CN106009997A - Flexible waterproof coating - Google Patents

Flexible waterproof coating Download PDF

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Publication number
CN106009997A
CN106009997A CN201610480570.4A CN201610480570A CN106009997A CN 106009997 A CN106009997 A CN 106009997A CN 201610480570 A CN201610480570 A CN 201610480570A CN 106009997 A CN106009997 A CN 106009997A
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CN
China
Prior art keywords
powder
parts
waterproof coating
flexible waterproof
liquid material
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Pending
Application number
CN201610480570.4A
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Chinese (zh)
Inventor
欧阳中卫
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Guangde Zhongwei New Materials Co Ltd
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Guangde Zhongwei New Materials Co Ltd
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Priority to CN201610480570.4A priority Critical patent/CN106009997A/en
Publication of CN106009997A publication Critical patent/CN106009997A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

A flexible waterproof coating is prepared from liquid and powder. The liquid is prepared from 90-100 parts of acrylic emulsion, 20-30 parts of distilled water, 3-6 parts of sodium pyrophosphate, 2-5 parts of polyoxyethylene polyoxypropylene pentaerythritol ether, 2-3 parts of 6-ethyoxyl-2,2,4-trimethyl-1,2-dihydroquinoline and 1-2 parts of para-phthalic sodium. The powder is prepared from 60-70 parts of portland cement, 20-25 parts of nano graphene, 20-25 parts of 200-300-mesh light calcium carbonate powder, 10-14 parts of 200-300-mesh tourmaline powder and 1-2 parts of water reducer. The flexible waterproof coating is high in binding force, active ingredients in the coating can permeate into pores and microcracks of a cement base face and generate a chemical reaction, the coating is integrated with the base face to form a dense crystal layer, the crystal layer can completely prevent water permeation, and the coating is good in flexibility, can resist slight vibration of a building base face and cover cracks generated due to thermal expansion and cold contraction, cracking, sinking and the like, can be directly constructed on the damp base face and is very good in adaptability.

Description

A kind of flexible waterproof coating
Technical field
The present invention relates to building water-proof paint field, be specifically related to a kind of flexible waterproof coating.
Background technology
Waterproof material is widely used in building materials protection field, uses water-repellent paint that building is carried out application After building can be isolated with external environment, be therefore prevented from because of the corrosive liquids such as rainwater, subsoil water and Dampness in air invades the corrosion that building material causes, and extends the service life of construction material.Waterproof Material mainly includes water-repellent paint and waterproof roll.Wherein, waterproof roll mainly have asphalt water-proof coiled material, Modified asphalt waterproof coiled material, high molecular polymer waterproof roll etc., waterproof coiled material construction complex process, and Requiring higher to workmen, therefore range of application is narrower, the existing waterproof material used mostly is water-repellent paint. The construction technology that use water-repellent paint carries out application is relatively simple, only water-repellent paint need to be coated on base material table Face, water-repellent paint solidify to form waterproof layer, and then makes to be applied object and water after being applied to substrate surface Environment is isolated, and plays protective action.Existing water-repellent paint mainly includes water-proof acrylic acid paint and gathers The polymer waterproof coating materials such as urethane water-repellent paint.Although this kind of coating construction is simple, but weatherability is poor, And the most easily ftracture, even depart from basic unit and lose waterproof effect.
Summary of the invention
The technical problem to be solved is to provide a kind of flexible waterproof coating, and water-repellent paint is stingless Swashing property abnormal smells from the patient, composition is soft, environmental protection, nontoxic, harmless, and cohesive force is strong, and the active component in coating can Penetrate into the pore of cement basal plane, micro-crack and produce chemical reaction, combining together with basal plane and form one The crystallizing layer that layer is fine and close, this crystallizing layer can completely waterproof infiltration, coating chemical resistance of the present invention, resistance to Aging, resistance to elevated temperatures are the most superior, and weatherability is very strong, and coating is flexible, can resist building base The slight vibrations in face, and can cover expand with heat and contract with cold, ftracture, the crack of the reason generation such as sinking, coating can Directly constructing on moisture substrate, adaptability is the best.
The technical problem to be solved realizes by the following technical solutions:
A kind of flexible waterproof coating, including: liquid material and powder, described liquid material and powder weight ratio be 1:2.1~ 2.3;
Described liquid material includes: acrylic emulsion 90-100 part, distilled water 20-30 part, sodium pyrophosphate 3-6 part, Polyoxyethylene polyoxypropylene tetramethylolmethane ether 2-5 part, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihydro Change quinoline 2-3 part, para-phthalic sodium 1-2 part;
Described powder includes: portland cement 60-70 part, nano-graphene 20-25 part, 200-300 mesh are light Matter calcium carbonate powder 20-25 part, 200-300 mesh tourmaline powder 10-14 part, water reducer 1-2 part.
Described water reducer is naphthalene sulfonic acid-formaldehyde condensation product.
The preparation method of described liquid material is as follows: first add acrylic emulsion in distilled water, after stirring, By mixed liquor freezing 30 minutes, re-heat the most again at a temperature of-20 DEG C, add sodium pyrophosphate, polyoxy second Alkene polyoxypropylene tetramethylolmethane ether, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline, to benzene Sodium diformate stirs, and obtains liquid material.
The preparation method of described powder is as follows: by portland cement, nano-graphene, 200-300 mesh lightweight Calcium carbonate powder, 200-300 mesh tourmaline powder, water reducer mixing and stirring, obtain powder.
The using method of a kind of flexible waterproof coating, comprises the steps:
(1) powder in the flexible waterproof coating described in Claims 1-4 any one is slowly added into In liquid material and be stirred continuously, until stirring into homogeneous paste and i.e. obtaining rubber cement without small particles or bubble;
(2) directly step (1) gained rubber cement is uniformly painted on basal plane with hairbrush or round brush, Rubber cement it is stirred continuously in smearing.
The invention has the beneficial effects as follows: water-repellent paint of the present invention has no irritating odor, and composition is soft, environmental protection, Nontoxic, harmless, cohesive force is strong, and the active component in coating can penetrate into the pore of cement basal plane, fine fisssure Stricture of vagina also produces chemical reaction, combines together with basal plane and forms one layer of fine and close crystallizing layer, this crystallizing layer energy Completely waterproof infiltration, coating chemical resistance of the present invention, resistance to ag(e)ing, resistance to elevated temperatures are the most superior, Weatherability is very strong, and coating is flexible, can resist the slight vibrations of building basal plane, and it is cold to cover flatulence of heat type Contract, ftracture, crack that the reason such as sinking produces, coating can directly construction on moisture substrate, adaptability The best.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of flexible waterproof coating, including: liquid material and powder, described liquid material and powder weight ratio are 1:2.2;
Described liquid material includes: acrylic emulsion 95kg, distilled water 25kg, sodium pyrophosphate 5kg, polyoxyethylene Polyoxypropylene tetramethylolmethane ether 4kg, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline 2kg, Para-phthalic sodium 1kg;
Described powder includes: portland cement 65kg, nano-graphene 22kg, 200-300 mesh lightweight carbonic acid Calcium powder 22kg, 200-300 mesh tourmaline powder 12kg, water reducer 1kg.
Described water reducer is naphthalene sulfonic acid-formaldehyde condensation product.
The preparation method of described liquid material is as follows: first add acrylic emulsion in distilled water, after stirring, By mixed liquor freezing 30 minutes, re-heat the most again at a temperature of-20 DEG C, add sodium pyrophosphate, polyoxy second Alkene polyoxypropylene tetramethylolmethane ether, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline, to benzene Sodium diformate stirs, and obtains liquid material.
The preparation method of described powder is as follows: by portland cement, nano-graphene, 200-300 mesh lightweight Calcium carbonate powder, 200-300 mesh tourmaline powder, water reducer mixing and stirring, obtain powder.
The using method of a kind of flexible waterproof coating, comprises the steps:
(1) powder in the flexible waterproof coating described in Claims 1-4 any one is slowly added into In liquid material and be stirred continuously, until stirring into homogeneous paste and i.e. obtaining rubber cement without small particles or bubble;
(2) directly step (1) gained rubber cement is uniformly painted on basal plane with hairbrush or round brush, Rubber cement it is stirred continuously in smearing.
Embodiment 2
A kind of flexible waterproof coating, including: liquid material and powder, described liquid material and powder weight ratio are 1:2.1;
Described liquid material includes: acrylic emulsion 90kg, distilled water 20kg, sodium pyrophosphate 3kg, polyoxyethylene Polyoxypropylene tetramethylolmethane ether 2kg, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline 2kg, Para-phthalic sodium 1kg;
Described powder includes: portland cement 70kg, nano-graphene 25kg, 200-300 mesh lightweight carbonic acid Calcium powder 25kg, 200-300 mesh tourmaline powder 14kg, water reducer 2kg.
Described water reducer is naphthalene sulfonic acid-formaldehyde condensation product.
The preparation method of described liquid material is as follows: first add acrylic emulsion in distilled water, after stirring, By mixed liquor freezing 30 minutes, re-heat the most again at a temperature of-20 DEG C, add sodium pyrophosphate, polyoxy second Alkene polyoxypropylene tetramethylolmethane ether, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline, to benzene Sodium diformate stirs, and obtains liquid material.
The preparation method of described powder is as follows: by portland cement, nano-graphene, 200-300 mesh lightweight Calcium carbonate powder, 200-300 mesh tourmaline powder, water reducer mixing and stirring, obtain powder.
The using method of a kind of flexible waterproof coating, comprises the steps:
(1) powder in the flexible waterproof coating described in Claims 1-4 any one is slowly added into In liquid material and be stirred continuously, until stirring into homogeneous paste and i.e. obtaining rubber cement without small particles or bubble;
(2) directly step (1) gained rubber cement is uniformly painted on basal plane with hairbrush or round brush, Rubber cement it is stirred continuously in smearing.
Embodiment 3
A kind of flexible waterproof coating, including: liquid material and powder, described liquid material and powder weight ratio are 1:2.3;
Described liquid material includes: acrylic emulsion 100kg, distilled water 30kg, sodium pyrophosphate 6kg, polyoxy second Alkene polyoxypropylene tetramethylolmethane ether 5kg, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline 3kg, Para-phthalic sodium 2kg;
Described powder includes: portland cement 70kg, nano-graphene 25kg, 200-300 mesh lightweight carbonic acid Calcium powder 25kg, 200-300 mesh tourmaline powder 14kg, water reducer 2kg.
Described water reducer is naphthalene sulfonic acid-formaldehyde condensation product.
The preparation method of described liquid material is as follows: first add acrylic emulsion in distilled water, after stirring, By mixed liquor freezing 30 minutes, re-heat the most again at a temperature of-20 DEG C, add sodium pyrophosphate, polyoxy second Alkene polyoxypropylene tetramethylolmethane ether, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline, to benzene Sodium diformate stirs, and obtains liquid material.
The preparation method of described powder is as follows: by portland cement, nano-graphene, 200-300 mesh lightweight Calcium carbonate powder, 200-300 mesh tourmaline powder, water reducer mixing and stirring, obtain powder.
The using method of a kind of flexible waterproof coating, comprises the steps:
(1) powder in the flexible waterproof coating described in Claims 1-4 any one is slowly added into In liquid material and be stirred continuously, until stirring into homogeneous paste and i.e. obtaining rubber cement without small particles or bubble;
(2) directly step (1) gained rubber cement is uniformly painted on basal plane with hairbrush or round brush, Rubber cement it is stirred continuously in smearing.
Test
The common coating of coating and market that the embodiment of the present invention 1,2,3 prepares carries out using test, test knot The most as shown in the table:
Be can be seen that by result of the test, performance of the present invention coating more common than market is superior.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (5)

1. a flexible waterproof coating, it is characterised in that including: liquid material and powder, described liquid material and powder Material weight ratio is 1:2.1~2.3;
Described liquid material includes: acrylic emulsion 90-100 part, distilled water 20-30 part, sodium pyrophosphate 3-6 part, Polyoxyethylene polyoxypropylene tetramethylolmethane ether 2-5 part, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihydro Change quinoline 2-3 part, para-phthalic sodium 1-2 part;
Described powder includes: portland cement 60-70 part, nano-graphene 20-25 part, 200-300 mesh are light Matter calcium carbonate powder 20-25 part, 200-300 mesh tourmaline powder 10-14 part, water reducer 1-2 part.
2. a kind of flexible waterproof coating as claimed in claim 1, it is characterised in that described water reducer is Naphthalene sulfonic acid-formaldehyde condensation product.
3. a kind of flexible waterproof coating as claimed in claim 1, it is characterised in that the system of described liquid material Preparation Method is as follows: first add acrylic emulsion in distilled water, after stirring, by mixed liquor at-20 DEG C At a temperature of freezing 30 minutes, re-heat the most again, add sodium pyrophosphate, polyoxyethylene polyoxypropylene season penta Four alcohol ethers, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline, para-phthalic sodium fully stir Mix uniformly, obtain liquid material.
4. a kind of flexible waterproof coating as claimed in claim 1, it is characterised in that the system of described powder Preparation Method is as follows: by portland cement, nano-graphene, 200-300 mesh light calcium carbonate powder, 200-300 Mesh tourmaline powder, water reducer mixing and stirring, obtain powder.
5. the using method of a flexible waterproof coating, it is characterised in that comprise the steps:
(1) powder in the flexible waterproof coating described in Claims 1-4 any one is slowly added into In liquid material and be stirred continuously, until stirring into homogeneous paste and i.e. obtaining rubber cement without small particles or bubble;
(2) directly step (1) gained rubber cement is uniformly painted on basal plane with hairbrush or round brush, Rubber cement it is stirred continuously in smearing.
CN201610480570.4A 2016-06-24 2016-06-24 Flexible waterproof coating Pending CN106009997A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106673570A (en) * 2017-01-09 2017-05-17 江苏中路交通科学技术有限公司 Waterproof and mold-proof self-cleaning flame-retardant paint for tunnel
CN107603313A (en) * 2017-11-07 2018-01-19 刘兴满 Pump shell spraying antirust paint
CN107674535A (en) * 2017-11-07 2018-02-09 邵莹 Bag type filtering machine mozzle external application antirust paint
CN107722779A (en) * 2017-11-07 2018-02-23 邵莹 Bag type filtering machine filter core antirust paint
CN107722778A (en) * 2017-11-07 2018-02-23 邵莹 High efficiency plate seals filter filter core antirust paint
CN108250868A (en) * 2018-01-17 2018-07-06 厦门力嘉诚防水工程有限公司 A kind of graphene Flexible waterproof paint
CN108250812A (en) * 2018-01-16 2018-07-06 厦门力嘉诚防水工程有限公司 A kind of universal water-repellent paint of graphene
CN108276910A (en) * 2018-01-30 2018-07-13 厦门力嘉诚防水工程有限公司 A kind of uncured modified pitch root resistance water-repellent paint of graphene
CN108384334A (en) * 2018-05-02 2018-08-10 厦门力嘉诚防水工程有限公司 A kind of graphene aqueous waterproofing paint
CN115710838A (en) * 2022-09-28 2023-02-24 南昌航空大学 Conductive super-hydrophobic cellulose paper and preparation method thereof

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CN104140728A (en) * 2014-08-08 2014-11-12 鳄鱼制漆(上海)有限公司 JS elastic waterproof coating
KR20160025263A (en) * 2014-08-27 2016-03-08 (주)삼성건업 Permeability waterproof stuff film and construction method of the same

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CN104140728A (en) * 2014-08-08 2014-11-12 鳄鱼制漆(上海)有限公司 JS elastic waterproof coating
KR20160025263A (en) * 2014-08-27 2016-03-08 (주)삼성건업 Permeability waterproof stuff film and construction method of the same

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106673570A (en) * 2017-01-09 2017-05-17 江苏中路交通科学技术有限公司 Waterproof and mold-proof self-cleaning flame-retardant paint for tunnel
CN107603313A (en) * 2017-11-07 2018-01-19 刘兴满 Pump shell spraying antirust paint
CN107674535A (en) * 2017-11-07 2018-02-09 邵莹 Bag type filtering machine mozzle external application antirust paint
CN107722779A (en) * 2017-11-07 2018-02-23 邵莹 Bag type filtering machine filter core antirust paint
CN107722778A (en) * 2017-11-07 2018-02-23 邵莹 High efficiency plate seals filter filter core antirust paint
CN108250812A (en) * 2018-01-16 2018-07-06 厦门力嘉诚防水工程有限公司 A kind of universal water-repellent paint of graphene
CN108250868A (en) * 2018-01-17 2018-07-06 厦门力嘉诚防水工程有限公司 A kind of graphene Flexible waterproof paint
CN108276910A (en) * 2018-01-30 2018-07-13 厦门力嘉诚防水工程有限公司 A kind of uncured modified pitch root resistance water-repellent paint of graphene
CN108384334A (en) * 2018-05-02 2018-08-10 厦门力嘉诚防水工程有限公司 A kind of graphene aqueous waterproofing paint
CN115710838A (en) * 2022-09-28 2023-02-24 南昌航空大学 Conductive super-hydrophobic cellulose paper and preparation method thereof

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Application publication date: 20161012