CN106018670A - Field in-situ monitoring method of ammonia volatilization from farmland soils - Google Patents

Field in-situ monitoring method of ammonia volatilization from farmland soils Download PDF

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Publication number
CN106018670A
CN106018670A CN201610505603.6A CN201610505603A CN106018670A CN 106018670 A CN106018670 A CN 106018670A CN 201610505603 A CN201610505603 A CN 201610505603A CN 106018670 A CN106018670 A CN 106018670A
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China
Prior art keywords
ammonia
boric acid
volatilization
field
ammonia volatilization
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CN201610505603.6A
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Inventor
杨虎德
马彦
李崇霄
冯丹妮
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Gansu Agricultural Ecological Environment Protection Management Station
INSTITUTE OF SOIL FERTILIZER AND WATER-SAVING AGRICULTURE GANSU ACADEMY OF AGRICULTURAL SCIENCES
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Gansu Agricultural Ecological Environment Protection Management Station
INSTITUTE OF SOIL FERTILIZER AND WATER-SAVING AGRICULTURE GANSU ACADEMY OF AGRICULTURAL SCIENCES
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Priority to CN201610505603.6A priority Critical patent/CN106018670A/en
Publication of CN106018670A publication Critical patent/CN106018670A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/16Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using titration
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/24Suction devices
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
    • G01N33/0054Ammonia

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Pathology (AREA)
  • Immunology (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Molecular Biology (AREA)
  • Combustion & Propulsion (AREA)
  • Medicinal Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Biomedical Technology (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a field in-situ monitoring method of ammonia volatilization from farmland soils. The method comprises the steps: adopting an intermittent airtight extraction method, enabling ammonia volatilized out of the soil in a cover to flow through a gas washing bottle with 2% boric acid by extracting a gas under reduced pressure by using a vacuum pump, enabling the ammonia to be absorbed in a boric acid solution, and then tiltrating the ammonia absorbed in the boric acid with standard boric acid. The method provided by the invention has the beneficial effects that the ammonia volatilization loss and influencing factors thereof under the conventional farmland fertilization conditions are effectively monitored by determining the loss of a nitrogen fertilizer applied to the farmland, and a basis is provided for understanding the ammonia volatilization loss characteristics, reducing N loss, and improving the utilization rate of the N fertilizer.

Description

The method of field in-situ monitoring agricultural land soil ammonia volatilization
Technical field
The method that the present invention relates to field in-situ monitoring agricultural land soil ammonia volatilization.
Background technology
Ammonia volatilization is one of important channel of fertilizer nitrogen loss, and loss rate exists the biggest difference because soil types, weather conditions, fertilizer amount, fertilization time and mode, cultivation mode etc. are different.In prior art, do not has the monitoring method of the system to soil ammonia volatilization.
Summary of the invention
The purpose of the present invention is aiming at above-mentioned defect of the prior art, it is provided that the method for field in-situ monitoring agricultural land soil ammonia volatilization.
To achieve these goals, the technical scheme that the present invention provides is: the method for field in-situ monitoring agricultural land soil ammonia volatilization, it is to use the airtight degassing method of interval, utilize vacuum pump pressure bleed the ammonia making soil in cover volatilize with air-flow by the Drexel bottle equipped with 2% boric acid, make ammonia be absorbed in boric acid solution, then with standard sulphuric acid titration boric acid absorbed in ammonia.
Further, the method for above-mentioned field in-situ monitoring agricultural land soil ammonia volatilization, the field of employing ammonia volatilization confined chamber air exchange subtraction unit in situ includes air exchange room, vent rod, vacuum suction control equipment, ammonia absorbent, ammonia mensuration agent;Wherein, air exchange room is that bottom is open, top is provided with the Plexiglas cylinder of two outlets, two outlets are respectively air inlet and gas outlet, air inlet is connected with the hollow plastic vent rod that height is 2.5m by corrugated tubing, gas outlet is connected with ammonia absorption plant, the ammonia produced in switch room is absorbed in absorbing liquid by the negative pressure that vacuum pump provides, in keeping switch room by control valve, air exchange frequency is 10-15 beat/min, after end of bleeding, with standard dilute sulfuric acid titrimetry, absorbing liquid is calculated ammonia volatilization amount.
Further, the method of above-mentioned field in-situ monitoring agricultural land soil ammonia volatilization, described absorbing liquid is 2% boric acid solution containing indicator, and described indicator is C.I. 13020 .-bromocresol green mixed indicator, being by C.I. 13020. 1 gram, bromocresol green 5 grams mixing adds 1000ml In the ethanol of 95%.
The method that the invention have the benefit that the field in-situ monitoring agricultural land soil ammonia volatilization that the present invention provides, the loss of nitrogenous fertilizer is applied by measuring farmland, effectively monitor ammonia loss by volatilization and influence factor thereof under the conditions of the conventional fertilizer application of farmland, for understanding ammonia loss by volatilization feature, reducing the loss of N element, improving N fertilizer utilization rate provides foundation.
The ammonia volatilization Field trapping method that the present invention provides uses the airtight degassing method principle of interval.It is to utilize vacuum pump pressure to bleed the ammonia (NH making soil in cover volatilize3) with air-flow by equipped with the Drexel bottle of 2% boric acid so that it is be absorbed in boric acid solution, then titrate the ammonia absorbed in boric acid with standard sulphuric acid.Ammonia volatilization confined chamber air exchange subtraction unit is as shown in Figure 1.
Accompanying drawing explanation
Fig. 1 is ammonia volatilization confined chamber air exchange subtraction unit schematic diagram.
Fig. 2 is that embodiment 1 monitors community process schematic diagram.
Detailed description of the invention
Embodiment 1:
The method of field in-situ monitoring agricultural land soil ammonia volatilization, it is to use the airtight degassing method of interval, utilize vacuum pump pressure bleed the ammonia making soil in cover volatilize with air-flow by the Drexel bottle equipped with 2% boric acid, make ammonia be absorbed in boric acid solution, then with the ammonia absorbed in standard sulphuric acid titration boric acid;The field used ammonia volatilization confined chamber air exchange subtraction unit in situ includes air exchange room, vent rod, vacuum suction control equipment, ammonia absorbent, ammonia mensuration agent;Wherein, air exchange room is that bottom is open, top is provided with the Plexiglas cylinder of two outlets, two outlets are respectively air inlet and gas outlet, air inlet is connected with the hollow plastic vent rod that height is 2.5m by corrugated tubing, gas outlet is connected with ammonia absorption plant, the ammonia produced in switch room is absorbed in absorbing liquid by the negative pressure that vacuum pump provides, in keeping switch room by control valve, air exchange frequency is 10-15 beat/min, after end of bleeding, with standard dilute sulfuric acid titrimetry, absorbing liquid is calculated ammonia volatilization amount;Absorbing liquid is 2% boric acid solution containing indicator, and indicator is C.I. 13020 .-bromocresol green mixed indicator, is by C.I. 13020. 1 gram, and bromocresol green 5 grams mixing adds 1000ml In the ethanol of 95%.
Experimental cultivar is Chinese cabbage.Sowing date is July 1.Being orchidization carbamide for examination nitrogenous fertilizer, usage amount is 20 kilograms.If 3 process, point 3 communities.3 process are respectively mulch film ridge culture, the flat work of full film, the flat work of half film.Plot area is 20m2.Ridge culture ridge is 10cm, and row spacing is 60cm.Putting down and make full film, the width of film is 80cm.Flat work half film, the width of film is 60cm.Wherein spacing in the rows is 35cm, and line-spacing is 50cm.Concrete form is as shown in Figure 2.
Measurement result:
1, the ammonia volatilization speed inside and outside ammonia absorption plant air chamber: the solution ammonia volatilization speed under ammonia volatilization collection device is significantly lower than the ammonia volatilization speed under outdoor mild wind state.
2, Different Fertilization ammonia volatilization in period rate change: more different fertilizing time ammonia loss by volatilization amounts and account for the ratio of dose and show, Different Fertilization ammonia volatilization in period speed is different.High temperature strengthens the speed of volatilization, pours water and inhibits soil table to heat, it is possible to decrease ammonia volatilization.
3, the dose impact on ammonia volatilization: test shows, increases with the increase of dose each fertilizer application period ammonia volatilization amount but ammonia volatilization N accounts for and applies N ratio in different trend.
Last it is noted that the foregoing is only the preferred embodiments of the present invention, it is not limited to the present invention, although the present invention being described in detail with reference to previous embodiment, for a person skilled in the art, technical scheme described in foregoing embodiments still can be modified by it, or wherein portion of techniques feature is carried out equivalent.All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (3)

1. the method for field in-situ monitoring agricultural land soil ammonia volatilization, it is characterized in that, it is to use the airtight degassing method of interval, utilize vacuum pump pressure bleed the ammonia making soil in cover volatilize with air-flow by the Drexel bottle equipped with 2% boric acid, make ammonia be absorbed in boric acid solution, then with standard sulphuric acid titration boric acid absorbed in ammonia.
The method of field the most according to claim 1 in-situ monitoring agricultural land soil ammonia volatilization, it is characterized in that, the field of employing ammonia volatilization confined chamber air exchange subtraction unit in situ includes air exchange room, vent rod, vacuum suction control equipment, ammonia absorbent, ammonia mensuration agent;Wherein, air exchange room is that bottom is open, top is provided with the Plexiglas cylinder of two outlets, two outlets are respectively air inlet and gas outlet, air inlet is connected with the hollow plastic vent rod that height is 2.5m by corrugated tubing, gas outlet is connected with ammonia absorption plant, the ammonia produced in switch room is absorbed in absorbing liquid by the negative pressure that vacuum pump provides, in keeping switch room by control valve, air exchange frequency is 10-15 beat/min, after end of bleeding, with standard dilute sulfuric acid titrimetry, absorbing liquid is calculated ammonia volatilization amount.
The method of field the most according to claim 2 in-situ monitoring agricultural land soil ammonia volatilization, it is characterized in that, described absorbing liquid is 2% boric acid solution containing indicator, described indicator is C.I. 13020 .-bromocresol green mixed indicator, being by C.I. 13020. 1 gram, bromocresol green 5 grams mixing adds in the ethanol of 1000ml 95%.
CN201610505603.6A 2016-07-01 2016-07-01 Field in-situ monitoring method of ammonia volatilization from farmland soils Pending CN106018670A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108008065A (en) * 2017-11-02 2018-05-08 潍坊中创生物科技有限公司 Ammonia gas detection device and ammonia gas detection method
CN108226378A (en) * 2018-01-30 2018-06-29 甘肃农业大学 A kind of device of Laboratory Observation ammonium fertilizer volatile quantity
CN108709782A (en) * 2018-07-12 2018-10-26 中国农业科学院农业环境与可持续发展研究所 A kind of the soil ammonia volatilization capture device and computational methods of ridge tillage method planting site
CN111272502A (en) * 2020-04-02 2020-06-12 沈阳农业大学 Collection device for exerting ammonia in field community and use method
CN111579318A (en) * 2020-06-09 2020-08-25 苏州方元智能环保科技有限公司 Sampling device and sampling method applied to determination of ammonium nitrogen isotope
CN114631412A (en) * 2022-03-17 2022-06-17 江苏省农业科学院泰州农科所 Organic fertilizer for reducing ammonia volatilization intensity of wheat field and distribution experiment method

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CN104407109A (en) * 2014-12-12 2015-03-11 河南农业大学 Soil ammonia volatilization in-situ monitoring device and detection method
CN204495627U (en) * 2015-04-17 2015-07-22 长江水利委员会长江科学院 Agricultural land soil ammonia volatilization in-situ monitoring device
CN205067468U (en) * 2015-10-28 2016-03-02 中国农业科学院农业资源与农业区划研究所 Test device of former position -finding soil ammonia volatilization
CN105424871A (en) * 2015-12-10 2016-03-23 苏州国环环境检测有限公司 Determination method for ammonia nitrogen in wastewater
CN205262971U (en) * 2015-11-30 2016-05-25 中国水稻研究所 Former position -finding device of paddy field ammonia volatilization

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108008065A (en) * 2017-11-02 2018-05-08 潍坊中创生物科技有限公司 Ammonia gas detection device and ammonia gas detection method
CN108226378A (en) * 2018-01-30 2018-06-29 甘肃农业大学 A kind of device of Laboratory Observation ammonium fertilizer volatile quantity
CN108709782A (en) * 2018-07-12 2018-10-26 中国农业科学院农业环境与可持续发展研究所 A kind of the soil ammonia volatilization capture device and computational methods of ridge tillage method planting site
CN111272502A (en) * 2020-04-02 2020-06-12 沈阳农业大学 Collection device for exerting ammonia in field community and use method
CN111579318A (en) * 2020-06-09 2020-08-25 苏州方元智能环保科技有限公司 Sampling device and sampling method applied to determination of ammonium nitrogen isotope
CN111579318B (en) * 2020-06-09 2022-12-23 苏州方元智能环保科技有限公司 Sampling device and sampling method applied to determination of ammonium nitrogen isotope
CN114631412A (en) * 2022-03-17 2022-06-17 江苏省农业科学院泰州农科所 Organic fertilizer for reducing ammonia volatilization intensity of wheat field and distribution experiment method

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Application publication date: 20161012