CN105969224B - Equal thermal bonding tape for electronic device - Google Patents

Equal thermal bonding tape for electronic device Download PDF

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Publication number
CN105969224B
CN105969224B CN201511028692.1A CN201511028692A CN105969224B CN 105969224 B CN105969224 B CN 105969224B CN 201511028692 A CN201511028692 A CN 201511028692A CN 105969224 B CN105969224 B CN 105969224B
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parts
kapton
graphite
film
coat
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CN201511028692.1A
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CN105969224A (en
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金闯
梁豪
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Jiangsu Stick New Materials Polytron Technologies Inc
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Jiangsu Stick New Materials Polytron Technologies Inc
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Abstract

A kind of equal thermal bonding tape for electronic device of the present invention, its first coat by film in Kapton upper surface graphite modified dosage form at this graphite modified dose painting is grouped as by the group of following parts by weight: 22.5 parts of benzophenone tetracarboxylic dianhydride, 18 parts of pyromellitic acid anhydride, 24.5 parts of diaminodiphenylmethane, 25 parts of dimethylformamide, 9 parts of N-Methyl pyrrolidone, 1.8 parts of ethylene glycol, 2.8 parts of dimethyl silicone polymer, 1.2 parts of dibutyl phthalate;Graphite modified dose of film is obtained into treated Kapton in the upper surface of Kapton;Will that treated is cooling after Kapton is warming up to 1200 DEG C, to obtain the carbonized film of pre-burned.The present invention avoids hot-spot, while realizing the uniformity of heating conduction, improves heat dissipation performance stability, the reliability of product, greatly reduces the cost of product.

Description

Equal thermal bonding tape for electronic device
Technical field
The present invention relates to a kind of equal thermal bonding tape for electronic device, belong to tape technology field.
Background technique
With modern microelectronic technology high speed development, electronic equipment (such as laptop, mobile phone, tablet computer) is increasingly Become ultra-thin, light, this structure significantly improves electronic equipment internal power density, and generated heat is not easy in operation It is discharged, is easy to accumulate rapidly and form high temperature.On the other hand, high temperature can reduce the performance of electronic equipment, reliability and use the longevity Life.Therefore, Current electronic industry proposes increasingly higher demands for the heat sink material as heat control system core component, urgently It needs a kind of high-efficiency heat conduction, light material to transfer heat away from rapidly, ensures that electronic equipment operates normally.
Kapton is mostly used for flexible circuit board in the prior art, is obtained although having using polyimide film sintered Graphite heat radiation fin, to be covered on heat source, but be constrained to Kapton product quality and performances the good and the bad not Together, influenced the performance of the two-sided pad pasting heat dissipation performance of heat dissipation, there are following technical problems: heat dissipation is uneven, adhesive tape easily occurs Hot-spot, the heat dissipation performance for improving product is unstable, reliability performance is poor, is unfavorable for product quality management control, influences product Competitiveness.
Summary of the invention
Objects of the present invention are to provide a kind of equal thermal bonding tape for electronic device, this is used for the equal hot glue of electronic device Band improves heating conduction in the vertical direction and the horizontal direction, avoids hot-spot, realizes the uniformity of heating conduction Meanwhile heat dissipation performance stability, the reliability of product are improved, greatly reduce the cost of product.
To achieve the above object of the invention, the technical solution adopted by the present invention is that: a kind of equal thermal bonding tape for electronic device, The equal thermal bonding tape includes heat conduction graphite patch, the thermally conductive adhesive layer positioned at heat conduction graphite patch surface, this thermally conductive adhesive layer with The opposite surface of heat conduction graphite patch is fitted with separated type material layer;The heat conduction graphite patch is applied by Kapton, first Coating and the second coat composition, first coat are located at Kapton upper surface;
First coat by film in Kapton upper surface graphite modified dosage form at this graphite modified dose Painting is grouped as by the group of following parts by weight: 22.5 parts of benzophenone tetracarboxylic dianhydride, 18 parts of pyromellitic acid anhydride, diamino hexichol 24.5 parts of methane, 25 parts of dimethylformamide, 9 parts of N-Methyl pyrrolidone, 1.8 parts of ethylene glycol, dimethyl silicone polymer 2.8 Part, 1.2 parts of dibutyl phthalate;
The heat conduction graphite patch is obtained by following steps:
Step 1: graphite modified dose of film is obtained in the upper surface of Kapton, treated that polyimides is thin Film;
Step 2: will that treated is cooling after Kapton is warming up to 1200 DEG C, to obtain the carbon of pre-burned Change film;
Step 3: rolling the carbonized film of the pre-burned using calender;
Step 4: it is cooling after carbonized film is warming up to 2850 DEG C ~ 2950 DEG C, to obtain the graphite film of main firing;
Step 5: the graphite film of resulting main firing is then carried out calendering to obtain the heat conduction graphite patch.
Since above-mentioned technical proposal is used, the present invention has following advantages and effect compared with prior art:
1, the present invention is used for the equal thermal bonding tape of electronic device, and graphite linings are coated with one layer of graphite by upper surface and change in structure Property agent Kapton be prepared, improve heating conduction in the vertical direction and the horizontal direction, avoid adhesive tape local Overheat, realizes the uniformity of adhesive tape heating conduction;Secondly, it is located at graphite modified dose of Kapton surface by hexichol 20 ~ 25 parts of ketone tetracid dianhydride, 12 ~ 18 parts of pyromellitic acid anhydride, 20 ~ 28 parts of diaminodiphenylmethane, dimethylformamide 30 ~ 35 parts, 1.5 ~ 2.5 parts of ethylene glycol, 2 ~ 3 parts of dimethyl silicone polymer compositions, are coated on Kapton, are filled with and add Pin hole in thermal process improves crystallinity simultaneously, also overcome be heat-shrinked it is excessive caused by it is uneven, it is double to improve graphite linings To tensile property.
2, the present invention is used for the equal thermal bonding tape of electronic device, is located at graphite modified dose of Kapton surface by two 20 ~ 25 parts of Benzophenone tetracid dianhydride, 12 ~ 18 parts of pyromellitic acid anhydride, 20 ~ 28 parts of diaminodiphenylmethane, dimethyl formyl 20 ~ 25 parts of amine, 8 ~ 10 parts of N-Methyl pyrrolidone, 1.5 ~ 2.5 parts of ethylene glycol, 2 ~ 3 parts of dimethyl silicone polymer compositions, using two 20 ~ 25 parts of methylformamide, 8 ~ 10 parts of N-Methyl pyrrolidone reduce azeotropic point and smooth boiling point area, improve final The flatness and flexibility of product film forming;;Secondly, 20 ~ 25 parts of dimethylformamide, 8 ~ 10 parts of N-Methyl pyrrolidone and adjacent benzene 0.8 ~ 1.5 part of Kapton surface of dibutyl carboxylic acid, prevents bubble from generating, is more advantageous to filled polyimide film Small pin hole, improve heat dissipation patch heating conduction uniformity.
3, the present invention is used for the equal thermal bonding tape of electronic device, increases calendering step between the carbonized film and graphitization of pre-burned Suddenly, and after re-forming heat conduction graphite patch roll again, the volume contraction for avoiding fold and being graphitized in sintering process mentions High compactness and crystallinity, further improve heating conduction in the vertical direction and the horizontal direction.
Detailed description of the invention
Attached drawing 1 is the soaking adhesive tape structure schematic diagram that the present invention is used for electronic device.
In the figures above: 1, heat conduction graphite patch;11, Kapton;12, the first coat;13, the second coating Layer;2, thermally conductive adhesive layer;3, separated type material layer.
Specific embodiment
The present invention will be further described below with reference to examples:
Embodiment: a kind of equal thermal bonding tape for electronic device, the equal thermal bonding tape include heat conduction graphite patch 1, are located at The thermally conductive adhesive layer 2 on 1 surface of heat conduction graphite patch, this thermally conductive adhesive layer 2 surface opposite with heat conduction graphite patch 1 be fitted with from The profile bed of material 3;The heat conduction graphite patch 1 is made of Kapton 11, the first coat 12 and the second coat 13, institute It states the first coat 12 and is located at 11 upper surface of Kapton;
First coat by film in Kapton upper surface graphite modified dosage form at this graphite modified dose Painting is grouped as by the group of following parts by weight: 22.5 parts of benzophenone tetracarboxylic dianhydride, 18 parts of pyromellitic acid anhydride, diamino hexichol 24.5 parts of methane, 25 parts of dimethylformamide, 9 parts of N-Methyl pyrrolidone, 1.8 parts of ethylene glycol, dimethyl silicone polymer 2.8 Part, 1.2 parts of dibutyl phthalate;
The heat conduction graphite patch 1 is obtained by following steps:
Step 1: graphite modified dose of film is obtained in the upper surface of Kapton 2, treated that polyimides is thin Film;
Step 2: will that treated is cooling after Kapton is warming up to 1200 DEG C, to obtain the carbon of pre-burned Change film;
Step 3: rolling the carbonized film of the pre-burned using calender;
Step 4: it is cooling after carbonized film is warming up to 2850 DEG C ~ 2950 DEG C, to obtain the graphite film of main firing;
Step 5: the graphite film of resulting main firing is then carried out calendering to obtain the heat conduction graphite patch 1.
When using the above-mentioned equal thermal bonding tape for electronic device, graphite linings are coated with one layer of graphite by upper surface in structure The Kapton of modifying agent is prepared, and improves heating conduction in the vertical direction and the horizontal direction, avoids adhesive tape office Portion's overheat, realizes the uniformity of adhesive tape heating conduction;Secondly, it is located at graphite modified dose of Kapton surface by two 20 ~ 25 parts of Benzophenone tetracid dianhydride, 12 ~ 18 parts of pyromellitic acid anhydride, 20 ~ 28 parts of diaminodiphenylmethane, dimethyl formyl 30 ~ 35 parts of amine, 1.5 ~ 2.5 parts of ethylene glycol, 2 ~ 3 parts of dimethyl silicone polymer compositions, are coated on Kapton, are filled with Pin hole in heating process improves crystallinity simultaneously, also overcome be heat-shrinked it is excessive caused by it is uneven, improve graphite linings Biaxial tension performance also reduces azeotropic point and smooth boiling point area, improves the flatness and flexible of final products film forming Property;Again, Kapton surface has graphite modified dose, and it is thermally conductive to improve graphite linings and thermally conductive adhesive layer in two-sided pad pasting Performance, and calender is used to roll the carbonized film of the pre-burned, it avoids fold and the volume being graphitized in sintering process is received Contracting, improves compactness and crystallinity, further improves heating conduction in the vertical direction and the horizontal direction;Again, diformazan 20 ~ 25 parts of base formamide, 8 ~ 10 parts of N-Methyl pyrrolidone and 0.8 ~ 1.5 part of Kapton of dibutyl phthalate Surface prevents bubble from generating, and is more advantageous to the small pin hole of filled polyimide film, improves heat dissipation patch heating conduction Uniformity.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention.It is all according to the present invention Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.

Claims (1)

1. a kind of equal thermal bonding tape for electronic device, the equal thermal bonding tape includes heat conduction graphite patch (1), is located at heat conductive graphite The thermally conductive adhesive layer (2) on patch (1) surface, this thermally conductive adhesive layer (2) surface opposite with heat conduction graphite patch (1) be fitted with from The profile bed of material (3);It is characterized by: the heat conduction graphite patch (1) by Kapton (11), the first coat (12) and Second coat (13) composition, first coat (12), the second coat (13) are located at Kapton (11) Upper and lower surfaces;
First coat by film in Kapton upper surface graphite modified dosage form at second coat (13) by film in Kapton lower surface graphite modified dosage form at, graphite modified dose of viscosity be 30000 ~ 48000cP, the graphite modified dose of group by following parts by weight are grouped as: 22.5 parts of benzophenone tetracarboxylic dianhydride, Pyromellitic Acid 18 parts of dianhydride, 24.5 parts of diaminodiphenylmethane, 25 parts of dimethylformamide, 9 parts of N-Methyl pyrrolidone, ethylene glycol 1.8 Part, 2.8 parts of dimethyl silicone polymer, 1.2 parts of dibutyl phthalate;
The heat conduction graphite patch (1) is obtained by following steps:
Step 1: graphite modified dose of film is obtained treated Kapton in the upper surface of Kapton (2);
Step 2: will treated Kapton under inert gas protection, rise to 240 DEG C ~ 260 DEG C from room temperature, 480 DEG C ~ 500 DEG C are risen to after heat preservation, are warming up to 780 DEG C ~ 820 DEG C after heat preservation again, it is cold after 1200 DEG C are risen to after heat preservation But, to obtain the carbonized film of pre-burned;
Step 3: rolling the carbonized film of the pre-burned using calender;
Step 4: carbonized film is warming up to 2350 DEG C ~ 2450 DEG C, keep the temperature, then cooled down after being warming up to 2850 ~ 2950 DEG C, To obtain the graphite film of main firing;
Step 5: the graphite film of resulting main firing is then carried out calendering to obtain the heat conduction graphite patch (1).
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CN201511028692.1A Active CN105969224B (en) 2014-01-26 2014-01-26 Equal thermal bonding tape for electronic device
CN201511029000.5A Active CN105979751B (en) 2014-01-26 2014-01-26 Adhesive tape graphite heat conducting and heat radiating fin
CN201610249636.9A Active CN105860866B (en) 2014-01-26 2014-01-26 Equal thermal bonding tape
CN201511028635.3A Active CN105979750B (en) 2014-01-26 2014-01-26 Flexibility heat conduction graphite patch
CN201610255486.2A Pending CN105860868A (en) 2014-01-26 2014-01-26 Preparation process of heat dissipation lamination film
CN201511028668.8A Active CN105966019B (en) 2014-01-26 2014-01-26 For the heat conduction graphite patch of adhesive tape
CN201511014593.8A Active CN105965985B (en) 2014-01-26 2014-01-26 Preparation method for the heat conduction graphite patch of adhesive tape
CN201511014587.2A Active CN105969223B (en) 2014-01-26 2014-01-26 Manufacturing process for equal thermal bonding tape
CN201610250630.3A Pending CN105860867A (en) 2014-01-26 2014-01-26 Preparation technology of uniform heating rubber belt applied in electronic device
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CN201610255486.2A Pending CN105860868A (en) 2014-01-26 2014-01-26 Preparation process of heat dissipation lamination film
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CN107441619A (en) * 2017-08-17 2017-12-08 成都三乙医疗科技有限公司 A kind of thermal conducting piece for electrotherapy
CN107551392A (en) * 2017-08-29 2018-01-09 成都三乙医疗科技有限公司 A kind of thermal conducting piece for thermotherapy

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CN105860868A (en) 2016-08-17

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