CN106010444A - Special composite snow-melting deicing agent prepared from marble slag for high-voltage cables and wires and preparation method thereof - Google Patents
Special composite snow-melting deicing agent prepared from marble slag for high-voltage cables and wires and preparation method thereof Download PDFInfo
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- CN106010444A CN106010444A CN201610506650.2A CN201610506650A CN106010444A CN 106010444 A CN106010444 A CN 106010444A CN 201610506650 A CN201610506650 A CN 201610506650A CN 106010444 A CN106010444 A CN 106010444A
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- snow
- rock ballast
- vinegar
- slag
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- 239000002893 slag Substances 0.000 title claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 title abstract description 24
- 238000002844 melting Methods 0.000 title abstract description 8
- 239000002131 composite material Substances 0.000 title abstract description 4
- 239000004579 marble Substances 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title description 6
- 239000000052 vinegar Substances 0.000 claims abstract description 18
- 235000021419 vinegar Nutrition 0.000 claims abstract description 18
- 241001149258 Sporobolus alterniflorus Species 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims abstract description 6
- 239000005413 snowmelt Substances 0.000 claims description 18
- 239000011435 rock Substances 0.000 claims description 17
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- 239000002023 wood Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 240000008564 Boehmeria nivea Species 0.000 claims description 6
- 229910052661 anorthite Inorganic materials 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052599 brucite Inorganic materials 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000010410 dusting Methods 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000000643 oven drying Methods 0.000 claims description 3
- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 claims description 3
- 235000006076 zinc citrate Nutrition 0.000 claims description 3
- 239000011746 zinc citrate Substances 0.000 claims description 3
- 229940068475 zinc citrate Drugs 0.000 claims description 3
- 238000003763 carbonization Methods 0.000 abstract description 3
- 210000002421 cell wall Anatomy 0.000 abstract description 2
- 238000011049 filling Methods 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract description 2
- 235000017060 Arachis glabrata Nutrition 0.000 abstract 2
- 241001553178 Arachis glabrata Species 0.000 abstract 2
- 235000010777 Arachis hypogaea Nutrition 0.000 abstract 2
- 235000018262 Arachis monticola Nutrition 0.000 abstract 2
- 235000020232 peanut Nutrition 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- ZORPJCONVDWMSP-UHFFFAOYSA-J calcium;magnesium;tetraacetate Chemical compound [Mg+2].[Ca+2].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O ZORPJCONVDWMSP-UHFFFAOYSA-J 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 description 1
- 230000008654 plant damage Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The invention discloses a composite snow-melting deicing agent prepared by marble slag and specially used for high-voltage cables and wires, wherein spartina alterniflora, peanut shells and vinegar residues are swelled by silicone-acrylic emulsion, cell walls of the spartina alterniflora, peanut shells and vinegar residues are enhanced after filling, resin is filled in gaps among staggered fibers, bonding among the fibers is enhanced, more micropores are introduced after carbonization, and adsorption capacity is improved The sustainable utilization of resources is realized.
Description
Technical field
The present invention relates to Snow Agent technical field, particularly relate to a kind of high tension cable electric wire specific complex snow melt deicer utilizing Dali rock ballast to prepare and preparation method thereof.
Background technology
Ice and snow not only had a strong impact on transportation and also the facilities such as outdoor high tension cable electric wire was caused important threat winter, if removing the ice and snow overstock on high tension cable electric wire not in time, bear a heavy burden and excessive cause electric pole underload to fracture danger, have a strong impact on personal safety and the daily life of people, therefore quickly ice-melt snow removing becomes China's high tension cable in winter electric wire key issue needing solution badly working properly undoubtedly, and Snow Agent produces therewith.
Snow Agent is as its name suggests, it is used to reduce the salt of ice and snow freezing point, its effect is deicing or snow melting, because it uses the many merits such as simple, deicing snow melt is effective, mainly as the snow-removing and ice-thawing of the facilities such as urban road, highway, airport, harbour, bridge and electric wire, some Snow Agent also act as agent for quick melting and the antifreezing admixture etc. of architectural engineering winter construction ice dissolution.Snow Agent can not have infringement to road, concrete component, bridge facility after using, and can not destroy flowers, plants and trees, crops, animal and people is had infringement.At present, villaumite type agent for melting ice and removing snow with sodium chloride as representative is widely used in different kinds of roads ice-melt snow removing, and the environmental problem using chloride Snow Agent to cause for a long time highlights the most day by day, the chloride ion corrosiveness to road and bridge, impact on plant growing, causes the extensive concern of people to problems such as the pollutions of water body.The eighties in 20th century, DOT company of the U.S. develops environment-friendly type calcium acetate magnesium salt (CMA) Snow Agent first, its low corrosivity and to the less harmful of vegetation by recognized by the world.But, due to the price problem of its raw material acetic acid so that CMA Snow Agent is difficult to Rapid Popularization, only minority place uses on airport etc. in China.Therefore, use cheap acetic acid and calcium, magnesium predecessor to research and develop the calcium acetate magnesium salt Snow Agent of low cost, become the important subject eradicating the harm of chloride salt Snow Agent.
" preparation of a kind of low-cost environment-friendly Snow Agent and performance study " selected works are selected by biomass waste material (straw, wood flour etc.) the russet waste liquid that produces during carbonization fuel gas, biodegradable and low cost wood vinegar is raw material, used by this method, its acetic acid content of wood vinegar raw material is up to 6%-12%, possibly together with a small amount of propanoic acid (about 0.6%), formic acid (about 0.3%), phenol, tar etc., have studied the process of the CMA class Snow Agent of preparation low cost, products obtained therefrom is low-carbon (LC) mixed carboxylic acid's calcium and magnesium salt, by a series of performance tesies of Snow Agent are shown, its snow melt temperature low (minimum up to-34 DEG C), snow melt efficiency is high (up to 208.3 cm3Snow/g Snow Agent), to the no corrosion such as metal, flowers and plants and infringement, the performance of each side is superior to the villaumite Snow Agent such as sodium chloride.
Current existing Snow Agent has powder and two kinds of forms of liquid, liquid is sprayed on ice and snow face with atomizing type melts ice and snow, it is uniformly dispersed but easily infiltrates into road surface, can bring certain corrosion-damaged, powder be directly spread on snow melt on snow face, but intensity is low and density little Yi is blown to four winds, cause disperseing uneven, snow melt effect declines, it is necessary to be improved and makes the snow melt deicer that intensity is high, not only it is difficult to be blown to four winds but also have preferably heat absorption, absorption property, accelerate snow melt deicing speed and there is low corrosion, pollute little, little to plant injury, combination property is high, function diversification, store the characteristics such as convenient.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of high tension cable electric wire specific complex snow melt deicer utilizing Dali rock ballast to prepare and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of high tension cable electric wire specific complex snow melt deicer utilizing Dali rock ballast to prepare, is prepared by the raw materials in: wood vinegar 61-64, anorthite powder 10-12, Dali rock ballast 13-15, zinc citrate 1-2, Maninot esculenta crantz. ground-slag 6-8, silicone acrylic emulsion 15-17, brucite fiber 7-9, vinegar 8-10, ramie stalk ash 8-9, Spartina alterniflora 5-7, Pericarppium arachidis hypogaeae 19-22, sodium bicarbonate 2-4.
The manufacture method of described a kind of high tension cable electric wire specific complex snow melt deicer utilizing Dali rock ballast to prepare, comprises the following steps:
(1) Spartina alterniflora, Pericarppium arachidis hypogaeae are dried to moisture content < 25%; attrition grinding crosses 200 mesh dusting covers; addition silicone acrylic emulsion, vinegar, Dali rock ballast stirring and evenly mixing stand 12-14 hour; pelletize; put in 80-100 DEG C of baking oven and be dried 10-12 hour; sinter 20-30 minute in 700-1000 DEG C under nitrogen protection, obtain anti-skidding auxiliary agent；
(2) by anorthite powder, ramie stalk ash stirring and evenly mixing, add sodium bicarbonate ultrasonic grinding 10-15 minute, obtain mixed material；
(3) mixed material that step (2) prepares is put into that to regulate pH in wood vinegar be about 8.5 at room temperature to react 2-3 hour, be filtered to remove insoluble matter, carry out filtrate concentrating, evaporating；
(4) anti-skidding auxiliary agent stirring and evenly mixing step (3) material and step (1) prepared, adds Maninot esculenta crantz. ground-slag, suitable quantity of water and other residual componentss and grinds 20-30 minute, pelletize, oven drying at low temperature, discharging.
The invention have the advantage that the present invention is by Spartina alterniflora, Pericarppium arachidis hypogaeae, vinegar is through silicone acrylic emulsion swollen, enhance its cell wall after filling and resin is filled in staggered interfibrous space, enhance fiber and interfibrous combination, more micropore is introduced after carbonization, absorbability is improved, the present invention substitutes glacial acetic acid with wood vinegar simultaneously, it is mixed to prepare Snow Agent for both calcium and magnesium predecessors with modified anorthite powder, last again by prepared Snow Agent and the parcel pelletize of anti-skidding auxiliary agent, dry and prepare composite snow-melting deicer low cost, adding in raw material that Dali rock ballast meets after ice dissolution after high-temperature calcination can heat release rapidly, reduce freezing point, accelerate Snow-melting speed, debris can be corroded road surface by anti-skidding auxiliary agent adsorption preventing, Dali rock ballast is fully used to turn waste into wealth, achieve the sustainable use of resource.
Detailed description of the invention
A kind of high tension cable electric wire specific complex snow melt deicer utilizing Dali rock ballast to prepare, is prepared by the raw materials in: wood vinegar 61, anorthite powder 10, Dali rock ballast 13, zinc citrate 1, Maninot esculenta crantz. ground-slag 6, silicone acrylic emulsion 15, brucite fiber 7, vinegar 8, ramie stalk ash 8, Spartina alterniflora 5, Pericarppium arachidis hypogaeae 19, sodium bicarbonate 2.
The manufacture method of described a kind of high tension cable electric wire specific complex snow melt deicer utilizing Dali rock ballast to prepare, comprises the following steps:
(1) Spartina alterniflora, Pericarppium arachidis hypogaeae are dried to moisture content < 25%, attrition grinding crosses 200 mesh dusting covers, adds silicone acrylic emulsion, vinegar, Dali rock ballast stirring and evenly mixing stand 12 hours; pelletize; put into and 80 DEG C of baking ovens are dried 10 hours, sinter 20 minutes in 700 DEG C under nitrogen protection, obtain anti-skidding auxiliary agent；
(2) by anorthite powder, ramie stalk ash stirring and evenly mixing, add sodium bicarbonate ultrasonic grinding 10 minutes, obtain mixed material；
(3) mixed material that step (2) prepares is put into that to regulate pH in wood vinegar be about 8.5 at room temperature to react 2 hours, be filtered to remove insoluble matter, carry out filtrate concentrating, evaporating；
(4) anti-skidding auxiliary agent stirring and evenly mixing step (3) material and step (1) prepared, adds Maninot esculenta crantz. ground-slag, suitable quantity of water and other residual componentss and grinds 20 minutes, pelletize, oven drying at low temperature, discharging.
Its snow melt temperature of composite snow-melting deicer utilizing the present invention to prepare is minimum up to-45 DEG C, and snow melt efficiency is up to 211.1cm3Snow/g Snow Agent, to the no corrosion such as metal, flowers and plants and infringement, the performance of each side is superior to the villaumite Snow Agent such as sodium chloride.
Claims (2)
1. the high tension cable electric wire specific complex snow melt deicer that a kind utilizes Dali rock ballast to prepare, it is characterized in that, be prepared by the raw materials in: wood vinegar 61-64, anorthite powder 10-12, Dali rock ballast 13-15, zinc citrate 1-2, Maninot esculenta crantz. ground-slag 6-8, silicone acrylic emulsion 15-17, brucite fiber 7-9, vinegar 8-10, ramie stalk ash 8-9, Spartina alterniflora 5-7, Pericarppium arachidis hypogaeae 19-22, sodium bicarbonate 2-4.
The manufacture method of a kind of high tension cable electric wire specific complex snow melt deicer utilizing Dali rock ballast to prepare the most according to claim 1, it is characterised in that comprise the following steps:
(1) Spartina alterniflora, Pericarppium arachidis hypogaeae are dried to moisture content < 25%; attrition grinding crosses 200 mesh dusting covers; addition silicone acrylic emulsion, vinegar, Dali rock ballast stirring and evenly mixing stand 12-14 hour; pelletize; put in 80-100 DEG C of baking oven and be dried 10-12 hour; sinter 20-30 minute in 700-1000 DEG C under nitrogen protection, obtain anti-skidding auxiliary agent；
(2) by anorthite powder, ramie stalk ash stirring and evenly mixing, add sodium bicarbonate ultrasonic grinding 10-15 minute, obtain mixed material；
(3) mixed material that step (2) prepares is put into that to regulate pH in wood vinegar be about 8.5 at room temperature to react 2-3 hour, be filtered to remove insoluble matter, carry out filtrate concentrating, evaporating；
(4) anti-skidding auxiliary agent stirring and evenly mixing step (3) material and step (1) prepared, adds Maninot esculenta crantz. ground-slag, suitable quantity of water and other residual componentss and grinds 20-30 minute, pelletize, oven drying at low temperature, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610506650.2A CN106010444A (en) | 2016-07-01 | 2016-07-01 | Special composite snow-melting deicing agent prepared from marble slag for high-voltage cables and wires and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610506650.2A CN106010444A (en) | 2016-07-01 | 2016-07-01 | Special composite snow-melting deicing agent prepared from marble slag for high-voltage cables and wires and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106010444A true CN106010444A (en) | 2016-10-12 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610506650.2A Pending CN106010444A (en) | 2016-07-01 | 2016-07-01 | Special composite snow-melting deicing agent prepared from marble slag for high-voltage cables and wires and preparation method thereof |
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| Country | Link |
|---|---|
| CN (1) | CN106010444A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101085910A (en) * | 2007-07-11 | 2007-12-12 | 吉林省交通科学研究所 | Environment-friendly type road soft anti-slip material |
| CN101629065A (en) * | 2009-08-14 | 2010-01-20 | 华南理工大学 | Environment protection snow-dissolved agent and preparation method thereof |
| CN105567163A (en) * | 2016-01-13 | 2016-05-11 | 田丹 | Preparation method of environment-friendly snow melting agent |
-
2016
- 2016-07-01 CN CN201610506650.2A patent/CN106010444A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101085910A (en) * | 2007-07-11 | 2007-12-12 | 吉林省交通科学研究所 | Environment-friendly type road soft anti-slip material |
| CN101629065A (en) * | 2009-08-14 | 2010-01-20 | 华南理工大学 | Environment protection snow-dissolved agent and preparation method thereof |
| CN105567163A (en) * | 2016-01-13 | 2016-05-11 | 田丹 | Preparation method of environment-friendly snow melting agent |
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Application publication date: 20161012 |
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