CN106046936A - Color ink composition safe to use - Google Patents
Color ink composition safe to use Download PDFInfo
- Publication number
- CN106046936A CN106046936A CN201610397616.6A CN201610397616A CN106046936A CN 106046936 A CN106046936 A CN 106046936A CN 201610397616 A CN201610397616 A CN 201610397616A CN 106046936 A CN106046936 A CN 106046936A
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- CN
- China
- Prior art keywords
- parts
- water
- color inks
- sodium
- triethanolamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/17—Writing inks characterised by colouring agents
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses color ink composition safe to use. The color ink composition is prepared from raw materials in parts by weight as follows: 2-5 parts of water-soluble pigment, 3-6 parts of triethanolamine, 3-7 parts of polyvinylpyrrolidone, 1-2 parts of sodium carbonate, 1-3 parts of oxalic acid crystals, 2-4 parts of sodium caseinate, 5-10 parts of beta-cyclodextrin, 1-3 parts of propylene glycol alginate, 3-5 parts of glycerin monostearate and 40-60 parts of deionized water. The raw materials are mixed under certain conditions, and the color ink composition is prepared. The obtained color ink composition has good water solubility, system stability and high safety, is very suitable for students, especially infants to use, is simple to process and has good popularization prospect, and the raw materials are easy to obtain.
Description
Technical field
The present invention relates to inks field, be specifically related to a kind of use safe color inks compositions.
Background technology
The color inks of the fine arts is often in contact with the article arrived in people's lives, as far back as the eighties, WHO
And Countries government proposes the safety criterion of paint ink of student, child drawing, the most in succession for organic volatile
It is made that clear stipulaties with content of beary metal.Student, child drawing paint ink often straight with the palm of painter, finger
Contact, from the perspective of hygiology, in the paint ink that those are riotous with colour, containing multiple harmful chemistry
Material, if do not noted protection, may cause the harm of potentiality, affect healthy human body, but student, especially baby children
Before youngster can't learn to hold and do fine movement completely, can be uncontrolled by a large amount of inks when using these color inks
Contamination, to finger, palm and face, is sucked to mouth from hand even indirectly, in view of existing colored ink safety is relatively low,
There is potential healthy and safe hidden danger, and not easy cleaning, often user is caused certain injury.
Summary of the invention
Not enough for prior art, the invention provides and a kind of use safe color inks compositions, be particularly suited for
Student, especially infant use.
The present invention solves the technical scheme that above-mentioned technical problem uses: a kind of use safe color inks compositions,
Raw material including following parts by weight: water colo(u)r 2～5 parts, triethanolamine 3～6 parts, polyvinylpyrrolidone 3～7 parts,
Sodium carbonate 1～2 parts, oxalic acid crystal 1～3 parts, sodium caseinate 2～4 parts, cycloheptaamylose 5～10 parts, propylene glycol alginate 1
～3 parts, glyceryl monostearate 3～5 parts and deionized water 40～60 parts；
Described a kind of preparation method using safe color inks compositions, comprises the following steps: by 10～15 parts
Deionized water is heated to 80～90 DEG C, adds glyceryl monostearate and naturally cools to room temperature after concussion is uniformly dispersed, as
Material A；Water colo(u)r is dissolved in the deionized water of surplus, adds sodium carbonate, oxalic acid crystal, triethanolamine and polyethylene pyrrole
Pyrrolidone, as material B after being sufficiently mixed uniformly；Material A and material B are mixed, adds the most slowly under stirring condition
Sodium caseinate, propylene glycol alginate and cycloheptaamylose, be the color inks compositions of the present invention after stirring.
Further, described water colo(u)r be lemon yellow, acid orange, D C Yellow No. 10, sunset yellow, amaranth, carmine,
Carminic acid, erythrosine, azorubine, temptation are red, blue No. 1 of food, edible blue No. 2, sodium copper chlorophllin, brilliant black, cyanine
The combination of one or more in element.
Further, described a kind of safe color inks compositions is used, including the raw material of following parts by weight: water-soluble
Property pigment 4 parts, triethanolamine 5 parts, polyvinylpyrrolidone 5 parts, sodium carbonate 1.5 parts, 2 parts of oxalic acid crystal, sodium caseinate 3
Part, cycloheptaamylose 7 parts, propylene glycol alginate 2 parts, glyceryl monostearate 4 parts and deionized water 50 parts.
Compared with prior art, a kind of color inks compositions of the present invention has the advantages that safety is good, this
The color inks of invention uses food grade materials to prepare completely, has tight security, is highly suitable for student especially baby children
Youngster uses；Water solublity is good, and the water color ink of the present invention has good water solublity, and system stability is good, places not over a long time
A large amount of precipitation can be produced, easy to use；It is readily cleaned, the ink in contamination to body skin is easily cleaned up with water, convenient
Health；Processing is simple, and the preparation method of the water color ink of the present invention is simple, and raw material is easy to get, and has good replicability.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1: a kind of use safe color inks compositions, including the raw material of following parts by weight: water solublity color
Element 4 parts, triethanolamine 5 parts, polyvinylpyrrolidone 5 parts, sodium carbonate 1.5 parts, 2 parts of oxalic acid crystal, sodium caseinate 3 parts, β-
Cyclodextrin 7 parts, propylene glycol alginate 2 parts, glyceryl monostearate 4 parts and deionized water 50 parts；
Described a kind of preparation method using safe color inks compositions, comprises the following steps: 13 parts are gone from
Sub-water is heated to 85 DEG C, adds glyceryl monostearate and naturally cools to room temperature, as material A after concussion is uniformly dispersed；Will
Water colo(u)r is dissolved in the deionized water of surplus, adds sodium carbonate, oxalic acid crystal, triethanolamine and polyvinylpyrrolidone,
As material B after being sufficiently mixed uniformly；Material A and material B are mixed, under stirring condition, adds caseinic acid the most slowly
Sodium, propylene glycol alginate and cycloheptaamylose, be the color inks compositions of the present invention after stirring.
Further, described water colo(u)r is lemon yellow and the mixture of blue No. 1 of food, and its mass parts ratio is 10:
1。
Embodiment 2: a kind of use safe color inks compositions, including the raw material of following parts by weight: water solublity color
Element 2 parts, triethanolamine 3 parts, polyvinylpyrrolidone 3 parts, sodium carbonate 1 part, 1 part of oxalic acid crystal, sodium caseinate 2 parts, β-ring
5 parts of shape dextrin, propylene glycol alginate 1 part, glyceryl monostearate 3 parts and deionized water 40 parts；
Described a kind of preparation method using safe color inks compositions, comprises the following steps: 10 parts are gone from
Sub-water is heated to 80 DEG C, adds glyceryl monostearate and naturally cools to room temperature, as material A after concussion is uniformly dispersed；Will
Water colo(u)r is dissolved in the deionized water of surplus, adds sodium carbonate, oxalic acid crystal, triethanolamine and polyvinylpyrrolidone,
As material B after being sufficiently mixed uniformly；Material A and material B are mixed, under stirring condition, adds caseinic acid the most slowly
Sodium, propylene glycol alginate and cycloheptaamylose, be the color inks compositions of the present invention after stirring.
Further, described water colo(u)r is amaranth.
Embodiment 3: a kind of use safe color inks compositions, including the raw material of following parts by weight: water solublity color
Element 5 parts, triethanolamine 6 parts, polyvinylpyrrolidone 7 parts, sodium carbonate 2 parts, 3 parts of oxalic acid crystal, sodium caseinate 4 parts, β-ring
10 parts of shape dextrin, propylene glycol alginate 3 parts, glyceryl monostearate 5 parts and deionized water 60 parts；
Described a kind of preparation method using safe color inks compositions, comprises the following steps: 15 parts are gone from
Sub-water is heated to 90 DEG C, adds glyceryl monostearate and naturally cools to room temperature, as material A after concussion is uniformly dispersed；Will
Water colo(u)r is dissolved in the deionized water of surplus, adds sodium carbonate, oxalic acid crystal, triethanolamine and polyvinylpyrrolidone,
As material B after being sufficiently mixed uniformly；Material A and material B are mixed, under stirring condition, adds caseinic acid the most slowly
Sodium, propylene glycol alginate and cycloheptaamylose, be the color inks compositions of the present invention after stirring.
Further, described water colo(u)r is acid orange, carminic acid and brilliant black, and its mass parts is than for 8:4:1.
Embodiment 4: a kind of use safe color inks compositions, including the raw material of following parts by weight: water solublity color
Element 2 parts, triethanolamine 6 parts, polyvinylpyrrolidone 3 parts, sodium carbonate 2 parts, 1 part of oxalic acid crystal, sodium caseinate 4 parts, β-ring
5 parts of shape dextrin, propylene glycol alginate 3 parts, glyceryl monostearate 3 parts and deionized water 60 parts；
Described a kind of preparation method using safe color inks compositions, comprises the following steps: 13 parts are gone from
Sub-water is heated to 85 DEG C, adds glyceryl monostearate and naturally cools to room temperature, as material A after concussion is uniformly dispersed；Will
Water colo(u)r is dissolved in the deionized water of surplus, adds sodium carbonate, oxalic acid crystal, triethanolamine and polyvinylpyrrolidone,
As material B after being sufficiently mixed uniformly；Material A and material B are mixed, under stirring condition, adds caseinic acid the most slowly
Sodium, propylene glycol alginate and cycloheptaamylose, be the color inks compositions of the present invention after stirring.
Further, described water colo(u)r is erythrosine.
Embodiment 5: a kind of use safe color inks compositions, including the raw material of following parts by weight: water solublity color
Element 4 parts, triethanolamine 4 parts, polyvinylpyrrolidone 6 parts, sodium carbonate 1 part, 2 parts of oxalic acid crystal, sodium caseinate 3 parts, β-ring
6 parts of shape dextrin, propylene glycol alginate 1 part, glyceryl monostearate 5 parts and deionized water 45 parts；
Described a kind of preparation method using safe color inks compositions, comprises the following steps: 14 parts are gone from
Sub-water is heated to 85 DEG C, adds glyceryl monostearate and naturally cools to room temperature, as material A after concussion is uniformly dispersed；Will
Water colo(u)r is dissolved in the deionized water of surplus, adds sodium carbonate, oxalic acid crystal, triethanolamine and polyvinylpyrrolidone,
As material B after being sufficiently mixed uniformly；Material A and material B are mixed, under stirring condition, adds caseinic acid the most slowly
Sodium, propylene glycol alginate and cycloheptaamylose, be the color inks compositions of the present invention after stirring.
Further, described water colo(u)r is edible blue No. 2.
By embodiment 1-5 gained water color ink employing QB/T2024-94 quality standard test method be averaged particle diameter and
Stability (placing mean diameter after 30d) performance test, and use GB/T4288-2008 quality standard test method to clean
Rate performance test, result is as shown in the table:
| Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Mean diameter/μm | ＜ 1 | ＜ 1 | ＜ 1 | ＜ 1 | ＜ 1 |
| Stability/μm | ＜ 1 | ＜ 1 | ＜ 1 | ＜ 1 | ＜ 1 |
| Clean rate/% | 91 | 92 | 88 | 93 | 90 |
The test result of upper table shows, the color inks of the present invention obtains good in the case of using food grade materials completely
Good system stability and storage stability, and the color inks of the present invention relatively easy cleaning, use conveniently, safely.
Claims (5)
1. one kind uses safe color inks compositions, it is characterised in that include the raw material of following parts by weight: water solublity color
Element 2～5 parts, triethanolamine 3～6 parts, polyvinylpyrrolidone 3～7 parts, sodium carbonate 1～2 parts, oxalic acid crystal 1～3 parts, cheese egg
White acid sodium 2～4 parts, cycloheptaamylose 5～10 parts, propylene glycol alginate 1～3 parts, glyceryl monostearate 3～5 parts and go from
Sub-water 40～60 parts；
Described a kind of preparation method using safe color inks compositions, comprises the following steps: 10～15 parts are gone from
Sub-water is heated to 80～90 DEG C, adds glyceryl monostearate and naturally cools to room temperature, as material after concussion is uniformly dispersed
A；Water colo(u)r is dissolved in the deionized water of surplus, adds sodium carbonate, oxalic acid crystal, triethanolamine and polyvinylpyrrolidine
Ketone, as material B after being sufficiently mixed uniformly；Material A and material B are mixed, descends addition cheese egg the most slowly in stirring condition
White acid sodium, propylene glycol alginate and cycloheptaamylose, be the color inks compositions of the present invention after stirring.
The most according to claim 1 a kind of use safe color inks compositions, it is characterised in that described raw material and
Its mass fraction is: water colo(u)r 4 parts, triethanolamine 5 parts, polyvinylpyrrolidone 5 parts, sodium carbonate 1.5 parts, oxalic acid crystal
2 parts, sodium caseinate 3 parts, cycloheptaamylose 7 parts, propylene glycol alginate 2 parts, glyceryl monostearate 4 parts and deionized water 50
Part.
The most according to claim 1 a kind of use safe color inks compositions, it is characterised in that described raw material and
Its mass fraction is: water colo(u)r 2 parts, triethanolamine 3 parts, polyvinylpyrrolidone 3 parts, sodium carbonate 1 part, oxalic acid crystal 1
Part, sodium caseinate 2 parts, cycloheptaamylose 5 parts, propylene glycol alginate 1 part, glyceryl monostearate 3 parts and deionized water 40
Part.
The most according to claim 1 a kind of use safe color inks compositions, it is characterised in that described raw material and
Its mass fraction is: water colo(u)r 5 parts, triethanolamine 6 parts, polyvinylpyrrolidone 7 parts, sodium carbonate 2 parts, oxalic acid crystal 3
Part, sodium caseinate 4 parts, cycloheptaamylose 10 parts, propylene glycol alginate 3 parts, glyceryl monostearate 5 parts and deionized water 60
Part.
5. use safe color inks compositions according to a kind of described in any one of claim 1-4, it is characterised in that: described
Water colo(u)r be lemon yellow, acid orange, D C Yellow No. 10, sunset yellow, amaranth, carmine, carminic acid, erythrosine, azo
Rubine, lure red, blue No. 1 of food, edible blue No. 2, sodium copper chlorophllin, brilliant black, the knot of one or more in anthocyanidin
Close.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610397616.6A CN106046936A (en) | 2016-06-07 | 2016-06-07 | Color ink composition safe to use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610397616.6A CN106046936A (en) | 2016-06-07 | 2016-06-07 | Color ink composition safe to use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106046936A true CN106046936A (en) | 2016-10-26 |
Family
ID=57169589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610397616.6A Pending CN106046936A (en) | 2016-06-07 | 2016-06-07 | Color ink composition safe to use |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106046936A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102108224A (en) * | 2010-12-30 | 2011-06-29 | 周震 | Washable water-soluble ink for marker pens for painting on surfaces of plastic toys |
-
2016
- 2016-06-07 CN CN201610397616.6A patent/CN106046936A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102108224A (en) * | 2010-12-30 | 2011-06-29 | 周震 | Washable water-soluble ink for marker pens for painting on surfaces of plastic toys |
Non-Patent Citations (3)
| Title |
|---|
| 凌云星等: "《油墨技术手册 上》", 31 May 2009, 印刷工业出版 * |
| 刘青: "《天天饮食小窍门》", 31 January 2008, 中国妇女出版社 * |
| 安广杰: "《保卫健康》", 31 May 2012, 河南大学出版社 * |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161026 |
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| RJ01 | Rejection of invention patent application after publication |