CN106007811A - Preparation method of microcrystalline diamond ceramic brick - Google Patents
Preparation method of microcrystalline diamond ceramic brick Download PDFInfo
- Publication number
- CN106007811A CN106007811A CN201610358021.XA CN201610358021A CN106007811A CN 106007811 A CN106007811 A CN 106007811A CN 201610358021 A CN201610358021 A CN 201610358021A CN 106007811 A CN106007811 A CN 106007811A
- Authority
- CN
- China
- Prior art keywords
- preparation
- ceramic tile
- microcrystalline diamond
- brick
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011449 brick Substances 0.000 title claims abstract description 46
- 239000000919 ceramic Substances 0.000 title claims abstract description 28
- 239000010432 diamond Substances 0.000 title claims abstract description 20
- 229910003460 diamond Inorganic materials 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 238000010304 firing Methods 0.000 claims abstract description 13
- 238000005498 polishing Methods 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 238000009966 trimming Methods 0.000 claims abstract description 7
- 238000007688 edging Methods 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 210000003298 dental enamel Anatomy 0.000 claims description 10
- 238000007639 printing Methods 0.000 claims description 5
- 230000003373 anti-fouling effect Effects 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 230000035515 penetration Effects 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 5
- 230000009471 action Effects 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000010431 corundum Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Finishing Walls (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
Abstract
The invention relates to the technical filed of building ceramics, in particular to a preparation method of a microcrystalline diamond ceramic brick. The preparation method comprises the following steps: 1) mixing and pressing raw materials for a green base brick into the green base brick; 2) applying surface glaze inside the surface of the green base brick; 3) performing inkjet and glaze penetration on the surface glaze to make a pattern; 4) applying a layer of diamond glaze on the surface of the pattern and then coating the periphery with a circle of transparent glaze; 5) firing in a kiln; 6) preparing a finished product through polishing, trimming and edging after firing. The microcrystalline diamond ceramic brick prepared by the preparation method has a thinner surface microcrystalline layer and is good in wear resistance and good in anti-fouling property.
Description
Technical field
The present invention relates to building dress ceramic technology field, in particular to the preparation side of a kind of microcrystalline diamond ceramic tile
Method.
Background technology
Pottery is applied to building trade more and more, and Ceramic Tiles product is widely used in communal facility, building trade
And in family.Along with the raising of modern architecture ceramic building material finishing requirements, there is the building of the characteristics such as lithotome fashion, noble quality
Ceramic microcrystalline diamond ceramic tile is increasingly used widely.
Although tradition microlite ceramic tile has sparkling and crystal-clear soft and moist, a brilliant decorative effect in plate face, but surface glaze layer glass
Xiang Duo, Mohs' hardness is relatively low, easily scratches.
Although the most traditional microlite ceramic tile solves pattern variation, color is more bright-coloured, svelteness, but production technology
Upper glassy layer is thicker is easily generated pore, and its antifouling property difference and production cost are higher.
Summary of the invention
It is an object of the invention to provide the preparation method of a kind of microcrystalline diamond ceramic tile, to solve the microcrystalline diamond of preparation
Ceramic tile top layer microcrystalline coating is thicker, the most wear-resisting, the problem of antifouling difference.
For realizing the purpose of the present invention, the technical scheme of employing is:
The preparation method of a kind of microcrystalline diamond ceramic tile, comprises the following steps:
1) mixing of base brick adobe raw material will be used for and be pressed into base brick adobe；
2) charity cover-coat enamel in base brick adobe surface；
3) on cover-coat enamel, colored printing pattern is oozed in ink-jet；
4) at one layer of Buddha's warrior attendant glaze of described surface profile charity, then clear frit is enclosed in surrounding charity one；
5) klining system is entered；
6) after polishing, trimming, edging, prepare finished product after firing.
Preferably, in described step 1), compacting is the press compacting using tonnage more than 1000 tons.
Preferably, at the base brick adobe marginal surface that described step 1) prepares, surrounding has regular groove.
Preferably, inside described groove, base brick adobe surface edge becomes flat.
Preferably, described groove distance base brick adobe edge 5-30mm, described recess width is 0.5 3cm, the degree of depth is 0.2
−3mm。
Preferably, described step 4) charity Buddha's warrior attendant glaze and clear frit also can use 2200 tons of press compactings to fill flat.
Preferably, described step 5) is once fired in kiln and is completed through two stages, and first stage firing temperature is
1150-1180 DEG C, second stage 1200-1350 DEG C.
The method have the benefit that
One, ink-jet is used to ooze flower, it is achieved that pattern variation, texture is more rich, and color development is more bright-coloured, and tone is distincter.
Two, full wafer brick texture is more perfect, and the effect of use is more preferable, and the corundum that surface charity contains 350-1000 mesh is transparent
Glaze, i.e. forms Buddha's warrior attendant glaze, and Buddha's warrior attendant glazed thickness is less than 1mm, and the clear frit layer thickness of edge, at 1-3mm, decreases the glass in brick face
Glass phase, is added with corundum and improves Mohs' hardness and the abrasion resistance of product, transparent in adobe surrounding flaky process charity again
Glaze, has the most i.e. saved raw material, makes its surface have the brick face texture of microlite simultaneously and side is apparent thicker microcrystalline coating,
Improve the mullite crystalline phase of product surface and do not affect the sparkling and crystal-clear penetrating texture effect in brick face.
Three, the present invention use adobe compacting use great tonnage press, make adobe compacting after the closeest tightly, glaze layer is also adopted simultaneously
Compressing compacting with press, then the temperature being equipped with the different gradient of later stage employing is fired, final products bubble-free produces, and surface only needs one
Secondary polishing, the small rut of generation is few, and therefore it also has the best soil resistance, all keeps gloss for a long time after using
Degree, cleaning is convenient.
Four, being formed around groove during adobe compacting, trimming is convenient, uses same clear frit bed material, top layer and four simultaneously
The glaze layer contact position in week does not haves lamination, reaches to be perfectly combined.
Five, the ceramic tile using the present invention to prepare, in the case of original process performance parameters does not reduces, has saved materials,
Reduce cost.
Accompanying drawing explanation
Fig. 1 is the top view of base brick adobe.
Fig. 2 is the sectional view of base brick adobe.
Detailed description of the invention
As shown in Figure 1, 2, use press that adobe is pressed into the brick adobe of structure base shown in Fig. 21, which is provided with groove 2,
Filling clear frit in groove 2, the base brick adobe surface inside groove 2 is sequentially provided with cover coat 3, printed layer 4 and Buddha's warrior attendant glaze layer 5,
Inside groove, adobe surface edge uses flat, later stage cutting rear side viewing can form the process of a gradual change, promote aesthetic feeling.
Design groove 1 also within it fills clear frit, and post-production is cut in groove 1 vertical direction, and such upper strata shows as micro-
Crystal layer, lower floor shows as base layer at the bottom of ceramic tile.
Embodiment 1
The preparation method of a kind of microcrystalline diamond ceramic tile, comprises the following steps:
1) will be used for the mixing of base brick adobe raw material, the press using tonnage to be 1000 tons is pressed into base brick adobe, base brick adobe table
Face edge surrounding has regular groove, and inside groove, base brick adobe surface edge becomes flat, groove distance base brick adobe edge
5mm, recess width is 0.5cm, the degree of depth is 0.2mm；
2) charity cover-coat enamel in base brick adobe surface, plays decoration and bottom buffer action；
3) on cover-coat enamel, colored printing pattern is oozed in ink-jet；
4) at one layer of Buddha's warrior attendant glaze of described surface profile charity, then enclose clear frit in surrounding charity one, after charity, use 2200 tons of pressures
Buddha's warrior attendant glaze and clear frit compacting are filled flat by machine；
5) entering klining system, once fire and complete through two stages in kiln, first stage firing temperature is 1150 DEG C, second-order
Section 1200 DEG C；
6) after polishing, trimming, edging, prepare finished product after firing.
Embodiment 2
The preparation method of a kind of microcrystalline diamond ceramic tile, comprises the following steps:
1) will be used for the mixing of base brick adobe raw material, the press using tonnage to be 8000 tons is pressed into base brick adobe, base brick adobe table
Face edge surrounding has regular groove, and inside groove, base brick adobe surface edge becomes flat, groove distance base brick adobe Surface Edge
Portion 15mm, recess width is 1.5cm, the degree of depth is 0.9mm；
2) charity cover-coat enamel in base brick adobe surface, plays decoration and bottom buffer action；
3) on cover-coat enamel, colored printing pattern is oozed in ink-jet；
4) at one layer of Buddha's warrior attendant glaze of described surface profile charity, then enclose clear frit in surrounding charity one, after charity, use 2200 tons of pressures
Buddha's warrior attendant glaze and clear frit compacting are filled flat by machine；
5) entering klining system, once fire and complete through two stages in kiln, first stage firing temperature is 1165 DEG C, second-order
Section 1290 DEG C；
6) after polishing, trimming, edging, prepare finished product after firing.
Embodiment 3
The preparation method of a kind of microcrystalline diamond ceramic tile, comprises the following steps:
1) will be used for the mixing of base brick adobe raw material, the press using tonnage to be 9000 tons is pressed into base brick adobe, base brick adobe table
Face edge surrounding has regular groove, and inside groove, base brick adobe surface edge becomes flat, groove distance base brick adobe Surface Edge
Portion 30mm, recess width is 3cm, the degree of depth is 3mm；
2) charity cover-coat enamel in base brick adobe surface, plays decoration and bottom buffer action；
3) on cover-coat enamel, colored printing pattern is oozed in ink-jet；
4) at one layer of Buddha's warrior attendant glaze of described surface profile charity, then enclose clear frit in surrounding charity one, after charity, use 2200 tons of pressures
Buddha's warrior attendant glaze and clear frit compacting are filled flat by machine；
5) entering klining system, once fire and complete through two stages in kiln, first stage firing temperature is 1180 DEG C, second-order
Section 1350 DEG C；
6) after polishing, trimming, edging, prepare finished product after firing.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved according to the above description or to convert, all these modifications and variations all should belong to the guarantor of claims of the present invention
Protect scope.
Claims (7)
1. the preparation method of a microcrystalline diamond ceramic tile, it is characterised in that: comprise the following steps:
1) mixing of base brick adobe raw material will be used for and be pressed into base brick adobe；
2) charity cover-coat enamel in base brick adobe surface；
3) on cover-coat enamel, colored printing pattern is oozed in ink-jet；
4) at one layer of Buddha's warrior attendant glaze of described surface profile charity, then clear frit is enclosed in surrounding charity one；
5) klining system is entered；
6) after polishing, trimming, edging, prepare finished product after firing.
The preparation method of microcrystalline diamond ceramic tile the most according to claim 1, it is characterised in that: in described step 1), compacting is
Use the tonnage press compacting more than more than 1000 tons.
The preparation method of microcrystalline diamond ceramic tile the most according to claim 1, it is characterised in that: the base that described step 1) prepares
Regular groove is had at brick adobe marginal surface.
The preparation method of microcrystalline diamond ceramic tile the most according to claim 3, it is characterised in that: base brick brick inside described groove
Flat is become at base marginal surface.
The preparation method of microcrystalline diamond ceramic tile the most according to claim 3, it is characterised in that: described groove distance base brick brick
Base edge 5-30mm, described recess width is 0.5 3cm, the degree of depth is 0.2 3mm.
The preparation method of microcrystalline diamond ceramic tile the most according to claim 1, it is characterised in that: described step 4) charity Buddha's warrior attendant
Glaze and clear frit use 2200 tons of press compactings to fill flat.
The preparation method of microcrystalline diamond ceramic tile the most according to claim 1, it is characterised in that: described step 5) is in kiln one
Secondary firing completed through two stages, and first stage firing temperature is 1150-1180 DEG C, second stage 1200-1350 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610358021.XA CN106007811B (en) | 2016-05-26 | 2016-05-26 | A kind of preparation method of microcrystalline diamond ceramic tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610358021.XA CN106007811B (en) | 2016-05-26 | 2016-05-26 | A kind of preparation method of microcrystalline diamond ceramic tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106007811A true CN106007811A (en) | 2016-10-12 |
| CN106007811B CN106007811B (en) | 2018-10-23 |
Family
ID=57094079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610358021.XA Expired - Fee Related CN106007811B (en) | 2016-05-26 | 2016-05-26 | A kind of preparation method of microcrystalline diamond ceramic tile |
Country Status (1)
| Country | Link |
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| CN (1) | CN106007811B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111848224A (en) * | 2020-07-22 | 2020-10-30 | 佛山欧神诺陶瓷有限公司 | Ceramic tile with metal flickering effect and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329135A (en) * | 2011-09-30 | 2012-01-25 | 广东东鹏陶瓷股份有限公司 | Production method capable of firing polished crystal tile in one step |
| CN104311162A (en) * | 2014-10-11 | 2015-01-28 | 德清诺贝尔陶瓷有限公司 | Bump texture glazed tile and preparation method thereof |
| CN105272375A (en) * | 2015-10-29 | 2016-01-27 | 佛山市中成硅酸盐科技有限公司 | Wear resistant and high-hardness diamond glaze, preparation method and application |
-
2016
- 2016-05-26 CN CN201610358021.XA patent/CN106007811B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329135A (en) * | 2011-09-30 | 2012-01-25 | 广东东鹏陶瓷股份有限公司 | Production method capable of firing polished crystal tile in one step |
| CN104311162A (en) * | 2014-10-11 | 2015-01-28 | 德清诺贝尔陶瓷有限公司 | Bump texture glazed tile and preparation method thereof |
| CN105272375A (en) * | 2015-10-29 | 2016-01-27 | 佛山市中成硅酸盐科技有限公司 | Wear resistant and high-hardness diamond glaze, preparation method and application |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111848224A (en) * | 2020-07-22 | 2020-10-30 | 佛山欧神诺陶瓷有限公司 | Ceramic tile with metal flickering effect and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN106007811B (en) | 2018-10-23 |
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| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method of microcrystalline diamond ceramic brick Effective date of registration: 20181205 Granted publication date: 20181023 Pledgee: Jiajiang County Branch of Agricultural Bank of China Ltd. Pledgor: SICHUAN XINWANXING PORCELAIN CO.,LTD. Registration number: 2018510000132 |
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Date of cancellation: 20220630 Granted publication date: 20181023 Pledgee: Jiajiang County Branch of Agricultural Bank of China Ltd. Pledgor: SICHUAN XINWANXING PORCELAIN CO.,LTD. Registration number: 2018510000132 |
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| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of microcrystalline diamond ceramic tile Effective date of registration: 20220708 Granted publication date: 20181023 Pledgee: Jiajiang County Branch of Agricultural Bank of China Ltd. Pledgor: SICHUAN XINWANXING PORCELAIN CO.,LTD. Registration number: Y2022980010172 |
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