates through Burdick lamp and leads to
The dried spraying binder of wind, covers patterned transfer film on the adhesive, uses Burdick lamp irradiation to carry out cold after covering
Transferring, transfer film counterdie thrown off by the pattern on film to be transferred after being transferred on seal coat, coating hood finish paint on calcium silicates substrate,
Finish uses Burdick lamp to irradiate and carries out overlay film after aeration-drying and suppress the UV resistant anion decorative panel i.e. obtained,
According to weight ratio, described finish preparation process is by equal to 70 parts of emulsions, 15 parts of coloring agent and 0.1 part of preservative dispersed with stirring
Even, add 3 parts of thickening agents and 5 parts of anion liquid are stirred, be eventually adding 0.5 part of defoamer and carry out low speed dispersion stirring,
To be mixed rear with the nylon net filter of 150 mesh, stand 2h after filtration, obtain finish；By 70 parts of emulsions, 15 parts of coloring agent
At 40 DEG C, carry out, with after 0.1 part of preservative mixing, the high-speed stirred that rotating speed is 1200 revs/min, stir 30min.
Described emulsion by acrylic emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethyl cellulose according to 40:
The ratio of 10:4:2:1 is sufficiently mixed prepared, wherein the solvent in sodium chloride solution be hardness be the soft water of 4, the quality of solute is divided
Number is 4%；
According to weight ratio, described anion liquid is fast by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part of former times
Purine natural gum, 0.05 part of disodiumedetate, 0.3 part of dodecyl sodium sulfate composition, wherein tourmaline powder and medical stone powder
Fineness be 3000 mesh；The preparation process of described anion liquid is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distillations
Water and 0.06 part of former times purine natural gum at room temperature carry out the stirring that rotating speed is 800 revs/min, and mixing time is 10min, adds
0.05 part of disodiumedetate and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasound wave aerofluxus,
Obtain anion liquid.
Described defoamer is organic silicon emulsion, and thickening agent is sodium carboxymethyl cellulose, and preservative is Methylisothiazolinone；
The seal coat of described UV resistant is to the addition of UV absorbent in commercially available seal coat, wherein according to volume ratio, and city
The adding proportion selling seal coat and UV absorbent is 30:1；Described UV absorbent include 50 parts of dehydrated alcohol, 3 part two
Titanium oxide, 6 parts of zinc oxide, 5 parts of benzophenone, 2 parts of cinoxates and 1 part of ethylhexyl methoxy cinnamate, preparation process is by 5
Part benzophenone, 2 parts of cinoxates, 1 part of ethylhexyl methoxy cinnamate and 50 parts of dehydrated alcohol are sufficiently mixed, and are subsequently adding 3
Part titanium dioxide and 6 parts of zinc oxide carry out the dispersion stirring 1h that rotating speed is 100 revs/min, use ultrasonic degas, i.e. after stirring
Obtain UV absorbent.
Embodiment 4
A kind of preparation technology of UV resistant anion decorative panel, the first closing of round brush UV resistant on calcium silicates substrate
Paint, calcium silicates substrate is through fixed thick sanding to 4cm, and round brush thickness is 40 grams every square, and seal coat irradiates through Burdick lamp and leads to
The dried spraying binder of wind, covers patterned transfer film on the adhesive, uses Burdick lamp irradiation to carry out cold after covering
Transferring, transfer film counterdie thrown off by the pattern on film to be transferred after being transferred on seal coat, coating hood finish paint on calcium silicates substrate,
Finish uses Burdick lamp to irradiate and carries out overlay film after aeration-drying and suppress the UV resistant anion decorative panel i.e. obtained,
According to weight ratio, described finish preparation process is by equal to 75 parts of emulsions, 15 parts of coloring agent and 0.11 part of preservative dispersed with stirring
Even, add 3.5 parts of thickening agents and 5.5 parts of anion liquid be stirred, be eventually adding 0.5 part of defoamer carry out low speed dispersion stir
Mixing, the use alkaline solution adjustment pH value containing hydroxide ion is to 9.5, with the nylon net filter of 150 mesh after standing 10min,
Filtrate stands 2h, obtains finish；Carry out turning at 40 DEG C after 75 parts of emulsions, 15 parts of coloring agent and 0.11 part of preservative mixing
Speed is the high-speed stirred of 1200 revs/min, stirs 30min.
Described emulsion by acrylic emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethyl cellulose according to 40:
The ratio of 10:4:2:1 is sufficiently mixed prepared, wherein the solvent in sodium chloride solution be hardness be the soft water of 4, the quality of solute is divided
Number is 4.5%；
According to weight ratio, described anion liquid is fast by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part of former times
Purine natural gum, 0.05 part of disodiumedetate, 0.3 part of dodecyl sodium sulfate composition, wherein tourmaline powder and medical stone powder
Fineness be 3000 mesh；The preparation process of described anion liquid is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distillations
Water and 0.06 part of former times purine natural gum at room temperature carry out the stirring that rotating speed is 800 revs/min, and mixing time is 10min, adds
0.05 part of disodiumedetate and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasound wave aerofluxus,
Obtain anion liquid.
Described defoamer is organic silicon emulsion, and thickening agent is sodium carboxymethyl cellulose, and preservative is Methylisothiazolinone；
The seal coat of described UV resistant is to the addition of UV absorbent in commercially available seal coat, wherein according to volume ratio, and city
The adding proportion selling seal coat and UV absorbent is 30:1；Described UV absorbent include 50 parts of dehydrated alcohol, 3 part two
Titanium oxide, 6 parts of zinc oxide, 5 parts of benzophenone, 2 parts of cinoxates and 1 part of ethylhexyl methoxy cinnamate, preparation process is by 5
Part benzophenone, 2 parts of cinoxates, 1 part of ethylhexyl methoxy cinnamate and 50 parts of dehydrated alcohol are sufficiently mixed, and are subsequently adding 3
Part titanium dioxide and 6 parts of zinc oxide carry out the dispersion stirring 1h that rotating speed is 100 revs/min, use ultrasonic degas, i.e. after stirring
Obtain UV absorbent.
Embodiment 5
A kind of preparation technology of UV resistant anion decorative panel, the first closing of round brush UV resistant on calcium silicates substrate
Paint, calcium silicates substrate is through fixed thick sanding to 4cm, and round brush thickness is 40 grams every square, and seal coat irradiates through Burdick lamp and leads to
The dried spraying binder of wind, covers patterned transfer film on the adhesive, uses Burdick lamp irradiation to carry out cold after covering
Transferring, transfer film counterdie thrown off by the pattern on film to be transferred after being transferred on seal coat, coating hood finish paint on calcium silicates substrate,
Finish uses Burdick lamp to irradiate and carries out overlay film after aeration-drying and suppress the UV resistant anion decorative panel i.e. obtained,
According to weight ratio, described finish preparation process is by equal to 80 parts of emulsions, 16 parts of coloring agent and 0.13 part of preservative dispersed with stirring
Even, add 4 parts of thickening agents and 6 parts of anion liquid are stirred, be eventually adding 0.7 part of defoamer and carry out low speed dispersion stirring,
The use alkaline solution adjustment pH value containing hydroxide ion is to 10, with the nylon net filter of 150 mesh, filtrate after standing 10min
Stand 2h, obtain finish；By carrying out rotating speed at 40 DEG C after 80 parts of emulsions, 16 parts of coloring agent and 0.13 part of preservative mixing it is
The high-speed stirred of 1200 revs/min, stirs 30min.
Described emulsion by acrylic emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethyl cellulose according to 40:
The ratio of 10:4:2:1 is sufficiently mixed prepared, wherein the solvent in sodium chloride solution be hardness be the soft water of 4, the quality of solute is divided
Number is 5%；
According to weight ratio, described anion liquid is fast by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part of former times
Purine natural gum, 0.05 part of disodiumedetate, 0.3 part of dodecyl sodium sulfate composition, wherein tourmaline powder and medical stone powder
Fineness be 3000 mesh；The preparation process of described anion liquid is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distillations
Water and 0.06 part of former times purine natural gum at room temperature carry out the stirring that rotating speed is 800 revs/min, and mixing time is 10min, adds
0.05 part of disodiumedetate and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasound wave aerofluxus,
Obtain anion liquid.
Described defoamer is organic silicon emulsion, and thickening agent is sodium carboxymethyl cellulose, and preservative is Methylisothiazolinone；
The seal coat of described UV resistant is to the addition of UV absorbent in commercially available seal coat, wherein according to volume ratio, and city
The adding proportion selling seal coat and UV absorbent is 30:1；Described UV absorbent include 50 parts of dehydrated alcohol, 3 part two
Titanium oxide, 6 parts of zinc oxide, 5 parts of benzophenone, 2 parts of cinoxates and 1 part of ethylhexyl methoxy cinnamate, preparation process is by 5
Part benzophenone, 2 parts of cinoxates, 1 part of ethylhexyl methoxy cinnamate and 50 parts of dehydrated alcohol are sufficiently mixed, and are subsequently adding 3
Part titanium dioxide and 6 parts of zinc oxide carry out the dispersion stirring 1h that rotating speed is 100 revs/min, use ultrasonic degas, i.e. after stirring
Obtain UV absorbent.
Claims (5)
1. a preparation technology for UV resistant anion decorative panel, the first closing of round brush UV resistant on calcium silicates substrate
Paint, seal coat irradiates and spraying binder after aeration-drying through Burdick lamp, covers patterned transfer film on the adhesive, cover
Using Burdick lamp to irradiate after lid and carry out cold transfer, the pattern on film to be transferred is thrown off at the bottom of transfer film after being transferred on seal coat
Film, coating hood finish paint on calcium silicates substrate, finish uses Burdick lamp to irradiate and carries out overlay film and compacting after aeration-drying
The UV resistant anion decorative panel i.e. obtained, it is characterised in that: according to weight ratio, described finish preparation process is by 60-
80 parts of emulsions, 10-16 part coloring agent and 0.05-0.13 part preservative dispersed with stirring are uniform, add 1-4 part thickening agent and 2-6
Part anion liquid is stirred, and is eventually adding 0.08-0.7 part defoamer and carries out low speed dispersion stirring, use containing hydroxyl from
The alkaline solution adjustment pH value of son, to 8.5-10, stands 2h with the nylon net filter of 150 mesh, filtrate, obtains cover after standing 10min
Finish paint；
Described emulsion by acrylic emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethyl cellulose according to 40:10:4:
The ratio of 2:1 is sufficiently mixed prepared, wherein the solvent in sodium chloride solution be hardness be the soft water of 4, the mass fraction of solute is
3-5%；
According to weight ratio, described anion liquid is fast by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part of former times
Purine natural gum, 0.05 part of disodiumedetate, 0.3 part of dodecyl sodium sulfate composition, wherein tourmaline powder and medical stone powder
Fineness be 3000 mesh；
Described defoamer is organic silicon emulsion, and thickening agent is sodium carboxymethyl cellulose, and preservative is Methylisothiazolinone；
The seal coat of described UV resistant is to the addition of UV absorbent in commercially available seal coat, wherein according to volume ratio, and city
The adding proportion selling seal coat and UV absorbent is 30:1；Described UV absorbent include 50 parts of dehydrated alcohol, 3 part two
Titanium oxide, 6 parts of zinc oxide, 5 parts of benzophenone, 2 parts of cinoxates and 1 part of ethylhexyl methoxy cinnamate, preparation process is by 5
Part benzophenone, 2 parts of cinoxates, 1 part of ethylhexyl methoxy cinnamate and 50 parts of dehydrated alcohol are sufficiently mixed, and are subsequently adding 3
Part titanium dioxide and 6 parts of zinc oxide carry out the dispersion stirring 1h that rotating speed is 100 revs/min, use ultrasonic degas, i.e. after stirring
Obtain UV absorbent.
The preparation technology of a kind of UV resistant anion decorative panel the most as claimed in claim 1, it is characterised in that: according to weight
Ratio, described finish preparation process is by uniform to 70 parts of emulsions, 15 parts of coloring agent and 0.1 part of preservative dispersed with stirring, adds 3
Part thickening agent and 5 parts of anion liquid are stirred, and are eventually adding 0.5 part of defoamer and carry out low speed dispersion stirring, to be mixed uniformly
Afterwards with the nylon net filter of 150 mesh, stand 2h after filtration, obtain finish.
The preparation technology of a kind of UV resistant anion decorative panel the most as claimed in claim 1, it is characterised in that: described cover
Enter at 40 DEG C after 60-80 part emulsion, 10-16 part coloring agent and 0.05-0.13 part preservative are mixed by finish paint preparation process
Row rotating speed is the high-speed stirred of 1200 revs/min, stirs 30min.
The preparation technology of a kind of UV resistant anion decorative panel the most as claimed in claim 1, it is characterised in that: described bear from
The preparation process of sub-liquid is in room by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06 part of former times purine natural gum
Carrying out the stirring that rotating speed is 800 revs/min under temperature, mixing time is 10min, add 0.05 part of disodiumedetate and
0.3 part of dodecyl sodium sulfate stirs, and gained mixture carries out ultrasound wave aerofluxus, obtains anion liquid.
The preparation technology of a kind of UV resistant anion decorative panel the most as claimed in claim 1, it is characterised in that: described silicic acid
Calcio plate is through fixed thick sanding to 4cm, and round brush seal coat on sanding face, round brush thickness is 40 grams every square.
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| CN110652969A (en) * | 2019-09-29 | 2020-01-07 | 陕西科技大学 | Preparation method of polyion liquid modified dialdehyde starch film as adsorbing material |
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| US20150202131A1 (en) * | 2012-07-26 | 2015-07-23 | Riemann Trading Aps | High protection water-resistant sunscreen composition |
| CN103305070A (en) * | 2013-06-26 | 2013-09-18 | 关锦池 | Nano environment-friendly coating for interior wall |
| CN104073072A (en) * | 2014-06-30 | 2014-10-01 | 南通蛇类治疗研究所 | Nano functional ecological environmental-friendly coating |
| CN104893214A (en) * | 2015-05-11 | 2015-09-09 | 广德县新杭镇聚源新型材料压膜厂 | Closestool cover coating capable of purifying air |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110652969A (en) * | 2019-09-29 | 2020-01-07 | 陕西科技大学 | Preparation method of polyion liquid modified dialdehyde starch film as adsorbing material |
| CN110652969B (en) * | 2019-09-29 | 2022-03-11 | 陕西科技大学 | Preparation method of polyion liquid modified dialdehyde starch film as adsorbing material |
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