CN106006562B - A kind of Portable chlorine dioxide generator and its application method - Google Patents
A kind of Portable chlorine dioxide generator and its application method Download PDFInfo
- Publication number
- CN106006562B CN106006562B CN201610508931.1A CN201610508931A CN106006562B CN 106006562 B CN106006562 B CN 106006562B CN 201610508931 A CN201610508931 A CN 201610508931A CN 106006562 B CN106006562 B CN 106006562B
- Authority
- CN
- China
- Prior art keywords
- piston
- reative cell
- reserve room
- chlorine dioxide
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/20—Gaseous substances, e.g. vapours
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/22—Phase substances, e.g. smokes, aerosols or sprayed or atomised substances
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/10—Apparatus features
- A61L2202/11—Apparatus for generating biocidal substances, e.g. vaporisers, UV lamps
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/10—Apparatus features
- A61L2209/13—Dispensing or storing means for active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Abstract
The invention discloses a kind of Portable chlorine dioxide generator and its application method, generator mainly includes generator body, with quantity regulating device, pressue device and sprayer unit；Moved with quantity regulating device by one-way piston and air is pressed into generator body, force the interface channel opened between reative cell and the first reserve room and the second reserve room, allowed stoste to enter reative cell according to set proportion and react, generate sterilizable gas and liquid；Air is pressed into reative cell by pressue device by way of one-way piston motion, is increased the pressure in reative cell, sterilizing gas and liquid is sprayed in a high voltage state；Sprayer unit is connected with reative cell, and the gases at high pressure in reative cell and liquid are formed into the vaporific ejection of high pressure by shower nozzle.The structure of the present invention is simple, easy-to-operate, by continuous operation quantity regulating device make generator rapidly, constantly produce sterilizing gas and liquid, disinfection efficiency can be significantly improved, simplify disinfecting process, save disinfecting time.
Description
Technical field
The present invention relates to field of disinfecting equipment, more particularly to it is a kind of it is safe and reliable, can Fast Persistence produce titanium dioxide
Chlorine, portable chlorine dioxide generator and the method to be carried out disinfection using the generator.
Background technology
Chlorine dioxide is not only a kind of wide spectrum, efficient bactericidal agent, and is a kind of safe and nontoxic disinfectant.It is domestic
Outer many results of study show that chlorine dioxide is under extremely low concentration (0.1ppm), you can kill such as Escherichia coli, golden yellow
Many pathogenic bacteria such as color staphylococcus.Under the interference of organic matter, in the slightly higher ppm rank concentration of concentration,
All microorganisms such as bacterial propagule, hepatitis viruse, bacteriophage and bacterial spore can be killed completely.Simultaneously in disinfecting process
Chlorination does not occur with organic matter and produce the organic chloride or other with " three-induced effect " (carcinogenic, teratogenesis, mutagenesis)
Poisonous class material.But because chlorine dioxide has extremely strong oxidability, should avoid in high concentration (>500ppm) make for a long time
With.When concentration is less than 500ppm, its influence to human body can be ignored, and human body will not be produced during below 100ppm and appointed
What influence, including the influence in terms of Physiology and biochemistry.To skin also without any sensitization.In fact, chlorine dioxide is normal
Advising concentration will be well below 500ppm, normally only in more than ten of ppm rank.Therefore, chlorine dioxide is also generally acknowledged in the world
For safe and nontoxic green disinfectant.Meanwhile in China since the eighties, successively by different regions health supervision department
Ratify it and can be used for food sterilization, fresh-keeping and food apparatus, equipment disinfection.
At present, there are many chlorine dioxide preparation methods and technology, but because chlorine dioxide meets strong light, heat, Qiang Zhen
Explosive decomposition is swung, chlorine dioxide typically exists with liquid or solid state stability, but chlorine dioxide is gas under normal temperature.And due to
The processing cost that liquefies is expensive, and the chlorine dioxide for causing these technologies to be prepared does not find cheap technology storage also and used.It is existing
There are chlorine dioxide Antibody Production Techniques to be generally the chlorine dioxide preparation method of now-making-now-using, particularly high-purity and suddenly treat that one kind is steady
Fixed chlorine dioxide preservation method.
Because Liquid chlorine dioxide solution or solid-state chloride dioxide corrosion inhibiter are generally not with single Chlorine Dioxide Molecules
In the presence of its disinfection effect is poor compared with gaseous chlorine dioxide effect, while gaseous chlorine dioxide unit mass sterilizing area
Width, so it is preferable to be typically used for Disinfection Effect using gaseous chlorine dioxide.
The content of the invention
, can be fast it is an object of the invention to overcome the deficiencies of the prior art and provide a kind of simple in construction, safe operation
Speed, the portable generator for persistently producing chlorine dioxide.
Another object of the present invention is to overcome the deficiencies in the prior art, there is provided one kind uses above-mentioned chlorine dioxide generator
The operating method to carry out disinfection.
The purpose of the present invention is achieved through the following technical solutions：
A kind of Portable chlorine dioxide generator, it is main to include using generator body made of light-proof material, be used for
Regulation stoste reaction dosage is sprayed with quantity regulating device, the pressue device for increasing reaction chamber pressure and for atomizing the liquid into
The sprayer unit gone out.
Specifically, the generator body includes reative cell, the first check valve, the second check valve and is arranged on reaction
The first reserve room and the second reserve room above room.First reserve room is located in the second reserve room, passes through resistant material
Separated with the second reserve room.The bottom of first reserve room is connected by the first check valve with reative cell, second deposit
The bottom of room is connected by the second check valve with reative cell.First piston, second deposit are provided with first reserve room
Interior is provided with second piston, and the first reserve room and the second reserve room are divided into the first liquid storage by the first piston and second piston
Chamber, the first air storing cavity and the second liquid storage cylinder, the second air storing cavity.First air storing cavity and the second air storing cavity are respectively positioned at the first storage
The top of sap cavity and the second liquid storage cylinder, and the first air storing cavity and the connection of the second air storing cavity, it is therefore, same with the gas of quantity regulating device
When be pressed into the first air storing cavity and the second air storing cavity.As another preferred scheme, first air storing cavity and the second air storing cavity can
To be set to same air storing cavity, the structure that can simplify generator body is so set, reduces manufacture difficulty, and improve generator
The arrangement mechanical property of body.
Preferably, the generator body also includes being used for the piston position for controlling first piston and second piston while declining
Put control rod.The piston position control rod is fixedly connected with first piston and second piston respectively.Due to the first reserve room with
The flow that second reserve room enters reative cell has been set, therefore, it is necessary to controls first piston and second piston synchronous in the same direction
Athleticism ensures that the set-mounted dosage of two kinds of stostes carries out highly effective reaction.
Specifically, described be filled with air by pipeline with quantity regulating device into the first air storing cavity and the second air storing cavity, make
First piston and second piston synchronously move downward, the dosage by the stoste in the first reserve room and the second reserve room according to setting
It is expressed to reative cell and carries out hybrid reaction.The pressue device is connected by pipeline with reative cell, for increasing in reative cell
Pressure.The sprayer unit is connected by pipeline with reative cell, and sterilizing gas caused by reaction and liquid atomization are sprayed.
Specifically, described include first piston cylinder, first band handle one-way piston and the first Non-return air valve with quantity regulating device.
The first piston cylinder is arranged on generator body, is connected by the first Non-return air valve and the first air storing cavity and the second air storing cavity
It is logical.The first band handle one-way piston is arranged in first piston cylinder, and the gas list in first piston cylinder is made by operation handle
To the first air storing cavity of inflow and the second air storing cavity.Because the pressure in the first air storing cavity and the second air storing cavity constantly increases, driving
First piston and second piston are moved downward, and the stoste in the first reserve room and the second reserve room is expressed in reative cell instead
Should.
Opened specifically, the pressue device includes second piston cylinder, the second band handle one-way piston, airway tube and atomization pressure head
Close.The second band handle one-way piston is arranged in second piston cylinder, and its operating side and atomization pressure head switch are be hinged.Described second
Piston cylinder is fixed on generator body, and its bottom is provided with the second Non-return air valve, and the second Non-return air valve passes through airway tube and reaction
Room connects.The atomization pressure head is connected with sprayer unit, by operating atomization pressure head switch by the air pressure in second piston cylinder
Enter reative cell, increase the pressure in reative cell, and open sprayer unit.
Specifically, the sprayer unit includes spraying body, the 3rd piston, the 4th piston, aerosol conduit and connecting conduit.
One end of the spraying body is fixed on generator body, is connected with one end of connecting conduit, the other end is provided with liquid mist
The shower nozzle of change, the other end of connecting conduit connect with reative cell.One end of the aerosol conduit is connected with the 4th piston, the other end
It is connected with shower nozzle.3rd piston connects with atomization pressure head switch, and relative with the 4th piston, forms extruding liquids and gases
Variable cavity (piston of atomization pressure head switch drive the 3rd can cause the 3rd piston closer or far from the 4th piston, this process
Air between the 4th piston becomes big or reduced, and the gas in the cavity and liquid is sprayed by compression), connecting conduit
One end connected with variable cavity, by operate atomization pressure head switch, the gas in reative cell and liquid is passed through connecting conduit
Variable cavity is flowed into, and drives the 3rd piston variable compression cavity, gas and liquid is atomized from shower nozzle and sprays.
As the preferred scheme of the present invention, the pressue device also includes the back-moving spring for resetting atomization pressure head switch.
The back-moving spring is inserted on the second band handle one-way piston, and its one end abuts with atomization pressure head switch, the other end and second piston
Cylinder abuts, and driving atomization pressure head switch resets upwards.After being atomized pressure head switch and pushing, the second band handle one-way piston is by air pressure
Enter reative cell, increase the pressure of reative cell, meanwhile, back-moving spring driving atomization pressure head switch resets upwards, prepares next time
Push.This is simple in construction, easy to use, saves artificial the step of being lifted up being atomized pressure head switch.
Further, the sprayer unit also includes rotary type L-shaped pipe, triple valve and drainage switch.The L-shaped pipe
One end is connected with the first port of triple valve, and the other end is put in reative cell.The second port of the connecting conduit and triple valve
Connection, the drainage switch are arranged on the 3rd port of triple valve.Make the gas of connecting conduit and reative cell by rotating L-shaped pipe
Body or fluid connection.When rotating the entrance of L-shaped pipe upward, because entrance is higher than the liquid level of reative cell, therefore there was only the inside
Sterilizing gas enters connecting conduit；When entering mouth down of L-shaped pipe of rotation, because entrance is less than the liquid level of reative cell, therefore, disappear
Venom body enters connecting conduit, and after liquid level is less than the entrance of L-shaped pipe, sterilizing gas enters connecting conduit, the entrance court of L-shaped pipe
It can be carried out down selecting gas depoisoning or liquid disinfection according to the actual conditions of sterilization, this is simple in construction, easy to operate, safety
Reliably, it is applied widely.In addition, when needing to pour out the liquid in reative cell, drainage switch, tilt generator body are opened
, this is simple in construction, easy to operate.
As the preferred scheme of the present invention, the structure of first check valve and the second check valve is consistent, by valve element and
Stage clip is formed, and described extension spring one end is fixed on reative cell bottom, and the other end is connected with valve element, and valve element is clogged to the stoste of reative cell
Entrance.Under default situations, the first check valve and the second check valve are by reative cell and the passage of the first reserve room and the second reserve room
Close, after gas is pressed into generator body with quantity regulating device, the stoste in the first reserve room and the second reserve room
Pressure increases, and reative cell progress hybrid reaction is flowed into after overcoming the resistance of the first check valve and the second check valve；Because stoste subtracts
Few, the pressure in the first reserve room and the second reserve room also decreases, when stoste insufficient pressure with overcome the first check valve and
During the resistance of the second check valve, the first check valve and the second check valve automatically close passage, have blocked the supplement of stoste.The knot
Structure is reasonable in design, easy to operate, it is not necessary to manual intervention.
As the preferred scheme of the present invention, because EDTA is a kind of weak acid, solubility is low, and disodium EDTA
It is EDTA sodium salt, as both effects here, but the solubility of disodium EDTA is big, can dissolve more
Chlorine dioxide, therefore, the present invention can also replace the EDTA aqueous solution using disodium EDTA.
The ratio between preferred scheme, the cross-sectional area of first reserve room and the second reserve room as the present invention is 1：1
To 4：1.The scope defines both sides reason：One contributes to reduce difficulty of processing, and ratio is smaller, and difficulty of processing is got over
Greatly；Second, avoiding producing excessive chlorine dioxide, make the excessive concentration of disinfectant in reative cell, chlorine dioxide can not be completely molten
Solution can cause internal pressure excessive, therefore the suitably increase of both ratios is helped to dilute caused chlorine dioxide, subtract
The pressure of light reative cell.
As the preferred scheme of the present invention, the resistant material can use polyvinyl chloride (PVC), polyphenylene sulfide
(PPS) one or more combinations and in pi (PI) material are made.Due to polyvinyl chloride (PVC), polyphenylene sulfide
(PPS) and the resistant material such as pi (PI) is neither with acid reaction, is not also reacted with strong oxidizer, and price is with respect to it
His resistant material is cheap, it is ensured that manufacturing cost is reduced in the case of performance and structural strength, obtains higher cost performance.
The invention also discloses a kind of method to be carried out disinfection using Portable chlorine dioxide generator, including following step
Suddenly：
Step S1:According to reaction coefficient relation, reactant is adjusted according to the amount of substance proportional to reactive chemistry stoichiometric number
Proportional concentration, and be separately stored in two storing solutions；
Step S2:First band handle one-way piston is operated repeatedly, makes the injection of the stoste of the first reserve room and the second reserve room anti-
Room is answered to carry out hybrid reaction；
Step S3:Gently vibrate or rock sterilizer；
Step S5:Regulation L-shaped pipe enters mouth down or upward；
Step S6:Repeatedly operation atomization pressure head switch by generation can sterilizing gas and/or liquid sprayed from shower nozzle.
Working process and principle of the invention are：Filled the invention mainly comprises generator body, with quantity regulating device, pressurization
Put and sprayer unit；Moved with quantity regulating device by one-way piston and air is pressed into generator body, opened instead so as to force
The interface channel between room and the first reserve room and the second reserve room is answered, allows two kinds of stostes to enter reative cell according to set proportion
Reaction, generates sterilizable gas and liquid；Air is pressed into by pressue device again by the mode that one-way piston moves to react
Room, the pressure in reative cell is increased with this, sterilizing gas and the liquid is sprayed in a high voltage state；Sprayer unit and reative cell
Connection, the gases at high pressure in reative cell and liquid are formed into the vaporific ejection of high pressure by shower nozzle.The structure of the present invention is simple, operation
Safe ready, by continuous operation quantity regulating device make generator rapidly, constantly produce sterilizing gas and liquid, can be with
Disinfection efficiency is significantly improved, simplifies disinfecting process, saves disinfecting time.
Compared with prior art, the present invention has further the advantage that：
(1) present invention uses the dosage in the form of piston that can easily control stoste to enter reative cell with quantity regulating device,
Enable reaction is quick, efficient, lasting to carry out, continuously spray disinfectant work can be carried out.
(2) present invention is using the chlorine dioxide that can be produced after two kinds of stoste hybrid reactions for sterilization, the gas
It as a kind of high effect disinfectants, can both be carried out disinfection by way of spraying the gas, one can also be reacted by mixed liquor
The chlorine dioxide that low concentration extraction raffinate after the section time slowly discharges is carried out disinfection, and both of which does not interfere with to be made next time
With the change in concentration of caused chlorine dioxide.
(3) present invention is pressurized using pressue device to reative cell, makes sterilised liq and gas after sprayer unit
High speed atomisation sprays, and spraying range is wide, speed is fast, effect is good.
(4) generator body of the invention is made of lighttight material, avoids the first reserve room and the second reserve room
Interior stoste chemically reacts after running into sunshine, causes the property of stoste to change, and reduces the growing amount of chlorine dioxide.
(5) chlorine dioxide generator provided by the present invention may be reused, and can produce lasting chlorine dioxide
Body.
Brief description of the drawings
Fig. 1 is the structural representation of Portable chlorine dioxide generator provided by the present invention.
Fig. 2 is the partial enlarged drawing of Portable chlorine dioxide generator provided by the present invention.
Fig. 3 is the partial enlarged drawing of sprayer unit provided by the present invention and reative cell junction.
Fig. 4 is the structural representation of the first check valve and the second check valve provided by the present invention.
Fig. 5 is structural representation when the first check valve and the second check valve provided by the present invention are opened.
Label declaration in above-mentioned accompanying drawing：
100- generator bodies, 110- reative cells, the reserve room of 120- first, the reserve room of 130- second, 140- first are unidirectional
Valve, 141- valve elements, 142- stage clips, the check valves of 150- second, 160- first pistons, 170- second pistons, 180- piston position controls
Rod processed；
200- quantity regulating devices, 210- first piston cylinders, 220- first band handle one-way pistons, the first unidirectional gas of 230-
Valve；
300- pressue devices, 310- second piston cylinders, 320- second is with handle one-way piston, 330- airway tubes, 340- atomizations
Pressure head switchs, the Non-return air valves of 350- second, 360- back-moving springs；
400- sprayer units, 410- spraying bodys, the pistons of 420- the 3rd, the pistons of 430- the 4th, 440- aerosol conduits, 450-
Connecting conduit, 460- shower nozzles, 470-L shape pipes, 480- triple valves, 490- drainage switches.
Embodiment
To make the objects, technical solutions and advantages of the present invention clearer, clear and definite, develop simultaneously embodiment pair referring to the drawings
The present invention is described further.
It is main to include occurring using made of light-proof material the invention discloses a kind of Portable chlorine dioxide generator
Device body 100, for adjust stoste reaction dosage with quantity regulating device 200, for increase the pressure of reative cell 110 pressurization fill
Put 300 and for atomizing the liquid into the sprayer unit 400 of ejection.
Specifically, as shown in figure 1, the generator body 100 includes reative cell 110, first the 140, second list of check valve
To valve 150 and the first reserve room 120 and the second reserve room 130 that are arranged on above reative cell 110.In first reserve room 120
Equipped with the first storing solution, the second reserve room 130 is built with the second storing solution.First reserve room 120 is located at the second reserve room
In 130, separated by resistant material and the second reserve room 130.The bottom of first reserve room 120 passes through the first check valve
140 are connected with reative cell 110, and the bottom of second reserve room 130 is connected by the second check valve 150 with reative cell 110.Institute
To state and be provided with first piston 160 in the first reserve room 120, second reserve room 130 is interior to be provided with second piston 170, and described first
First reserve room 120 and the second reserve room 130 are divided into the first liquid storage cylinder, the first air storing cavity by piston 160 and second piston 170
With the second liquid storage cylinder, the second air storing cavity.First air storing cavity and the second air storing cavity are respectively positioned at the first liquid storage cylinder and the second storage
The top of sap cavity, and the first air storing cavity and the connection of the second air storing cavity, therefore, it is pressed into the simultaneously with the gas of quantity regulating device 200
One air storing cavity and the second air storing cavity.
As another preferred scheme, first air storing cavity and the second air storing cavity can be set to same air storing cavity, this
Sample sets the structure that can simplify generator body 100, reduces manufacture difficulty, and improve the arrangement mechanics of generator body 100
Performance.
Preferably, the generator body 100 also includes being used to control first piston 160 and second piston 170 with present
The piston position control rod 180 of drop.The piston position control rod 180 is fixed with first piston 160 and second piston 170 respectively
Connection.Because the first reserve room 120 and the flow of the second reserve room 130 entrance reative cell 110 have been set, therefore, it is necessary to
Control first piston 160 and second piston 170, which are synchronized with the movement, just can guarantee that the set-mounted dosage of two kinds of stostes carries out height
Validity response.
Specifically, described be filled with air by pipeline with quantity regulating device 200 into the first air storing cavity and the second air storing cavity,
First piston 160 and second piston 170 is set synchronously to move downward, by the stoste in the first reserve room 120 and the second reserve room 130
Dosage according to setting is expressed to reative cell 110 and carries out hybrid reaction.The pressue device 300 passes through pipeline and reative cell 110
Connection, for increasing the pressure in reative cell 110.The sprayer unit 400 is connected by pipeline with reative cell 110, will be reacted
Caused sterilizing gas and liquid atomization sprays.
Specifically, with reference to shown in Fig. 1 and Fig. 2, it is described to include first piston cylinder 210, first band handle with quantity regulating device 200
The Non-return air valve 230 of one-way piston 220 and first.The first piston cylinder 210 is arranged on generator body 100, passes through first
Non-return air valve 230 connects with the first air storing cavity and the second air storing cavity.The first band handle one-way piston 220 is arranged on first piston
In cylinder 210, the gas unidirectional in first piston cylinder 210 is set to flow into the first air storing cavity and the second air storing cavity by operation handle.By
Constantly increase in the pressure in the first air storing cavity and the second air storing cavity, drive first piston 160 and second piston 170 to transport downwards
It is dynamic, the stoste in the first reserve room 120 and the second reserve room 130 is expressed in reative cell 110 and reacted.
Specifically, with reference to shown in Fig. 1 and Fig. 2, it is unidirectional that the pressue device 300 includes the band handle of second piston cylinder 310, second
Piston 320, airway tube 330 and atomization pressure head switch 340.The second band handle one-way piston 320 is arranged on second piston cylinder 310
Interior, its operating side and atomization pressure head switch 340 are be hinged.The second piston cylinder 310 is fixed on generator body 100, its bottom
Portion is provided with the second Non-return air valve 350, and the second Non-return air valve 350 is connected by airway tube 330 with reative cell 110.The atomization pressure
Head is connected with sprayer unit 400, and the air in second piston cylinder 310 is pressed into reative cell by operating atomization pressure head switch 340
110, increase the pressure in reative cell 110, and open sprayer unit 400.
Specifically, with reference to shown in Fig. 1 and Fig. 2, the sprayer unit 400 includes spraying body 410, the 3rd piston 420, the
Four pistons 430, aerosol conduit 440 and connecting conduit 450.One end of the spraying body 410 is fixed on generator body 100
On, connected with one end of connecting conduit 450, the other end is provided with the shower nozzle 460 atomized the liquid into, the other end of connecting conduit 450
Connected with reative cell 110.One end of the aerosol conduit 440 is connected with the 4th piston 430, and the other end is connected with shower nozzle 460.Institute
State the 3rd piston 420 340 be connected with atomization pressure head switch, and relative with the 4th piston 430, form extrude liquids and gases can
Becoming cavity, (the 3rd piston 420 of driving of atomization pressure head switch 340 can cause the 3rd closer or far from the 4th piston 430, this process
Air between the piston 430 of piston 420 and the 4th becomes big or reduced, and the gas in the cavity and liquid is sprayed by compression
Go out), one end of connecting conduit 450 connects with variable cavity, by operating atomization pressure head switch 340, makes the gas in reative cell 110
Body and liquid flow into variable cavity by connecting conduit 450, and drive the variable compression cavity of the 3rd piston 420, make gas and liquid
Body is atomized from shower nozzle 460 to be sprayed.
As the preferred scheme of the present invention, the pressue device 300 also includes the reset for resetting atomization pressure head switch 340
Spring 360.The back-moving spring 360 is inserted on the second band handle one-way piston 320, and its one end abuts with atomization pressure head switch 340,
The other end abuts with second piston cylinder 310, and driving atomization pressure head switch 340 resets upwards.When atomization pressure head switch 340 pushes
Afterwards, air is pressed into reative cell 110 by the second band handle one-way piston 320, increases the pressure of reative cell 110, meanwhile, back-moving spring
360 driving atomization pressure heads switches 340 reset upwards, prepare pushing next time.This is simple in construction, easy to use, saves people
The step of work is lifted up being atomized pressure head switch 340.
Further, as shown in Figure 1, Figure 2 and Figure 3, the sprayer unit 400 also includes rotary type L-shaped pipe 470, three
Port valve 480 and drainage switch 490.One end of the L-shaped pipe 470 is connected with the first port of triple valve 480, and the other end is put in instead
Answer in room 110.The connecting conduit 450 connects with the second port of triple valve 480, and the drainage switch 490 is arranged on threeway
On 3rd port of valve 480.Make the gas or fluid connection of connecting conduit 450 and reative cell 110 by rotating L-shaped pipe 470.When
When rotating the entrance of L-shaped pipe 470 upward, because entrance is higher than the liquid level of reative cell 110, therefore the sterilizing gas of only the inside enters
Enter connecting conduit 450；When entering mouth down of L-shaped pipe 470 of rotation, because entrance is less than the liquid level of reative cell 110, therefore, disappear
Venom body enters connecting conduit 450, and after liquid level is less than the entrance of L-shaped pipe 470, sterilizing gas enters connecting conduit 450, L-shaped
Pipe 470 enters mouth down and can be carried out selecting gas depoisoning or liquid disinfection according to the actual conditions of sterilization, and this is simple in construction,
It is easy to operate, it is securely and reliably, applied widely.In addition, when needing to pour out the liquid in reative cell 110, open draining and open
490 are closed, tilt generator body 100, this is simple in construction, easy to operate.
As the preferred scheme of the present invention, with reference to shown in Fig. 1, Fig. 4 and Fig. 5, first check valve 140 and second is unidirectional
The structure of valve 150 is consistent, is formed by valve element 141 and stage clip 142, and described extension spring one end is fixed on the bottom of reative cell 110, another
End is connected with valve element 141, and valve element 141 is clogged to the stoste entrance of reative cell 110.Under default situations, the first check valve 140 and
Two check valves 150 close the passage of the reserve room 120 of reative cell 110 and first and the second reserve room 130, when with quantity regulating device
After gas is pressed into generator body 100 by 200, the stoste pressure in the first reserve room 120 and the second reserve room 130 increases
Greatly, the progress hybrid reaction of reative cell 110 is flowed into after overcoming the resistance of the first check valve 140 and the second check valve 150；Due to stoste
Reduce, the pressure in the first reserve room 120 and the second reserve room 130 also decreases, when stoste insufficient pressure to overcome first
During the resistance of the check valve 150 of check valve 140 and second, the first check valve 140 and the second check valve 150 automatically close passage,
The supplement of stoste is blocked.This is reasonable in design, easy to operate, it is not necessary to manual intervention.
The ratio between preferred scheme, the cross-sectional area of first reserve room and the second reserve room as the present invention is 1：1
To 4：1.The scope defines both sides reason：One contributes to reduce difficulty of processing, and ratio is smaller, and difficulty of processing is got over
Greatly；Second, avoiding producing excessive chlorine dioxide, make the excessive concentration of disinfectant in reative cell, chlorine dioxide can not be completely molten
Solution can cause internal pressure excessive, therefore the suitably increase of both ratios is helped to dilute caused chlorine dioxide, subtract
The pressure of light reative cell.
As the preferred scheme of the present invention, the resistant material can use polyvinyl chloride (PVC), polyphenylene sulfide
(PPS) one or more combinations and in pi (PI) material are made.Due to polyvinyl chloride (PVC), polyphenylene sulfide
(PPS) and the resistant material such as pi (PI) is neither with acid reaction, is not also reacted with strong oxidizer, and price is with respect to it
His resistant material is cheap, it is ensured that manufacturing cost is reduced in the case of performance and structural strength, obtains higher cost performance.
The invention also discloses a kind of method to be carried out disinfection using Portable chlorine dioxide generator, including following step
Suddenly：
Step S1:According to reaction coefficient relation, reactant is adjusted according to the amount of substance proportional to reactive chemistry stoichiometric number
Proportional concentration, and be separately stored in two storing solutions；
Step S2:First band handle one-way piston 220 is operated repeatedly, makes the original of the first reserve room 120 and the second reserve room 130
Liquid injection reative cell 110 carries out hybrid reaction；
Step S3:Gently vibrate or rock sterilizer；
Step S5:Regulation L-shaped pipe 470 enters mouth down or upward；
Step S6:Repeatedly operation atomization pressure head switch 340 by generation can sterilizing gas and/or liquid sprayed from shower nozzle 460
Go out.
Because disinfecting substance caused by the present invention has gas and liquid, therefore, the operation side of sterilised liq is used during sterilization
Method is as follows：
First, the material solution of two kinds of certain concentration is being injected according to reactive chemistry stoichiometric number ratio in reserve room；Then,
Stretch manually and compress first band handle one-way piston more than 220 times so that solution certain volume is than injection reative cell in reserve room
110；Then, somewhat gently vibrate or rock generator body 100；Then, adjusting L-shaped pipe 470 makes it enter mouth down；Finally,
The closure and open configuration of repetitive control atomization pressure head switch 340, you can injection liquefied substance in required sterilised object surface, as
Surface disinfection acts on.
The operating method to be carried out disinfection using sterilizing gas is as follows：
First, the material solution of metered proportions concentration is being injected according to reaction principle in reserve room；Then, stretching manually
First band handle one-way piston more than 220 times so that solution is with certain volume ratio injection reative cell 110 in reserve room；Then, somewhat gently
Gently vibrate or rock generator body 100；After a period of time, the entrance of regulation L-shaped pipe 470 is upward；Finally, atomization pressure head is pressed to open
Close 340, you can in required sterilised object surface, unclamping atomization pressure head can close continuous injection chlorine dioxide.
Working process and principle of the invention are：The invention mainly comprises generator body 100, with quantity regulating device 200,
Pressue device 300 and sprayer unit 400；Moved with quantity regulating device 200 by one-way piston and air is pressed into generator body
100, interface channel between the reserve room 120 of reative cell 110 and first and the second reserve room 130 is opened so as to force, allows two kinds
Stoste is reacted into reative cell 110 according to set proportion, generates sterilizable gas and liquid；Pressue device 300 is equally logical
Air is pressed into reative cell 110 by the mode for crossing one-way piston motion, is increased the pressure in reative cell 110 with this, is made sterilization gas
Body and liquid spray in a high voltage state；Sprayer unit 400 connects with reative cell 110, by the gases at high pressure in reative cell 110 and
Liquid forms the vaporific ejection of high pressure by shower nozzle 460.The structure of the present invention is simple, easy-to-operate, is used by operating continuously
Quantity regulating device 200 make generator rapidly, constantly produce sterilizing gas and liquid, disinfection efficiency can be significantly improved, letter
Change disinfecting process, save disinfecting time.
The first storing solution mentioned by the present invention preferably uses the EDTA aqueous solution, and the aqueous solution is by absorbing other chemistry instead
Chlorine dioxide caused by answering, form the ClO 2 solution of stable high concentrations.Second storing solution using ferric ion or
The aqueous solution of zinc ion, such as ferric sulfate, iron chloride, zinc sulfate solution.First storing solution and the second storing solution are separately stored in
, it is necessary to it is pushed into when using reative cell 110 in two reserve room, two storing solutions are mixed in reative cell 110, react generation
Chlorine dioxide simultaneously is used to sterilize.
The chlorine dioxide raw material of the high concentration of chlorine dioxide aqueous solution involved in the present invention passes through sodium chlorite and salt
Acid reaction is made, and the chemical equation of the reaction is as follows：
5NaClO2+ 4HCl=4ClO2+5NaCl+2H2O formulas 1
Gas purity by the chlorine dioxide of the technique productions is high, and chlorine dioxide is passed directly into saturation EDTA water
Absorbed in solution, you can obtain the stable high concentration of chlorine dioxide aqueous solution (the EDTA aqueous solution).Due to the titanium dioxide of 20 volumes
Chlorine can be dissolved in the water of 1 volume, while EDTA can form coordinate bond to Chlorine Dioxide Molecules, and due to the formation of complex compound, significantly
Stability and solubility of the chlorine dioxide in water are increased, makes chlorine dioxide sustainedly and stably soluble in water.During reaction,
Ferric ion or zinc ion in second storing solution can be from EDTA with being captured in chlorine dioxide complex by Ligand Competition
Part, so as to discharge chlorine dioxide.Therefore, the second storing solution is using ferric sulfate or (such as Fe2 of zinc sulfate
(SO4) 3, ZnSO4) aqueous solution helps to activate the first storing solution, and it is quick, continue, efficiently produce chlorine dioxide, simultaneously should
Chlorine dioxide generator is also a kind of safe and environment-friendly, easily sterilizer.In addition, because EDTA is a kind of weak acid, dissolving
Spend low, and disodium EDTA is EDTA sodium salt, as both effects here, but disodium ethylene diamine tetraacetate
The solubility of salt is big, can dissolve more chlorine dioxides, and therefore, the present embodiment can also use ethylenediamine tetra-acetic acid two
Sodium salt replaces the EDTA aqueous solution.
Embodiment 1：
Under normal temperature, the disodium ethylene diamine tetra-acetic acid aqueous solution 100ml that mass fraction is 10% nearly saturation is prepared, and sub- chlorine
The gas that sour sodium is prepared with hydrochloric acid reaction method is passed through the EDTA aqueous solution and the absorbing liquid is placed in the first reserve room after 30 minutes
120, it is another to prepare 0.05mol/L Fe2(SO4)3Aqueous solution 100ml is placed in the second reserve room 130, stretches repeatedly manually, pushes the
One band handle one-way piston more than 220 times, shake sterilizer gently, then pressing atomization pressure head switch 340 repeatedly in the short time, you can
So that thimerosal is sprayed at required processing object surface with spray film state, disinfective action is realized.
Embodiment 2：
Under normal temperature, prepare the disodium ethylene diamine tetra-acetic acid aqueous solution 100ml that mass fraction is 8%, and sodium chlorite and
Gas prepared by hydrochloric acid reaction method is passed through the EDTA aqueous solution and the absorbing liquid is placed in the first reserve room 120 after 30 minutes, separately matches somebody with somebody
0.1mol/L ZnSO processed4Aqueous solution 100ml is placed in the second reserve room 130, stretches repeatedly manually, pushing first band handle is unidirectionally lived
Fill in more than 220 times, shake sterilizer gently, then in the short time repeatedly pressing atomization pressure head switch 340, you can so that thimerosal with
Spray film state handles object surface needed for being sprayed at, and realizes disinfective action.
Embodiment 3：
Under normal temperature, the disodium ethylene diamine tetra-acetic acid aqueous solution 100ml that mass fraction is 10% nearly saturation is prepared, and sub- chlorine
The gas that sour sodium is prepared with hydrochloric acid reaction method is passed through the EDTA aqueous solution and the absorbing liquid is placed in the first reserve room after 30 minutes
120, it is another to prepare 0.1mol/L Fe2(SO4)3Aqueous solution 100ml is placed in the second reserve room 130, stretches repeatedly manually, pushes first
Band handle one-way piston more than 220 times, shake sterilizer gently, a period of time press hand pressure atomization pressure head switch (after 20 minutes)
340, you can so that thimerosal is sprayed at required processing object surface with spray film state, realize disinfective action.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. a kind of Portable chlorine dioxide generator, it is characterised in that filled including generator body, with quantity regulating device, pressurization
Put and sprayer unit；
The generator body include reative cell, the first check valve, the second check valve and be arranged on above reative cell first
Reserve room and the second reserve room；First reserve room is located in the second reserve room, passes through resistant material and the second reserve room
Separate, the bottom of first reserve room is connected by the first check valve with reative cell, and the bottom of second reserve room passes through
Second check valve connects with reative cell；First piston is provided with first reserve room, second is provided with second reserve room
First reserve room and the second reserve room are divided into the first liquid storage cylinder, the first gas storage by piston, the first piston and second piston
Chamber and the second liquid storage cylinder, the second air storing cavity；
It is described that air is filled with into the first air storing cavity and the second air storing cavity by pipeline with quantity regulating device, make first piston and
Two pistons move downward, and the stoste in the first reserve room and the second reserve room is expressed into reative cell carries out hybrid reaction；It is described
Pressue device is connected by pipeline with reative cell, for increasing the pressure in reative cell；The sprayer unit is by pipeline and instead
Answer room to connect, sterilizing gas caused by reaction and liquid atomization are sprayed.
2. Portable chlorine dioxide generator according to claim 1, it is characterised in that the quantity regulating device includes
First piston cylinder, first band handle one-way piston and the first Non-return air valve；The first piston cylinder is arranged on generator body, is led to
The first Non-return air valve is crossed to connect with the first air storing cavity and the second air storing cavity；The first band handle one-way piston is arranged on first piston
In cylinder, the gas unidirectional in first piston cylinder is set to flow into the first air storing cavity and the second air storing cavity by operation handle.
3. Portable chlorine dioxide generator according to claim 1, it is characterised in that the pressue device includes second
Piston cylinder, the second band handle one-way piston, airway tube and atomization pressure head switch；The second band handle one-way piston is arranged on the second work
In plug cylinder, its operating side and atomization pressure head switch are be hinged；The second piston cylinder is fixed on generator body, and its bottom is provided with
Second Non-return air valve, the second Non-return air valve are connected by airway tube with reative cell；The atomization pressure head is connected with sprayer unit, is led to
Cross operation atomization pressure head switch and the air in second piston cylinder is pressed into reative cell, and open sprayer unit.
4. Portable chlorine dioxide generator according to claim 3, it is characterised in that the sprayer unit includes spraying
Body, the 3rd piston, the 4th piston, aerosol conduit and connecting conduit；One end of the spraying body is fixed on generator body
On, connected with one end of connecting conduit, the other end is provided with the shower nozzle atomized the liquid into, and the other end and the reative cell of connecting conduit connect
It is logical；One end of the aerosol conduit is connected with the 4th piston, and the other end is connected with shower nozzle；3rd piston is opened with atomization pressure head
Connection connects, and relative with the 4th piston, forms the variable cavity of extruding liquids and gases, one end of connecting conduit and variable cavity
Connection, switched by operating atomization pressure head, the gas-liquid in reative cell is flowed into variable cavity, and drive the 3rd piston variable compression
Cavity, gas and liquid is atomized from shower nozzle and spray.
5. Portable chlorine dioxide generator according to claim 1, it is characterised in that the generator body also includes
Piston position control rod；The piston position control rod is fixedly connected with first piston and second piston respectively.
6. Portable chlorine dioxide generator according to claim 3, it is characterised in that the pressue device also includes making
It is atomized the back-moving spring that pressure head switch resets；The back-moving spring is inserted on the second band handle one-way piston, and its one end is pressed with atomization
Head switch abuts, and the other end abuts with second piston cylinder, and driving atomization pressure head switch resets upwards.
7. Portable chlorine dioxide generator according to claim 4, it is characterised in that the sprayer unit also includes can
Rotary L-shaped pipe, triple valve and drainage switch；One end of the L-shaped pipe is connected with the first port of triple valve, and the other end is put in
In reative cell, the connecting conduit connects with the second port of triple valve, and the drainage switch is arranged on the 3rd end of triple valve
On mouth；Make the gas or fluid connection of connecting conduit and reative cell by rotating L-shaped pipe.
8. Portable chlorine dioxide generator according to claim 1, it is characterised in that first check valve and second
The structure of check valve is consistent, is formed by valve element and stage clip, described stage clip one end is fixed on reative cell bottom, the other end and valve element
Connection, valve element is clogged to the stoste entrance of reative cell.
9. Portable chlorine dioxide generator according to claim 1, it is characterised in that first reserve room and second
The ratio between cross-sectional area of reserve room is 1：1 to 4：1.
A kind of 10. method to be carried out disinfection using Portable chlorine dioxide generator, it is characterised in that comprise the following steps：
Step S1:According to reaction coefficient relation, according to the ratio of the amount of substance regulation reactant proportional to reactive chemistry stoichiometric number
Example concentration, and be separately stored in two storing solutions；
Step S2:First band handle one-way piston is operated repeatedly, the stoste of the first reserve room and the second reserve room is injected reative cell
Carry out hybrid reaction；
Step S3:Gently vibrate or rock sterilizer；
Step S5:Regulation L-shaped pipe enters mouth down or upward；
Step S6:Repeatedly operation atomization pressure head switch, when L-shaped tube inlet upward when, sterilizing gas from shower nozzle spray；When L-shaped pipe
When entering mouth down, sterilised liq sprays from shower nozzle, when L-shaped tube inlet is down and when liquid level is less than L-shaped tube inlet, sterilizing gas from
Shower nozzle sprays.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610508931.1A CN106006562B (en) | 2016-06-29 | 2016-06-29 | A kind of Portable chlorine dioxide generator and its application method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610508931.1A CN106006562B (en) | 2016-06-29 | 2016-06-29 | A kind of Portable chlorine dioxide generator and its application method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106006562A CN106006562A (en) | 2016-10-12 |
| CN106006562B true CN106006562B (en) | 2018-02-06 |
Family
ID=57105640
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610508931.1A Expired - Fee Related CN106006562B (en) | 2016-06-29 | 2016-06-29 | A kind of Portable chlorine dioxide generator and its application method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106006562B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110102128A (en) * | 2019-05-10 | 2019-08-09 | 中国矿业大学(北京) | A kind of more liquid separate types mixing controllable foam spraying device and dust-removing method |
| CN111298755A (en) * | 2020-03-18 | 2020-06-19 | 安徽敦临医疗设备有限公司 | Liquid generating device and liquid ejecting device |
| CN111847627B (en) * | 2020-08-11 | 2021-09-21 | 四川大学华西医院 | Low-consumption energy-saving operating room waste liquid harmless treatment device |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5197636A (en) * | 1992-02-03 | 1993-03-30 | Allergan, Inc. | Fast activation chlorine dioxide delivery apparatus |
| CN101124155A (en) * | 2004-08-11 | 2008-02-13 | 水技术有限公司 | Chlorine dioxide generator and associated methods |
| KR100884330B1 (en) * | 2008-08-14 | 2009-02-18 | 이승채 | Apparatus and method for the production of pure aqueous chlorine dioxide solution |
| CN201362589Y (en) * | 2009-03-13 | 2009-12-16 | 河北科技大学 | Chlorine dioxide generator with safety valve |
| CN201362588Y (en) * | 2009-03-13 | 2009-12-16 | 河北科技大学 | Chlorine dioxide solution generator by taking sodium chlorate as reacting raw material |
| JP4575234B2 (en) * | 2005-04-10 | 2010-11-04 | 株式会社タイコー | Generation method of chlorine dioxide gas |
| EP2481283A2 (en) * | 2009-09-18 | 2012-08-01 | Sung Soo Wui | Ultra-low volume spraying device |
| CN102834350A (en) * | 2010-03-26 | 2012-12-19 | 大幸药品株式会社 | Device for generating chlorine dioxide |
| GB2494623B (en) * | 2011-09-02 | 2013-09-25 | Tristel Plc | Pump apparatus |
| WO2014170971A1 (en) * | 2013-04-17 | 2014-10-23 | 株式会社Ｆｍｉ | Chlorine-dioxide-gas generation device and medical-device sterilization box |
| CN105363051A (en) * | 2015-12-15 | 2016-03-02 | 中国人民解放军军事医学科学院卫生装备研究所 | Portable integrated chlorine dioxide gas space sterilization device |
| CN205933218U (en) * | 2016-06-29 | 2017-02-08 | 广东工业大学 | Portable chlorine dioxide generator |
-
2016
- 2016-06-29 CN CN201610508931.1A patent/CN106006562B/en not_active Expired - Fee Related
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5197636A (en) * | 1992-02-03 | 1993-03-30 | Allergan, Inc. | Fast activation chlorine dioxide delivery apparatus |
| CN101124155A (en) * | 2004-08-11 | 2008-02-13 | 水技术有限公司 | Chlorine dioxide generator and associated methods |
| JP4575234B2 (en) * | 2005-04-10 | 2010-11-04 | 株式会社タイコー | Generation method of chlorine dioxide gas |
| KR100884330B1 (en) * | 2008-08-14 | 2009-02-18 | 이승채 | Apparatus and method for the production of pure aqueous chlorine dioxide solution |
| CN201362589Y (en) * | 2009-03-13 | 2009-12-16 | 河北科技大学 | Chlorine dioxide generator with safety valve |
| CN201362588Y (en) * | 2009-03-13 | 2009-12-16 | 河北科技大学 | Chlorine dioxide solution generator by taking sodium chlorate as reacting raw material |
| EP2481283A2 (en) * | 2009-09-18 | 2012-08-01 | Sung Soo Wui | Ultra-low volume spraying device |
| CN102834350A (en) * | 2010-03-26 | 2012-12-19 | 大幸药品株式会社 | Device for generating chlorine dioxide |
| GB2494623B (en) * | 2011-09-02 | 2013-09-25 | Tristel Plc | Pump apparatus |
| WO2014170971A1 (en) * | 2013-04-17 | 2014-10-23 | 株式会社Ｆｍｉ | Chlorine-dioxide-gas generation device and medical-device sterilization box |
| CN105363051A (en) * | 2015-12-15 | 2016-03-02 | 中国人民解放军军事医学科学院卫生装备研究所 | Portable integrated chlorine dioxide gas space sterilization device |
| CN205933218U (en) * | 2016-06-29 | 2017-02-08 | 广东工业大学 | Portable chlorine dioxide generator |
Non-Patent Citations (2)
| Title |
|---|
| 二氧化氯有机稳定化的探讨;沈晓东 等;《工业水处理》;20070430;第27卷(第4期);全文 * |
| 德国BelloZon纯二氧化氯发生器及其应用;金时 等;《给水排水》;19970831;第23卷(第8期);全文 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106006562A (en) | 2016-10-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106006562B (en) | A kind of Portable chlorine dioxide generator and its application method | |
| CN205933218U (en) | Portable chlorine dioxide generator | |
| US11772968B2 (en) | Multi-chamber hypochlorous acid dispenser | |
| US6821443B2 (en) | Process for producing ozone-containing sterilizing water and an apparatus used therefor | |
| CN203539735U (en) | Ozone water spraying device | |
| CN105289342A (en) | High-concentration ozone water preparation device, high-concentration ozone water preparation method and application of high-concentration ozone water preparation device | |
| CN108634793A (en) | A kind of sterilization method of sterilizing drinking equipment and the drinking equipment | |
| CN215460493U (en) | Automatic sterilizing device | |
| CN113521360B (en) | Indoor environment pollution detection, disinfection and purification system | |
| US11485638B2 (en) | Multi-chamber hypochlorous acid dispenser | |
| WO2004091757A1 (en) | Method and device for generating carbonated water | |
| AU2001280225B2 (en) | A process for producing ozone-containing sterilizing water and an apparatus used therefor | |
| CN2933595Y (en) | Air intake and exhaust for sprayer | |
| CN209530747U (en) | A kind of efficient mixing equipment of pesticide proportion | |
| CN207322481U (en) | Pesticide spraying device in a kind of citrus nursery stock incubation | |
| CN108543214B (en) | Induction type disinfection equipment and disinfection method using same | |
| CN2776562Y (en) | Multifunction aromatic therapy bath spray nozzle | |
| AU2001280225A1 (en) | A process for producing ozone-containing sterilizing water and an apparatus used therefor | |
| JP5738945B2 (en) | Solution spray system | |
| CN206273371U (en) | The automatic mixing sprayer of liquid with environmental protection and saving feature | |
| CN206954899U (en) | Disinfection bottle | |
| CN216616071U (en) | Automatic disinfectant preparation water tank for disinfection equipment | |
| TWM560342U (en) | Multifunctional ultra-micro sparkling water production device | |
| CN205472642U (en) | Chlorine dioxide solution preparation facilities | |
| CN220495322U (en) | Automatic sterilization room for veterinary drug oral liquid non-high temperature resistant packaging material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180206 Termination date: 20190629 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |