CN105979751A - Graphite heat conduction heat dissipation sheet applied to tape - Google Patents

Graphite heat conduction heat dissipation sheet applied to tape Download PDF

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Publication number
CN105979751A
CN105979751A CN201511029000.5A CN201511029000A CN105979751A CN 105979751 A CN105979751 A CN 105979751A CN 201511029000 A CN201511029000 A CN 201511029000A CN 105979751 A CN105979751 A CN 105979751A
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China
Prior art keywords
parts
graphite
heat
kapton
film
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Granted
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CN201511029000.5A
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CN105979751B (en
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金闯
梁豪
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Suzhou Sidike New Material Science and Technology Co Ltd
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Suzhou Sidike New Material Science and Technology Co Ltd
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    • C04B35/522Graphite
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    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
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Abstract

The invention provides a graphite heat conduction heat dissipation sheet applied to a tape. The first coating layer is located on the upper surface of a polyimide film. The first coating layer is formed by a graphite modifier coated on the upper surface of the polyimide film. The graphite modifier comprises, by weight, 22 parts of benzophenonetetracarboxylic dianhydride, 12.5 parts of pyromellitic dianhydride, 26 parts of diaminodiphenylmethane, 22.5 parts of dimethylformamide, 9.5 parts of N-methylpyrrolidone, 2.2 parts of ethylene glycol, 2.8 parts of polydimethylsiloxane and 0.9 part of dibutyl phthalate. The graphite modifier is coated on the upper surface of the polyimide film to acquire a treated polyimide film. The treated polyimide film is heated to 1200 DEG C, and then is cooled to acquire a pre-fired carbonized film. According to the invention, local overheating is avoided; the uniformity of thermal conductivity is realized; the stability and the reliability of the heat dissipation of a product are improved; and the product cost is greatly reduced.

Description

Adhesive tape graphite heat conducting and heat radiating fin
Technical field
The present invention relates to a kind of adhesive tape graphite heat conducting and heat radiating fin, belong to tape technology field.
Background technology
Along with modern microelectronic technology high-speed develops, electronic equipment (such as notebook computer, mobile phone, panel computer etc.) becomes ultra-thin, light day by day, this structure makes electronic equipment internal power density significantly improve, and in operation, produced heat is difficult to discharge, be prone to accumulate rapidly and form high temperature.On the other hand, high temperature can reduce the performance of electronic equipment, reliability and service life.Therefore, Current electronic industry proposes the highest requirement for the heat sink material as heat control system core component, transfers heat away from rapidly in the urgent need to a kind of high-efficiency heat conduction, light material, ensures that electronic equipment is properly functioning.
In prior art, Kapton is mostly used for flexible PCB, although there being the polyimide film sintered acquisition graphite heat radiation fin of employing, thus be covered on thermal source, but it is constrained to the very different of the product quality and performances of Kapton, have influence on the performance of heat radiation two-sided pad pasting heat dispersion, there is techniques below problem: dispel the heat uneven, adhesive tape hot-spot easily occurs, the heat dispersion that improve product is unstable, reliability performance is poor, it is unfavorable for product quality management control, affects the competitiveness of product.
Summary of the invention
Objects of the present invention are to provide a kind of adhesive tape graphite heat conducting and heat radiating fin, this adhesive tape graphite heat conducting and heat radiating fin is the most all improve heat conductivility, avoid hot-spot, while achieving the uniformity of heat conductivility, improve the heat dispersion stability of product, reliability, greatly reduce the cost of product.
To achieve the above object of the invention, the technical solution used in the present invention is: a kind of adhesive tape graphite heat conducting and heat radiating fin, the surface that described graphite heat conducting and heat radiating fin surface-coated has heat-conducting glue adhesion coating, this heat-conducting glue adhesion coating opposing with graphite heat conducting and heat radiating fin is fitted with separated type material layer;Described graphite heat conducting and heat radiating fin is made up of Kapton, the first coat and the second coat, and described first coat is positioned at Kapton upper surface;
Described first coat is formed in graphite modified dose of Kapton upper surface by film, and this graphite modified dose painting is made up of the component of following weight portion: benzophenone tetracarboxylic dianhydride 22 parts, pyromellitic acid anhydride 12.5 parts, MDA 26 parts, dimethylformamide 22.5 parts, N-Methyl pyrrolidone 9.5 parts, ethylene glycol 2.2 parts, polydimethylsiloxane 2.8 parts, dibutyl phthalate 0.9 part;
Described graphite heat conducting and heat radiating fin is obtained by following steps:
Step one, by graphite modified dose of film in Kapton upper surface acquisition process after Kapton;
Step 2, will process after Kapton be warming up to 1200 DEG C after cool down, thus obtain the carbonized film of pre-burned;
Step 3, employing calender roll the carbonized film of described pre-burned;
Step 4, carbonized film is warming up to 2850 DEG C ~ 2950 DEG C after cool down, thus obtain the main graphite film fired;
Step 5, then carry out rolling by the graphite film that the master of gained fires thus obtain described graphite heat conducting and heat radiating fin.
Owing to technique scheme is used, the present invention compared with prior art has following advantages and an effect:
1, adhesive tape graphite heat conducting and heat radiating fin of the present invention, the Kapton that in its structure, graphite linings is coated with one layer graphite modified dose by upper surface is prepared from, improve at heat conductivility both vertically and horizontally, it is to avoid adhesive tape hot-spot, it is achieved that the uniformity of adhesive tape heat conductivility;Secondly, its be positioned at Kapton surface graphite modified dose is made up of benzophenone tetracarboxylic dianhydride 22 parts, pyromellitic acid anhydride 12.5 parts, MDA 26 parts, dimethylformamide 22.5 parts, ethylene glycol 2.2 parts, polydimethylsiloxane 2.8 parts, it is coated on Kapton, the pin hole being filled with in heating process, improve degree of crystallinity simultaneously, also overcome thermal contraction excessive cause uneven, improve graphite linings biaxial tension performance.
2, adhesive tape graphite heat conducting and heat radiating fin of the present invention, its be positioned at Kapton surface graphite modified dose is made up of benzophenone tetracarboxylic dianhydride 20 ~ 25 parts, pyromellitic acid anhydride 12 ~ 18 parts, MDA 20 ~ 28 parts, dimethylformamide 20 ~ 25 parts, N-Methyl pyrrolidone 8 ~ 10 parts, ethylene glycol 1.5 ~ 2.5 parts, polydimethylsiloxane 2 ~ 3 parts, use dimethylformamide 20 ~ 25 parts, N-Methyl pyrrolidone 8 ~ 10 parts to reduce azeotropic point and smooth boiling point district, improve flatness and the pliability of final products film forming;;Secondly, dimethylformamide 20 ~ 25 parts, N-Methyl pyrrolidone 8 ~ 10 parts and 0.8 ~ 1.5 part of Kapton surface of dibutyl phthalate, prevent bubble from producing, be more beneficial for the small pin hole of filled polyimide thin film, improve the uniformity of heat radiation paster heat conductivility.
3, adhesive tape graphite heat conducting and heat radiating fin of the present invention, calendaring processes is increased between the carbonized film and graphitization of pre-burned, and again roll after forming heat conduction graphite patch again, avoid the volume contraction in fold and graphitization sintering process, improve compactness and degree of crystallinity, further increase at heat conductivility both vertically and horizontally.
Accompanying drawing explanation
Accompanying drawing 1 is adhesive tape graphite heat conducting and heat radiating fin structural representation of the present invention;
Accompanying drawing 2 is the partial structurtes schematic diagram of accompanying drawing 1.
In the figures above: 1, graphite heat conducting and heat radiating fin;11, Kapton;12, the first coat;13, the second coat;2, heat-conducting glue adhesion coating;3, separated type material layer.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Embodiment: a kind of adhesive tape graphite heat conducting and heat radiating fin, the surface that described graphite heat conducting and heat radiating fin 1 surface-coated has heat-conducting glue adhesion coating 2, this heat-conducting glue adhesion coating 2 opposing with graphite heat conducting and heat radiating fin 1 is fitted with separated type material layer 3;Described graphite heat conducting and heat radiating fin 1 is made up of Kapton the 11, first coat 12 and the second coat 13, and described first coat 12 is positioned at Kapton 11 upper surface;
Described first coat is formed in graphite modified dose of Kapton upper surface by film, and this graphite modified dose painting is made up of the component of following weight portion: benzophenone tetracarboxylic dianhydride 22 parts, pyromellitic acid anhydride 12.5 parts, MDA 26 parts, dimethylformamide 22.5 parts, N-Methyl pyrrolidone 9.5 parts, ethylene glycol 2.2 parts, polydimethylsiloxane 2.8 parts, dibutyl phthalate 0.9 part;
Described graphite heat conducting and heat radiating fin 1 is obtained by following steps:
Step one, by graphite modified dose of film in Kapton 2 upper surface acquisition process after Kapton;
Step 2, will process after Kapton be warming up to 1200 DEG C after cool down, thus obtain the carbonized film of pre-burned;
Step 3, employing calender roll the carbonized film of described pre-burned;
Step 4, carbonized film is warming up to 2850 DEG C ~ 2950 DEG C after cool down, thus obtain the main graphite film fired;
Step 5, then carry out rolling by the graphite film that the master of gained fires thus obtain described graphite heat conducting and heat radiating fin 1.
When using above-mentioned adhesive tape graphite heat conducting and heat radiating fin, the Kapton that in its structure, graphite linings is coated with one layer graphite modified dose by upper surface is prepared from, improve at heat conductivility both vertically and horizontally, it is to avoid adhesive tape hot-spot, it is achieved that the uniformity of adhesive tape heat conductivility;Secondly, it is positioned at graphite modified dose of Kapton surface by benzophenone tetracarboxylic dianhydride 20 ~ 25 parts, pyromellitic acid anhydride 12 ~ 18 parts, MDA 20 ~ 28 parts, dimethylformamide 30 ~ 35 parts, ethylene glycol 1.5 ~ 2.5 parts, polydimethylsiloxane 2 ~ 3 parts composition, it is coated on Kapton, the pin hole being filled with in heating process, improve degree of crystallinity simultaneously, also overcome thermal contraction excessive cause uneven, improve graphite linings biaxial tension performance, also reduce azeotropic point and smooth boiling point district, improve flatness and the pliability of final products film forming;Again, Kapton surface has graphite modified dose, improve graphite linings and heat-conducting glue adhesion coating heat conductivility in two-sided pad pasting, and use calender to roll the carbonized film of described pre-burned, avoid the volume contraction in fold and graphitization sintering process, improve compactness and degree of crystallinity, further increase at heat conductivility both vertically and horizontally;Again, dimethylformamide 20 ~ 25 parts, N-Methyl pyrrolidone 8 ~ 10 parts and 0.8 ~ 1.5 part of Kapton surface of dibutyl phthalate, prevent bubble from producing, be more beneficial for the small pin hole of filled polyimide thin film, improve the uniformity of heat radiation paster heat conductivility.
Above-described embodiment only for technology design and the feature of the present invention are described, its object is to allow person skilled in the art will appreciate that present disclosure and to implement according to this, can not limit the scope of the invention with this.All equivalence changes made according to spirit of the invention or modification, all should contain within protection scope of the present invention.

Claims (1)

1. an adhesive tape graphite heat conducting and heat radiating fin, the surface that described graphite heat conducting and heat radiating fin (1) surface-coated has heat-conducting glue adhesion coating (2), this heat-conducting glue adhesion coating (2) and graphite heat conducting and heat radiating fin (1) opposing is fitted with separated type material layer (3);It is characterized in that: described graphite heat conducting and heat radiating fin (1) is made up of Kapton (11), the first coat (12) and the second coat (13), described first coat (12) is positioned at Kapton (11) upper surface;
Described first coat is formed in graphite modified dose of Kapton upper surface by film, and this graphite modified dose painting is made up of the component of following weight portion: benzophenone tetracarboxylic dianhydride 22 parts, pyromellitic acid anhydride 12.5 parts, MDA 26 parts, dimethylformamide 22.5 parts, N-Methyl pyrrolidone 9.5 parts, ethylene glycol 2.2 parts, polydimethylsiloxane 2.8 parts, dibutyl phthalate 0.9 part;
Described graphite heat conducting and heat radiating fin (1) is obtained by following steps:
Step one, by graphite modified dose of film in Kapton (2) upper surface acquisition process after Kapton;
Step 2, will process after Kapton be warming up to Cool down after 1200 DEG C, thus obtain the carbonized film of pre-burned;
Step 3, employing calender roll the carbonized film of described pre-burned;
Step 4, carbonized film is warming up to 2850 DEG C ~ 2950 DEG C Rear cooling, thus obtain the main graphite film fired;
Step 5, then carry out rolling by the graphite film that the master of gained fires thus obtain described graphite heat conducting and heat radiating fin (1).
CN201511029000.5A 2014-01-26 2014-01-26 Adhesive tape graphite heat conducting and heat radiating fin Active CN105979751B (en)

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CN201511029000.5A CN105979751B (en) 2014-01-26 2014-01-26 Adhesive tape graphite heat conducting and heat radiating fin

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CN201511028692.1A Active CN105969224B (en) 2014-01-26 2014-01-26 Equal thermal bonding tape for electronic device
CN201610255486.2A Pending CN105860868A (en) 2014-01-26 2014-01-26 Preparation process of heat dissipation lamination film
CN201610250630.3A Pending CN105860867A (en) 2014-01-26 2014-01-26 Preparation technology of uniform heating rubber belt applied in electronic device
CN201511028668.8A Active CN105966019B (en) 2014-01-26 2014-01-26 For the heat conduction graphite patch of adhesive tape
CN201410036121.1A Active CN103796493B (en) 2014-01-26 2014-01-26 Heat conduction graphite patch for adhesive tape and preparation method thereof
CN201610249636.9A Active CN105860866B (en) 2014-01-26 2014-01-26 Equal thermal bonding tape
CN201511014593.8A Active CN105965985B (en) 2014-01-26 2014-01-26 Preparation method for the heat conduction graphite patch of adhesive tape
CN201511014587.2A Active CN105969223B (en) 2014-01-26 2014-01-26 Manufacturing process for equal thermal bonding tape
CN201610250629.0A Active CN105873414B (en) 2014-01-26 2014-01-26 Manufacturing process for graphite heat conducting heat dissipation patch
CN201511028635.3A Active CN105979750B (en) 2014-01-26 2014-01-26 Flexibility heat conduction graphite patch
CN201511029000.5A Active CN105979751B (en) 2014-01-26 2014-01-26 Adhesive tape graphite heat conducting and heat radiating fin

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CN201610255486.2A Pending CN105860868A (en) 2014-01-26 2014-01-26 Preparation process of heat dissipation lamination film
CN201610250630.3A Pending CN105860867A (en) 2014-01-26 2014-01-26 Preparation technology of uniform heating rubber belt applied in electronic device
CN201511028668.8A Active CN105966019B (en) 2014-01-26 2014-01-26 For the heat conduction graphite patch of adhesive tape
CN201410036121.1A Active CN103796493B (en) 2014-01-26 2014-01-26 Heat conduction graphite patch for adhesive tape and preparation method thereof
CN201610249636.9A Active CN105860866B (en) 2014-01-26 2014-01-26 Equal thermal bonding tape
CN201511014593.8A Active CN105965985B (en) 2014-01-26 2014-01-26 Preparation method for the heat conduction graphite patch of adhesive tape
CN201511014587.2A Active CN105969223B (en) 2014-01-26 2014-01-26 Manufacturing process for equal thermal bonding tape
CN201610250629.0A Active CN105873414B (en) 2014-01-26 2014-01-26 Manufacturing process for graphite heat conducting heat dissipation patch
CN201511028635.3A Active CN105979750B (en) 2014-01-26 2014-01-26 Flexibility heat conduction graphite patch

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CN107418392A (en) * 2017-08-02 2017-12-01 合肥东恒锐电子科技有限公司 A kind of heat radiation coating of household electrical appliance and preparation method thereof
CN107441619A (en) * 2017-08-17 2017-12-08 成都三乙医疗科技有限公司 A kind of thermal conducting piece for electrotherapy
CN107551392A (en) * 2017-08-29 2018-01-09 成都三乙医疗科技有限公司 A kind of thermal conducting piece for thermotherapy

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CN105860866A (en) 2016-08-17
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CN105969224B (en) 2019-03-26
CN105965985A (en) 2016-09-28
CN105979750A (en) 2016-09-28
CN103796493B (en) 2016-06-15
CN105966019A (en) 2016-09-28
CN105969223A (en) 2016-09-28
CN105873414A (en) 2016-08-17
CN105873414B (en) 2018-08-31
CN105979750B (en) 2018-06-19
CN105965985B (en) 2018-04-24
CN105860868A (en) 2016-08-17
CN105966019B (en) 2018-06-19
CN105969224A (en) 2016-09-28
CN103796493A (en) 2014-05-14
CN105860866B (en) 2019-01-01
CN105969223B (en) 2019-01-01

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