CN105542716A - Environment-friendly snow quick melting agent and preparing method thereof - Google Patents
Environment-friendly snow quick melting agent and preparing method thereof Download PDFInfo
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- CN105542716A CN105542716A CN201610088134.2A CN201610088134A CN105542716A CN 105542716 A CN105542716 A CN 105542716A CN 201610088134 A CN201610088134 A CN 201610088134A CN 105542716 A CN105542716 A CN 105542716A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
- C09K3/185—Thawing materials
Abstract
The invention discloses an environment-friendly snow quick melting agent. The environment-friendly snow quick melting agent is prepared from 12-65 parts of water, 2-6 parts of ethyl alcohol, 0.5-0.9 part of saccharose, 0.5-1.0 part of isosorbide, 0.2-10 parts of ethanediol, 2-50 parts of glycerol, 0.3-1 part of acesulfame potassium, 2-5 parts of sodium tripolyphosphate, 0.2-1 part of aspartame, 0.5-1 part of sodium hexametaphosphate, 6-30 parts of methyl alcohol, 0.5-1 part of threitol, 14-40 parts of sodium hexametaphosphate, 8-21 parts of sodium silicate, 6-20 parts of zinc dihydrogen phosphate, 5-12 parts of sodium dodecyl benzene sulfonate, 5-20 parts of sodium tartrate, 4-12 parts of hexamine, and 6-13 parts of allyl thiourea. The environment-friendly snow quick melting agent is superhigh in snow melting efficiency, convenient to transport, and safe in use and storage; spraying is convenient, labor intensity is low, and manual work investment is low; the usage amount is small, the snow melting speed is high, no residue is left, pollution to the water source is avoided, corrosion to buildings or road surfaces is avoided, damage to plants or aquatic animals is avoided, damage to the pH of soil is avoided, and soil salinization is avoided.
Description
Technical field
The present invention relates to Snow Agent field, particularly relate to a kind of environmental protection fast snow melting agent and preparation method thereof.
Background technology
Tradition Snow Agent is villaumite type Snow Agent, and its composition is or containing inorganic villaumites such as sodium-chlor, magnesium chloride, calcium chloride, is wherein Main Function composition with calcium chloride.Such Snow Agent is inevitably to building and road surface, and water source, soil, plant and hydrocoles cause certain injury.Given this, afterwards villaumite type Snow Agent was improved, and improved as other Nitrateses and mix certain ethylene glycol.If number of patent application is 99109322.4 patent names be: the environment-friendly snowmelt agent of ice and snow quick-dissolving agent and preparation method thereof.Disclose bicarbonate of ammonia, red phosphorus, Repone K, nitrocalcite, magnesium nitrate, the compositions such as ethylene glycol, decrease the content of villaumite, become other inorganic salt from villaumite type, although solve etching problem to a certain extent, but to soil, water source, unresolved in the injury of plant and hydrocoles, on the contrary also can cause nitrogen content to raise, water body eutrophication, and the environment-friendly snowmelt agent of really.All kinds of environment-friendly snowmelt agents occurred successively afterwards all can not break away from inorganic salt, all fail fundamentally to solve environmental protection and eco-friendly problem.
Snowing winter is China's communications and transportation " formidable enemy ", has a strong impact on Road safety and transports unobstructed, so people study the technology of road deicing snow melt.Snow Agent is wherein adopted to be application method the most widely.Snow Agent is mainly used in the places such as airport, highway, railway, avenue, plays deicing snow melt effect.Snow Agent has numerous species, mainly villaumite type and non-villaumite type.Non-chloride salt Snow Agent is high due to cost, applies now less.And chloride salt Snow Agent is because its snow melt is effective, low price, be widely used in the snow-removing and ice-thawing of road always.Up to the present, chloride salt Snow Agent is still main body.Use sodium-chlor more in early days, also use calcium chloride, magnesium chloride, Repone K or their mixture afterwards.
Chloride salt Snow Agent is one " double-edged sword ", it is while thawing ice and snow, huge negative harm can be brought, be mainly reflected in its corrodibility (to Infrastructure, bridge, road, parking lot, underground utilities etc.), freeze-thaw damage (to concrete etc.).Villaumite Snow Agent is very serious to the corrosion of the metal (as carbon steel) of road both sides and bridge, and the safe handling of harm bridge, financial loss is huge.The inhibiter of current chloride salt Snow Agent mostly is as one-component, and corrosion inhibiting ability is limited.
Summary of the invention
For above-mentioned problems of the prior art, the object of the present invention is to provide a kind of environmental protection fast snow melting agent and preparation method thereof.
The agent of a kind of environmental protection fast snow melting, starting material form according to following portion rate:
Water 12-65 part, ethanol 2-6 part, sucrose 0.5-0.9 part, Soquad 0.5-1.0 part, ethylene glycol 0.2-10 part, glycerol 2-50 part, acesulfame potassium 0.3-1 part, tripoly phosphate sodium STPP 2-5 part, aspartame 0.2-1 part, Sodium hexametaphosphate 99 0.5-1 part, methyl alcohol 6-30 part, threitol 0.5-1 part, Sodium hexametaphosphate 99 14-40 part, water glass 8-21 part, primary zinc phosphate 6-20 part, Sodium dodecylbenzene sulfonate 5-12 part, sodium tartrate 5-20 part, vulkacit H 4-12 part, Allyl thiourea 6-13 part.
Further illustrate, the agent of a kind of environmental protection fast snow melting, starting material form according to following portion rate:
20 parts, water, ethanol 5 parts, sucrose 0.7 part, Soquad 0.6 part, ethylene glycol 5 parts, glycerol 12 parts, acesulfame potassium 0.7 part, tripoly phosphate sodium STPP 4 parts, aspartame 0.8 part, Sodium hexametaphosphate 99 0.7 part, methyl alcohol 12 parts, threitol 0.8 part, Sodium hexametaphosphate 99 19 parts, water glass 12 parts, primary zinc phosphate 18 parts, Sodium dodecylbenzene sulfonate 7 parts, sodium tartrate 18 parts, vulkacit H 10 parts, Allyl thiourea 7 parts.
Further illustrate, the preparation method of a kind of environmental protection fast snow melting agent, comprises the following steps:
(1) join in reactor by ethanol and water wiring solution-forming, stir, nitrogen replacement pressurization makes reactor oxygen level be reduced to less than 0.1%, and reactor pressure 0.8-1.1MPa, is warming up to 178-185 DEG C, stirs 12-24 hour;
(2) then add successively in reactor water, sucrose, Soquad, ethylene glycol, glycerol, acesulfame potassium, tripoly phosphate sodium STPP, aspartame, Sodium hexametaphosphate 99, methyl alcohol and, sugar alcohol, Sodium hexametaphosphate 99, water glass, primary zinc phosphate, Sodium dodecylbenzene sulfonate, sodium tartrate, vulkacit H, Allyl thiourea, heating makes it dissolve, stir, churning time is 1-48 hour.
(3) in reactor, inject water again, be warming up to 195-205 DEG C, boost to 3.8-4.2MPa with nitrogen, keep 23-25 hour;
(4) cooling is for being down to 20-30 DEG C, and release is depressed into normal pressure for unloading, and filter, filtrate is environment-friendly snowmelt agent.
Beneficial effect of the present invention is as follows:
Snow Agent prepared by the present invention, not containing inorganic salt, adopts low molecule organic matter reaction completely; The raw materials used overwhelming majority is foodstuff additive, except methyl alcohol, also can not damage human body even if other materials are edible.The Snow Agent snow melt efficiency superelevation that the present invention obtains, convenient transportation, uses storage safe; Be convenient to spray, use labour intensity low, artificial input is little; Consumption is few, and Snow-melting speed is fast, noresidue, not polluted source, does not corrode building and road surface, does not injure plant and hydrocoles, not spoiled soil pH, can not cause salting of soil.
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, exercising ordinary skill, not making the every other embodiment obtained under creative work prerequisite, belongs to the scope of protection of the invention.
Embodiment 1
The agent of a kind of environmental protection fast snow melting, starting material form according to following portion rate:
12 parts, water, ethanol 2 parts, sucrose 0.5 part, Soquad 0.5 part, ethylene glycol 0.2 part, glycerol 2 parts, acesulfame potassium 0.3 part, tripoly phosphate sodium STPP 2 parts, aspartame 0.2 part, Sodium hexametaphosphate 99 0.5 part, methyl alcohol 6 parts, threitol 0.5 part, Sodium hexametaphosphate 99 14 parts, water glass 8 parts, primary zinc phosphate 6 parts, Sodium dodecylbenzene sulfonate 5 parts, sodium tartrate 5 parts, vulkacit H 4 parts, Allyl thiourea 6 parts.
A preparation method for environmental protection fast snow melting agent, comprises the following steps:
(1) join in reactor by ethanol and water wiring solution-forming, stir, nitrogen replacement pressurization makes reactor oxygen level be reduced to less than 0.1%, and reactor pressure 0.8MPa, is warming up to 178 DEG C, stirs 12 hours;
(2) then add successively in reactor water, sucrose, Soquad, ethylene glycol, glycerol, acesulfame potassium, tripoly phosphate sodium STPP, aspartame, Sodium hexametaphosphate 99, methyl alcohol and, sugar alcohol, Sodium hexametaphosphate 99, water glass, primary zinc phosphate, Sodium dodecylbenzene sulfonate, sodium tartrate, vulkacit H, Allyl thiourea, heating makes it dissolve, stir, churning time is 1 hour.
(3) in reactor, inject water again, be warming up to 195 DEG C, boost to 3.8MPa with nitrogen, keep 23 hours;
(4) cooling is for being down to 20 DEG C, and release is depressed into normal pressure for unloading, and filter, filtrate is environment-friendly snowmelt agent.
Embodiment 2
The agent of a kind of environmental protection fast snow melting, starting material form according to following portion rate:
65 parts, water, ethanol 6 parts, sucrose 0.9 part, Soquad 1.0 parts, ethylene glycol 10 parts, glycerol 50 parts, acesulfame potassium 1 part, tripoly phosphate sodium STPP 5 parts, aspartame 1 part, Sodium hexametaphosphate 99 1 part, methyl alcohol 30 parts, threitol 1 part, Sodium hexametaphosphate 99 40 parts, water glass 21 parts, primary zinc phosphate 20 parts, Sodium dodecylbenzene sulfonate 12 parts, sodium tartrate 20 parts, vulkacit H 12 parts, Allyl thiourea 13 parts.
A preparation method for environmental protection fast snow melting agent, comprises the following steps:
(1) join in reactor by ethanol and water wiring solution-forming, stir, nitrogen replacement pressurization makes reactor oxygen level be reduced to less than 0.1%, and reactor pressure 1.1MPa, is warming up to 185 DEG C, stirs 24 hours;
(2) then add successively in reactor water, sucrose, Soquad, ethylene glycol, glycerol, acesulfame potassium, tripoly phosphate sodium STPP, aspartame, Sodium hexametaphosphate 99, methyl alcohol and, sugar alcohol, Sodium hexametaphosphate 99, water glass, primary zinc phosphate, Sodium dodecylbenzene sulfonate, sodium tartrate, vulkacit H, Allyl thiourea, heating makes it dissolve, stir, churning time is 48 hours.
(3) in reactor, inject water again, be warming up to 205 DEG C, boost to 4.2MPa with nitrogen, keep 25 hours;
(4) cooling is for being down to 30 DEG C, and release is depressed into normal pressure for unloading, and filter, filtrate is environment-friendly snowmelt agent.
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from spirit of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (3)
1. the agent of environmental protection fast snow melting, is characterized in that, starting material form according to following portion rate:
Water 12-65 part, ethanol 2-6 part, sucrose 0.5-0.9 part, Soquad 0.5-1.0 part, ethylene glycol 0.2-10 part, glycerol 2-50 part, acesulfame potassium 0.3-1 part, tripoly phosphate sodium STPP 2-5 part, aspartame 0.2-1 part, Sodium hexametaphosphate 99 0.5-1 part, methyl alcohol 6-30 part, threitol 0.5-1 part, Sodium hexametaphosphate 99 14-40 part, water glass 8-21 part, primary zinc phosphate 6-20 part, Sodium dodecylbenzene sulfonate 5-12 part, sodium tartrate 5-20 part, vulkacit H 4-12 part, Allyl thiourea 6-13 part.
2., according to the agent of a claim 1 environmental protection fast snow melting, it is characterized in that, starting material form according to following portion rate:
20 parts, water, ethanol 5 parts, sucrose 0.7 part, Soquad 0.6 part, ethylene glycol 5 parts, glycerol 12 parts, acesulfame potassium 0.7 part, tripoly phosphate sodium STPP 4 parts, aspartame 0.8 part, Sodium hexametaphosphate 99 0.7 part, methyl alcohol 12 parts, threitol 0.8 part, Sodium hexametaphosphate 99 19 parts, water glass 12 parts, primary zinc phosphate 18 parts, Sodium dodecylbenzene sulfonate 7 parts, sodium tartrate 18 parts, vulkacit H 10 parts, Allyl thiourea 7 parts.
3., according to the preparation method of claim 1 environmental protection fast snow melting agent, it is characterized in that, comprise the following steps:
(1) join in reactor by ethanol and water wiring solution-forming, stir, nitrogen replacement pressurization makes reactor oxygen level be reduced to less than 0.1%, and reactor pressure 0.8-1.1MPa, is warming up to 178-185 DEG C, stirs 12-24 hour;
(2) then add successively in reactor water, sucrose, Soquad, ethylene glycol, glycerol, acesulfame potassium, tripoly phosphate sodium STPP, aspartame, Sodium hexametaphosphate 99, methyl alcohol and, sugar alcohol, Sodium hexametaphosphate 99, water glass, primary zinc phosphate, Sodium dodecylbenzene sulfonate, sodium tartrate, vulkacit H, Allyl thiourea, heating makes it dissolve, stir, churning time is 1-48 hour;
(3) in reactor, inject water again, be warming up to 195-205 DEG C, boost to 3.8-4.2MPa with nitrogen, keep 23-25 hour;
(4) cooling is for being down to 20-30 DEG C, and release is depressed into normal pressure for unloading, and filter, filtrate is environment-friendly snowmelt agent.
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| CN201610088134.2A CN105542716A (en) | 2016-02-17 | 2016-02-17 | Environment-friendly snow quick melting agent and preparing method thereof |
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| CN201610088134.2A CN105542716A (en) | 2016-02-17 | 2016-02-17 | Environment-friendly snow quick melting agent and preparing method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108048037A (en) * | 2017-12-29 | 2018-05-18 | 刘志浩 | A kind of deicing salt |
| CN108084966A (en) * | 2017-12-29 | 2018-05-29 | 刘志浩 | A kind of environment-friendly snowmelt agent |
| CN109266310A (en) * | 2018-11-08 | 2019-01-25 | 黄山九星环保科技有限公司 | A kind of non-chlorine of environment-friendly biomass is except ice and snow melting agent and preparation method thereof |
| CN112920775A (en) * | 2019-12-06 | 2021-06-08 | 济南圣泉集团股份有限公司 | Sugar alcohol composition and preparation method and application thereof |
| CN115085659A (en) * | 2022-06-07 | 2022-09-20 | 黄山九星环保科技股份有限公司 | Automatic deicing and snow melting system applied to solar photovoltaic panel |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104031610A (en) * | 2014-07-01 | 2014-09-10 | 滨州市旭泰化工科技有限公司 | Environment-friendly snow-melting agent and preparation method thereof |
| CN104073221A (en) * | 2014-06-25 | 2014-10-01 | 陕西省建筑材料工业设计研究院 | Environment-friendly non-chlorine-salt snow melting and deicing agent and preparation method thereof |
| CN104650811A (en) * | 2015-02-28 | 2015-05-27 | 辽宁石化职业技术学院 | Environment-friendly snow melting agent and preparation method thereof |
-
2016
- 2016-02-17 CN CN201610088134.2A patent/CN105542716A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104073221A (en) * | 2014-06-25 | 2014-10-01 | 陕西省建筑材料工业设计研究院 | Environment-friendly non-chlorine-salt snow melting and deicing agent and preparation method thereof |
| CN104031610A (en) * | 2014-07-01 | 2014-09-10 | 滨州市旭泰化工科技有限公司 | Environment-friendly snow-melting agent and preparation method thereof |
| CN104650811A (en) * | 2015-02-28 | 2015-05-27 | 辽宁石化职业技术学院 | Environment-friendly snow melting agent and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108048037A (en) * | 2017-12-29 | 2018-05-18 | 刘志浩 | A kind of deicing salt |
| CN108084966A (en) * | 2017-12-29 | 2018-05-29 | 刘志浩 | A kind of environment-friendly snowmelt agent |
| CN109266310A (en) * | 2018-11-08 | 2019-01-25 | 黄山九星环保科技有限公司 | A kind of non-chlorine of environment-friendly biomass is except ice and snow melting agent and preparation method thereof |
| CN112920775A (en) * | 2019-12-06 | 2021-06-08 | 济南圣泉集团股份有限公司 | Sugar alcohol composition and preparation method and application thereof |
| CN112920775B (en) * | 2019-12-06 | 2022-12-09 | 济南圣泉集团股份有限公司 | Sugar alcohol composition and preparation method and application thereof |
| CN115085659A (en) * | 2022-06-07 | 2022-09-20 | 黄山九星环保科技股份有限公司 | Automatic deicing and snow melting system applied to solar photovoltaic panel |
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Application publication date: 20160504 |
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