CN106010168A - Base brush-off composition for wood products, method for preparing base brush-off composition and process for coating same - Google Patents

Base brush-off composition for wood products, method for preparing base brush-off composition and process for coating same Download PDF

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Publication number
CN106010168A
CN106010168A CN201610579556.XA CN201610579556A CN106010168A CN 106010168 A CN106010168 A CN 106010168A CN 201610579556 A CN201610579556 A CN 201610579556A CN 106010168 A CN106010168 A CN 106010168A
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CN
China
Prior art keywords
woodenware
colour cell
cell compound
wiped
composition
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Granted
Application number
CN201610579556.XA
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Chinese (zh)
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CN106010168B (en
Inventor
杨岳森
罗俊君
梁斌
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GUANGDONG CARPOLY SCIENCE & TECHNOLOGY MATERIAL Co Ltd
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GUANGDONG CARPOLY SCIENCE & TECHNOLOGY MATERIAL Co Ltd
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Priority to CN201610579556.XA priority Critical patent/CN106010168B/en
Publication of CN106010168A publication Critical patent/CN106010168A/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a base brush-off composition for wood products, a method for preparing the base brush-off composition and a process for coating the same. The base brush-off composition for the wood products comprises, by weight, 10-60 parts of water-soluble hydroxy resin, 20-60 parts of solvents, 0.5-2 parts of dispersing agents, 5-20 parts of fillers, 1-10 parts of thickening agents, 2-90 parts of toner and 0.2-1 part of anti-skinning agents. A molar percent of hydroxy in the water-soluble hydroxy resin is 5%-20%. The base brush-off composition for the wood products, the method and the process have the advantages that base brush-off composition is high in adhesion, steps for coating priming paint prior to brush-off can be omitted, and the process can be simplified while grains of plates are highlighted.

Description

Colour cell compound and preparation method thereof and coating process are wiped in the woodenware end
Technical field
The present invention relates to coating products, particularly relate to wipe colour cell compound and preparation method thereof at the bottom of a kind of woodenware And coating process.
Background technology
Nowadays, along with growth in the living standard, in decoration design for residence, the personalization of color is needed by people Asking and increasingly focus on, coating products " coloration " consumption has formed a kind of main trend.
In the coating process of woodcare paint, deeply consumed with " technique is repaiied in wiping face, the end " that stereovision is famous always The favor of person." technique is repaiied in wiping face, the end " is through the background color collocation with complexion to highlight the one of plate grain Coating process.Wherein, chromatic effect is wiped to overall stereovision impact maximum in the end.In other words, want to obtain Obtaining excellent grain effect, color product is wiped at the end and coating process is crucial.
When the construction of color product is wiped at the most traditional end, a transparent priming need to be brushed on sheet material, after doing solid work Construct again background color.If not having oily Gongshi Fu of construction experience to construct, owing to brushing transparent priming Coating layer thickness is uneven, can cause the background color uneven problem maybe cannot painted of colouring, finally executing of sheet material occur Work efficiency fruit also will be had a greatly reduced quality.But, if not brushing a transparent priming, using traditional end to wipe color and producing Product directly colour on sheet material, there will be again color delamination or uneven phenomenon after primer spray Lacquer finish.
Summary of the invention
Based on this, it is necessary to while providing one to highlight plate grain, simplify coating process, improve color Colour cell compound is wiped at the woodenware of the adhesive force end.
Colour cell compound is wiped, in parts by weight, including following raw material components in a kind of woodenware end:
In described water soluble hydroxy resin, the molar percentage of hydroxyl is 5%～20%.
Toner of the present invention can be allocated according to required color, and being preferably and using mass ratio is (1～30): (1～30): the red toner of (1～30), yellow toner are arranged in pairs or groups with black toner.Wherein, red color Powder preferably uses organic red and/or iron oxide red；Yellow toner is preferably and uses organic yellow and/or ferrum oxide Yellow；Black toner is preferably high-carbon black pigment.
Wipe colour cell compound at the bottom of above-mentioned woodenware, in parts by weight, preferably comprise following raw material components: water-soluble Property hydroxy resin 10～20 parts, solvent 40～60 parts, dispersant 0.5～1 part, filler 10～15 parts, thickening agent 5～10 parts, toner 5～15 parts, anti skinning agent 0.2～1 part.
Wherein in an embodiment, in described water soluble hydroxy resin, the molar percentage of hydroxyl is 6%～9%.
Wherein in an embodiment, described dispersant is modified copolymer.
Wherein in an embodiment, described dispersant is high molecular modified acrylic acid terpolymer.
Wherein in an embodiment, described anti skinning agent is preferably diacetylmonoxime.It is therefore prevented from the bottom of the present invention wiping Colour cell compound occurs skinning during preserving, and reduces product quality.
Wherein in an embodiment, described thickening agent is in bentonite, aerosil, polyamide wax One or more.
Wherein in an embodiment, described filler is Pulvis Talci and/or transparent powder；Described solvent is alkanes Solvent and/or alcohol ether solvent.Described solvent is preferably dipropylene glycol monomethyl ether (DPM) or dipropylene glycol list Methyl ether (DPM) and the mixture of alkane solvents.
The present invention separately provides the preparation method wiping colour cell compound at the bottom of described woodenware, comprises the steps:
In described water soluble hydroxy resin, adding part described solvent adjustment viscosity is 200～350mpa.s； Then described dispersant, low speed 500～800 turns/min stirring 5～10min are added；
Sequentially add described filler and described toner, at a high speed after 1400～1800 turns/min stirring 10～15min, Obtain mixture, grind；
Being sequentially added into remaining described solvent and described anti skinning agent, low speed 500～800 turns/min stirs 5～10min, to obtain final product.
Wherein in an embodiment, the method for described grinding is: be ground to filler described in described mixture It is less than 30 μm with the fineness of described toner.
The present invention also provides for wiping at the bottom of described woodenware the coating process of colour cell compound, comprises the steps:
Obtain the sheet material treating application；
Wipe colour cell compound at the bottom of woodenware described in employing to carry out the described sheet material treating application wiping color process, stand 2～24h；
Spray-applied primer on sheet material after described wiping color processes, carries out rear operation,.
Principle and the advantage of the present invention are as follows:
The present invention be experimental studies have found that, by water soluble hydroxy resin, with other raw material components by substantial amounts of Carry out compounding making and at the bottom of woodenware, wipe colour cell compound, it is possible to be effectively improved end wiping color product attachment on sheet material Power, highlights the texture of sheet material.
This is the resin system containing certain hydroxyl owing to using, and has between the priming paint of follow-up coating The good compatibility, the two interpenetrates, and the sealing process of available priming paint is effectively improved the adhesive force of color, Color uniformity is good simultaneously；It addition, water soluble hydroxy resin system can also well penetrate into the gap of sheet material, In the effective texture that toner is imported timber, increase color adhesive force the most further, highlight sheet material simultaneously Texture.
Additionally, the woodenware of the present invention is strong, with aqueous priming paint or solvent bottom paint by end wiping colour cell compound matching All can be good with the use of, it is achieved the effect above.
In view of wiping the color adhesive force that colour cell compound is stronger at the bottom of the woodenware of the present invention, therefore it can when application Creative omits the priming paint painting process before wiping color, directly uses the woodenware of the present invention to wipe colour cell compound the end of with Carry out the end wipe color sheet material during follow-up primer coating, uniform in color, do not have the defects such as delamination, Plate grain understands, natural.
Further, to wipe at the bottom of woodenware of the present invention in colour cell compound dispersant, thickening agent, filler etc. its Its raw material components carries out preferably, coordinating with water soluble hydroxy resin, can the materialization of optimum organization objects system Character so that it is while Performance optimization, it is simple to construction, is suitable for large area operation.
The preparation method of colour cell compound is wiped, by conservative control charging sequence and work at the bottom of woodenware of the present invention Skill condition, it is ensured that the performance of each raw material components performance, method is simple simultaneously, it is simple to technique is applied.
Wiping the coating process of colour cell compound at the bottom of woodenware of the present invention, creative eliminates the end before wiping color Paint painting process, reduces the coating process requirement to technical staff, improves coating quality, and application simultaneously is imitated Rate is high, low cost.
Accompanying drawing explanation
Fig. 1 is to use to wipe the sheet material schematic diagram that colour cell compound application obtains at the bottom of embodiment 1 woodenware；
Fig. 2 is above-mentioned sheet material schematic diagram after drawing lattice experiment.
Detailed description of the invention
Below in conjunction with specific embodiment, the woodenware of the present invention is wiped colour cell compound and preparation method thereof and application the end of with Technique is described in further detail.
Embodiment 1
Colour cell compound is wiped at 1 one kinds of woodenware of embodiment end, in parts by weight, including following raw material components:
In described water soluble hydroxy resin, the molar percentage of hydroxyl is 6.8%, purchased from Germany's moral letter profit chemistry (Worlee) modified soluble alkyd resin sol 30.
Described solvent is DPM.
Described dispersant is high molecular modified acrylic acid terpolymer, purchased from special (Cytec) company of cyanogen VXW6208/60。
Described filler is transparent powder.
Described thickening agent is bentonite.
Described anti skinning agent is diacetylmonoxime.
Wipe the preparation method of colour cell compound at the bottom of above-mentioned woodenware, comprise the steps:
In described water soluble hydroxy resin, the viscosity adding part described solvent adjustment mixture is 320mpa.s, then adds described dispersant, and 500 turns/min of low speed stirs 10min；
Sequentially add described filler and described toner, at a high speed after 1600 turns/min stirring 10min, grind mixed Compound fineness is less than 30 μm；
Being sequentially added into remaining described solvent and described anti skinning agent, 700 turns/min of low speed stirs 5min, Obtain.
The coating process wiping colour cell compound at the bottom of above-mentioned woodenware comprises the steps:
Obtain the Cortex Fraxini mandshuricae sheet material treating application；
Use wiping colour cell compound at the bottom of above-mentioned woodenware that described Cortex Fraxini mandshuricae sheet material carries out wipe color to process, stand 2h；
Spraying polyurethane (PU) transparent priming on Cortex Fraxini mandshuricae sheet material after described wiping color processes, work routinely Skill carries out rear operation,.Gained sheet material is as it is shown in figure 1, uniform in color, clean mark.
Embodiment 2
Colour cell compound is wiped at 2 one kinds of woodenware of embodiment end, in parts by weight, including following raw material components:
In described water soluble hydroxy resin, the molar percentage of hydroxyl is 8.6%, purchased from Germany's moral letter profit chemistry (Worlee) modified soluble alkyd resin sol 30.
Described solvent is DPM.
Described dispersant is high molecular modified acrylic acid terpolymer, purchased from special (Cytec) company of cyanogen VXW6208/60。
Described filler is transparent powder.
Described thickening agent is aerosil.
Described anti skinning agent is diacetylmonoxime.
Wipe the preparation method of colour cell compound at the bottom of above-mentioned woodenware, comprise the steps:
In described water soluble hydroxy resin, the viscosity adding part described solvent adjustment mixture is 350mpa.s, then adds described dispersant, and 600 turns/min of low speed stirs 10min；
Sequentially add described filler and described toner, at a high speed after 1600 turns/min stirring 15min, grind mixed Compound fineness is less than 30 μm；
Being sequentially added into remaining described solvent and described anti skinning agent, 600 turns/min of low speed stirs 5min, Obtain.
The coating process wiping colour cell compound at the bottom of above-mentioned woodenware comprises the steps:
Obtain the Cortex Fraxini mandshuricae sheet material treating application；
Use wiping colour cell compound at the bottom of above-mentioned woodenware that described Cortex Fraxini mandshuricae sheet material carries out wipe color to process, stand 24h；
Aqueous transparent priming paint is sprayed, after technique is carried out routinely on Cortex Fraxini mandshuricae sheet material after described wiping color processes Operation,.
Embodiment 3
Colour cell compound is wiped at 3 one kinds of woodenware of embodiment end, in parts by weight, including following raw material components:
In described water soluble hydroxy resin, the molar percentage of hydroxyl is 8.6%, purchased from Germany's moral letter profit chemistry (Worlee) modified soluble alkyd resin sol 30.
Described solvent is DPM and alkane solvents mixture.
Described dispersant is high molecular modified acrylic acid terpolymer, purchased from special (Cytec) company of cyanogen VXW6208/60。
Described filler is Pulvis Talci.
Described thickening agent is polyamide wax.
Described anti skinning agent is diacetylmonoxime.
Wipe the preparation method of colour cell compound at the bottom of above-mentioned woodenware, comprise the steps:
In described water soluble hydroxy resin, the viscosity adding part described solvent adjustment mixture is 250mpa.s, then adds described dispersant, and 500 turns/min of low speed stirs 5min；
Sequentially add described filler and described toner, at a high speed after 1550 turns/min stirring 15min, grind mixed Compound fineness is less than 30 μm；
Being sequentially added into remaining described solvent and described anti skinning agent, 700 turns/min of low speed stirs 10min, Obtain.
The coating process wiping colour cell compound at the bottom of above-mentioned woodenware comprises the steps:
Obtain the Cortex Fraxini mandshuricae sheet material treating application；
Use wiping colour cell compound at the bottom of above-mentioned woodenware that described Cortex Fraxini mandshuricae sheet material carries out wipe color to process, stand 10h；
Aqueous transparent priming paint is sprayed, after technique is carried out routinely on Cortex Fraxini mandshuricae sheet material after described wiping color processes Operation,.
Embodiment 4
Colour cell compound is wiped at 4 one kinds of woodenware of embodiment end, in parts by weight, including following raw material components:
In described water soluble hydroxy resin, the molar percentage of hydroxyl is 8.6%, purchased from Germany's moral letter profit chemistry (Worlee) modified soluble alkyd resin sol 30.
Described solvent is DPM and alkane solvents mixture.
Described dispersant is high molecular modified acrylic acid terpolymer, purchased from special (Cytec) company of cyanogen VXW6208/60。
Described filler is Pulvis Talci.
Described thickening agent is polyamide wax.
Described anti skinning agent is diacetylmonoxime.
Wipe the preparation method of colour cell compound at the bottom of above-mentioned woodenware, comprise the steps:
In described water soluble hydroxy resin, the viscosity adding part described solvent adjustment mixture is 320mpa.s, then adds described dispersant, and 600 turns/min of low speed stirs 7min；
Sequentially add described filler and described toner, at a high speed after 1800 turns/min stirring 12min, grind mixed Compound fineness is less than 30 μm；
Being sequentially added into remaining described solvent and described anti skinning agent, 550 turns/min of low speed stirs 7min, Obtain.
The coating process wiping colour cell compound at the bottom of above-mentioned woodenware comprises the steps:
Obtain the Cortex Fraxini mandshuricae sheet material treating application；
Use wiping colour cell compound at the bottom of above-mentioned woodenware that described Cortex Fraxini mandshuricae sheet material carries out wipe color to process, stand 15h；
Spraying PU transparent priming on Cortex Fraxini mandshuricae sheet material after described wiping color processes, technique carries out rear work routinely Sequence,.
Comparative example 1
Colour cell compound is wiped at 1 one kinds of woodenware of comparative example end, and its raw material components and preparation method are with embodiment 1, district It is not: the resin of employing is blowing oleum lini, not hydroxyl.
The method identical according to embodiment 1 carries out application.
Comparative example 2
Colour cell compound is wiped at 2 one kinds of woodenware of comparative example end, and its raw material components and preparation method are with embodiment 1, district It is not: the resin of employing is the aldehyde ketone resin of oiliness.
The method identical according to embodiment 1 carries out application.
Use and draw lattice experimental test procedures (reference standard GB/T 9286) to embodiment 1-4 and comparative example 1-2 Wooden paint at the bottom of wipe the performance after colour cell compound application and test, result is as shown in table 1:
Table 1
It addition, the sheet material that embodiment 1 is after drawing lattice experiment test is as in figure 2 it is shown, color texture is substantially without becoming Change, illustrate that sheet material adhesive force is good.
Each technical characteristic of embodiment described above can combine arbitrarily, for making description succinct, the most right The all possible combination of each technical characteristic in above-described embodiment is all described, but, if these skills There is not contradiction in the combination of art feature, is all considered to be the scope that this specification is recorded.
Embodiment described above only have expressed the several embodiments of the present invention, and it describes more concrete and detailed, But can not therefore be construed as limiting the scope of the patent.It should be pointed out that, for this area For those of ordinary skill, without departing from the inventive concept of the premise, it is also possible to make some deformation and change Entering, these broadly fall into protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be with appended power Profit requires to be as the criterion.

Claims (10)

1. colour cell compound is wiped at a woodenware end, it is characterised in that in parts by weight, including following raw material group Point:
In described water soluble hydroxy resin, the molar percentage of hydroxyl is 5%～20%.
Colour cell compound is wiped, it is characterised in that described water solublity at the bottom of woodenware the most according to claim 1 In hydroxy resin, the molar percentage of hydroxyl is 6%～9%.
Colour cell compound is wiped, it is characterised in that described dispersant at the bottom of woodenware the most according to claim 1 For modified copolymer.
Colour cell compound is wiped, it is characterised in that described dispersant at the bottom of woodenware the most according to claim 3 For high molecular modified acrylic acid terpolymer.
5. wipe colour cell compound according to the end of the woodenware described in any one of claim 1-4, it is characterised in that institute Stating thickening agent is one or more in bentonite, aerosil, polyamide wax.
6. wipe colour cell compound according to the end of the woodenware described in any one of claim 1-4, it is characterised in that institute Stating anti skinning agent is diacetylmonoxime.
7. wipe colour cell compound according to the end of the woodenware described in any one of claim 1-4, it is characterised in that institute Stating filler is Pulvis Talci and/or transparent powder；Described solvent is alkane solvents and/or alcohol ether solvent.
8. the preparation method of colour cell compound wiped by the woodenware described in any one of claim 1-7 the end of with, and its feature exists In, comprise the steps:
In described water soluble hydroxy resin, adding part described solvent adjustment viscosity is 200～350mpa.s； Then described dispersant, low speed 500～800 turns/min stirring 5～10min are added；
Sequentially add described filler and described toner, at a high speed after 1400～1800 turns/min stirring 10～15min, Obtain mixture, be ground；
Sequentially adding remaining described solvent and described anti skinning agent, low speed 500～800 turns/min stirs 5～10min, to obtain final product.
9. the preparation method of colour cell compound wiped by the woodenware described in claim 8 end of with, it is characterised in that described The method ground is: be ground to the fineness of filler and described toner described in described mixture less than 30 μm.
10. the coating process of colour cell compound wiped by the woodenware described in any one of claim 1-7 the end of with, and its feature exists In, comprise the steps:
Obtain the sheet material treating application；
Use wiping colour cell compound at the bottom of the woodenware described in any one of claim 1-8 that the described sheet material treating application is entered Row is wiped color and is processed, and stands 2～24h；
Primer coating on sheet material after described wiping color processes, carries out rear operation,.
CN201610579556.XA 2016-07-21 2016-07-21 Woodenware wipes color composition and preparation method thereof and coating process the bottom of with Active CN106010168B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108913028A (en) * 2018-07-06 2018-11-30 东莞大宝化工制品有限公司 glaze and preparation method thereof

Citations (4)

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Publication number Priority date Publication date Assignee Title
WO2010114728A1 (en) * 2009-03-30 2010-10-07 Isp Investments Inc. Penetrating uv-protecting compositions to protect wood and lignin
CN102363679A (en) * 2011-06-30 2012-02-29 成都倍大涂料有限公司 Water-soluble glaze and preparation method thereof
CN102504649A (en) * 2011-11-08 2012-06-20 陈绍球 Wooden ware surface colorizing agent and preparation method thereof
CN104046240A (en) * 2014-07-02 2014-09-17 江苏海田技术有限公司 Aqueous color-wrapping glaze base material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010114728A1 (en) * 2009-03-30 2010-10-07 Isp Investments Inc. Penetrating uv-protecting compositions to protect wood and lignin
CN102363679A (en) * 2011-06-30 2012-02-29 成都倍大涂料有限公司 Water-soluble glaze and preparation method thereof
CN102504649A (en) * 2011-11-08 2012-06-20 陈绍球 Wooden ware surface colorizing agent and preparation method thereof
CN104046240A (en) * 2014-07-02 2014-09-17 江苏海田技术有限公司 Aqueous color-wrapping glaze base material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108913028A (en) * 2018-07-06 2018-11-30 东莞大宝化工制品有限公司 glaze and preparation method thereof

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