CN106009976B - A kind of nano-antibacterial interiro wall latex paint - Google Patents
A kind of nano-antibacterial interiro wall latex paint Download PDFInfo
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- CN106009976B CN106009976B CN201610342659.4A CN201610342659A CN106009976B CN 106009976 B CN106009976 B CN 106009976B CN 201610342659 A CN201610342659 A CN 201610342659A CN 106009976 B CN106009976 B CN 106009976B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- Engineering & Computer Science (AREA)
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Abstract
The invention discloses a kind of nano-antibacterial interiro wall latex paint, belong to architectural decoration material field.The present invention includes acrylate and vinyl acetate emulsion, organosilicon modified terpene resin, nano-carbon powder, titanium dioxide, filler, wetting agent, dispersant, defoamer, coalescents, the Chinese medicine sterilizing Aqueous extracts through decoloration；The Chinese medicine sterilizing Aqueous extracts are lopseed, Song Luo, Chenopodium glaucum L., radix ampelopsis, the Aqueous extracts of fushen.Organosilicon modified terpene resin adds the crack resistance of nano-antibacterial interiro wall latex paint in the present invention, while adds the hardness and glossiness of emulsion paint；Nano-carbon powder can eliminate electrostatic, be dispersed in emulsion paint.Chinese medicine antibacterial component is easily dispersed uniformly, the mutual compatibility of each Chinese medicine antibacterial component and synergy, antibacterial effect are splendid；Chinese medicine antibacterial component is safe to use.There is antibacterial, anlistatig effect at the same time, and crack resistance is good, hardness is high.
Description
Technical field
The present invention relates to architectural decoration material field, more particularly to a kind of nano-antibacterial interiro wall latex paint.
Background technology
In China, people are traditionally base-material synthetic resin emulsion, using water as decentralized medium, add pigment, filler（Also
Claim extender pigment）And auxiliary agent, through coating made of certain technical process, it is called emulsion paint, is also latex paint.
Emulsion paint is applied to metope outermost, and for decorated wall surface, but existing emulsion paint easily cracks and difference of hardness, has
Electrostatic, and anti-corrosion material used in existing emulsion paint includes the volatile hazardous substancess such as formaldehyde, benzene, ammonia more, and people are good for
Health brings harm.
The content of the invention
In order to make up for the deficiencies of the prior art, the present invention provides a kind of antibacterial, antistatic property are good, and crack resistance it is good,
The high nano-antibacterial interiro wall latex paint of hardness.
The technical scheme is that：
A kind of nano-antibacterial interiro wall latex paint, in parts by weight, including 200-300 parts of acrylate and vinyl acetate emulsions, 100-200 parts
Organosilicon modified terpene resin, 0.2-1 part nano-carbon powder, 60-120 parts of titanium dioxides, 200-300 parts of fillers, 2-10 parts of wetting agents,
8-20 parts of dispersants, 1-5 parts of defoamers, 10-20 parts of coalescents, the 100-200 parts of Chinese medicine sterilizing Aqueous extracts through decoloration；It is described
Chinese medicine sterilizing Aqueous extracts are lopseed, Song Luo, Chenopodium glaucum L., radix ampelopsis, fushen according to weight ratio 1:0.5-1:0.2-0.5:0.2-0.5:
1-2 is mixed, and then adds the water of 2-4 times of Chinese medicine gross weight, boils extraction 50-100 minutes, filters out gained Aqueous extracts after the dregs of a decoction.
Preferably, the filler is at least one of silicon dioxide powder, talcum powder, kaolin.
Preferably, the wetting agent is at least one of ethylene glycol or propane diols.In emulsion agent base of the present invention
On the premise of material determines, using ethylene glycol or propane diols as wetting agent, wetting agent dosage is few and wetting effect is good, reduces cost.
Preferably, the dispersant is at least one of alkylsulfonate, CPA dispersants.In breast of the invention
It is optimal using alkylsulfonate, CPA dispersants as dispersant, dispersion effect on the premise of jelly base-material determines.
Preferably, the defoamer is higher fatty acid ester.Before emulsion agent base-material of the present invention determines
Put, using higher fatty acid ester as defoamer, defoaming effect is good, and dosage is few, reduces cost.
Preferably, coalescents are propylene glycol methyl ether acetate.Acrylate and vinyl acetate emulsion and organosilicon modified terpene resin
During collectively as base-material, using propylene glycol methyl ether acetate as coalescents, dosage is few, and film-formation result is good.
Preferably, the nano-antibacterial interiro wall latex paint, in parts by weight, including 230-280 portions of vinegar third
Lotion, 130-180 part organosilicon modified terpene resin, 0.3-0.6 parts of nano-carbon powders, 80-100 parts of titanium dioxides, 230-280 parts fill out
Material, 4-8 parts of wetting agents, 10-15 parts of dispersants, 2-4 parts of defoamers, 13-18 parts of coalescents, 130-180 parts through in decoloration
Medicine sterilizing Aqueous extracts.
Preferably, the particle diameter of titanium dioxide and filler is 10-20 microns.
Beneficial effects of the present invention are：
The present invention emulsion paint in, acrylate and vinyl acetate emulsion and organosilicon modified terpene resin collectively as base-material, wherein, organosilicon
The addition of modified terpene resin adds the crack resistance of nano-antibacterial interiro wall latex paint, while adds the hardness and light of emulsion paint
Damp degree；Nano-carbon powder is dispersed in emulsion paint, has the function that to eliminate electrostatic.
Chinese medicine antibacterial component is easily dispersed uniformly, the mutual compatibility of each Chinese medicine antibacterial component and synergy, antibacterial effect pole
It is good；Chinese medicine antibacterial component is safe to use.
The environment-friendly type emulsion paint of the present invention easily forms a film, has antibacterial, anlistatig effect, and crack resistance is good, hardness is high.
Embodiment
Number in following embodiment is parts by weight.
Embodiment 1
A kind of nano-antibacterial interiro wall latex paint, including 260 parts of acrylate and vinyl acetate emulsions, 150 parts of organosilicon modified terpene resins, 0.6
Part nano-carbon powder, 90 parts of titanium dioxides（15 microns of particle diameter）, 260 parts of silicon dioxide powders（15 microns of particle diameter）, 6 parts of ethylene glycol, 10 parts
Sodium alkyl sulfonate, 5 parts of CPA dispersants, 3 parts of higher fatty acid esters, 15 parts of propylene glycol methyl ether acetates, 150 parts through decoloration
Chinese medicine sterilizing Aqueous extracts；The Chinese medicine sterilizing Aqueous extracts are lopseed, Song Luo, Chenopodium glaucum L., radix ampelopsis, fushen according to weight ratio 1:
0.7:0.3:0.3:1.5 mixing, then add the water of 3 times of Chinese medicine gross weights, boil extraction 60 minutes, filter out gained water after the dregs of a decoction
Extract.
The adhesion strength of the present embodiment nano-antibacterial interiro wall latex paint is 3.11Mpa, and attachment is uniform, and 3 years nothings are de- after construction
Layer phenomenon, has no any crackle；Have no mouldy；Antistatic property is good, and soundproof effect is good.
Embodiment 2
A kind of nano-antibacterial interiro wall latex paint, including 280 parts of acrylate and vinyl acetate emulsions, 120 parts of organosilicon modified terpene resins, 0.3
Part nano-carbon powder, 100 parts of titanium dioxides（10 microns of particle diameter）, 280 parts of talcum powder（10 microns of particle diameter）, 8 parts of ethylene glycol, 9 parts of alkyl
Sodium sulfonate, 5 parts of polyoxyethylene polyoxypropylene pentaerythrite ethers, 12 parts of propylene glycol methyl ether acetates, 180 parts of Chinese medicines through decoloration go out
Bacterium Aqueous extracts；The Chinese medicine sterilizing Aqueous extracts are lopseed, Song Luo, Chenopodium glaucum L., radix ampelopsis, fushen according to weight ratio 1:0.5: 0.5:
0.2:1 mixing, then adds the water of 4 times of Chinese medicine gross weights, boils extraction 100 minutes, filters out gained Aqueous extracts after the dregs of a decoction.
The adhesion strength of the present embodiment nano-antibacterial interiro wall latex paint is 2.97Mpa, and attachment is uniform, and 3 years nothings are de- after construction
Layer phenomenon, has no any crackle；Have no mouldy；Antistatic property is good, and soundproof effect is good.
Embodiment 3
A kind of nano-antibacterial interiro wall latex paint, including 220 parts of acrylate and vinyl acetate emulsions, 180 parts of organosilicon modified terpene resins, 0.8
Part nano-carbon powder, 70 parts of titanium dioxides（20 microns of particle diameter）, 220 parts of kaolin（20 microns of particle diameter）, 3 parts of propane diols, 8 parts of alkyl sulphurs
Sour sodium, 2 parts of higher fatty acid esters, 10 parts of propylene glycol methyl ether acetates, 160 parts of Chinese medicine sterilizing Aqueous extracts through decoloration；Institute
State that Chinese medicine sterilizing Aqueous extracts are lopseed, Song Luo, Chenopodium glaucum L., radix ampelopsis, fushen is according to weight ratio 1: 1:0.2: 0.5:2 mixing, so
The water of 2-4 times of Chinese medicine gross weight is added afterwards, boils extraction 50-100 minutes, filters out gained Aqueous extracts after the dregs of a decoction.
The adhesion strength of the present embodiment nano-antibacterial interiro wall latex paint is 2.91Mpa, and attachment is uniform, and 3 years nothings are de- after construction
Layer phenomenon, has no any crackle；Have no mouldy；Antistatic property is good, and soundproof effect is good.
Embodiment 4
A kind of nano-antibacterial interiro wall latex paint, including 300 parts of acrylate and vinyl acetate emulsions, 100 parts of organosilicon modified terpene resins, 1 part
Nano-carbon powder, 60 parts of titanium dioxides（15 microns of particle diameter）, 200 parts of silicon dioxide powders（15 microns of particle diameter）, 100 parts of talcum powder（Particle diameter
15 microns）, 1 part of ethylene glycol, 1 part of propane diols, 20 parts of CPA dispersants, 1 part of higher fatty acid ester, 20 parts of propandiol butyl ethers,
100 parts of Chinese medicine sterilizing Aqueous extracts through decoloration；Chinese medicine sterilizing Aqueous extracts are lopseed, Song Luo, Chenopodium glaucum L., radix ampelopsis, fushen press
According to weight ratio 1:0.6:0.4:0.4:1.2 mixing, then add the water of 2 times of Chinese medicine gross weights, boil extraction 50 minutes, filter out medicine
Gained Aqueous extracts after slag.
The adhesion strength of the present embodiment nano-antibacterial interiro wall latex paint is 3.02Mpa, and attachment is uniform, and 3 years nothings are de- after construction
Layer phenomenon, has no any crackle；Have no mouldy；Antistatic property is good, and soundproof effect is good.
Embodiment 5
A kind of nano-antibacterial interiro wall latex paint, including 200 parts of acrylate and vinyl acetate emulsions, 200 parts of organosilicon modified terpene resins, 0.2
Part nano-carbon powder, 60 parts of titanium dioxides（15 microns of particle diameter）, 100 parts of talcum powder（15 microns of particle diameter）, 100 parts of kaolin（Particle diameter 15
Micron）, 2 parts of ethylene glycol, 8 parts of CPA dispersants, 1 part of higher fatty acid ester, 10 parts of propylene glycol methyl ether acetates, 100 parts of warps
The Chinese medicine sterilizing Aqueous extracts of decoloration；The Chinese medicine sterilizing Aqueous extracts are lopseed, Song Luo, Chenopodium glaucum L., radix ampelopsis, fushen according to weight ratio
1:0.8:0.3:0.3:1.6 mixing, then add the water of 3 times of Chinese medicine gross weights, boil extraction 70 minutes, filter out gained after the dregs of a decoction
Aqueous extracts.
The adhesion strength of the present embodiment nano-antibacterial interiro wall latex paint is 3.05Mpa, and attachment is uniform, and 3 years nothings are de- after construction
Layer phenomenon, has no any crackle；Have no mouldy；Antistatic property is good, and soundproof effect is good.
Comparative example 1
A kind of nano-antibacterial interiro wall latex paint, including 260 parts of acrylate and vinyl acetate emulsions, 150 parts of organosilicon modified terpene resins, 0.6
Part nano-carbon powder, 90 parts of titanium dioxides（15 microns of particle diameter）, 260 parts of silicon dioxide powders（15 microns of particle diameter）, 6 parts of ethylene glycol, 10 parts
Sodium alkyl sulfonate, 5 parts of CPA dispersants, 3 parts of higher fatty acid esters, 15 parts of propylene glycol methyl ether acetates, 150 parts of water.
The adhesion strength of this comparative example nano-antibacterial interiro wall latex paint is 3.07Mpa, and attachment is uniform, and 3 years nothings are de- after construction
Layer phenomenon, has no any crackle；There is mouldy situation within 1 year after construction；Antistatic property is good, and soundproof effect is good.
Humiture is same as Example 1 after execution conditions and construction.
Comparative example 2
A kind of nano-antibacterial interiro wall latex paint, including 410 parts of acrylate and vinyl acetate emulsions, 0.6 part of nano-carbon powder, 90 parts of titanium dioxides（Grain
15 microns of footpath）, 260 parts of silicon dioxide powders（15 microns of particle diameter）, 6 parts of ethylene glycol, 10 parts of sodium alkyl sulfonates, 5 parts of CPA dispersants, 3
Part higher fatty acid ester, 15 parts of propylene glycol methyl ether acetates, 150 parts of Chinese medicines sterilizing Aqueous extracts through decoloration；The Chinese medicine
Sterilizing Aqueous extracts are lopseed, Song Luo, Chenopodium glaucum L., radix ampelopsis, fushen according to weight ratio 1:0.7:0.3:0.3:1.5 mixing, Ran Houjia
Enter the water of 3 times of Chinese medicine gross weights, boil extraction 60 minutes, filter out gained Aqueous extracts after the dregs of a decoction.
The adhesion strength of this comparative example nano-antibacterial interiro wall latex paint is 2.61Mpa, adheres to more uniform, a year and a half after construction
It was found that delamination and crackle；Have no mouldy；Antistatic property is good, and soundproof effect is good.
Humiture is same as Example 1 after execution conditions and construction.
Claims (4)
- A kind of 1. nano-antibacterial interiro wall latex paint, it is characterised in that：In parts by weight, including 200-300 parts of acrylate and vinyl acetate emulsions, 100-200 parts of organosilicon modified terpene resins, 0.2-1 parts of nano-carbon powders, 60-120 parts of titanium dioxides, 200-300 parts of fillers, 2-10 Part wetting agent, 8-20 parts of dispersants, 1-5 parts of defoamers, 10-20 parts of coalescents, the 100-200 parts of Chinese medicine aqua sterilisas through decoloration Extract；The Chinese medicine sterilizing Aqueous extracts are lopseed, Song Luo, Chenopodium glaucum L., radix ampelopsis, fushen according to weight ratio 1:0.5-1:0.2-0.5: 0.2-0.5:1-2 is mixed, and then adds the water of 2-4 times of Chinese medicine gross weight, boils extraction 50-100 minutes, filters out gained after the dregs of a decoction Chinese medicine sterilizing Aqueous extracts；The wetting agent is at least one of ethylene glycol or propane diols；The dispersant for alkylsulfonate, At least one of CPA dispersants；The defoamer is higher fatty acid ester；The coalescents are propylene glycol monomethyl ether vinegar Acid esters.
- 2. nano-antibacterial interiro wall latex paint as claimed in claim 1, it is characterised in that：The filler is silicon dioxide powder, talcum At least one of powder, kaolin.
- 3. nano-antibacterial interiro wall latex paint as claimed in claim 1, it is characterised in that：In parts by weight, including 230-280 Part acrylate and vinyl acetate emulsion, 130-180 parts of organosilicon modified terpene resins, 0.3-0.6 parts of nano-carbon powders, 80-100 parts of titanium dioxides, 230- 280 parts of fillers, 4-8 parts of wetting agents, 10-15 parts of dispersants, 2-4 parts of defoamers, 13-18 parts of coalescents, 130-180 parts of warps are de- The Chinese medicine sterilizing Aqueous extracts of color.
- 4. the nano-antibacterial interiro wall latex paint as described in claim any one of 1-3, it is characterised in that：The grain of titanium dioxide and filler Footpath is 10-20 microns.
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| CN106590307A (en) * | 2016-12-19 | 2017-04-26 | 江西宜信堂医疗科技有限公司 | Antibacterial waterproof paint and preparation method thereof |
| CN107446393A (en) * | 2017-09-21 | 2017-12-08 | 苏州振振好新型建材科技有限公司 | A kind of environmentally friendly radiation proof interiro wall latex paint |
| CN107383989A (en) * | 2017-09-21 | 2017-11-24 | 苏州振振好新型建材科技有限公司 | A kind of exterior wall heat preservation water proof anti-crack mastic powder |
| CN107502123A (en) * | 2017-09-21 | 2017-12-22 | 苏州振振好新型建材科技有限公司 | A kind of preparation method of environmentally friendly radiation proof interiro wall latex paint |
| CN109082172A (en) * | 2018-08-09 | 2018-12-25 | 安徽欧尚制漆有限公司 | A kind of preparation method of dual mildew-proof latex paint |
| CN109777213A (en) * | 2019-03-07 | 2019-05-21 | 南京淳彩建材有限公司 | A kind of dirt-resistant self-cleaning emulsion paint and preparation method thereof |
| CN112608684A (en) * | 2020-12-10 | 2021-04-06 | 西洞庭凯兴建材有限公司 | Processing method of antibacterial harmless latex paint for interior decoration |
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| CN101245207A (en) * | 2007-02-16 | 2008-08-20 | 朱庆成 | Inner wall paint |
| CN104592841A (en) * | 2014-12-30 | 2015-05-06 | 三棵树涂料股份有限公司 | Inorganic antibacterial formaldehyde-removing paint and preparation method thereof |
| CN105111858A (en) * | 2015-08-06 | 2015-12-02 | 天长市巨龙车船涂料有限公司 | Fruit peel and pearl powder containing high-quality healthy interior latex wall paint and preparation method therefor |
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