CN106042560A - Flax waterproof anti-corrosion fabric - Google Patents

Flax waterproof anti-corrosion fabric Download PDF

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Publication number
CN106042560A
CN106042560A CN201610335124.4A CN201610335124A CN106042560A CN 106042560 A CN106042560 A CN 106042560A CN 201610335124 A CN201610335124 A CN 201610335124A CN 106042560 A CN106042560 A CN 106042560A
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Prior art keywords
layer
fabric
corrosion
waterproof
fiber
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Granted
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CN201610335124.4A
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Chinese (zh)
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CN106042560B (en
Inventor
相里海霞
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Changshu Changhong Textile Co ltd
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Individual
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • B32B2262/065Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/106Carbon fibres, e.g. graphite fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21Anti-static
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/73Hydrophobic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/752Corrosion inhibitor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00Clothing

Landscapes

  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides a flax waterproof anti-corrosion fabric which comprises a waterproof layer, a flax layer, an anti-corrosion layer and a contact layer, wherein the waterproof layer is composed of PVC, hot melt adhesive and elastic fiber, and the flax layer is composed of pure flax woven fabric; the corrosion-resistant layer is composed of waterborne polyurethane flame-retardant coating and flame-retardant polyurethane, the contact layer is composed of bamboo charcoal fiber, mint fiber and viscose fiber, and compared with the prior art, the corrosion-resistant layer has the following beneficial effects: the defects of poor washability, weak antistatic ability, uncomfortable wearing, water resistance and the like of the traditional fabric are overcome, so that the wider development space of the fabric is expanded, and the functionality has good environmental protection characteristic, production and operation safety, no toxicity, no side effect and good function durability of the final product.

Description

One grows flax waterproof anticorrosion fabric
Technical field
The present invention is one to grow flax waterproof anticorrosion fabric, a kind of resistance possessing corrosion-resistant function waterproof, anti-scratch Combustion composite material.
Background technology
The flame-retarding characteristic that inflaming retarding fabric possesses due to it, it is possible to the generation of fire is even avoided in effectively minimizing, thus receives Popular likes, increasing enterprise is devoted to the research and development of inflaming retarding fabric.Inflaming retarding fabric in the market mostly is compound This utility model disclosed in fabric, such as Patent No. 2012205980394 relates to a kind of fabric, particularly relates to a kind of fire-retardant Composite material, belongs to field of textiles, including nonwoven layer and fire-retardant glue-line, described fire-retardant composite material by two-layer nonwoven layer and One layer of fire-retardant glue-line is composited, and described fire-retardant glue-line is between two-layer nonwoven layer, containing heat-resisting glass in described fire-retardant glue-line Glass fiber, described nonwoven layer is terylene layer.The fire-retardant composite material of one involved by this utility model, it provides the benefit that: The nonwoven layer of this kind of fabric, has the most combustion-supporting, resistance to elevated temperatures;Fire-retardant glue-line and the thermally resistant fiber glass of inside thereof, more have Imitate improves fabric fire resistance, additionally, this inflaming retarding fabric intensity is high, free from extraneous odour, safety is good.But due to non-woven fabrics certainly Body properties of materials, its resistance to corrosion and anti-scratch ability are poor, the most easy to wear, so come for user Saying, fabric is easy to wear can bring no small economic loss, therefore, works out a kind of good flame retardation effect and can be effectively increased cloth Expect wear-resisting, corrosion-resistant can fire-retardant composite material be one of problem that solution is presently required.
Summary of the invention
The deficiency existed for prior art, it is an object of the present invention to provide one and grows flax waterproof anticorrosion fabric, to solve The problem proposed in above-mentioned background technology, the present invention designs ingenious, improves the market competitiveness, has reached simple in construction and design Reasonably purpose
To achieve these goals, the present invention is to realize by the following technical solutions: one grows flax waterproof anticorrosion fabric, Including waterproof layer, burlap layer, anti-corrosion layer and contact layer, waterproof layer is made up of PVC, PUR and elastic fiber, wherein The mass ratio of PVC is 20-30%, and the mass ratio of PUR is 10-20%, and the mass ratio of elastic fiber is 50-60%;Burlap layer by Pure hemp weaving is constituted;Anti-corrosion layer is made up of aqueous polyurethane anti-flaming dope and fire-retardant polyurethane, and wherein aqueous polyurethane is fire-retardant The mass ratio of coating is 30-40%, and the mass ratio of fire-retardant polyurethane is 60-70%;Contact layer is by bamboo carbon fiber, mint fibers and sticks Glue fiber is constituted, and wherein the mass ratio of bamboo carbon fiber is 50-65%, and the mass ratio of mint fibers is 25-40%, the matter of viscose fiber Amount ratio is 7-13%.
Further, waterproof layer covers the outer surface at burlap layer, and burlap layer covers the outer surface at anti-corrosion layer, corrosion resistant Erosion layer covers the outer surface at contact layer.
Further, waterproof layer covers the outer surface at anti-corrosion layer, and anti-corrosion layer covers the outer surface at burlap layer, fiber crops Layer of cloth covers the outer surface at contact layer.
A kind of technique making Caulis et Folium Lini waterproof anticorrosion fabric, comprises the following steps:
A) make waterproof layer, PVC powder is dissolved in oil-based solvent, obtains PVC solution;Under conditions of temperature is 50 ° PVC solution is stirred;By the PVC solution left standstill deaeration after stirring, pour PUR and elastic fiber into, import spray webbing and set Standby, then, by solution slow cooling in 60 DEG C of warm water of mixing, after taking-up, at a temperature of 120 DEG C-130 DEG C, it is dried place Reason, strikes off with scraper plate, and then using longitude and latitude woven fabric, longitude and latitude number of share of stock ratio is 2: 1, forms fabric.
B) prepare burlap layer, pure hemp weaving is woven into the size of needs;
C) prepare anti-corrosion layer, aqueous polyurethane anti-flaming dope is sufficiently stirred for, rise viscous, when viscosity reaches the feelings of room temperature 50 DEG C When viscosity number is 500-600pa.s under condition, adds fire-retardant polyurethane, stir simultaneously, stop when viscosity number reaches 200pa.s Only stirring, after mixed solution is cooled to room temperature, strikes off with scraper plate, dries it under 120-150 DEG C of temperature conditions;
D) prepare contact layer, select viscose fiber as warp, make parallel with mint fibers and bamboo carbon fiber, use 14 to combine Frame one, along wearing, uses 14*14 alternative construction intertexture rule, floats long alternate by longitude and latitude, forms fabric, dry In the environment of temperature is 200 DEG C, dry 2 min.
E) connect, waterproof layer, burlap layer, anti-corrosion layer and contact layer sizing are bonded together.
Beneficial effects of the present invention: the one of the present invention grows flax waterproof anticorrosion fabric, overcomes that tradition fabric washability is poor, resists The drawbacks such as electrostatic capacity is weak, dress is not easypro, non-watertight, thus expanded the development space that fabric is broader, and functional tool There is good environmental protection characteristic, production operation safety and final products are nontoxic, have no side effect and good function persistency.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with Detailed description of the invention, is expanded on further the present invention.
The present invention provides a kind of technical scheme: one grows flax waterproof anticorrosion fabric, including waterproof layer, burlap layer, corrosion resistant Erosion layer and contact layer, waterproof layer is made up of PVC, PUR and elastic fiber, and wherein the mass ratio of PVC is 20-30%, heat The mass ratio of melten gel is 10-20%, and the mass ratio of elastic fiber is 50-60%.
Burlap layer is made up of pure hemp weaving;Anti-corrosion layer is made up of aqueous polyurethane anti-flaming dope and fire-retardant polyurethane, its The mass ratio of middle aqueous polyurethane anti-flaming dope is 30-40%, and the mass ratio of fire-retardant polyurethane is 60-70%.
Contact layer is made up of bamboo carbon fiber, mint fibers and viscose fiber, and wherein the mass ratio of bamboo carbon fiber is 50-65%, The mass ratio of mint fibers is 25-40%, and the mass ratio of viscose fiber is 7-13%.
As one embodiment of the present of invention: the present invention provides a kind of technique making Caulis et Folium Lini waterproof anticorrosion fabric, bag Include following steps:
A) make waterproof layer, PVC powder is dissolved in oil-based solvent, obtains PVC solution;Under conditions of temperature is 50 ° PVC solution is stirred;By the PVC solution left standstill deaeration after stirring, pour PUR and elastic fiber into, import spray webbing and set Standby, then, by solution slow cooling in 60 DEG C of warm water of mixing, after taking-up, at a temperature of 120 DEG C-130 DEG C, it is dried place Reason, strikes off with scraper plate, and then using longitude and latitude woven fabric, longitude and latitude number of share of stock ratio is 2: 1, forms fabric.
B) prepare burlap layer, pure hemp weaving is woven into the size of needs;
C) prepare anti-corrosion layer, aqueous polyurethane anti-flaming dope is sufficiently stirred for, rise viscous, when viscosity reaches the feelings of room temperature 50 DEG C When viscosity number is 500-600pa.s under condition, adds fire-retardant polyurethane, stir simultaneously, stop when viscosity number reaches 200pa.s Only stirring, after mixed solution is cooled to room temperature, strikes off with scraper plate, dries it under 120-150 DEG C of temperature conditions;
D) prepare contact layer, select viscose fiber as warp, make parallel with mint fibers and bamboo carbon fiber, use 14 to combine Frame one, along wearing, uses 14*14 alternative construction intertexture rule, floats long alternate by longitude and latitude, forms fabric, dry In the environment of temperature is 200 DEG C, dry 2 min.
E) connect, waterproof layer, burlap layer, anti-corrosion layer and contact layer sizing are bonded together, wherein waterproof layer Covering the outer surface at burlap layer, burlap layer covers the outer surface at anti-corrosion layer, and anti-corrosion layer covers the appearance at contact layer Face.
As an alternative embodiment of the invention: the present invention provides a kind of technique making Caulis et Folium Lini waterproof anticorrosion fabric, Comprise the following steps:
A) make waterproof layer, PVC powder is dissolved in oil-based solvent, obtains PVC solution;Under conditions of temperature is 50 ° PVC solution is stirred;By the PVC solution left standstill deaeration after stirring, pour PUR and elastic fiber into, import spray webbing and set Standby, then, by solution slow cooling in 60 DEG C of warm water of mixing, after taking-up, at a temperature of 120 DEG C-130 DEG C, it is dried place Reason, strikes off with scraper plate, and then using longitude and latitude woven fabric, longitude and latitude number of share of stock ratio is 2: 1, forms fabric.
B) prepare burlap layer, pure hemp weaving is woven into the size of needs;
C) prepare anti-corrosion layer, aqueous polyurethane anti-flaming dope is sufficiently stirred for, rise viscous, when viscosity reaches the feelings of room temperature 50 DEG C When viscosity number is 500-600pa.s under condition, adds fire-retardant polyurethane, stir simultaneously, stop when viscosity number reaches 200pa.s Only stirring, after mixed solution is cooled to room temperature, strikes off with scraper plate, dries it under 120-150 DEG C of temperature conditions;
D) prepare contact layer, select viscose fiber as warp, make parallel with mint fibers and bamboo carbon fiber, use 14 to combine Frame one, along wearing, uses 14*14 alternative construction intertexture rule, floats long alternate by longitude and latitude, forms fabric, dry In the environment of temperature is 200 DEG C, dry 2 min.
E) connect, waterproof layer, burlap layer, anti-corrosion layer and contact layer sizing are bonded together, wherein waterproof layer Covering the outer surface at anti-corrosion layer, anti-corrosion layer covers the outer surface at burlap layer, and burlap layer covers the appearance at contact layer Face.
The ultimate principle of the present invention and principal character and advantages of the present invention are more than shown and described, for this area skill For art personnel, it is clear that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and without departing substantially from the present invention spirit or In the case of basic feature, it is possible to realize the present invention in other specific forms.Therefore, no matter from the point of view of which point, all should be by Embodiment regards exemplary as, and is nonrestrictive, the scope of the present invention by claims rather than on state Bright restriction, it is intended that include all changes fallen in the implication of equivalency and scope of claim in the present invention In.
Although moreover, it will be appreciated that this specification is been described by according to embodiment, but the most each embodiment only wraps Containing an independent technical scheme, this narrating mode of description is only that for clarity sake those skilled in the art should Description can also be formed those skilled in the art through appropriately combined as an entirety, the technical scheme in each embodiment May be appreciated other embodiments.

Claims (4)

1. one grow flax waterproof anticorrosion fabric, including waterproof layer, burlap layer, anti-corrosion layer and contact layer, it is characterised in that: Described waterproof layer is made up of PVC, PUR and elastic fiber, and wherein the mass ratio of PVC is 20-30%, the mass ratio of PUR For 10-20%, the mass ratio of elastic fiber is 50-60%;
Described burlap layer is made up of pure hemp weaving;
Described anti-corrosion layer is made up of aqueous polyurethane anti-flaming dope and fire-retardant polyurethane, wherein aqueous polyurethane anti-flaming dope Mass ratio is 30-40%, and the mass ratio of fire-retardant polyurethane is 60-70%;
Described contact layer is made up of bamboo carbon fiber, mint fibers and viscose fiber, and wherein the mass ratio of bamboo carbon fiber is 50-65%, The mass ratio of mint fibers is 25-40%, and the mass ratio of viscose fiber is 7-13%.
The most according to claim 1 one grows flax waterproof anticorrosion fabric, it is characterised in that: described waterproof layer covers fiber crops The outer surface of layer of cloth, described burlap layer covers the outer surface at anti-corrosion layer, and described anti-corrosion layer covers the appearance at contact layer Face.
The most according to claim 1 one grows flax waterproof anticorrosion fabric, it is characterised in that: described waterproof layer covers resistance to The outer surface of corrosion layer, described anti-corrosion layer covers the outer surface at burlap layer, and described burlap layer covers the appearance at contact layer Face.
4. one kind makes described in claim 1 technique growing flax waterproof anticorrosion fabric, it is characterised in that: include with Lower step:
A) make waterproof layer, PVC powder is dissolved in oil-based solvent, obtains PVC solution;Under conditions of temperature is 50 ° Described PVC solution is stirred;By the PVC solution left standstill deaeration after stirring, pour PUR and elastic fiber into, import spray Silk equipment, then, by solution slow cooling in 60 DEG C of warm water of mixing, is dried after taking-up at a temperature of 120 DEG C-130 DEG C Processing, strike off with scraper plate, then using longitude and latitude woven fabric, longitude and latitude number of share of stock ratio is 2: 1, forms fabric;
B) prepare burlap layer, pure hemp weaving is woven into the size of needs;
C) prepare anti-corrosion layer, aqueous polyurethane anti-flaming dope is sufficiently stirred for, rise viscous, when viscosity reaches the feelings of room temperature 50 DEG C When viscosity number is 500-600pa.s under condition, adds fire-retardant polyurethane, stir simultaneously, stop when viscosity number reaches 200pa.s Only stirring, after mixed solution is cooled to room temperature, strikes off with scraper plate, dries it under 120-150 DEG C of temperature conditions;
D) prepare contact layer, select viscose fiber as warp, make parallel with mint fibers and bamboo carbon fiber, use 14 to combine Frame one, along wearing, uses 14*14 alternative construction intertexture rule, floats long alternate by longitude and latitude, forms fabric, dry In the environment of temperature is 200 DEG C, dry 2 min;
E) connect, waterproof layer, burlap layer, anti-corrosion layer and contact layer sizing are bonded together.
CN201610335124.4A 2016-05-19 2016-05-19 Flax waterproof anti-corrosion fabric Active CN106042560B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610335124.4A CN106042560B (en) 2016-05-19 2016-05-19 Flax waterproof anti-corrosion fabric

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113978073A (en) * 2021-09-28 2022-01-28 读布科技(杭州)有限公司 Processing technology of PVC fabric for clothing

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102987621A (en) * 2012-11-26 2013-03-27 吴江市满江红纺织有限公司 Fireproof and waterproof fabric
CN103496201A (en) * 2013-10-22 2014-01-08 哈建薇 Corrosion-resistance, waterproof and fireproof cloth
CN103496219A (en) * 2013-10-21 2014-01-08 田艳 Corrosion-resistance and waterproof cloth
CN103556467A (en) * 2013-11-05 2014-02-05 北京麻世纪流行面料研发有限公司 Linen shell fabric and production method
CN105483905A (en) * 2015-12-01 2016-04-13 惠安华晨贸易有限公司 Process for manufacturing waterproof, flame-retardant and breathable fabric
CN105584177A (en) * 2014-11-06 2016-05-18 刘正华 Flame-retarding anti-stain breathable fabric

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102987621A (en) * 2012-11-26 2013-03-27 吴江市满江红纺织有限公司 Fireproof and waterproof fabric
CN103496219A (en) * 2013-10-21 2014-01-08 田艳 Corrosion-resistance and waterproof cloth
CN103496201A (en) * 2013-10-22 2014-01-08 哈建薇 Corrosion-resistance, waterproof and fireproof cloth
CN103556467A (en) * 2013-11-05 2014-02-05 北京麻世纪流行面料研发有限公司 Linen shell fabric and production method
CN105584177A (en) * 2014-11-06 2016-05-18 刘正华 Flame-retarding anti-stain breathable fabric
CN105483905A (en) * 2015-12-01 2016-04-13 惠安华晨贸易有限公司 Process for manufacturing waterproof, flame-retardant and breathable fabric

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113978073A (en) * 2021-09-28 2022-01-28 读布科技(杭州)有限公司 Processing technology of PVC fabric for clothing
CN113978073B (en) * 2021-09-28 2023-09-12 读布科技(杭州)有限公司 PVC fabric processing technology for clothing

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Effective date of registration: 20190131

Address after: 314409 No. 6 Nanyuan Road, Xucun Town, Haining City, Jiaxing City, Zhejiang Province

Patentee after: Haining Carter household goods Co., Ltd.

Address before: 528402 four phase 6-603 of Qishan garden, Shiqi District, Zhongshan, Guangdong

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Effective date of registration: 20200611

Address after: Meili Zhen Tang Qiao Cun, Changshu City, Suzhou City, 215500 Jiangsu Province

Patentee after: CHANGSHU CHANGHONG TEXTILE Co.,Ltd.

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Patentee before: HAINING CARTER HOUSEHOLD ITEMS Co.,Ltd.

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