CN106010168B - Woodenware wipes color composition and preparation method thereof and coating process the bottom of with - Google Patents
Woodenware wipes color composition and preparation method thereof and coating process the bottom of with Download PDFInfo
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- CN106010168B CN106010168B CN201610579556.XA CN201610579556A CN106010168B CN 106010168 B CN106010168 B CN 106010168B CN 201610579556 A CN201610579556 A CN 201610579556A CN 106010168 B CN106010168 B CN 106010168B
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- woodenware
- color composition
- wipes
- color
- plank
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention relates to a kind of woodenware bottoms to wipe color composition and preparation method thereof and coating process.The woodenware wipes color composition in parts by weight the bottom of with, including the following raw material component：10~60 parts of water soluble hydroxy resin, 20~60 parts of solvent, 0.5~2 part of dispersant, 5~20 parts of filler, 1~10 part of thickener, 2~90 parts of toner, 0.2~1 part of anti skinning agent, wherein, the molar percentage of hydroxyl is 5%~20% in the water soluble hydroxy resin.The woodenware wipes color composition strong adhesive force the bottom of with, can omit the priming paint application step before wiping color, while highlighting plate grain, simplifies coating process.
Description
Technical field
The present invention relates to coating products, and color composition and preparation method thereof and application are wiped more particularly to a kind of woodenware bottom
Technique.
Background technology
Nowadays, with the improvement of living standards, in decoration design for residence, people to the individual demand of color increasingly
Focus on, " coloration " consumption of coating products has formed a kind of main trend.
In the coating process of woodcare paint, with stereovision famous " wipe face and repair technique in bottom " always deeply by the blueness of consumer
It looks at." wipe face and repair technique in bottom " is exactly to highlight a kind of coating process of plate grain by the collocation of background color and complexion.Wherein, bottom
Wipe color effect influences maximum to whole stereovision.In other words, to obtain excellent grain effect, bottom wipe color product and
Its coating process is crucial.
When the construction of color product is wiped at traditional bottom on the market, a transparent priming need to be brushed on plank, is constructed again after doing solid work
Background color.It constructs if it is oily Gongshi Fu of not construction experience, since the coating layer thickness for brushing transparent priming is uneven, can lead
Cause occurs that background color colouring is uneven or the problem of can not paint, and the final construction effect of plank will also have a greatly reduced quality.But if
A transparent priming is not brushed, and wiping color product using traditional bottom directly colours on plank, will appear again after primer spray Lacquer finish
Color delamination or non-uniform phenomenon.
Invention content
Based on this, it is necessary to while providing one kind and highlighting plate grain, simplify coating process, improve color adhesive force
Woodenware wipes color composition the bottom of with.
A kind of woodenware bottom wiping color composition, in parts by weight, including the following raw material component：
The molar percentage of hydroxyl is 5%~20% in the water soluble hydroxy resin.
Toner of the present invention can be allocated according to required color, preferably use mass ratio for (1~30)：(1~
30)：Red toner, yellow toner and the black toner of (1~30) are arranged in pairs or groups.Wherein, red toner is preferably using organic
Red and/or iron oxide red；Yellow toner preferably uses organic yellow and/or iron oxide yellow；Black toner is preferably high pigment carbon
It is black.
Above-mentioned woodenware wipes color composition the bottom of with and preferably comprises the following raw material component in parts by weight：Water soluble hydroxy tree
10~20 parts of fat, 40~60 parts of solvent, 0.5~1 part of dispersant, 10~15 parts of filler, 5~10 parts of thickener, toner 5~15
Part, 0.2~1 part of anti skinning agent.
The molar percentage of hydroxyl is 6%~9% in the water soluble hydroxy resin in one of the embodiments,.
The dispersant is modified copolymer in one of the embodiments,.
The dispersant is high molecular weight modified acrylic acid terpolymer in one of the embodiments,.
The anti skinning agent is preferably diacetylmonoxime in one of the embodiments,.Thus it prevents from bottom of the present invention from wiping colour cell to close
There is skinning during preserving in object, and reduces product quality.
In one of the embodiments, the thickener be bentonite, aerosil, one kind in polyamide wax or
It is a variety of.
The filler is talcum powder and/or transparent powder in one of the embodiments,；The solvent is alkane solvents
And/or alcohol ethers solvent.The solvent is preferably dipropylene glycol monomethyl ether (DPM) or dipropylene glycol monomethyl ether (DPM) and alkane
The mixture of class solvent.
The present invention separately provides the preparation method that the woodenware wipes color composition the bottom of with, includes the following steps：
In the water soluble hydroxy resin, the addition part solvent adjustment viscosity is 200~350mpa.s；Then again
The dispersant is added, 500~800 turns/min of low speed stirs 5~10min；
The filler and the toner is sequentially added to obtain mixed after 1400~1800 turns/min of high speed stirs 10~15min
Close object, grinding；
Sequentially adding the remaining solvent and the anti skinning agent, 500~800 turns/min of low speed stirrings 5~
10min to get.
The method of the grinding is in one of the embodiments,：It is ground to filler described in the mixture and described
The fineness of toner is less than 30 μm.
The present invention also provides the woodenware coating process of bottom wiping color composition, include the following steps：
Obtain the plank for waiting for application；
Wiping color is carried out using the woodenware to the plank for waiting for application with bottom wiping color composition to handle, standing 2~
24h；
In spray-applied primer, process after progress on the wiping color treated plank, you can.
The principle of the present invention and advantage are as follows：
The present invention the study found that by water soluble hydroxy resin, is answered through a large number of experiments with other raw material components
It is configured to woodenware bottom and wipes color composition, bottom can be effectively improved and wipe adhesive force of the color product on plank, highlight the line of plank
Reason.
This is because the resin system containing certain hydroxyl used, good with having between the priming paint that is subsequently coated with
Compatibility, the two interpenetrate, and the adhesive force of color, while color uniformity are effectively improved using the sealing process of priming paint
It is good；In addition, water soluble hydroxy resin system can also penetrate into the gap of plank well, toner is effectively imported to the line of timber
In reason, color adhesive force is thus further increased, while highlighting the texture of plank.
In addition, the woodenware of the present invention is strong with bottom wiping color composition matching, can with aqueous priming paint or solvent bottom paint
It is good to be used cooperatively, realize said effect.
The stronger color adhesive force of color composition is wiped in view of the woodenware bottom of the present invention, therefore it can be creative in application
Omission wipe the priming paint painting process before color, direct woodenware using the present invention wipes the plank that color composition carries out bottom wiping color the bottom of with
During follow-up primer coating, the defects of uniform in color is not in delamination, plate grain understands, natural.
Further, other raw material groups such as dispersant, thickener, filler in color composition are wiped to woodenware of the present invention bottom
Point carry out preferred, coordinated with water soluble hydroxy resin, can optimum organization objects system physico-chemical property, make its Performance optimization
While, convenient for construction, it is suitble to large area operation.
Woodenware of the present invention wipes the preparation method of color composition the bottom of with, by rationally controlling charging sequence and technique item
Part, it is ensured that the performance of each raw material component performance, while method is simple, is convenient for technique application.
Woodenware of the present invention wipes the coating process of color composition, the creative priming paint coating being omitted before wiping color the bottom of with
Process reduces requirement of the coating process to technical staff, improves coating quality, while coating efficiency is high, at low cost.
Description of the drawings
Fig. 1 is to wipe the plank schematic diagram that color composition application obtains the bottom of with using 1 woodenware of embodiment；
Fig. 2 is schematic diagram of the above-mentioned plank after drawing lattice experiment.
Specific implementation mode
Color composition and preparation method thereof and coating process are wiped to the woodenware bottom of the present invention below in conjunction with specific embodiment
It is described in further detail.
Embodiment 1
A kind of 1 woodenware of embodiment wipes color composition the bottom of with, in parts by weight, including the following raw material component：
The molar percentage of hydroxyl is 6.8% in the water soluble hydroxy resin, purchased from German moral letter profit chemistry
(Worlee) modified soluble alkyd resin sol 30.
The solvent is DPM.
The dispersant is high molecular weight modified acrylic acid terpolymer, the VXW6208/60 purchased from special (Cytec) company of cyanogen.
The filler is transparent powder.
The thickener is bentonite.
The anti skinning agent is diacetylmonoxime.
Above-mentioned woodenware wipes the preparation method of color composition the bottom of with, includes the following steps：
In the water soluble hydroxy resin, the viscosity that the part solvent adjustment mixture is added is 320mpa.s, so
After add the dispersant, 500 turns/min of low speed stirs 10min；
The filler and the toner are sequentially added, after 1600 turns/min of high speed stirs 10min, milled mixtures fineness
Less than 30 μm；
Sequentially adding the remaining solvent and the anti skinning agent, 700 turns/min of low speed stirring 5min to get.
The coating process that color composition is wiped at above-mentioned woodenware bottom includes the following steps：
Obtain the Manchurian ash plank for waiting for application；
Color composition is wiped the bottom of with the Manchurian ash plank is carried out to wipe color processing, stand 2h using above-mentioned woodenware；
In spraying polyurethane (PU) transparent priming on the wiping color treated Manchurian ash plank, after routinely technique carries out
Process, you can.Gained plank is as shown in Figure 1, uniform in color, clean mark.
Embodiment 2
A kind of 2 woodenware of embodiment wipes color composition the bottom of with, in parts by weight, including the following raw material component：
The molar percentage of hydroxyl is 8.6% in the water soluble hydroxy resin, purchased from German moral letter profit chemistry
(Worlee) modified soluble alkyd resin sol 30.
The solvent is DPM.
The dispersant is high molecular weight modified acrylic acid terpolymer, the VXW6208/60 purchased from special (Cytec) company of cyanogen.
The filler is transparent powder.
The thickener is aerosil.
The anti skinning agent is diacetylmonoxime.
Above-mentioned woodenware wipes the preparation method of color composition the bottom of with, includes the following steps：
In the water soluble hydroxy resin, the viscosity that the part solvent adjustment mixture is added is 350mpa.s, so
After add the dispersant, 600 turns/min of low speed stirs 10min；
The filler and the toner are sequentially added, after 1600 turns/min of high speed stirs 15min, milled mixtures fineness
Less than 30 μm；
Sequentially adding the remaining solvent and the anti skinning agent, 600 turns/min of low speed stirring 5min to get.
The coating process that color composition is wiped at above-mentioned woodenware bottom includes the following steps：
Obtain the Manchurian ash plank for waiting for application；
Color composition is wiped the bottom of with the Manchurian ash plank is carried out to wipe color processing, stand for 24 hours using above-mentioned woodenware；
In spraying aqueous transparent priming paint on the wiping color treated Manchurian ash plank, process after routinely technique carries out,
.
Embodiment 3
A kind of 3 woodenware of embodiment wipes color composition the bottom of with, in parts by weight, including the following raw material component：
The molar percentage of hydroxyl is 8.6% in the water soluble hydroxy resin, purchased from German moral letter profit chemistry
(Worlee) modified soluble alkyd resin sol 30.
The solvent is DPM and alkane solvents mixture.
The dispersant is high molecular weight modified acrylic acid terpolymer, the VXW6208/60 purchased from special (Cytec) company of cyanogen.
The filler is talcum powder.
The thickener is polyamide wax.
The anti skinning agent is diacetylmonoxime.
Above-mentioned woodenware wipes the preparation method of color composition the bottom of with, includes the following steps：
In the water soluble hydroxy resin, the viscosity that the part solvent adjustment mixture is added is 250mpa.s, so
After add the dispersant, 500 turns/min of low speed stirs 5min；
The filler and the toner are sequentially added, after 1550 turns/min of high speed stirs 15min, milled mixtures fineness
Less than 30 μm；
Sequentially adding the remaining solvent and the anti skinning agent, 700 turns/min of low speed stirring 10min to get.
The coating process that color composition is wiped at above-mentioned woodenware bottom includes the following steps：
Obtain the Manchurian ash plank for waiting for application；
Color composition is wiped the bottom of with the Manchurian ash plank is carried out to wipe color processing, stand 10h using above-mentioned woodenware；
In spraying aqueous transparent priming paint on the wiping color treated Manchurian ash plank, process after routinely technique carries out,
.
Embodiment 4
A kind of 4 woodenware of embodiment wipes color composition the bottom of with, in parts by weight, including the following raw material component：
The molar percentage of hydroxyl is 8.6% in the water soluble hydroxy resin, purchased from German moral letter profit chemistry
(Worlee) modified soluble alkyd resin sol 30.
The solvent is DPM and alkane solvents mixture.
The dispersant is high molecular weight modified acrylic acid terpolymer, the VXW6208/60 purchased from special (Cytec) company of cyanogen.
The filler is talcum powder.
The thickener is polyamide wax.
The anti skinning agent is diacetylmonoxime.
Above-mentioned woodenware wipes the preparation method of color composition the bottom of with, includes the following steps：
In the water soluble hydroxy resin, the viscosity that the part solvent adjustment mixture is added is 320mpa.s, so
After add the dispersant, 600 turns/min of low speed stirs 7min；
The filler and the toner are sequentially added, after 1800 turns/min of high speed stirs 12min, milled mixtures fineness
Less than 30 μm；
Sequentially adding the remaining solvent and the anti skinning agent, 550 turns/min of low speed stirring 7min to get.
The coating process that color composition is wiped at above-mentioned woodenware bottom includes the following steps：
Obtain the Manchurian ash plank for waiting for application；
Color composition is wiped the bottom of with the Manchurian ash plank is carried out to wipe color processing, stand 15h using above-mentioned woodenware；
In spraying PU transparent primings on the wiping color treated Manchurian ash plank, process after routinely technique carries out, i.e.,
It can.
Comparative example 1
A kind of 1 woodenware of comparative example wipes color composition the bottom of with, raw material components and the preparation method is the same as that of Example 1, difference lies in：
The resin used is blows linseed oil, not hydroxyl.
Application is carried out according to 1 identical method of embodiment.
Comparative example 2
A kind of 2 woodenware of comparative example wipes color composition the bottom of with, raw material components and the preparation method is the same as that of Example 1, difference lies in：
The resin used is the aldehyde ketone resin of oiliness.
Application is carried out according to 1 identical method of embodiment.
The wood of embodiment 1-4 and comparative example 1-2 is painted using lattice experimental test procedures (reference standard GB/T 9286) are drawn
Performance after wiping color composition application the bottom of with is tested, and the results are shown in Table 1：
Table 1
In addition, plank of the embodiment 1 after drawing lattice experiment test illustrates plate as shown in Fig. 2, color texture is substantially unchanged
Material adhesive force is good.
Each technical characteristic of embodiment described above can be combined arbitrarily, to keep description succinct, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, it is all considered to be the range of this specification record.
Several embodiments of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. a kind of woodenware wipes color composition the bottom of with, which is characterized in that in parts by weight, including the following raw material component：
The molar percentage of hydroxyl is 5%~20% in the water soluble hydroxy resin.
2. woodenware according to claim 1 wipes color composition the bottom of with, which is characterized in that hydroxyl in the water soluble hydroxy resin
The molar percentage of base is 6%~9%.
3. woodenware according to claim 1 wipes color composition the bottom of with, which is characterized in that the dispersant is modified copolymer
Object.
4. woodenware according to claim 3 wipes color composition the bottom of with, which is characterized in that the dispersant changes for high molecular weight
Property acrylic copolymer.
5. wiping color composition according to claim 1-4 any one of them woodenware bottom, which is characterized in that the thickener is swollen
Moisten one or more in soil, aerosil, polyamide wax.
6. wiping color composition according to claim 1-4 any one of them woodenware bottom, which is characterized in that the anti skinning agent is
Diacetylmonoxime.
7. wiping color composition according to claim 1-4 any one of them woodenware bottom, which is characterized in that the filler is talcum
Powder and/or transparent powder；The solvent is alkane solvents and/or alcohol ethers solvent.
8. claim 1-7 any one of them woodenware wipes the preparation method of color composition the bottom of with, which is characterized in that including as follows
Step：
In the water soluble hydroxy resin, the addition part solvent adjustment viscosity is 200~350mpa.s；Then it adds
The dispersant, 500~800 turns/min of low speed stir 5~10min；
Sequentially adding the filler and the toner must mix after 1400~1800 turns/min of high speed stirs 10~15min
Object is ground；
The remaining solvent and the anti skinning agent are sequentially added, 500~800 turns/min of low speed stirs 5~10min, i.e.,
.
9. woodenware according to any one of claims 8 wipes the preparation method of color composition the bottom of with, which is characterized in that the method for the grinding
For：It is ground to the fineness of filler and the toner described in the mixture and is less than 30 μm.
10. claim 1-7 any one of them woodenware wipes the coating process of color composition the bottom of with, which is characterized in that including such as
Lower step：
Obtain the plank for waiting for application；
Color composition is wiped using claim 1-7 any one of them woodenware the bottom of with the plank for waiting for application wipe at color
Reason, standing 2~for 24 hours；
In primer coating, process after progress on the wiping color treated plank, you can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610579556.XA CN106010168B (en) | 2016-07-21 | 2016-07-21 | Woodenware wipes color composition and preparation method thereof and coating process the bottom of with |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610579556.XA CN106010168B (en) | 2016-07-21 | 2016-07-21 | Woodenware wipes color composition and preparation method thereof and coating process the bottom of with |
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| CN106010168A CN106010168A (en) | 2016-10-12 |
| CN106010168B true CN106010168B (en) | 2018-09-11 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108913028A (en) * | 2018-07-06 | 2018-11-30 | 东莞大宝化工制品有限公司 | glaze and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010114728A1 (en) * | 2009-03-30 | 2010-10-07 | Isp Investments Inc. | Penetrating uv-protecting compositions to protect wood and lignin |
| CN102363679A (en) * | 2011-06-30 | 2012-02-29 | 成都倍大涂料有限公司 | Water-soluble glaze and preparation method thereof |
| CN102504649A (en) * | 2011-11-08 | 2012-06-20 | 陈绍球 | Wooden ware surface colorizing agent and preparation method thereof |
| CN104046240A (en) * | 2014-07-02 | 2014-09-17 | 江苏海田技术有限公司 | Aqueous color-wrapping glaze base material and preparation method thereof |
-
2016
- 2016-07-21 CN CN201610579556.XA patent/CN106010168B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010114728A1 (en) * | 2009-03-30 | 2010-10-07 | Isp Investments Inc. | Penetrating uv-protecting compositions to protect wood and lignin |
| CN102363679A (en) * | 2011-06-30 | 2012-02-29 | 成都倍大涂料有限公司 | Water-soluble glaze and preparation method thereof |
| CN102504649A (en) * | 2011-11-08 | 2012-06-20 | 陈绍球 | Wooden ware surface colorizing agent and preparation method thereof |
| CN104046240A (en) * | 2014-07-02 | 2014-09-17 | 江苏海田技术有限公司 | Aqueous color-wrapping glaze base material and preparation method thereof |
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